Acids: Understand The Chemistry and Remember The Equations

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Understand the chemistry

Acids react with metal carbonates or Acids:


bicarbonates to form salt and water with the
evolution of carbon dioxide gas.
and remember the An acid is a substance which dissociates (or
ionises) when dissolved in water to release
For Example: equations hydrogen ions.

1. Hydrochloric acid reacts with sodium For Example:


carbonate to form sodium chloride and water An aqueous solution of hydrochloric acid
with the release of carbon dioxide gas. The reaction between an acid and a base to form
dissociates to form hydrogen ions. Since hydrogen
salt and water is called a neutralisation reaction.
Na2CO3(s) + 2 HCl(aq) → 2NaCl(aq) + CO2(g) + ions do not exist as H+ in solution, they combine
For example: with polar water molecules to form hydronium
H2O(l)
Hydrochloric acid reacts with sodium hydroxide to
ions. [H3O+].
ii. Similarly, sodium bicarbonate also reacts with
form sodium chloride and water. HCl (aq) → H+ (aq) + Cl- (aq) H+ + H2O → H3O+
hydrochloric acid to form sodium chloride and
water with the release of carbon dioxide gas. HCl + NaOH → NaCl + H2O
The presence of hydrogen ions [H+] in hydrochloric
NaHCO3(s) + HCl (aq) → NaCl (aq) + CO2(g) + acid solution makes it behave like an acid.
H2O(l)

Neutralisation

Acids react with metals to produce Reaction with Metal Acids react with metallic oxides to
salt by displacing hydrogen. Carbonates & In Water form salt and water.
For Example: Bicarbonates For Example:
1. When dilute sulphuric acid reacts Copper oxide (II), a black metal
with the metal zinc, zinc sulphate is
formed with the evolution of ACIDS oxide reacts with dilute
hydrochloric acid to form a blue-
hydrogen gas.
green coloured
Zn + H2SO4 → ZnSO4 + H2
Reaction with Reaction of copper chloride (II) solution.
2. Zinc is the only metal which reacts
with sodium hydroxide to form
sodium zincate with the release of
Metals
Acids, Bases & Metallic Oxides CuO + 2HCl → CuCl2(aq) + H2O

hydrogen gas.
Salts
Zn + 2NaOH → Na2ZnO2 + H2

In Water BASES SALTS Bleaching Powder

Reaction of Non- Baking Soda Common Salt Bleaching powder is


A base is a substance which dissolves manufactured from chlorine
Metallic Oxides
in water to produce hydroxide ions gas. It is produced by the
[OH- ions]. Bases which are soluble in Chemical formula: NaHCO3 Chemical name: Sodium chloride action of chlorine on dry
water are called alkalis. Bases react with non-metallic slaked lime [Ca(OH)2].
It is produced on a large scale by Common salt is a neutral salt and
For Example: oxides to form salt and water.
treating cold and concentrated can be prepared in the laboratory Ca(OH)2 + Cl2 → CaOCl2 + H2O
For Example: solution of sodium chloride by the reaction of sodium hydroxide
Sodium hydroxide dissolves in water It is represented as CaOCl2
to produce hydroxide and sodium (brine) with ammonia and carbon and hydrochloric acid.
Calcium hydroxide reacts with
ions. dioxide. Uses: For bleaching cotton
non-metallic oxides like NaOH(aq) + HCl(aq) → NaCl(aq) +
and linen in the textile
NaOH (aq) → Na+ (aq) + OH- (aq) carbon dioxide to form NaCl + H2O + CO2 + NH3 → NH4Cl + H2O(aq)
industry and for bleaching
calcium carbonate salt and NaHCO3
It is an important raw material for wood pulp in the paper
The presence of hydroxide ions [OH-]
water. On heating, it decomposes to give products of daily use such as NaOH, industry. Used for disinfecting
in sodium hydroxide solution makes it
sodium carbonate with the baking soda, washing soda and drinking water to make it free
behave like a base. Ca(OH)2 + CO2 → CaCO3 + H2O
evolution of carbon dioxide. bleaching powder. of germs.

2NaHCO3 Na2CO3 + H2O + CO2

Importance of pH in everyday life Universal Indicator Plaster of Paris Water Of Crystallisation


o Our body works well within a narrow Uses
In case of a colourless liquid, the accurate Plaster of Paris is prepared by heating Water molecules which form a part of the structure of
pH range of 7.0 to 7.8. pH can be obtained by adding a universal Used asgypsum a crystal are called water of crystallisation. The salts
an antacid to treat
at 373 K. On heating, it loses
o When the pH of rain water is less than indicator. which contain water of crystallisation are called
acidity ofwater
the stomach.
molecules and becomes calcium
5.6, it is known as acid rain. hydrated salts. Every hydrated salt has a fixed number
o To get rid of this pain, bases called It is a mixture of several indicators and Used tosulphate hemihydrate (CaSO4.1/2 H2O)
make baking of molecules of crystallisation in its one formula unit.
antacids are used. shows different colours at different which is called Plaster of Paris.
powder, which is used in
o Antacids are a group of mild bases concentration of hydrogen ions in a solution. For Example: CuSO4.5H2O, Na2CO3.10H2O,
preparation of4cakes,
CaSO breads,
.2H2O CaSO 4. ½ H2O + 1 ½ H2O
which react with the excess acid and CaSO4.5H2O, and FeSO4.7H2O
neutralise it.
For Example: etc.
Gypsum Plaster of Paris Copper sulphate crystals (CuSO4.5H2O) are blue in
o Commonly used antacids are o A universal indicator produces green Used in soda-acid fire
colour, and on heating strongly they lose all the water
magnesium hydroxide [Mg(OH)2] & Uses
colour in a neutral solution, pH = 7.extinguishers.
of crystallisation and form anhydrous copper sulphate,
sodium bicarbonate[NaHCO3] o The colour changes from blue to
Used in hospitals as plaster for which is white. On adding water to anhydrous copper
Tooth decay starts when the pH in the violet as pH increases from 7 to 14.
supporting fractured bones in the right sulphate, it gets hydrated and turns blue.
mouth falls below 5.5.
o The colour changes from yellow to
o Tooth enamel is made up of calcium position. Used as a fire-proofing CuSO4.5H2O →CuSO4 + 5H2O
pink and then to red as pH
phosphate which is the hardest material.
substance in the body.
decreases from 7 to 1. CuSO4 + 5H2O→ CuSO4.5H2O

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