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Environmental Earth Sciences (2020) 79:461

https://doi.org/10.1007/s12665-020-09189-8

ORIGINAL ARTICLE

Carbon emission assessment and control measures for coal mining


in China
Aitao Zhou1,2,3 · Jiaying Hu1 · Kai Wang1

Received: 2 April 2019 / Accepted: 11 September 2020 / Published online: 26 September 2020
© Springer-Verlag GmbH Germany, part of Springer Nature 2020

Abstract
Coal is the most important primary energy in China. Although the proportion of coal in China’s total energy consumption
continues to decline it will still be the main energy in China for a long time in the future. As the largest contributor to China’s
greenhouse gas emissions, the energy conservation and emission reduction of coal industry will be the most critical step
for China to cope with global climate change and solve environmental problems at present and in the future for a long time.
The object of this study was coal mining in China. Life cycle assessment (LCA) was used to quantify carbon emissions in
whole process of coal mining, including mining, ventilation, drainage, power consumption, transportation, and post-mining
activities. The analysis result shows that the carbon emissions of producing tons of coal are 164.403 kg of carbon dioxide
equivalent per ton. The analysis further emphasizes that the methane contributes the most, accounting for 62.21% of the total
emissions, and plays an important role in the full life cycle of coal mining. Therefore, it presents a potential to mitigate the
environmental impact of coal mining, and its main task is to recover and recycle methane. Based on the technical level, this
study puts forward the low-carbon development countermeasures for coal enterprises. Then the technical system of methane
emission control and utilization is constructed from three aspects: coal-bed methane development, gas extraction, and utiliza-
tion and gas utilization. Finally, a trinity resource utilization system of coal mine gas is constructed. This study hopes to help
practitioners to realize the importance of coal mine methane to the coal mining process. If the efficient resource utilization
of methane be realized, it could not only save energy and reduce emissions in coal enterprises, but also promote the safety
production of coal mines and improve the economic benefits of coal mines. It is also of great significance for optimizing
China’s energy structure, realizing low-carbon transformation, and safeguarding China’s strategic energy security.

Keywords  Greenhouse gas emissions · Coal mining · Low-carbon development measures · China

Introduce coal with gas" and "Replacing coal with electricity”, China’s
coal consumption and production began to decline gradu-
As the main energy source in China, coal is the main driving ally from 2013 to 2016. However, in the following three
force of China’s economic development. As shown in Fig. 1, years (2016–2018), coal consumption remained stable and
under the influence of relevant policies such as “Replacing coal production even showed a rebound trend. In addition,
coal production still accounts for 70 percents of total energy
production in 2018. China is undergoing a transition from
* Kai Wang relying on high-energy and high-coal consumption indus-
safety226@126.com tries to energy-intensive and power-intensive industries. If
1
College of Emergency Management and Safety Engineering, the expected increase in electricity demand cannot be met
China University of Mining and Technology (Beijing), by non-coal energy sources in the coming years, China’s
Beijing 100083, China coal consumption is likely to continue to grow (Lin et al.
2
State and Local Joint Engineering Laboratory for Gas 2018). Therefore, China’s coal-based energy structure will
Drainage & Ground Control of Deep Mines, Henan not change for a long time to come.
Polytechnic University, Jiaozuo, China While promoting China’s economic development, coal
3
Department of Energy and Mineral Engineering, EMS has also caused serious damage to China’s ecological envi-
Energy Institute and G3 Center, Pennsylvania State ronment. According to the latest 2014 global greenhouse
University, University Park, PA, USA

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Page 2 of 15 Environmental Earth Sciences (2020) 79:461

Fig. 1  Annual coal consump- Coal consumption Proportion of coal consumption


tion/production and its propor-
Coal production Proportion of coal production 100
tion in total energy consump-
tion/production of China 5
3.0x10

Proportion of coal consumption/production in


total energy consumption/production (%)
80

(ten thousand tons of standard coal)


2.5x105

Coal consumption/production
2.0x105 60

1.5x105
40

1.0x105

20
5.0x104

0.0 0
20 0 1
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Year

gas emissions data released by the World Resources Institute paper. By establishing carbon emission model of coal enter-
(WRI), China’s total CO2 CO2 emissions are up to 12Gt, prises, this paper analyzes the source of carbon emissions
accounting for one-third of the world’s total emissions, while and its influence proportion, and obtains the key part of car-
the use of coal and its derivatives contributes more than 80% bon emissions reduction, which provides the optimal choice
of the total CO2 emissions (WRI 2018). Therefore, the coal- for the development strategy of Chinese coal enterprises.
based energy structure is the main source of China’s carbon Finally, based on the technical level, this study constructs
emissions, which requires that coal-related industries adjust low-carbon system for coal enterprises. This study hopes to
and optimize their structure and accelerate transformation. provide a reference for the low-carbon development of Chi-
While ensuring the development of national economy, China nese coal enterprises, whose low-carbon behavior is not only
will significantly reduce coal consumption to achieve the about the compensation and repair after environmental dam-
goal of emission reduction. And Chinese government will age, but also about the key points of low-carbon develop-
fulfilled promise of “peak carbon dioxide emissions around ment in the strategic deployment so that coal enterprises can
2030 and do its best to reach the peak earlier”(Bloch et al. implement low-carbon behavior and benefit from it in the
2012; NDRC 2016). Based on this, the paper chooses coal mining process. Finally, the goal of coal mine transforma-
mining as the research object to discuss the sustainable tion and upgrading, improvement of quality, and efficiency
development mode of coal enterprises. To be specific, coal will be achieved, making contributions to the development
enterprises need to achieve energy conservation, emission of China’s multi-polar energy pattern and low-carbon energy
reduction, and clean utilization of coal resources while structure (NEA 2017).
maintaining economic benefits, and meet China’s energy
needs, so as to achieve synchronous benefits for coal enter-
prises, ecological environment, and national economy under Method discussion
low-carbon and green development of coal enterprises.
The above content mainly introduces the dual role of coal Review of carbon emissions measurement methods
in China’s economic and social development. In considera-
tion of the energy conservation and emission reduction prob- The purpose of this study was to explore the mode to make
lems that need to be solved urgently in China’s coal industry, coal mining achieve high efficiency in energy conserva-
this paper chooses the mining process of coal enterprises as tion and emission reduction. It is necessary to measure
the research object, and where to take measures and how and evaluate the carbon emissions in the mining process,
to take measures are the two key points discussed in this obtaining the different degrees of influence of each link

13
Environmental Earth Sciences (2020) 79:461 Page 3 of 15  461

on carbon emissions, and finally take appropriate coun- widely used assessment method in environmental impact
termeasures based on this. With the increasing severity of management at present. In this paper, the systematic analysis
global warming and climate change caused by greenhouse method of LCA was adopted to conduct a relatively com-
gas emissions, a considerable number of carbon emission prehensive and comprehensive analysis of carbon emissions
assessment methods have been adopted in various fields. of coal mining enterprises in China. The output of China’s
Through field investigation and literature review, Lou et al. underground coal mines accounts for more than 90% of the
(2017) used first-order attenuation method to analyze key annual coal output, so this paper took underground coal
parameters such as waste composition, correction factor, mine as the research object and used LCA to calculate the
methane content, and oxidation factor, and finally estimated carbon emissions of each link of underground coal mine
the change trend of greenhouse gas emissions in Chinese to provide theoretical guidance for the implementation of
landfills over the years. Fugiel et al. (2017) established a decision-making.
greenhouse gas emission assessment model for large oil and
gas companies based on the production process and corpo- Applications of LCA
rate behavior and carried out a comparative test between the
assessment results and the greenhouse gas emission data LCA is an important environmental management tool, which
released by enterprises. Lv et al. (2019) used COPERT IV can quantify the resource consumption and various emis-
model to analyze the emission parameters of various types of sions in the whole process from raw materials to production,
vehicles and calculated the emissions of automobile exhaust use, and waste. It not only considers the environmental prob-
in Yunnan province, China. Finally, they used Monte Carlo lems directly caused by the implementation of the activity,
simulation to carry out the uncertainty analysis of estima- but also analyzes its related and potential impact, so as to
tion. Tanha et al. (2019) proposed a monitoring method of more comprehensively evaluate the environmental conse-
carbon emissions from gas combustion for a natural gas- quences caused by the research object, and finally provides
processing plant in Iran. By establishing a model to calcu- the basis for taking corresponding measures (Corrado et al.
late the composition and flow rate of combustion gas and 2006).
other parameters, the online monitoring of greenhouse gas The main objective of LCA is to reduce energy use and
emissions from the treatment plant was realized, which was environmental emissions in activities and improve their
in good agreement with the field measurement results. In socio-economic performance throughout their life cycle.
addition, many carbon emission studies have been conducted Therefore, LCA has become an important tool for resource
in coal-related activities, among which the most common management and sustainable development assessment and
method is the direct measurement method. For example, has been widely used in various fields. Yan et al. (2015)
Engle et al. (2011) evaluated the greenhouse gas emissions used LCA to quantify greenhouse gas emissions from
of coal mine fires by directly measuring the gas emissions three major food crops (rice, wheat, and corn) in eastern
from rock formations. However, direct measurement is often China and evaluated the carbon footprint of China’s grain
not feasible and not suitable for provincial or national macro crop production. Then the impacts of farm scale, agri-
analysis. On this basis, they also used the aviation infra- cultural input, and grain yield on crop carbon footprint
red imaging technology to obtain the fire thermal data and were further analyzed in the paper. Alkatheri et al. (2018)
estimated the fire parameters after the algorithm analysis. estimated the greenhouse gas emissions per kilowatt-hour
Finally, two methods were used to estimate and compare (kWh) in the whole process of UAE natural gas power
greenhouse gas emissions from coal mine fires. Van Dijk generation by using mathematical model and simulation
et al. (2011) simulated the spatial details of coal mine fire by software. The greenhouse gas emission’s life cycle of the
establishing a three-dimensional model containing geologi- whole process including natural gas extraction, collection,
cal factors, mine characteristics, coal properties and other transportation, processing and power generation, distri-
information, and calculated the fire combustion volume to bution, transportation, and final use was established, and
estimate the greenhouse gas emissions of coal mine fire. compared with the greenhouse gas footprint of ultra-acidic
Jeon et al. (2010) compared the carbon dioxide emissions natural gas between conventional natural gas. Wang et al.
of coal-fired power plants by combining the emission gas (2018) evaluated the environmental impact of coal min-
sampling measurement method with the chemical compo- ing, washing, and transportation stages in the life cycle
sition analysis method of fuel coal. Aguirre-Villegas et al. of coal-fired power generation in China by using the full
(2017) compiled a carbon emission life cycle list for each life cycle method and calculated the resource consumption
link of the Indonesian coal supply chain to evaluate green- cost and external environmental cost of coal-fired power
house gas emissions and resource consumption at each link generation by using the cost accounting theory. Soni et al.
and finally obtained the impact of the coal supply chain on (2016) further proposed the life cycle cost method (LCC)
the environment). Life Cycle Assessment (LCA) is the most based on the traditional net present value (NPV) method.

13
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Page 4 of 15 Environmental Earth Sciences (2020) 79:461

In addition, the theory of real option analysis (ROA) was carbon emissions of coal mining life cycle chain (GAQSIQ
applied to combine LCC and ROA in the field of energy 2017).
and power to solve the investment problem of coal infra-
structure projects. Finally, the paper evaluates the enter- Analysis of carbon emissions source in coal mining
prise’s R&D cost, project operation structure, environmen-
tal degradation and other aspects. Burchart-Korol et al. Determination of carbon emissions field
(2016) developed an environmental life cycle assessment
model suitable for coal mine operations, which in addition Each link of the coal mining process will produce corre-
to being applicable to greenhouse gas emission assess- sponding carbon emissions, so the carbon emissions of each
ment, can also be combined with ReCiPe method to assess link should be measured comprehensively. In addition to the
damage categories such as human health, ecosystem, and analysis of the direct production link of coal, carbon emis-
resources. By evaluating the factors that directly or indi- sions of relevant links in the whole process of coal mining
rectly affect the environment as well as those related to raw (such as energy consumption of the staff, methane escaping
materials and energy used in the production process, the after mining activity, etc.) should also be taken into account.
monitoring of human and mine environment was achieved. All links that may generate carbon emissions in coal mining
The above research provides a reference for the life cycle are analyzed, as shown in Fig. 2.
carbon emission assessment of coal mining in this paper.
In this study, a model of greenhouse gas emissions ( CO2 Carbon emissions’ accounting boundaries
equivalent) from the cradle to the gate of coal mining was
established, and normalized CO2 equivalent emissions of The primary task of life cycle analysis is to determine the
various emission activities were analyzed to obtain the full scope of system boundaries. Starting from the whole life
life cycle greenhouse gas emissions of a ton of coal produc- cycle of coal mining, this paper analyzes all activities related
tion in underground mine coal mine in China. Through the to greenhouse gas emissions and divides all emission activi-
evaluation and interpretation of the results, it provides the ties into three categories according to emissions methods:
basis for the energy conservation and emission reduction energy consumption emissions, direct emissions, and coal
measures of coal mining enterprises. In this study, the LCA spontaneous combustion emissions. The energy consump-
research framework is defined in GB/T32151 which is put tion emissions include three parts: power consumption of
under the administration of China technical committee on equipment (including power consumption of direct pro-
carbon emission management of standardization adminis- duction equipment, power consumption of auxiliary facili-
tration of China (SAC/TC548)) and adopted to evaluate the ties, and power consumption of workers, etc.), raw coal

Fig. 2  Carbon emission struc-


ture of coal mining Emissions of Electrical power system
auxiliary
production Transport system

Ventilation and drainage system

Post-mineral activities
Carbon
emissions from Emissions of coal Coalbed methane escape
coal mining
Material consumption

Coal mining and excavation

Emissions of life Personnel energy consumption

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Environmental Earth Sciences (2020) 79:461 Page 5 of 15  461

consumption (such as coal burning for boilers in mining Pe = P1 + P2 + P3 (1)


areas, power generation by coal burning, etc.), and other
consumption (including gasoline and diesel consumption Pe = P1 + P2 + P3 , where P1,P2,P3 are the carbon emis-
of transport vehicles, natural gas consumption, etc.). Direct sions of the above three parts, respectively, and the unit is
emissions include three parts: methane and carbon dioxide kgCO2 ∕t.
emissions due to ventilation and pre-extraction of CBM
during mining and escape from post-mining activities. Coal Calculation of carbon emissions from energy consumption
spontaneous combustion carbon emission is mainly caused
by coal and gangue accumulation (Xia et al. 2010). The greenhouse gas emissions during coal mining mainly
The accounting boundaries of carbon emissions from coal come from the electricity consumption of mining equipment
mining were shown in Fig. 3. The determination of carbon and auxiliary equipment, as well as the raw coal and natural
emissions’ source is the primary task of this work. It requires gas consumption in mining areas. According to statistics, the
systematic analysis and classification of carbon emission comprehensive energy and power consumption of raw coal
from mining. Then based on this, the corresponding param- production in large and medium-sized coal mines in China
eters can be selected according to the contribution to carbon are 11.6 kg standard coal/ton and 21.2 kWh/ton, respectively
emission to determine the carbon emission of each activity. (CNCA 2018). In recent years, large modern coal mines have
become the main body of coal production after the industrial
adjustment of reducing capacity in China. Among them, the
Construction of carbon emission measurement output of large and modern coal mines with an annual out-
model put of 1.2 million tons or more accounts for more than 75%
of the country’s total energy consumption. Therefore, the
Based on the above analysis, the accounting boundaries of comprehensive energy and power consumption of raw coal
carbon emissions in coal mining are determined, and the production of large and medium-sized coal mines in this
carbon emissions sources are divided into three parts: energy report can be regarded as the average level of coal in China
consumption emissions, coal bed methane emissions, and (CNCA 2018). The carbon emission generated by raw coal
coal spontaneous combustion emissions. In this paper, we consumption per unit of production should be calculated
build a carbon emission calculation model for coal min- based on the carbon emission coefficient, and the power con-
ing and divide coal mining activities into three aspects to sumption should also include the standard coal consumption
explore the carbon footprint in this process. The following parameters of power supply. Finally, normalized CO2 equiva-
three parameters are selected to represent the corresponding lent can be used to uniformly represent the carbon emission.
mining activities: The selection based on this parameter is as follows:

Extraction
system
Direct Post-mining
Methane recycle
emissions activities
Ventilation Carbon dioxide and
system methane escape emissions

The workers consume


Subsidiary activities
water, energy, etc
Energy
Underground Auxiliary Power supply, drainage, Fossil fuel combustion
consumption
mining production activities transportation,etc emissions
emissions
Direct production Coal mining and
activities excavation

Coal
spontaneous
combustion

Fig. 3  Carbon emission accounting boundary for coal production

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Page 6 of 15 Environmental Earth Sciences (2020) 79:461

8758.35 g. The calculation shows that the greenhouse gas


P1i = qi umk, (2)
emissions of mining a ton of raw coal are about 8758.35 g
where P11 and P12 are the greenhouse gas emissions of pro- CO2 and 4091.224 g CH4 , the normalized CO2 equivalent
ducing one ton of raw coal using electricity and raw coal, emissions of CH4 are about 102.28 kg CO2 ∕t , and the GWP
respectively, and the unit is gCO2 ∕kWh ; q1 and q2 are the value of CH4 within 100 years is 25 (IPCC 2007).
comprehensive energy consumption (kg/t) and production Therefore, the greenhouse gas emissions P2 caused by
power consumption (kWh/t) of producing a ton of raw coal, direct emissions of mining a ton of raw coal are: normalized
respectively; u is the CO2 emissions coefficient (t/tce) of a CO2 equivalent emissions 111.038 kg CO2 ∕t.
ton of standard coal; u = 2.4567t CO2/tce (GAQSIQ 2017);
m is the power supply standard coal consumption g/kWh, Calculation of coal carbon emissions from spontaneous
m = 309 g/kWh (CEC 2017); k is the normalized CO2 equiv- combustion
alent coefficient, i.e. GWP value, the amount of N2 O pro-
duced by the combustion of fossil energy is very small, so it China is one of the countries most seriously affected by
is believed that all the greenhouse gases emitted by energy spontaneous combustion of coal fields in the world. The
consumption are CO2 , GWP = 1. carbon emissions caused by spontaneous combustion of coal
The normalized CO2 equivalent of a gas is the ton of the in coal mining and storage cannot be ignored (Voigt et al.
gas multiplied by its Global Warming Potential (GWP), 2004). The annual coal loss caused by spontaneous com-
and the GWP value of CO2 within 100 years is 1 (IPCC bustion of coal fields is about 20 million tons, accounting
2007), so the normalized CO2 equivalent of CO2 is equal to for about 0.5% of the annual total mining output (Xu et al.
itself. The calculation shows that the greenhouse gas emis- 2018). In this stage, the conversion coefficient of raw coal
sions caused by the power consumption of mining a ton and standard coal shall be used to convert the spontaneous
of raw coal (21.2kwh for mining a ton of coal) are about raw coal to standard coal, and then the carbon emission shall
16.093  kgCO2 , so the normalized CO2 equivalent emis- be calculated as follows:
sions are 16.093 kgCO2 ∕t ; the greenhouse gas emissions
caused by mining one ton of raw coal comprehensive energy
P3 = ieu, (4)
consumption (11.6 kg for mining a ton of coal) are about where i is the loss amount due to spontaneous combustion
28.498 kgCO2 , so the normalized CO2 equivalent emissions of coal for mining a ton of raw coal on average, i = 0.005t; e
are 28.498 kgCO2 ∕t. is the conversion coefficient of raw coal and standard coal,
e = 0.7143; u is the CO2 emissions coefficient of a ton of
P1 = P11 + P12 (3)
standard coal (t/tce), and u = 2.4567 tCO2 ∕tce (GAQSIQ
Therefore, the greenhouse gas emissions P1 caused by the 2017).
energy consumption of mining a ton of raw coal are: normal- The calculation shows that the greenhouse gas emissions
ized CO2 equivalent emissions 44.591 kg CO2 ∕t. caused by spontaneous combustion of mining a ton of raw
coal are about 8.774 kgCO2 , and the normalized CO2 equiva-
Calculation of carbon emissions from direct emissions lent of CO2 is equal to itself, so the greenhouse gas emis-
sions P3 caused by spontaneous combustion of mining a ton
From the statistics, in recent years China’s annual emis- of raw coal are the following: normalized CO2 equivalent
sions of methane mining amount to 20 billion m3 , and raw emissions 8.774 kgCO2 ∕t.
coal production is about 3.5 billion tons, so the calculated
tons of coal mining methane emissions are about 5.714 m3 . Carbon emission assessment results
NDRC(2011) recommended average CH4 emission factors
for China’s coal mine and post-mining activities: the key The result shows that the greenhouse gas emissions P of
coal mine and the local coal mine, respectively, are 8.37 mining a ton of raw coal are as follows: normalized CO2
m3 ∕t and 8.35 m3 ∕t (NDRC 2011). And Yu et al. (2008) equivalent emissions 164.403  kg CO2 ∕t . Among them,
estimated that the average CO2 escaping emissions of China direct carbon emission contributes the most, and meth-
coal mine in 2011 was 6.57 m3 ∕t raw coal production. (under ane emissions are the main part of direct carbon emission,
standard conditions). In comparison, the methane emissions accounting for 62.21% of the total emissions, as shown in
per ton of coal have fallen slightly in recent years, and it Fig. 4 and Table 1. Therefore, methane emissions are the
is estimated that the carbon dioxide emissions per ton of largest contribution of carbon emissions during coal min-
coal in recent years is 4.5 m3. Under standard conditions, ing, and if the methane of mining coal could be recycled,
the weight of CH4 in each ton of coal mined is 4091.224 g, it would improve the level of safety and economic benefits
and the weight of CO2 in each ton of coal mined is about while reducing emissions in mines (Bibler et  al. 1998).

13
Environmental Earth Sciences (2020) 79:461 Page 7 of 15  461

Comprehensive energy consumption the gas (Bibler et al.1998). Compared with other countries,
Power consumption China’s coal mine methane emission problem is more seri-
Direct emissions of CH4 ous. On the one hand, China is not only the world’s larg-
Direct emissions of CO2 est coal producer, but also produces more than 90% of the
62.21% Emissions of Spontaneous combustion country’s coal from underground mines, which emit far more
methane than open-pit mines. On the other hand, the geolog-
ical structure of coal mines in China is complex, and more
than 80% of coal seams are characterized by deformed coal,
low permeability, and high gas (Yuan 2016). In 2015, the
5.33% utilization rate of coal mine gas in China was only 35.3%,
5.34% much lower than 83% in the United States (NEA 2016).
9.79% Therefore, China faces challenge in coal mine gas recovery
17.33% and utilization. Moreover, with the increasing gap between
China’s natural gas supply and demand in recent years, as
Fig. 4  The proportion of carbon emission sources in coal mining shown in Fig. 5 (IIC 2018), the recycling of methane from
coal mines could supplement China’s scarce natural gas
reserves, and as an opportunity to mitigate greenhouse gas
Therefore, the coal mine emission reduction work is mainly emissions, which has a huge development prospect.
focused on the resource utilization of the methane, making To build a “abatement-recovery-utilization” system of
it the focus of reducing China’s greenhouse gas emissions coal mine methane, it is necessary to determine the pro-
from coal mining, which has positive significance for the duction and emission methods of the methane and to adopt
environmental demand and the benefit of coal enterprises.

3000 output
Technical measures 2800 consumption
2600
Natural gas output and consumption

2400
As early as 1993, Simpson et al. (1993) predicted that meth-
(100 million cubic meters)

2200
ane emissions from coal mining activities would increase by 2000
0.6% annually until 2025. Due to the seriousness of methane 1800
pollution to the environment and its own characteristics as a 1600
1400
clean energy, the control and utilization of coal mine meth-
1200
ane has been studied worldwide for a long time. Since the 1000
1960s, Britain’s coal mines have been recycling methane to 800
produce steam for mining facilities and selling it as methane 600
to homes and industrial users. In 1977, the methane recov- 400
200
ered from Ayr coal mine was used for power generation by
0
gas turbine system. In the 1990s, the United States used the 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 2018
drainage system to collect gas for sale, while Poland and the Year
Czech Republic used the gas for mine boilers, nearby steel
mills, and thermal power plants, etc., and the coal-producing Fig. 5  Natural gas output and consumption in China from 1998 to
countries worldwide began to extensively extract and recycle 2018

Table 1  Carbon emission assessment results


Type of Carbon emissions in coal mining The source of carbon emissions Emissions of CO2 equiva-
lent (kg/t)

Energy consumption Comprehensive energy consumption 16.093 44.591


Power consumption 28.498
Coal bed methane emissions Direct emissions of CH4 102.28 111.038
Direct emissions of CO2 8.75835
Coal spontaneous combustion emissions Emissions of Spontaneous combustion 8.774 8.774
Total (kg/t) 164.403

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Page 8 of 15 Environmental Earth Sciences (2020) 79:461

corresponding technical measures Ji et al. (2017) divided it 3. Ventilation Air Methane (VAM): Utilization technology
into two parts according to the mining sequence: pre-mining of dirty air methane.
gas drainage and post-mining gas release. Then, an evalua- 4. Abandoned mine methane (A-MM): Development of
tion method of pre-drainage gas quantity is established, and abandoned mine CBM.
the influence factors of mining activities are cited to estimate
the gas emissions in coal mines. Ju et al. (2016) believed
that there were three sources of methane release: excavation CBM and AMM mining technology
roadway, working face, and goaf. There are two sources in
excavation roadway and working face: surrounding rock and Methane extraction principle and process
coal block, and the goaf has three sources: residual raw coal,
adjacent coal seam, and surrounding rock, on which the gas CBM mining includes coal bed methane (CBM) and aban-
emissions of the coal mine can be determined. In view of doned mine methane (AMM). The most important charac-
the effectiveness and practicability of gas control and utili- teristic of CBM that is different from conventional natural
zation technologies, the definition of methane release from gas is that CBM is mainly stored in the coal seam in the
coal mines should take into account both comprehensive adsorption state. Therefore, the prerequisite of CBM mining
and technical feasibility. This paper decided to construct the technology is decompression and desorption, and its output
system according to the following classification (Singh et al. mechanism is shown in Fig. 6.
2016): From drainage and pressure reduction to the end of gas
extraction, CBM mining can be divided into three processes:
1. Coal bed methane (CBM): C-BM mining technology. 1. Stage of single-phase flow
2. Coal mine methane (CMM): CMM extraction technol- The stage at the initial stage of CBM mining, CBM is still
ogy. in the adsorption stage before the reservoir pressure has been

Distance from the wellbore


Initial formation pressure

Critical desorption pressure


Formation pressure

State three State two State one


Two-phase flow state Unsaturated flow state One-phase flow state

Exist in two phases (water and gas) Exist in a single


ph ase (water)
Two-phase flow Single-phase flow
1.0
permeability

Relative permeability to water


Relative

Relative permeability to gas

0.0

Fig. 6  Schematic diagram of coal seam gas output mechanism

13
Environmental Earth Sciences (2020) 79:461 Page 9 of 15  461

reduced to the critical desorption pressure, and only the water 3. Stage of pure gas production
phase flows in one direction in this stage. In the later stage of mining, the water saturation in the
qw fluid is equal to the critical water saturation, and the main
= mx + b (5) fluid is coal seam gas.
pi − pwf
Assuming that under the conditions of circular closed
boundary gas reservoir and fixed production of gas well,
−1 the quasi-steady state flow material balance equation at
m= (6)
NW bpss this stage is as follows:
qg
Q ( ) = mx + b (12)
x= w
( )
(7) m pi − m pwf
Δpct

−1
1 m= (13)
b= (8) Gb,pss
bpss

( ) 2qg t∗ca pi
Bw 𝜇w re 3 x= [ ( ) (14)
bpss = ln − , (9) m pi − m pwf × μg c∗t Z∗ i
( )] ( )
543Kh rw 4

where pi is the original formation stress, MPa; pwf is bottom ( )


1 B 𝜇 r 3
hole pressure MPa; K is the formation permeability, μm2 ; h b= , bpss = w w ln e − (15)
bpss 543Kh rw 4
is the formation thickness, m3 ; Qw is the cumulative water
rate, m3 ; ct is the sum of formation compressibility and fluid
The original reserves of CBM and the permeability of
compressibility.
coal seam can be determined using the flow material bal-
2. Stage of gas–water two-phase flow
ance equation and geological parameters, and the perme-
When the pressure of the coal seam decreases, the methane
ability of coal seam is a key factor in the development of
in the matrix pores of the local reservoir is desorbed and mixed
CBM. Table 2 shows the characteristics of CBM reservoirs
with the water in the fracture to form a gas–water two-phase
in China, the United States, and Australia (Wang et al.
flow. Under the condition of quasi-steady flow at this stage, the
2017).
flow material balance equation is:
The permeability of coal seam in China is four orders
qg
[ ∗( )
m pi −m∗ pR
( )] of magnitude lower than that of San Juan coal field in
[ ( ) ( )] = mG [ ( ) ( )] + b (10) the United States and three orders of magnitude lower
m∗ pi −m∗ pwf m∗ pi −m∗ pwf than that of Bowen coal field in Australia, excluding the
Jincheng coal field. And the gas content in China’s coal
p pKrg (p) fields is higher than that in the United States and Australia.

m∗ (p) = 2 dp (11) Therefore, although China has huge reserves of CBM,
pb 𝜇g Z
the low permeability of coal seam makes it much more

Table 2  Characteristics of Coal field Coal seam character


coalbed methane reservoirs
Permeability (mD) Gas pressure (MPa) Content of
gas ( m3 ∕t)

Huainan 0.00028 6.5 10–40


Huaibei 0.00121 5.1 10–35
Yangquan 0.00037 2.3 10–40
Zhengzhou 0.00118 2.6 8–20
Shenyang 0.00035 8.3 10–35
Yaojie 0.00244 7.3 10–30
Jincheng 1.55 1.25 5–50
San Juan (The United States) 10–100 – 9–19
Bowen (Australia) 1–10 – 8–17

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difficult to exploit CBM in China. Therefore, solving this 𝜕C


J = −Df , (16)
problem has become the key to increase the production of 𝜕X
CBM Wells in China.
where Kn is the Knudsen number representing the relative
size of void diameter and the average free path of molecu-
Stimulation techniques of CBM Wells
lar motion; J is the gas diffusion rate per unit area, kg/s
­m2; 𝜕C∕𝜕X is the concentration gradient along the diffusion
Hydraulic fracturing is a stimulation technique widely used
direction; Df is Fick diffusion coefficient, m2 ∕s ; C is the
in conventional oil and gas fields. The main principle of
concentration of the gas, kg∕m2.
hydraulic fracturing (hydraulic fracturing) is to maintain
Effective Fick diffusion coefficient:
high permeability of coal seams by injecting fracturing fluid
and large particles of solid proppant to cause incomplete Df 𝜃
fracture closure in coal seams. At present, more than 90% of Dfe = , (17)
𝜏
coal seams in the United States are transformed by hydraulic
fracturing. After fracturing, the number and size of fractures
in the coal seam are greatly increased, which increases the where 𝜃 is the effective surface porosity; 𝜏 is the tortuous
pressure drop area around the borehole and ensures the rapid factor.
and relatively lasting release of gas in a large area of coal 2. Knudsen diffusion condition is as follows: when
seam. Kn ≪ 0.1,
CBM injection is also suitable for the development of low √
permeability CBM fields. In field tests, N2 and CO2 are usu- 2 8RT
Dk = r , (18)
ally injected into the reservoir, which can directly increase 3 𝜋M
the flow energy in the coal seam and change the void char- where Dk is Knudsen diffusion coefficient; r is the average
acteristics of the coal seam to improve the permeability (Wu radius of the void, m; R is the universal gas constant; T is
et al. 2013). Moreover, injected gas can compete with meth- the absolute temperature, K; M is the molecular weight of
ane to adsorb in coal seam and promote methane desorption, the gas.
thus improving the extraction efficiency of CBM. Field test Considering factors such as effective surface porosity and
analysis shows that CO2 injection can increase methane pro- tortuous factor, the effective Knudsen diffusion coefficient
duction by 140% compared with direct extraction of CBM is as follows:
(Das et al. 2017).
Therefore, in addition to pumping and discharging con-

8𝜃 2 2RT
fined water from coal seam to release the adsorbed gas, Dke = , (19)
3𝜏s 𝜌 𝜋M
China should also vigorously develop and popularize the
technology of increasing production of CBM and improve where ρ is the density of coal, kg∕m3.
the productivity of CBM Wells by effectively improving the 3. Transitional diffusion condition is as follows:
permeability of coal seam or injecting gas displacement. 0.1 < Kn < 10 . The diffusion process is restricted by the
above two diffusion mechanisms, and the effective diffusion
CMM extraction technology coefficient under constant pressure is related to Fick diffu-
sion coefficient and Knudsen diffusion coefficient as follows:
The characteristic of gas in coal mine lies in the co-storage
1 1 1
of coal and gas and their mutual influence. Under high- = + (20)
Dpe Dfe Dke
pressure conditions, gas extraction is often difficult due to
the adsorption of coal seam and low permeability, and the
presence of gas may also cause coal and gas outburst or gas Linear seepage theory of coal seam gas
explosion. In the process of gas extraction, the movement
modes of gas from coal seam to borehole includes desorp- The reason for gas seepage in coal is the existence of pres-
tion, diffusion and seepage (Zhou et al. 2019). sure difference. For one-dimensional single-phase porous
coal seam, Darcy’s law is described as (Wang et al. 2012)
Principle of gas diffusion follows:

The theory of coal seam gas diffusion mainly includes Fick kx ( 𝜕P 𝜕D


)
vx = − − 𝜌gx , (21)
diffusion, Knudsen diffusion, and Transitional diffusion. 𝜇 𝜕x 𝜕x
1. Fick diffusion condition is as follows: when Kn ≫ 10 ,
and the random motion of the gas molecules occurs.

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Environmental Earth Sciences (2020) 79:461 Page 11 of 15  461

where vx is the volume flux in this direction, kx is the per- Construction of "spatial–temporal coupling and stereo
meability of the coal seam, 𝜇 is the fluid viscosity, and gx optimization" gas extraction system
is the pressure drop increment. Permeability is sensitive to
the effective stress caused by geological structure and the There are many mines in China with a high gas content mak-
shrinkage or expansion of coal matrix caused by methane ing it difficult to extract the coal. The existing extraction
desorption or adsorption. technology has single effect and low efficiency, so it is nec-
essary to carry out systematic and efficient gas extraction in
Optimization of gas extraction technology coal mines. In this paper, the "spatial–temporal coupling and
stereo optimization" gas extraction scheme is proposed, as
Gas extraction drilling, whether horizontal, vertical or bed- shown in Fig. 7 (Yuan 2016; Hu et al. 2017), which has the
ding or penetra-ting, needs to directly communicate with following characteristics:
the gas source and transport through the gas migration path.
Drilling depth, extraction time, and extraction pressure 1. Coordination and cooperation of "coal mining–tun-
directly affect the gas extraction effect. At present, under neling–extraction", which requires appropriate arrange-
severe conditions such as deep mining, high stress, low per- ment of gas extraction operation, and mining technol-
meability, and complex geological conditions in China’s ogy, requires that gas extraction operation does not
coal mines, low permeability of coal seam directly leads affect mining activities, and at the same time gas disaster
to slow gas extraction speed, low efficiency, and high cost, should be solved to improve mining efficiency.
and seriously affects the gas extraction effect (ECE 2010). 2. "Working face–goaf–adjacent coalseam" all-around
Whether the gas source can be communicated accurately and extraction. In the process of coal mine gas extraction, it
effectively is of great importance to gas extraction. There- is necessary to ensure the effective gas extraction in all
fore, to achieve reasonable and efficient gas extraction, it directions in the mine so as to prevent and control the
is necessary to develop relevant technologies to ensure the gas disaster. Especially under the condition of coal seam
accuracy of drilling targets and improve the permeability group mining, the pressure relief gas in the adjacent coal
of coal seam. seam will surge to the mining seam through the inter-
1. Directional long-distance drilling technology layer cracks, so the gas control in the adjacent coal seam
Due to the complexity of geological conditions in China’s is also of great importance (Xiaocun et al. 2018).
coal mines and the increase of mining depth and intensity, 3. "Downhole and surface" three-dimensional extraction.
the traditional special roadway technology and extensive China’s high-gas mines mainly use underground drain-
short drilling technology are no longer applicable. The age, while surface drainage of gas will make the coordi-
directional long-distance drilling techno-logy can realize nated exploitation of coal and CBM possible. Multiple
the random directional measurement and precisely control exploitation methods are used to combine mining above
the drilling track by using the directional long drilling rig, and below the well to realize" protect coal mining by
which has the advantages of high drilling efficiency and cen- coal mining, promote gas mining by coal mining" (Xie
tralized extraction. It greatly increases the effective length et al. 2014).
of gas extraction and makes the borehole extend along the 4. Anti-reflection and pressure relief extraction. It is nec-
seam fracture zone. The effective utilization rate of borehole essary to make extensive use of hydraulic fracturing,
is greatly improved, and the high efficiency of gas extraction hydraulic fracturing, high-pressure water jet drilling,
is guaranteed. loose blasting, pre-splitting blasting, cross-drilling anti-
2. Pressure relief and anti-reflection technology reflection, and other technologies to effectively improve
Most coal seams in China belong to low-permeability the permeability of coal seam, realize efficient and opti-
coal seams, and it is much more difficult to pre-extract gas mized extraction of gas, and provide safety guarantee for
from low-permeability coal seams. The high cost and heavy high-yield and high-efficiency of coal mine.
workload of simply drilling more boreholes and extend-
ing extraction time cannot realize efficient gas extraction. The significance of "spatial–temporal coupling and stereo
The following technologies could be adopted to increase optimization" lies in fully coordinating the spatial–tempo-
the permeability of the coal seam. Common pressure relief ral relationship between gas extraction and mining activi-
and anti-reflection extraction methods include the follow- ties, making full use of favorable conditions such as coal
ing: hydraulic fracturing, hydraulic fracturing, high-pressure seam mining and pressure relief, so as to achieve dynamic
water jet drilling, loose blasting, pre-splitting blasting, and cooperation between gas extraction and mining activities.
cross-drilling anti-reflection, etc., which through improv- The utilization of gas can effectively prevent and control the
ing the permeability of coal seam to achieve efficient gas occurrence of gas disasters so that gas extraction and mining
extraction. activities complement and promote each other. At the same

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Page 12 of 15 Environmental Earth Sciences (2020) 79:461

Adjacent Upper adjacent layer pressure relief Drilling and drainage, drainage of
layer and extraction special roadway roof
Lower adjacent layer pressure relief Borehole extraction
and extraction
Ground boreholes are drilled to extract upper
and lower adjacent layers of gas
Roadway pre-extraction of seam gas
Before
mining Drill holes for pre-extraction of seam gas
Advance drilling of coal roadway for
Before pre-extraction of gas
excavation First extraction and then excavation in the Pressure relief and
Working coal roadway Optimized
seam Drilling from roadway to the front of technology
anti-reflection
working face while mining coal technology
In mining
Drilling through layers to the layers without
mining in the layered mining
Gas extraction by inclined boreholes on the
In side of the roadway
excavation Gas extraction by side hole drilling combined
with advance drilling
After Caving zone drilling, buried pipe
mining Gas extraction in semi-closed goaf extraction,pump station extraction
Gas extraction in fully enclosed goaf Underground drilling, surface drilling,
Goaf intubation extraction

Fig. 7  “Spatial–temporal coupling and stereo optimization.” gas extraction system

time, it is of great significance to promote coal mine safety, Gas concentration


low carbon production and improve coal mine production <1%
benefit to carry on the three-dimensional extraction. 1%-9%
9%-30%
Utilization of gas extraction 7% 1% 30%-80%
10% >80%
The gas extracted underground is medium- and high-con-
centration gas with a concentration of 30% ~ 80%. The rea- 6%
sonable technical application of different concentrations of
gas can not only improve the utilization rate, but also ensure
the safe use of gas. In general, gas with a concentration of
30% ~ 40% can be directly used as civil fuel. Gas with a 76%
concentration of 30% ~ 56% can be used for power genera-
tion, and > 40% can be used for industrial fuels and chemical
raw materials. Fig. 8  Distribution map of methane emission concentration in coal
mine
Utilization technology of dirty air
fuel for gas turbines, internal combustion engines, and coal-
According to the data provided by coal mine methane emis- fired power stations. Dirty air serves in the role of oxygen
sion control and utilization technology enterprises in 2010 in combustion system combined with the main fuel to pro-
(Wang 2013; Zhou et al. 2018), although the concentration duce energy. In the main utilization of technologies, thermal
of methane in China’s coal mine exhaust is extremely low countercurrent oxidation technology and thermal counter-
(< 1%), its total amount is extremely large, which is the main current catalytic oxidation technology are mainly used to
source of methane emissions from coal mines. The distri- increase the concentration of dirty air methane to about 1%.
bution diagram of methane emission concentration in coal Then the treated dirty air methane is used as the main fuel
mines in 2010 is shown in Fig. 8, and it is of great signifi- to generate heat, which is often used in heat flow reversal
cance to study how to utilize dirty air methane. reactors, catalytic flow reversal reactors, regenerative gas
There are three kinds of auxiliary utilization technologies, turbines, dilute combustion catalytic turbines, and catalytic
main utilization technologies and other technologies for the monolithic reactors. Among the other technologies, energy
ultra-low concentration of dirty air methane. In the auxiliary development corporation (ELD) has developed a regenera-
use technology, dirty air methane is used as an auxiliary tive gas turbine that can burn a mixture of methane gas as

13
Environmental Earth Sciences (2020) 79:461 Page 13 of 15  461

low as 1.6 percent. And Ingersoll Rand Company of the for the adoption of carbon emission control measures. Tak-
United States has developed a micro-turbine with catalytic ing the largest carbon emission source (direct emission of
combustion capacity, which can generate electricity from 1% methane) in the process of coal mining as the purpose of
of spent wind methane (Singh et al. 2015). In Moonidih coal carbon emission control, we can adopt more targeted tech-
mine in India, the dirty air methane is sent to rotary kiln for nologies to make the implementation of carbon emission
combustion, and the generated hot gas is fed to waste heat measures more efficient. Finally, the application of technol-
recovery boiler, which then generates steam for steam tur- ogy makes it possible to solve the core problem, which is
bine generator to generate electricity (Singh et al. 2016). In also the ultimate goal of this paper. The research results of
addition, as the latest technologies such as ultra-low concen- this paper are as follows:
tration methane power station boiler mixed firing and low-
concentration psa technique, dirty air methane has a great 1. China is the country with the highest carbon emissions
application prospect, which needs to be further developed. in the world, and the use of coal and its derivatives con-
Coal mine has long been the engine of China’s economic tributes more than 80% of total CO2 emissions. Although
and industrial development, but it also has long been criti- the proportion of China’s coal consumption has con-
cized for its environmental problems it caused. The technol- tinued to decline, the amount of coal consumption has
ogies mentioned above can capture and utilize the methane rebounded since 2017. Given the power demand, eco-
released in different forms in coal mining. Direct emission of nomic growth and other factors, coal consumption is
methane is the main component of carbon emission in coal likely to grow further, so China will continue to face
mining. Therefore, the resource utilization of this part of environmental pressure from the coal industry, which is
methane is the key to reduce carbon emission in coal mining crucial for energy conservation and emission reduction.
process. Meanwhile, the methane produced can also be used 2. As an important tool for environmental impact inves-
as a clean energy to replace coal. The application of these tigation and evaluation, this study takes the coal min-
technologies can achieve efficient carbon emission control ing process as the research object and analyzes the life
without affecting China’s energy supply. Most importantly, cycle carbon emission sources of China’s underground
it can also ensure that coal mining enterprises can obtain coal mining by using LCA. Then the greenhouse gas
certain economic benefits, which enables coal mining enter- emissions of the whole life cycle of coal production are
prises to actively and efficiently respond to emission reduc- quantified, and the results are evaluated and explained.
tion policies and carry out development transformation, According to the analysis, the carbon emission per ton
instead of passively and reluctantly implementing policies. of coal mined is 164.403 kg of carbon dioxide equivalent
The development of methane exploitation and utilization per ton, and the emission’s contribution rate of coal-
technology in coal mines undoubtedly plays a positive role bed methane can reach 62.21%. As a greenhouse gas,
in China’s carbon emission control and energy structure methane itself is a clean energy source. Therefore, to
optimization, and it also plays a significant exemplary for effectively reduce the carbon emissions of coal mining,
the green transformation of other industries in China. it is suggested to focus on the resource utilization of coal
mine methane.
3. Based on the technical level, in view of the character-
Conclusion istics of deep mining, low permeability and high gas
in China’s coal mines, and from the aspects of CBM
Coal is historically China’s main energy source and will be development, gas drainage and utilization of dirty air
so for years to come. Based on this, the paper first describes methane, the ideas of stimulation techniques of CBM
the key position of coal industry in China’s implementa- Wells, "spatial–temporal coupling and stereo optimiza-
tion of emission reduction and then discusses the two parts tion" gas extraction system and utilization technology
of determining carbon emission sources and how to con- of dirty air were put forward. A system of systematic,
trol carbon emissions. Taking coal mining as the research clean, and efficient exploitation of methane in coal mine
object, the greenhouse gas emission in underground mining has been formed, which makes the exploitation of meth-
in China is calculated by life cycle assessment method, and ane complement and promote the normal production of
the direct emission of methane is determined as the main coal mine.
source of carbon emission in coal mining. Aiming at this
problem, this paper puts forward some measures for methane
emission reduction and resource utilization, and constructs a Acknowledgements  Financially supported by the State Key Research
Development Program of China (Grant No. 2018YFC0808101),
coal mine carbon emission control system from the technical National Natural Science Foundation of China (Grant No. 51774292,
level. The calculation of carbon emission sources provides a 51874314, 51604278, 51804312), the Research Fund of State and
reliable reference and a core problem to be solved urgently Local Joint Engineering Laboratory for Gas Drainage & Ground

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