Class-XII (CBSE)

Chemistry

12Ch02_DPP05_Solution & Colligative Properties

Topic Covered: Elevation of Boiling point

1. On dissolving 10.8 g glucose (mol. Mass 180) in 240 g of water, its boiling point
increases by 0.130C. Calculate the molecular elevation constant of water.
2. A solution of 2.5 g of a non-volatile solid in 100 g benzene boiled at 0.420C higher
than the boiling point of pure benzene. Calculate the molecular mass of the
substance. Molal elevation constant of benzene is 2.67 K kg mol-1.
3. The molal elevation constant for water is 0.56 K kg mol-1. Calculate the boiling
point of a solution made by dissolving 6.0 g of urea  NH 2CONH 2  in 200 g of water.
4. The b.p. of pure acetone is 56.380C. When 0.707 g of a compound is dissolved in 10
g of acetone there is elevation to 56.880C in b.p. What is the mol. Wt. of the
compound? ( K M for acetone = 16.70)
5. The b.p. of solvent was raised by 0.0710C when 1.17 g of sucrose was dissolved in
25 g solvent. Calculate molar elevation constant of the solvent.
6. 0.9 g urea when dissolved in 45 g water caused elevation of 0.170C in b.p.. Calculate
molecular elevation constant  K M  of water.
7. The vapour pressure of a solution of 6.5 g solute in 100 g water at 1000C is 732
mm. What will be the b.p. of solution?  Kb  0.52 K mol 1 
8. When 1 mole of a solute is dissolved in 1 kg of H 2O boiling point of solution was
found to be 100.50C. K b for H 2O is:
(a) 0.5 (b) 100 (c) 100.5 (d) 95.5
9. Chloroform, CHCl3 , boils at 61.7 C. If the K b for chloroform is 3.630C/molal, what
0

is the boiling point of a solution of 15.0 kg of CHCl3 and 0.616 kg of

acenaphthalene, C12 H10 ?
(a) 61.9 (b) 62.0 (c) 52.2 (d) 62.67
10. A compound has the empirical formula C10 H 8 Fe . A solution of 0.26 g of the
compound in 11.2 g of benzene  C6 H 6  boils at 80.260C. The boiling point of
benzene is 80.100C; the K b is 2.530C/molal. What is the molecular formula of the
compound?
(a) C30 H 24 Fe3 (b) C10 H 8 Fe (c) C5 H 4 Fe (d) C20 H16 Fe2
11. A solution of 0.640 g of azulene in 100.0 g of benzene boils at 80.23 0C. the boiling
point of benzene is 80.100C; the K b is 2.530C/molal. What is the molecular weight
of azulene?
(a) 108 (b) 99 (c) 125 (d) 134
12 The boiling point elevation constant for toluene is 3.32 K kg mol-1. The normal
boiling point of toluene is 110.70C. The enthalpy of vaporization of toluene would
be nearly.
 (a) 17.0 kJ mol-1 (b) 34.0 kJ mol- (c) 51.0 kJ mol- (d) 68.0 kJ mol-
13. An aqueous solution of glucose (m = 180) containing 12 g dissolved in 100 g of
water is found to boil at 100.340C while the boiling point of pure water was 1000C.
Calculate the molal elevation constant for water.
Answer
1. 5.2 0 2. 158.9 3. 100.280C
4. 236.1 5. 5.190 6. 5.10 7. 101.0640C
8. (a) 9. (d) 10. (d) 11. (c)
12. (b) 13. 746.32 mm