Engineering Admission Program Concept Book C-02

Ill�� "1'til! Ill<!$� ��9!.f, � � q(1'lllj_'1<il "'� 15IT1R!T Concept Book� IS'j_ Type �
'ffi!'fl "!Pl I� Text �� � "'li110>j(.<I � � ffl>"°f � I

• -rtfm "l!ln'l:
'Ill� 'fif mt C�i1>1 lj_�M> Ill� � Cilc'I � 15111'4'¼115 Olli1C<I>t9Pj_(li � frmr ell '>lllf!il "3RI TI'! � '3TC<I'
-rlfm '>llilfil WI' I

� \olTllill ell -rlfm '>llllfil C'NC\o � '31 WIT, "'Ri'Jf-i<l' -rlfm '>llllfil I <Jllt;! 'lj_i1 "lfi'I W,I CiiC"lifo'ICll''ii -rlfm '>llllfil I
-rtfm'>llilf� �I (i) � -rtfm '<l (ii) 151i�IC'iiif6 �'I I
[� �/ �c'i'l'C<I' A '<l Bt'IG!lfi!CG\5T'l<l'il!Wf'<l� 1 � 18 9IIRl>J�'>/JT� �TI1�1)

• � a!lfct� �� FMJ1t>111 !emtG)

�C"l<ll]l\l� R'1JIC>l'ii t'lil � � � -rtfm '>llllfil'ii (Long form periodic table) �� � lC<I' 15!'1 <l'l!I
� I c>r�OO wrr S, p, d <Jlqz f� I
• s- ff c>ltor:
�.q �C"l<ll]'i!G s \!il'il!4ll1C"I � "<ill:l! 1 �'I l(IA) '<l 2(11A) <Jlq� He s-�� 1 clili1>!t"(Jl 14 Ii; 1

• p-ff c>ltor:
�1q�<ll]�'6 p 151<!114'f;ICi1 �<l'Clll �'I 13(111A) � 18(Zero Group) (He� ffi p��I
Ill m'I �. 151� <Jlqt 'Ill'!� QffC<li1 OO"I >rt-.rJT 30 lt1 \Ol::11 F/(114), Lv(116) � OWi >r�� � 32 lt1
�. s '<l p � C�"l>ilj_�C<il representative OWi q1��OWi<ICi11

♦ d- � c>ltor:
�Jq �C"l<ll]'if6 a \51<!114'f;l(,"I �<l'Cll I � 3(UIB) � �'I 12(UB) 9llRI Ill�� I <.'<lifii�I• fh (90) '<l
C-<J>i'll'iif.if>i9111 Cn (112) � OWi >rt-.rJI 41fi; I

• f- � c>ltor:
�1q �C"l'll'LHIG f 151'ii!4lliC"l "IC<l"t � 1 Ill� block lll"ll' � (lllB) <Jl"ll' � 1 -rtfm-6 lll"ll' La (57) "1IC<I' Lu (71)
9llRI 15 fi;�,ur�wr, ffl-7 lll"ll' Ac (89) � Lr (103) 9llRI 15
Ii; OO"i'l.<J> 151Jl<ilf6'i� � <ICi11 � La (57), Ac (89), Th (90) OWi � d� � 1 1l'Ci'[ f-block OWi
>!�'>/JI 27 jt I
�� block lll'ii �'ll'ITT!'I e- ��'RT�:
s- � 00'1: ns 12
• <Jl-.fll'l, n = >1�4�!l orbit <Jl"ll' Principle Quantum Number
p- ii<!' 00'1: ns np,..
2
n -1 = >t«� orbit lll"ll''llllt'lll' orbit <Jl"ll' Principle Quantum Number
d- ii<!' 00'1: (n- I) d'-10 ns ·2 1

f- � clll""I: (n-2Jr-" (n-1)d0 nsz

Engineering Admission Program Concept Book C-02

• 1514!/J<iil �."!tor: elf >Fl 0000! �� GlmC'lll' e- R'IJPI (n -1 )d' ... 1

• Gl'SJ<ill•r Gl4!1J<i4 """: elf >1<1 cs'm-1,si �� � e- R'IJPI (n -2)r-13 1
♦ -rtfrn S\l ill'lf.\!S �o1tta,ir � f.i'fll:
• � � f.i<fll:
S· � OOif�t'i'fij' � .!l''f'J\Z-.rJI = �� •tRli<wiiil �ca,ajjc� >IZ-.rJI ['!Fl.!!"! A)
p- ii<!' �t"ITil' � .!l'9f'J\�-.rJI = �:� •rRl-<tCilli Clli& �ca,ajj� 'lt-.rJI (ns <!l<!Z np <!Iii e- <!I'll C41'1•1"1)
['l'Fl.!l'9f Al [t"lll<f<i'i'f � WI '311_'!1 .!l'C'fil c:s'it-r)
d- ii<!' �t"ITil' � .!l'9f 'J\�-.rJI = (n-1) d+ns t9f<tCilil Ofi& �C'1<15Jit.'lil >IZ-.rJI [t"lll'fll'o! 8, 9, 10 WI Group VIII
<!l<!t 11, 12 WI Group 18 '8 Group II B � ['l'Fl.!l'9f BJ
f. � OOil�t"ITil' C'IR:ilf .!Ji'!'J\Z-.rJI = Ill B

• � • f.i<fll: � 'J\#'tl<I' �lfR c'l'1�1-ll111 -s,z-.m (n) '3lil �,� f.lC�'I' 1

• � .!Fl:9fil '11'1Til'1 'flf:

Siiliil
• 'll'ITil'I e- R'IJPI: ns' <!l!'filC<I' "Flil � <ft-! 1
• � """: Li, Na, K, Rb, Cs, Fr
• <!!ill 'J\11ffi1''1'3 � CW! 'IF-'( <ml I

• �>flf:
(i) <lltcrn ci!t'l "lll!T � ffl-1 � 9fTt1I I 'J\ll!t: LiC/, NaCl, KN03, Na,so•• Na3PO,. Na,co,
ffl-1: Na,CrO, ➔ <l'"l!iil, K2Cr207 ➔ <l'"l!iil, KMnO, ➔ �
(ii) <!!ill C9lfi'l1il Em<i' �qhi I
(iii) �Ii!ftfi161: � � � <ft-! <!l!'filC<I' � mil ffl 11m I
(iv) 911illli'lf.14' �: <!I� .!l'C'f t'fli � � � � 9frn I
(v) �: 9ffiflll'ffi'J\Z-.rJI �'J\ICQf 'J\ICQf � � 9fll! I [<IJR'5Ji.ll PNa(=0.97)>P, (=0.86))[9/ml] �. Li,
Na <!l<!t K "ITf.iil C5rn � <!I<!� ffitl3 i5rc>I I
(vi) 'l"r-lit� '8 ��: 9ffiflll'ffl 'J\t-.rJI � � 'J\lCQf � 9frn I

� <!<'I
Na ��
K Cq'��
Ca �1!\3i'llif
Sr � i'l1if ('J.lflC?Bil -!Jlll�)
Ba � <511t9fCii'il 1113 � 'J\¥l / � 'J\¥i
Rb � Cq'��
Cs �
Li ��. �<!l�<!<'f
Engineering Admission Program Concept Book C-02

113. [Fe(CN)6 ] 3- 91JlilTlm� �'6 [Fe(CN) 6] 4- 15rnTllJT� C<I"!?

114. izj�tl\ilCiilU.'iil 15@:j\<l'lM � 13.6 eV/atom� 25mg �tl\ill!St'i "llrl!f'J. C"IC<I' H+ l5l1ll'i \'!,�9fl! 'Rtl3 <lit �'1
"Im�?
115. Na lllil' ,,119:j\<1>il'1 � 111'1 5.1403eV/atom� 0.75 mole Na <.'I' Na+ l5l1llC'i '®'113 � <1'15 kJ "Im
�?
116. � � � He ?fiflll'.(t<I' He + l5l1llC'i '®'113 � 3.9387x 10- 1• J "Im � lll<!Z Li + �
15jjfi:j\<j>ij•f � 7298kJmoIe-' � Li + � 15119:j\<i>il•t � He lllil 15/jfl:j\<l'ilC•tl! � � �'1?
117. Ni(C0)4 C'!l•fltil'IF-1 <!4-lr <l'il' lll<!t lllil m'ff � �9f \31� TI'1
118. 'Iliilf�'I'[� 15/'ll�l5'1'[� s::(C� �•1<1'15iPI •C<ll� C<I"!?
119. Zn, Fe, Co, Ni, Cu, Cr lllil' � �9l.4151i<l'MC<l'il "IT"f '6 '>lt'C<i>l5� TI" 1
120. S8 151'J.il' 'IF-'(�<!'l.l! l.'l"i >rfi'f<l'f� 151f�C<!t'i ,;JC�� '>!m '31�TI' I
121. lll<I' � � 151Ni'lll} q'f '{llffi � lllf>rosil '>IZ""fC"f 15/Al � I lllil'9fil lllil >i!CQf � HCI lllil � WlC'il
� I <lit\'!,�9fl!�?
122. Na,so. C'!I� � <1>15 lfil'C'lil lll<!t � <!'<i'i �? �'llll5/JIN'1 � (Ill) C$Piil� dm<fil �'<3151'J.lfi"f

=
�<l'il'I
123. CH2 = CH - C CH C'!lt<lf>l<flll '6 �<m'iil''>IZ>JJI lll<!Z ��!ii'lil'>lt<l'il''f�TI"1

Practice Problem (MCQ)

124. Srm �f<is<l4 C'f!I?
(a)�� (b)� (c)��
125. � � <ora<Jllrn?
(a) Li,CO, (b) Na,co, (c) Rb,CO, (d) K,co,
""
126. "16!filmll r.<l'l<!ifit """',_
'1M:f.il�Cilil >r�� '6 <14 f<is?
(a) K.ICO (N02)6I; >iT'il (b) K3ICO (N03)6 I; <!� (c) K,ICO (N03),J; � (d) K3ICO(N02)6J; �
127. �� 9fji'!,(51Cilil '11'� � � �?
(a) Ca(OCl)Cl (b) NaOCI (c) Ca(OCI) (d) Ca (OCl>,+CaCI,
128. RCo,l r.<1>1-1 f4Jili.«ifl �tl\ill!St'i "'ffil � � � -U?
(a) Na20+H20➔ (b) Na202 +H20➔ (c) K02+H20➔ (d) H,0+02 ➔
129. Ba m
�f<is<l<'f C'f!I?
(a) �ii'fi! (b )��
( c) <IIWI 15/TC"fCii'l! '11\3 � '>!¥! (d) 15Ri<II� � "1JTll � <1.f
130. C'ffill'iil •fRPlr-il C'!l'I C<i>Aft?
(a) � � (b) <.<!RR '1M:J.i� (d) f>lf.r<A �
131. � 1519flfJW?
(a) C (b) Pb (c) Ge (d) Sn
132. � C'IM � 'it'fl'i:i<I'?
(a) C (b) Si (c) Sn (d) Pb
133.��"f\ol�?
(a) C (b) Si (c) Sn (d) Pb
134. Si lllil<l'<'f� -
(a) Al (b) Be (c) B (d) C
135. RCo,l � ·Wlr-il �?
Engineering Admission Program Concept Book C-02

(a) LiAJH, (b) NaAl02 (c) NaBHg (d) AJ,03

136. Pb,O,cl Pb cl�� <l'W?
(a) 4 (b) 3 (c) 2,3 (d) 2,4
137. !>lfo'tr.4'1'1 '<"I-
(a) Si (b)9flil"ll!l! (c)�t (d) b+c
138. Pllllfi1<11 c1� 'l'i�lllii1-
(a)� (b) �911il (c)'q'fiJ_ (d)��"Ci11
139. istlt'1f.@Cllll �;jt., ;i!ffil'f � �
(a) +3 (b) +2 (c) +4 (d) + 1
140. '1�c\ilC<ltl'lll C<l'R � � �<lfil?
(a) NO (b) N02 (c) N203 (d) N205
141. �,'1I<l'>i<l'lll>i clffi(H,PO,)�
(a) l!C'1IC4Pl<II (b) i!i�4Pl<II (c) Ji�4f>t<11 (d) �
142. �;il <l'>t<l'fii'I' clml! � >r�"l'l"5 �-
(a) H,PO, (b) H,Po. (c) H.P,05 (d) H.P,07
143. f.rn!lr �"1� MC-Oli!ltl'l N, '1Nl"!l11i'm?
(a) Pb (NO,>, (b) AgNO, (c) NH.NO, (d) NH.NO,
144. �151)1'1�� f'icR �?
(a) N203 (b) N2 05 (c) N02 (d) HN03
145. �cl�� "<ltTll'I' '6 Ristlil'I' � � <l'Cll?
(a) H,so. (b) so, (c) H,S (d) HNO,
146. P, Gi"'.!C'5 � C<fil'f 60 �"!lllf ................... P, Gi"'.ll'5 ..................... .
°

=1 ,41-1
(a) � C'lf-1, f�.!ftii'-'I ,41-1 (b) � <l'11, a�.e��,lft=.,"
(c) � WI, �.!fti1'-'I <ell (d) � �. �.!ftii'-'I <ell
..,,.,..-.
147. C� �111 '1�c\ilC>tl ,'<'l!PI >ili1C>iC ,�
(a) [Fe (NO) (0H)5 [SO, (b) [Fe (N02)(H20)s[SO,
(c) [Fe (NO) (H20)s[SO, (d) IFe(N0),(H20)5 ) SO,
148. <l'>t<l'fli<ll lllffi (H,PO,) �-
(a) cl'I' "ll'Jll$1-0 (b) N-'♦lll�-0
149. �T.S.P?
(a) Ca (H2PO,>,. 4H20 (b) 3Ca (H2PO.J, (c) Ca(H2PO,) (d) (NH,)2HPO•
150. C'l'Mfilr;G Glf�Cistl'lll <lifl!'I >J�-.fJI 4Jfi6J).l! (-1)?
(a) >rl'I� (b) 911il� (c) �� (d)>J_911il�
151. ��clf>li&GIJl'l��lli?
(a) SO, (b) N205 (c) NO, (d) N2 0
152. Cll'1fiRcl'l'!il 1!Tilf �'1 � (-1) Clf"-.rll! 'l'lil'l-
(a) � � 41'1I\:il'l'l!il (b) 'ffl'f,1' T§f-!J' d -151llflroili1ll ""'l.•
(c) � >tlll<il� 'IJT>tlll (d) C'l'A!t-l om
153. f.ico-,:i :i.JICiilC<lt'1�fo,l! "llt'IJ � �Ci1�'1 "'lf>!Rli �?
(a) I �,.,,.,.= (b) CJ (c) F (d) Br
..,.,.,,.,,,,.,.,,
154. f.ico-,:i :i.JICiilC<lt'1�fo,jj "llt'IJ � ,t"J6 Glle-Ollli�i!i '1'1'1i!ltC<II :j\., "<lllll?
(a) F2 (b) CJ, (c) Br, (d) 12
155. f.ico,l C'l'R Cl!lt<l-,:i GlHIICi!ltC'1ll �iRl'I �+2?
Engineering Admission Program Concept Book C-02

(a) Na202 (b) OF, (c)CI,O (d)Na20

156. f.lffil � � 1519RI � ajiCi11Ciili'lt4 \3lC'RI di!'!� �9(\0 <ml?
(a) F (b) CI (c)Br (d)I
157. F- F � "1ffi 11A CI- CI� "1fui 151C'f'!ff <11"11 C<l'-l?
(a)� 91lfl!l'.I� � <Jl<IZ�� F �'.('aCl!l! 1TCl!If.t>t'! �Ci1qlij'l � 1TCl!I�'f <j"ij czjvr
(b)Clf'ffl 91lrll!'J.il crnl �lfiic.'1il �Ci1qlij'l � czjvr
(c)�Ifiic.'1ll' '>(a,.mr Cll'M-l '51°flf<I' �� 'ii�
(d)�� -rn
158. 1511�1C'ill' 'lft'il m
151.,.
IC-mm
ffli�L'1=
il "im�f.lffil C<ll"R Cill<flt� 9f!Cll?
(a) C4!iir.4fii (b)firc;w (c)l!IG4'1'11 (d)�
159. :i.JIC'11/.'St'1 �CllilPll5<1fo'!il 1TCl!I � <llffi � -
(a) HF (b) HCI (c)HBr (d)HI
-.,.,..,.,,
160. �Ifiic.'1il � <Jlffi<lfo'!il � t� 1511.'IIC'ii � �
(a) HCIO < HCIO,< HCI03 (b)HCIO•< HCI03 < HCIO, < HCIO
(c)HCIO,< HCIO,< HCIO, < HCI03< HCIO (d)HCl03 < HCIO < HCIO,< HCI02
161. CIO,- � CI 91lrllf'l C4'1'PIZ<Rffi?
(a) sp' (b)sp' (c) sp (d)C4'l'l� '!lf
162. f.lffil l5ICW <Jl�tii'lil 1TC'!f � � 'at"Rl4'?
(a) HCIO (b) HCI02 (c)HCI03 (d)HCIO•
163. Rfui;ll '1Jlt>lil �: =?
(a)1.33 (b)1.75 (c)1.42 (d)1.66
164. XeOF4 <Jlll' �9f? <w-l
(a) "'lili1� (b)�1?1�9 (c)6�<!1'1�� (d)<1�-11 Mlllfil��
165. � Ra 151C'f'!ff C4M CGiilifui.�?
(a) Xe (b) Rn (c)He (d)F
166. �'1��9��?
(a) Xe04 (b) Xe03F (c)XeO,F, (d)XeF4
167. XeF, <JI� tfll'c.'1lPlt<l'il'1 C'i-.ffll'lll?
(a)sp' (b)sp'd' (c)sp (d)sp2d3
168. Rfui;ll '1JTC>ll! � dilt<fil >rlt!lil'f ">IZ"r.4"5 �?
(a) He.nBF, (b) Kr.nBF, (c) Ar.nBF, (d) Xe.nBF,
169. �'fTCilil � � Rfui;ll 'UTC'lil dilt<fil Rfui;ll 'fJT>I "{J 9fif.lil 1511.91113 �?
(a) 1:1 (b)1:6 (c)1:1.5
170. Ne ���di!'! <w-l <ITT "1?
(a) Ar, Kr, Xe �"'1ffl (b)Ne <Jlil� ff�
(c)� �u Rl'llli "'ll'l"''lmmf.1
r.i ""<11 ,<71,r-rn (d)�-rn
171. 151f<t-i ll'Jl'<iCillGll' ">IZ"r.4"5-
(a) Ar (C.H..02), (b) Ar,CC.H.02)
---e,,.,..,,,..
172. � 15119�<11l!'I •1Rl-'1"'1J1 Noble gas�
(a) He (b) Ar (c)Xe (d)Kr
173. XeF 2 CG� ">lt<l'il'f � �
(a)sp (b)sp' (c) sp3d
174. � � 9fffil'1 � C4rl?
Engineering Admission Program Concept Book C-02

(a) He (b) Ne (c) Ar (d) Kr

"""'""
175. f.iml �ft •ll$1"5Ci1 '11'6"!11�"!1?
""'
(a) He (b) Rn (c) Ar (d) Xe
176. �">!mRfui;;l<uPr�?
(a) Xe (b) Rn (c) He (d) Kr
177. (<l'ii'f>I "ll">l'I Eq��-
(a) 1-0�U\i"A "ffili> C<l'i11C>lil � "1fu; (b) C'l'i11C>lil � "ffili> iift:tlli•A "IRl>
(c) C'l'i11C>lil "1)$:>r "ffili = 1-0�U\i"Fl "ffili (d) 1-0�U\i-A � 11A "['!I
178. �'<l'll���">l"lf!!"ll�
(a) � C"mi'f '<l �" '11W (b) � �'1 '<l C"mi'l 'IIW
(c) C'l'4i1111ili � C"ml'l 'IIW (d) C'1'4i111fill -� �'1 'IIW
179. C<l'T'I � C<l'i1l'Pftl�<i\?
(a) K2S,Naf =- (b) K2S,MgO (c) MgCI 2,CaCii (d) NaF,MgO
180. f.<l>T'l151�� >111�9 'J.<fll M\l>IS!l'l'iil?
(a) BeCI,
(b) BCI 3 (c) CH, (d) NH,
181. � �<f � ��"!I?
(a) BF3 (b) BeCI, (c) AICI, (d) NCI,
182. � S iO, <Jlil l:f1f -rn?
(a) Z<t\3Jl'l'iil '<II'.( (b) <fil"!f�<l'<fl! (c) ��<II C4"fit (d)ffl91'il4
183. 151� >iTIIJ � f.w � "lfu; '<l � "lfu;.
(a)"ll��'<l�(b)"ll��'<l� (c)">fl!A
184. Ag (NH3)2CI 151'.(t"5 <li"!I ���?
w1 (�2 �3 �)4
185. CO,- <Jlil >rt�'f C<l'T'f �?
(a) sp (b) sp' (c) sp' (d) sp'd
186. (HF) ,. C'm<I �� f.it<t)lli'l?
(a)�. >IIICW� (b) =>111= .a
c�-1�,, iift:tllilC'et'l (c) iift:tllilC'et'l, 15119H<II (d)�. >m1W1
187. C<l'T'I � fflT >rt� 151ilf.itilli1>1lj_ll. ��"!I?
(a) " (b) cr (c) � (d) C<IIA1t-l-rn
188. .!li<jil�c:Gil @�!'1Tl! "l!Jtq/ C<l'T'l ��?
(a) >IIIC�ii!lll (b) >m1W1 (c)� (d) "'Mi!ilil '<lmar>iqif
2
189. � sp >r�<llfii\3151ilf.itilli1� ,'11'1?
(a) CH. (b) � (c) � (d) CO2
190. f.lcmr C'l'A � >lll�C"l<ll]�9 ��?
(a) He'•,i-r (b) Na.,K. (c) F,F (d) i-r, 02•
191. <1iW, <Ill!���?
w1 (�2 �3 �)4
192. AICI, >IIIC�iill <i>lil'f-
(a) <llllilM'lil �� (b) 151Jl'l19C'lil �� (c) <111/flrnt'!il <>ll<lllil� (d) �9frn! >14 �
193. <ll<llft �<f 3 ft �-1 �Ci1<1\ii'l � '<l 1 ft HI� �Ci1<1\ii'l ,'€!� Qff<ll(.i113"fil � �-
(a) �1;!<M$\9 (b) �\3"1$19 (c) Millfsi�9 (d) �� �Millfsi�9
.,,""" =i<lm
194. f.ttilr � '1Jiillk�$\9?
Engineering Admission Program Concept Book C-02

(a) 02- (b) H2O (c) CW (d) NH3

,..r,1,,...,.,. 3
195. H,C = CH - CH,- C = C - CH, ditt<f C<l'l-1 <111�'1>t>!_ll_sp ">lt�<l'Wl �<!iii?
(a) 1 lll<ft 5 (b) 1 lll<ft 3 (c) 3 lll<ft 6 (d) 1 lll<ft 4
196. � �?
(a) C - C <flfi'I� > C = C <flfi'I� (b) C = C <flfi'I� > C4'1!%ir.'1 C = C <flfi'I�
(c) C = C <flfi'I� < C = C <flfi'I� (d) C4'1f@iC'1 C = C <flfi'I� > C - C ��
197. NH, "<l H,0 � � �l\\ilCiilt'l4'<i"I 'IF-I <liil"5 "'f!Cll?
(a) 5 fi; "<l 4 fi; (b) 4 fi; "<l 4 fi; (c) 1 fi; "<l 2 fi; (d) 2 fi; "<l 2 fi;
198. F!C"!!l! � ditt<I sp3 ">1t<liil<f �?
(a) H20 (b) BeCl2 (c) fiPlmi'1 (d) BCI,
199. F!lil! � C9f1i!Tl! mms � :!i<ll!rn?
(a) AICI, (b) CH. (c) CCI, (d) KCI
200. � Rf.iRT '{; >t11c�,� f.lPl-mil ,1fi5..--
(aJ 11�&'\0'8 "ll""� (b) lf�"ll""� "<l&'\O (c) >fl!R (d) �W\O
201. ZnS0,.7H20 ditt<f <II"!! tfll'C'1l! � M�Jlli'l?
001 (�2 �3 �)4
202. >rr.fl<f"f<flfiil ���� �?
(a) �<liU'lc.""rnll! (b) �<liU'l'11'1 (c) <5lfll'I � (d) r.41'!�-T!I
203. >tllC�I� ,ql<t<ll">R��-rlS<l'll!?
(a) �e_ 'il<fl\:ij4\!ilil >IA C4r'l � (b) "'�"- '11•iil:ij4\!ilil "'11� C4r'l �
(c) C'1ii1Ifii"' � (d) C4Aft-�-rn
204. � ,•ui1iillfi'1 -ll'"ll'\!iT 15IT>f<li?
(a) Lt (b) Na• (c) Mg'• (d) Al,.
205. RCo,l C4'T'1 Ciilt1tl;> >tIIWI� q� �?
(a) Ca, Br (b) Na, Br (c) N, Br (d) Sr, 0
206. N2151'.(t'3�� M�Jlli'l?
(a) 3 (b) 2 (c) 1 (d) "J.'li
207. N2 03 ditt<f�<flfi'!�?
(a) 2 (b) 4 (c) 6 (d) 8
208. ��t<f'C4r'l?
(a) He (b) Ne (c) Ar (d) H20
209. AgCPl!lff�AgBr��?
(a) �<liU-1 � (b) MM-fill!��
(c) Br-lllil C'1ii1Illi�'1 � Cr151C"f'1'1 C4f'iI (d) CI-lll'1 ,'1ii1Illlfi'1 � Br- �"1'1'1 C4f'iI
210. 1co (NH,),CIICI, ClITt'lil�� M�Jlll'l?
(a) 15 (b) 18 (c) 21 (d) 23
211. ?fT'I "11lol 9f1RC\!i \5TC>r �?
(a) ill>tifiM4 Rf.iRT <mr <fWf �•r.pra (b) ��l\\ilC<!t'l'l'<i"l 'IF-I <l'til
(c) ��l\\ilCiilt'l�e_"fl'M <l'Cl! (d) "'1fM 151C"f'1'1 �
212. �'1i'Rlt<f'�?
(a) CaF2 (b) CaCI, (c) CaBr2 (d) Cal,
213. � 00'1lPfl!lfi"f\!il��<ff<rs?
Engineering Admission Program Concept Book C-02

(a)� ffi � (b) '511ml �Cii<II]�� <Prart'lll (c)�� «'111\l<lll!ii (d) IS•tClllPl�Oi-tl
214. (<l'f'I c:,nc'll!� �Cii<ll�<II �il11l'I�?
(a)� dil'I (b) >!IIC�i.s!l dil'1 (c) >!IIC�i.s!l � di),r (d) r.41'!� -m
215. f.!co,j r.4fil ���'IF-{ ">!"11¢.l <l'Cl!-U?
(a) �"111511�H<llli'l "1fui "<ll"l! (b)Gi����
(c) �Cii<ll]'I �'1 q'f \!iJlC'1l! il1;jjrsrll"'l4""qil!i'-"I (d) c:,nc'lil�i'f)$-t"!Rl>
216. r.4T'!it >!IIC�i.s!l °l4fill:°�JiPl�<I' �?
(a) AIC1 3<MgC1 2<NaCI (b) AICI,> MgCI,>NaCI (c) NaCl> MgCI, <AIC13 (d) b '8 c �
21 7. f.!co,j r.4T'!ltil � �?
(a) Na (b) Mg (c) Al
218. r.4T'!it��ffl H ��'1'111?
(a) HF (b) <111.ff�f.i<II <JlP{I.; (c) 0-nitro phenol
219. f.!co,j r.4T'!it sp3d �f?li5�C'et•f'l?
(a) IF, (b) PC!, (c) SF• (d) LF,
220. NF3 <Jlil � C<ll1'1 <l'l!i?
(a) 103.2 ° (b) 102.5° (c) 107.3° (d) 105.6°
221. r.4T'!itNl!iJl<llill151'.( 'I'll?
(a) qlfll' (b) � (c) � (d) r.41'!� -m
222. (<l'f'l l!il� 911ffl 151Tt"!m 0� � W
(a) o•c (b) 4°C (c) o - 4°C (d) �
223. z lh-.,asr.:r
(<l'f'I � 'Rfl!f'["l'I Clll'etJl!il<!IC'ii ns nps �Cii<ll]'I R'!JT>I Qff<lll:i'f <a � � • ">!lilf'fCl!i C<lllC'II m"f �?
(a) 15 (SA) (b) 5 (SB) (c) 17(7A) (d) 2 (2A)
224. f.!co,j r.4fil 15l11!C'!il l5l1<ll1il >r4Cm1 � �?
2
(a) F" (b) 0 • (c) N,.. (d) Na•
225. • ">!lilfclil (<l'f'I m'fil diliiooo � �?
(a) �-1 (b) .!1'91-2 (c) .!1'91-17 (d) .!1'91-16
226. (<l'f'l 151ill'4Cii1'6 <1'">1'!'8 � (rr) � � 151�"'1 C'!l! -U?
(a) s 151lll4iliii (b) p-Gil!Miliii (c) d-151lll4iliii
227. POCI3 •i�'l'l'ICii � 9flrll1<J.il C<l'A � >JZ<l'il'f W?

�iti• �
00� 00� Ws� (d) sp3d
228.� C<ill'$?
(a) Na.<K•<cs•<Rb• (b) F"<Br<Cr<r (c) Fe'•<Fe'•<Fe,. (d) ca 2•<�<Cr<s'·
229. �Ci'l<ll]'I �">It� r.4fil � >ll!iJ 'I'll?
(a) � 'UK'!il �('1<11]1 151!>!1$li �'1 � 1.'!J �
(b) �1"11 �Ci'l<ll]'I �� 151C9f"J'l �
(c) )11 �Cii<ll]'I � 'il'fll:i'I' mJ
�°!l �Cii<ll]'I � l:Rl\\l"<I'
(d)151f1!C<ltC'lli )11 '8 {!l �Ci1<11]'1151i>!RJ.li Clll� l:Rl\\l"<I' �
230. f.!co,j �"1'115il��<llil'1 "lfui �?
(a) Na• (b) Ne (c) � ">!"llf'l (d) Wii"'lf>l�4 'I'll
231. C<ill'$151Jli1Tl!?
(a) NaAI02 (b) Na,SO,.AI, (S0,h.24H,O
(c) KCI.MgCI,.6H,O (d) FeSO,. (NH,), SO,. 6H,O
232.��
Engineering Admission Program Concept Book C-02

(a)�
233. Mg:,N,+6H20➔?
(a)Mg (NO,)+H, (b)MgO+NH, (c)Mg(NO,)+HNO, (d)3Mg(OH),+2NH,
234. �� NaOH+CJ,➔ ?
(a) Na0CI+H2 0 (b)HCI+Na20 (c) NaHCI03 +H20 (d)NaOCI+NaCI+H20
235.C<!'r-1oo-r�i-rr
>J.'fll! � 'IF-I <!'Cl!?
(a) K, Rb, C� (b)Ba, Ra, Cu (c) K, Na, Cs (d) K, Na, Li
236. (<l'f'I di!� 'IF-I�?
(a) sc,. (b)NCI, (c) NaCl, (d) SF.
237. <l'"l! \!\I� lf1f f.w1l :i,JIC'11C¾'1 �?
(a) F (b)CI (c) Br (d) I
238. RCii1 C4'A � � Fe (11) r.4 f.roi'-r <l'tl! -U?
2
(a) !Fe (NH 3),I'• (b) !Fe (C,0,hl3- (c) !Fe (CN)6 1'- (d) !Fe (NH2CH2CH2NH2)3 1 •
239. � � m'll!� di!��
(i) NaBr, BaF,, C�CI, KCI (ii) NaCl, HCI, ICI, BeF, (iii) NF,. BaF ,. F,O.H,S
���
(a) i (b) ii (c) ii, iii (d)i, ii
240. �� c1iCT ll'>tll'fii4' '-'lffi?
(a)HPO, (b)H,PO, (c)H,PO, (d) H.,P 207
241. :fll'<ltilil � ">fm� <l'"l! �'1\31 ">t""lll � � �-
(a) Argon (b)Helium (c) Xenon (d) Krypton
242. Ag(NH 3h ICI \!\l<J:tl3 'I'll� � �?
(a)1 (b)2 (c) 3 (d) 4
243. NH, \!\l<J:tl3 � C4'1'1109.5 C"IC4' 107 � � 911ll C<i><!?
° °

(a) Lone pair- Lone pair mer (b) Lone pair - Bond pair mer
(c) Bond pair - Bond pair (d)W<>1 <!ll�Miliii N 91ll"IT'F5 ��'!fl!
244. RC"!lil C4'Aiil '1Mi2���?
(a) 02- (b)NO• (c) N 2 (d)r.41'!� -T!I
245.� >tllC<ll��clrn ffl�?
(a) LiCI>NaCl>KCI> RbCI>c�c, (b)CsCI> RbCI> KCI>NaCl>LiCI
(c)��i-r! ">fl!l'I >tllC<II� (d)<llt'fl! >tIIC<ll<itJGI � 'lll
246. �� sp3d >rt�er?
(a) IF, (b) PCI, (c) SF• (d) LF,
247. C<!'r-1 dilt<I \!\l<J.11� �Cl\ill"1'1 <WI�?
(a)� 'li�CillC<l''1'1 (b)'fJlill '1�CiliCll''l'1 (d) HF
248. H,C=CH -C :CH dilc'I C4'A (<l'f'I >rt<llil'l M�J•1'1?
(a) sp, spz, sp' (b) sp, sp' (c) sp', sp (d) sp' spz
249. 9PfflPl1� -!l''l 1 (IA) <ll;f OOif � � � �� "lll'll°!l'Plllf � -
(i)�Ci1'11f.il'1� <ll� � � �
(ii)911ifll'l"lm' �tf � 911ll
(iii)� �Cii'llf.i'1 (ns') f.i\SB,�i>t �>1@1i'l'llmll' lll'l!-11 >t!Ji.�"'' �Ni 911ll
���
Engineering Admission Program Concept Book C-02

(a) i, ii (b) ii, iii (c) i, iii (d) i, ii, iii

250. NH,Cl s!lil 151'.(tl3 Cl! <1'6'i>IIJ.ll_ �
(i) � (ii) >t�C�ieil (iii)'>tfflC<l't
f.rcR��
(a) i, ii (b) ii, iii (c) i, iii (d) i, ii, iii
251. s!1<1$ � � �� >t�C�ieil '<'lf!!Tl! � -
(i) 'l'JfCJ-OC'iil "'1l'l'Tll � '<l <!l(MJ-OC'iil <5l'f<ll1il � �
(iiJ "'1rc1!.'lil ""l<l'lil � -e � m �
(iii) <!l(Jl'il-0!.'iil � � '<l � ffl Qff<ll'/;i'[
f.rcR��
(a) i, ii (b) ii, iii (c) i, iii (d) i, ii, iii
252. f.rcR (<l'l'I 151�00 -!'I c9f1iilil?
(i) CH2 F2 (ii) CO, (iii) CH3COCH3
f.rcR��
(a) i (b) ii (c) iii (d) i, iii
253. DNA s!iil i5l<li'f � � ffl<f­
(i) Electro static Attraction
(ii) Dipole dipole interaction
(iii) H-bond
f.rcR��
(a) ii (b) iii (c) i, ii (d) ii, iii
254. � '·1Ji>t>t'{C�il >tM-Ul!ilil .,R-
(i) Ar< Kr<Xe (ii) Kr< Ar< Ne (iii) Ar<Ne< Kr
f.rcR��
(a) i (b) ii (c) iii (d) None
255. � "''li\:l<ll'Oill � -
(i) F> Cl> 1> Br (ii) Cl<F<Br<1 (iii) I<Br< Cl< F
f.rcR��
(a) i (b) ii (c) iii (d) i,iii
f.rcR� Glit'IIW 256 -e 257'1��ffi�:
<!l(tl!ill '!!i!R, lil>tl«H'I' � � 1l'i-r 'fil'lll'l �"1 91fi14-,,"'1 -mr, 'fil'lll'lil 'l<f�>t � 'II 1
2Na + Cl2 -+ 2NaCI
256. �<t � 14!Ji.u'I' '(j t"-"lfC'iil � >t�>IITTI l!if-i91113 � C<l'T'ift?
1
(a) 2N.: NA: 2N. (b)2NA :NA (c) NA :,l NA:NA
257. t"-91!1 ditt<fil C<liill! C<l'T'ift �'Ill?
(a) "1fHtl!i:!i<lqhr (b) ffl
NaCl Fl'i"- � (c) 151'1-,,.,�9 ,'l'iil>t
f.rcR� Glit'IIW 258 -e 259'1��ffi�:
ill>tl-OH<II q� qJ'1'>/JT!f 151'1<11 �g (;q-,, '>j'�T,f<f W'f[ "ITlfllfffl '<$ 151ilf4'Cli1 � 1 P '8 Cl, s!lil Mf.ii.WJ J'C' 3 '<l
PCls � � 1 2P + 4Cl 2 -+ PCl 3 + PCl 5
A B C 0

258. C •t�'i'l'IC"l (<l'l'I � � �?

(a) 151'1<11 � (b) 151l1Milli1 � (c) <5ll�<I' 151ilf4'Cli1 � (d) 151ilf4'Cli1 '>t'�<f'il<f �
259. D s!lil '1�'1'1'1Ci1 Mrn! C'l'r-$ � �?
Engineering Admission Program Concept Book C-02

(a)�>F-PITT!'I (b) 41il >lllt.lli� 'll 11il��

f.irnl� Gill"IICqS .260 'll 261 'l��ffllit'6:
y z
24.3 35.5
260. XZ cili<$Wf[­
(i)lll<l$ '31� cwt (iii) 9f1f.lc\, :!f<ll!rn
f.irnl ""1'$.?
(a) i, ii (b)i, ii, iii (c) i, iii (d)ii, iii
261. (<l'A di)<$ �t!<li >lllt.lli� tnf C'i-.rro?
(a) xz (b)XZi (c) YZ (d)YZ,
262. <flfrn>mlfctll� ·�?
WA M� �� �)�
263. i'flf� � � dili'f ">IZ-.iJI <l"3?
(a)13 (b)14 (c)15 (d)16
264. ffl>mlfctll � ffl �?
(a)'fllrlll'!m' <Sil (b) Glf'lm' l5;i (c)�C'1<11°G'1 mJl>I (d) 'fllrlllffl ">lt-.rJI
265. � '31<1�1@ q!Wl! � om?
(a)lli>ll�f.i<I' HWm <mr 'II (b) � "llit'f ml'I <IIN (c)ffi cwt 'IF-I <l'tl! (d)� dil'I 'IF-I <IIN
266. 29 'fllrlll'lm' ">IZ-.iJI � dilOOf � C<l'T�?
(a)'ll:il ffl
12 � (b)'ll:il ffl
11 .!l''f ( c)84 ffl 12 .!l''f (d)8 4 ffl 11 .!l''f
267. ">l<lrnlf � 'll ">l<lrnlf <1'"11 � 'R1l1l<I' dili'f �?
(a)Ra, CI (b) fr, CI (c) fr, f (d) Ra, f
268. <Jl<l$ dilOOf ">lt"C<li'3 M lll<rt Ill� �Cii<il'G'1 mJl>I ls 2s 2p 3s � � �
2 2 6 2

(a) � �:ii 9flfrtll� (b) �"Fill� (c) \ol'Jl�M '1t"C<li'3 MO (d) �cllil'Jl�I& tv!OH
269.��?
(a)MnO, (b) KMnO, (c) K2Mn0, (d)Mn20
270. � �IA''fflrn?
(a) K20 (b) SrO (c)MgO (d)NiO
271.� ">l�.C�i'Sfffi �?
(a) Be (b) Ba (c) Ra (d) Mg
272.� ">l<lrnlf <1'"11 �?
(a) MgCI, (b) CaCI, (c)SrCI, (d)Pbl,
273. (<l')'! � �'lR<I' 'Ut>lt� $.I>!$!?
(a) Fe, Co (b) Na, Mg (c) Li, Be (d) Cl, F
27 4. Na, P, S, Cl dil-f�"C'i'll! 111t<11 � <rJP!I� ">!<lrnlJ �?
WP (�Na �s �)a
--
275. <Jl<l$ C1m'1'g �<il'G'1 R'1WI 1s 2s 2p 3s 3p 3d 4s ; � �'Ill � di!OOl 'fllrlll'!m' >r�-.m ""3?
2 2 6 2 2 6 2

w� (�" �� �)�
276.� >J'TiftAS �?
(a)He (b) 0 (c)C (d) Na
277. mil� dil-f�"C'i'll! � >l'tC>l)ll 'fllrlll'lm' >rt-.rJT �?
Engineering Admission Program Concept Book C-02

w11 (�ro ��
278. �<5lTIR�ffi � 9\llillfii�!I lf1f �<mr?
(a) K+ (b) Mg2+ (c) Ni2+ (d) Cu+
279. C<ll"R � � i,,�ffiJl!A?
Ws -- (� p �d (d) f
280. � {!I 1511!1�4-li<f � 111"{ � �?
(a) Na (b) K (c) Al (d) Mg
_ _,,. _ _,,,
281. C<ll"R � �!l 151i!l�<llil•1 �111"{ )"ll 1511!1�4-li•t ����?
(a) Mg (b) Na (c) Li (d) Rb
282. � �tf 2f'IR\3 f<lir>ril i,,"11 f.i�"lr-1?

283. 151<1ll'.l<lil �"C'i'I � 9\Jilllfi��!I?

(a)�'!> 'tr,,<liii-1 f<i'illli'1 (b) d-141 C1lli!
(c) f-lC<II� �f<ilfflf (d) <1ffi<1"6-1"1r-i � � <mr f<ilfflf
284. �., 9\Jilllfii�!I ,�?
(a) 4s'4p64d' (c) 4s'4p•4d'• (d) 4s24p 64d'
285. � � "f<il�?
(a) Caso, a,.,,f,.,,, (b) ZnSO, (c) K,SO, (d) Na,SO,
286. "lm-T'ff<i<ll 'IZ'IJI HC-i'-� � � p-� OOi!?
(a) 37, 38 (b) 47, 48 (c) 53, 54 (d) 67, 68
287. '1<1>'1151�6!1'-" 'IJ1t>Rl �Cii<liii-1 K-UT>I �?
(a) ns 2 np 3 (b) ns2 np4 (c) ns 2 np6 (d) ns 2np 5
288. Nd, Pm, Lu� "IIC'l "1Rif616?
(a) 151�etll6 ,'llil (b)151<11l)@ OOi! (C) m,[ � C1llif (d) 1J:t-"l'lil C1lli!
289. <fl1rn 'llil� � d- 141 C1lli! R'i)II1'1?
(a) 21 (b) 29 (c) 37 (d) 41
290. C<ll"RlC<II� � Cllt., R'i)lli'1?
(a)s (b)p (c) d (d) f
291. 1-<oiilHCiii -o191.cf WI�� .!FC"lil C1lli!?
(a)11 (b)12 (c) 3 (d) 4
292.�1l"'J<I"' ��?
(a) Au (b) Ag (c) Hg (d) er
293.���?
(a) Sn (b) Pb (c) Si (d) t91m 'l<l�"Cill
294. � "''lil:i<ll'-"ill �151'J.>ilCli ,4'1'$ .?
(a)Al< Si< P < S (b) Te< Se< S < 0 (c) Sn< Ge< Si<C (d) B <Al< Ga< In
295. � "''li\:1<11'-"lll � � �?
(a)"'�"- 'il'ill/il<lll!ilil '11'1 '1il1l
(b)"'�"- 'il'ill/il<lll61151i!l�<llil•l � "($ �Cii<liii'11511>iM>'!i (.,,,1 f.l.!'ll"lr-1 '1!1
(c) ?flrl!f'J.il 15ilffl '8 �� �-i<liii-1 <llellil t"lil � f.\(SB,mll �� � "'�t. -.i.•iil:il'l''-"I lf1f f.rnil<t .mr-
Engineering Admission Program Concept Book C-02

(d)�e_ <il'ii\:il<l>\31 ll� •1RJ.'l!!Cg9 �C"l<i\la�tj <i>l�il.ill9 l;'fll' AA�

296. 15iltj�<i>9'i"IRJ.'>IZ� C<i>A ��?
(a)<o@�<l>g"l "IRJ. o:: .,_;_,. (b)<o@�<l>g'l"IRJ. o:: 9ffifl!l'IR<i>'>!�
(c) 1511«�<1>9"1 "IRJ. o:: 'll��l"l'l&'i 'llllllll'>IZSIJI (d)
c;sm.rg >till,�-,,, o:: oltooRl�-115
297. �11 � 151jtj�•fiM � C"full C<i>A C<i>A OOt"I � Clf'lf 11111?
(a)Be, B IJlqz C, N (b) Be, 0 IJlqt B, N (c)C, N IJlqz Be, 0 (d) Be, B IJlqz N, 0
298. N Ill� )1i 151jtj�<j>g•1 "IRJ. 0 Ill� )11 \oljtj�<i>g•f -iRJ.lr <:ml i;qfit �?
(a)N 91ifl!T'J:;j'�!� 3 lt 151gf<iCIC"l 31t �l"l'l&'i 'J.�•.,11.4 H'U"l!l
(b)N 91ifl!T'J:;j'�!� 3 lt 151gf<iCICi1 3 lt �li1'1&'1 ,>!00! lJ.4'! � «lqt lJ."IC'iil Fi<ll'<l Ill�
(c) N 91ifl!T'.(ll �<1> �li1'1&'1 'lilTC'il <lift-I
(d)>A�ti11
299. '1i1'lllJ '<l �"l,t"''6"''1=
1tq:
--
19 � ��?
9• 'f.\2'�-6-:Ijjir..,=-,,=
(a)� 'l!lt� �Ci1<i\la'1 ,� � � � <fi'R1lJ: <11'1.iT
(b)� �'fl! "1� >i'iC>ijg � <1Jf\5J!.11•� Clf'/f 1l'lll
(c) 'li1'1"' <11�\5<1'1 «l'i�'fll' 1iTC'1l! 1S'fl! '1i1'lllJ '<l "\l!G'11Cl$g -11"1 f.i-£9:it.,
(d)a'<lb
300. � • '111?
(a)� qi�>t'!_/A.il 151m�'l'g•f "IRJ. <l'1I (b)'1'Tll qi�>t '{IA.ll NGl'!i 151m�'l'g•f"IRJ.151t'i<!' <l"lr
(c) Plf¾-0111 1 (IA)�'fl! Olli1 (d) �� s 1<1i Olli1
301. ��'111?
(a) "l'lil � � \!>1.ljj-0s1C<1 �:it., (b)� � � '31.ljj9.,1c<1 <:11�:iti1
(c) l5l'1m C>iiN,tjll! 'l'l�C'I' ,� l5IJM qc,i
302. 2RbN03 ... ?
• (d)<i>Jill1Wl9 C'11"11919'i -�� 1511<1>1Cilli 1S'fl!AA<l'l?I

l
(a)��-ll (b) 2Rb 2 0 + 2N02 + 20 2 (c)2RbN02+02 (d) 2Rb+2N02+02
303. � Na Ill� 1511<i>flt<li?
(a)<1>1,t.,1�1l (b)CijR! (C)�
304. C<l'T'i .!ii<IJ\319 "1'll1t �?
(a)Mg (OHh < Ca (OHh (b) Sr (OHh >Ba (OH>, (c) Mg (OH),>Ba (OH>, (d) Ca(OH),>Ba(OHh

Solution to Practice Problems (\'Vritten)

¥f411iii
05. Sol": Na2C03 +Si02➔Na 2Si03 + CO 2
CaC03+ Si02 ➔CaSi0,+C02
06. Sol": � ,lll·•1>t'{ll.C'I' <ff1I HCI Ill mi; <l'Cll' � �'I fi1""11I �fl �. <a >A � "11<1 � lfl'\3"<1 �igi�l.'5
'ffii'l\3 � I fi1"'flll' ffl'( '11'(,q Cli'@�(.i!,g � � �fl � �li1�'i � •iRJ.<W/1 � � I � 'f'1J'l!R
l5l1ti1T f.lfi1't � C"tffi � 1J1qz >r"J.il<I' � � �q(4 eorc-4 "'Ro"'fo'I"' �
1 HCI «i� >m<11 141J!.-019 <f'"C"i lf1'(o<I
��'I� Cli'l9�/.15 "ffii'l\3 �I �. «lit�� I lf1'(o<I �'I� Cli'l9� "ffii'l\3 -!I� fir,n �
<liil'f ��-!II
07. Sol": Be «)qt Mg Ill� 91ifl!T'J:;j' <51J<ffi! 1,!ii<l>l9 1 >J.13illt «lt'RI' 'fl1'111',IC\3 � � f.i1S8'«1r.>rn ,mQI 1J:@ Qffl<li 1
� '31'f"IRJ. "1ll!f'i 'fill.'1 �li1'1&'i � •iRJ.'l!!C9 cm'3 911ll! -!I I � «im fir,n � qcf �-!II
08. Soi": (i)��qlf't9'����� 10% NaOCI (C>iiN>mll ��C1i�l91°®) ��I
(ii) �z "ll'1'1��" NaOCI�� I
Engineering Admission Program Concept Book C-02

(iii) i'.;qs,, "1V'f ijfi;z '11\SISIC'ilil � NaOCI ��I

09. Sol": (i) CuS0,+2NaOH = Cu (OHh!+Na2S0,
��\!\Ill!)
(ii) Fe (N03h+2Na0H= Fe(OH>,.!.+3NaN03
('!¥i\!\111!)
(iii) AgN03+ NaOH: NaN03+ AgOH
2Ag0H:Ag,O !+H,O
(� \!\I'll)
(iv) Al i'fq'CJ! AICI3 +3Na0H = Al(OHh!+3NaCI
�-IITTP!t'f \!\Ill!)
Al(OH>.,+NaOH = NaAI0,+2H,O
(v) \!\IJIClllf.@li '1'W!il��! NH 4CI +NaOH: NaCl +NH.,+H 20
(vi) znso. + 2NaOH ➔ Zn(OH)z l +Na 2 s0.
(>11111 151'11)
Zn(OH), + 2Na0H ➔ Na,zno, + 2H,O
10. Sol": Na 2 co , C<I' c>1115115!11"f�1
� '1>161111'1; rm,, CO2 , NaCl � '11f.l)
NH,+ H,O ➔ NH,OH
2NH.0H + CO2 ➔ (NH,hC03 + H20
(NH,),CO, + H,O+C02 ➔ 2NH,HCO,
NH.HCO, +NaCl➔ NaHCO, + NH.CI
tso�c
2NaHC03 ---+ Na2C03 +CO2 + H20.
11. Sol": 2NH.CI+ Ca(OHh➔ 2NH3 +CaCI,+2H20
12. Sol": Na2C0,➔2Na •+ co,"
2H20➔2W+201f"
Na 2C03+ 2H20➔2Na0H+H2C03.
lll-.r!C'I, NaOH � "Fill' \!\lte, � :!Mt<! "l"'J.ltilit'1 Olf" � 'fR <l'til I H,co, Ill� 11'1 \!\Ill � � �'I
\!\IIU"i<l'ol!.4 W \!\lllR C'i1I I
H+ +Olf"➔ H20
�. :!Ml.•t \!\INiRI& OH-� 11'rn1 � C>tlN>UIII <l'lfulilil � EqCJ 'lFfll'l!{t 1

Group-14(1\'.\)
13. Sol": AICI 3 (s) + aq ➔ AJH (aq) + 3CI- (aq)

AJ l+ (aq) + 6H2 0: ➔ [AI(H,O: ).r• (aq)

o:tiiMifM <.:.Ji'ffefi,411:q {III)�
3+ 2+
[AI (H,O: ).] ( aq) + H�) ➔ [AI( OH)(H,6: ).] (aq) + H, o+

[AI(OH)(H2 0: )5 ]
2+
(aq) + H2 0(1) ➔ [AI(OH)2 (H2 0: ).r (aq) + H,o +

lll�'1 �1 �lf.@11 '51TlR � <l'lilC'I �"lil pH lllil 'llA 7 <Jlil C5Cll <!"II � ��. AICI, lllil' � �'I <5l'§rn
� 1 lll�<l"filt<I <Jl<fZ <JI�� Al 2 (S04 )3 <Jlil� :!M'l'<l \!\1!1��1 �. AJ l+ lllil'� ��'<l'!lllf <Jlil
on:f � � <Jl<f� c,-.so�- <Jlil C'11i11ilrnCiiil 'iil'<1 AICI,,A)z(SO.), \!\If� >tllC�l<Sil 1 <Jlil 'll't'i', AICI, +
Engineering Admission Program Concept Book C-02

3H 2 0 ➔ Al(OHh + 3HCI; <!I tfll'C'lll' Rf-iRl � llW "'!f 'lilt t� � AICl3,Al2 (S04)3 <!Iii� :!M'I
'm!��I
14. Sol":

:. SiCl4 + 4H 2 0 ➔ Si(OH)4 + 4HCI

<!1-.nt'I, Si <!Iii �ff/ ffil -:>'!I "fRliffil �'!ITTI � <519l,<f 3d Orbital� 1 <!il � � H 2 O <!Iii Oxygen 1llilf
� lone pair e- ��1 lllft loll:ifHC'1!C'lil � 1
C lllil �ff/ ffil �'!I "ffi ffil �<l'!ITTI � � 2d Orbital� 1 � C "f1Rll Oxygen 1llilf � lone pair e- �'I
� 9lfCil "'!f, � cc1. ,,11:ifHc:1fi115� "'!f,
15. Sol":4'Jlf.i4IUS: 4Al,.+I2e-=4AJ GIJIOllCIS: 602--I2e-=302

16. Sol": C'i"S'lff "flRll� � ��'f'Cil Cilll> �Cl\ilii!i� 'IF-I <!'till� 9f1f.lt'5 �>mlR)' ffllt'l:!M� lllilt
9f1RC<l' 'iP!\5 <l'til I Pb+ 2H,0 = Pb(OH), + H,, Ill� 9f1R 9ffC"( "lfu f.ii�lfh.fii '<IW1IIC<I' i:-ft15'g f.ii�lfh.fii <11:"f 1
17. Sol":� co, C<I' � <11"11Rl\!i � ���15ft"1 � �� ?ffii'IG�1 Ill�� CilC"fm-1 \!ii
'>!lll>lfii ilfC"1 ?ffii'f\!i� I lll'C<I' Ory ice <Ito'[ I
18. Sol": Al ��1llilf "iWl! Gliil�l\5il �<i'C<I' ��'l<lti'fl
�m<J: 3 <Sf<f Cr,O, + I iSf<f Al �� m'! 1
Cll'll"l· (i) Fe2 03 + 2AI ➔ 2Fe + A/2 03 (ii) 3Cu0 + 2Al ➔ 3Cu + A/2 03

Group -15(VA)
19. Sol": NaN0 2+ NH4C/ ➔NaCl+ NH,N02
•
NH,NO, -➔N,+2H,O
20. Sol": Gi�c>!i 80% Ca3 (PO,>, Qff'C<I' 1
l200°-150D°c ti
Ca,(PO,l,+3Si0,----3CaSi03 + P,Os; P,0,+5C-➔2P +5CO
21. Soi•: c>UC!liletki � � (Cu(NH 3)4 (H 2 0) 2 ](H0) 2 'llRI ili>il-OH<il '!I'll 'cilm � � GIJ1fli'l '<i'911il �
aj�Cl\jli,l�l5· 1
� �crf.11: CuS04 + 2NH 4 0H ➔ Cu(OH)2 + (NH 4)2 S04
Cu(OH) 2 + 4NH 40H ➔ [Cu(NH 3)4 (H 2 0)2 ](0H) 2 + 2H 2 0
<!l'C<I' C'l'J.C'11Cefil � :!im' � lllilt Cil'!f-1 ��f?61.\6 ��I
22. Sol": P205+H 20 � ➔2HP03 meta- <j>>j<j>fli<il ll!PJI,,
P205+3H 20 �) ➔ 2H 3P04 OrthO· ll'>i<j>fii<il "'ffi
College Dorpon Concept Book C-02

23. Sol": P20 5+2HN03 ➔ N20s+2HP03 P,0, >tli1f7i<ISflt4' <!I� 1113 Hll'lt<IIQll'<:1 Hll'M15'm' 1
P,Os+H,S0, ➔ SO,+ 2HP0, I "J.15li'f� <!I� <!l'f'1t •iRPtr-ft � 1
24. Sol": ISCillf%i-,i � P <!Iii C'li1Tll 3s GiilflroICi1il <!l'f'1t �Ci1�'1 3d Cl5 ��<It"! P <!I'll >tlllC4I<ltJl5I 5 � 1
2

�. �'!l"IRJ.'l!ll.li d Glilf4'Cli1 -!I� N <!Iii Cll1<atJG1 5 � 9fltll"!f 1 �. PC/5 "11<flt"j1l �'Cl NCI, �-!f 1
N(7l---+ls 2p 2p

00 [1[11111111
P(ISl- 1s2 2s2 2¢ 3s1 J<IO
3�3
Dil fill 11kMCl1klffi-l 1111]1 I '--I --'-----'---'--I�,

2S0"C, l2
25. Sol": C"Jl5 P4 --�
CO2/N2
P0
""'
� P4 - �"' ="""�
SSO"C
ll'>t<l"!IIC>til <11"91 ----+ (t"Jl5 P0)
C0 2/N2
26. Sol": N <!Iii cm! P �'lil Glf<lilil� �ml! p,- Glrn'l �6? 'l'Jlilrn�il � �� '� 9fl'Cil 'ITI
�

27. Sol": (i) GiJICIIIHm (NH,) -== (ii) ��!lil™'1 (1i2N-NH,)

(iii) �Cl\ill'et'1 GIJl<ltl�I& si �Cllilfli<II <!IPII& (HN,) (iv) GIJICIIIHfilll GIJl<at� (NH.N,)
=
28. Sol": P• 151'.(C\5 P-P � <!l"lQfliWI 209kJ/mol 'lll N2 l5l'.(Cl5 N N � MCfil<lt'1 lll'1QllilM 945KJ/mol <!Iii cm!
=
'l"ll I <!I� P• 151'.(C\5 � C'l'IC'lil '11A 60° 'lll N N � <Nil C<ill'I (180°) 151C"f"fi 15!l'l'l' 'l"ll I � P• 151'.(C\5
� Cq'fwt � 151 N2 <!Iii crnl Cq'fwt >Im I

p'.:..rsp

"p©
29. Sol":
Cl 2 N-CI +1120 -Cl 2 �I NHCl2+HOCI

1 IL
- 'Q-H
l J. t 2H,O
NH3+2HOCI
:. NCl3 + 3H2 0 _. NH3 + 3HOCI

-uct+ll-0- P('i:
j,....-li2H,O
.,...o._ + 2HCI
11-0-P-o H
(H3PO3)
:. PCI, + 3H2 0-+ H 3P04 + 3HCI

30. Sol": N q'! F '1'I1.lil� <l'i'I'! d Giilflroli1 �<It"[ NF, �f.lc:ifll-,, �"!fl q'!f<rijj� ii,Jli1�'<1'Ci!l��:lM"' �I
31. Sol": (i) NCl3 + 3H2 0➔ NH3 + 3HOCI} Hydride
(ii) PCl3 + 3H2 0➔H3 P03 + 3HCI
(iii) AsCl3 + 3H2 0➔ H3As03 + 3HCI } Acid
College Dorpon Concept Book C-02

(iv) SbC13+ H2 0➔Sb0Cl+ 2HC1

(v) BiC13+ H2 0➔Bi0Cl+ 2HC1 } Oxyhalide

32. Sol•: 4Zn+IOHN03 � ➔ 4Zn (N03),+ N20 +5H20

3Zn+8HNO, ('l!l1fJ"ll <fW) ➔ 3Zn (NO,), +2N0+4H,O
2HN03+As203+2H20➔ N203+2H,As0•
Zn+4HNO, (<fW) ➔Zn (NO,),+ 2N0,+2H,O
2HNO,+ P,Os➔ N,0,+2HPO,
33. soi•:� f.iM>filU C<l'A 91'ilt4li <JI�� Wl!'l-�'I � '3ITT' �wu f.ifil'lnqti!,
+3 >20oc +S +2
3H N02 (aq)---+ H N 03 (aq)+ 2 N O(g)+ H2 0(1)
� (ffllffl)
<Jl"fi'C'I � <JIFl'i., � � �:"'t<telC<l MCUlfer� W-1 �WU f.ifil'ln O'fll 1 � <Jlt<l' ,g�'IIT'il3 �WU
f.ifil'ln qtif I
+3 +2
34. Sol•: 2H N 02 + 2Kl➔ 2KOH+ 2 NO+ 1 2 {1!ffil'I �
+3 +5
CI,+ H20+ H N 02 ➔ H NO,+ 2HC1 �'I lflf)
PcRh
35. Sol•: 4NH,+502---+
°
4NO+ 6H2 0
900 c
50°c
4NO + 20 2 ---+ 4N02
4N02+ 02+ 2H20➔ 4HNO,
36. Sol•: Fe, Al, Cr� <fW HNO, <Jl'jf >it""W'f � <Jlt'i'l! IS"lll MM'mt.iUfll Gi'!l�C\5'l! �'I� qtoJ <Jli'll f.ifui;lr
W-1 � I �'I "II M<ltlliC<l'li '1� f.ifil'ln ll1mr <JI� 1til <liil1 'll1'll I
37. Sol•: Cu+4HNO, ('1W) ➔ Cu(NO,),+ 2N0,+2H,O
3Cu+8HN03 ('l!'IJ"ll '1W) ➔ 3Cu (N03),+2N0+4H20
4Cu+IOHN03 � ➔ 4Cu (N03l:,+ N20+5H20
8Cu+20HN03 (151Rii11ij) ➔ 8Cu (N03)2+2NH,N03+{5H20
5Cu+2HN03 (<ll""f) ➔ 5Cu0 + H20 + N2
38. Sol•: (i) li'>JCli'lll�: Ca 3 (P04),
(ii) Clffil <i!Jl�: 3Ca3(P04),. CaF2
(iii) � GIJT�: 3Ca 3(P04>,.CaCI,
39. Sol•: li'>Jli'lll>J '(j ll'>Jli'Ri<I' lllmll �: li'>Jli'lllC>Jli � <!!Pli!i>J'{Cil_i1'� "l�t<l'tl3 P <Jl'l! '>J'lCQf �'tiil OH
1J.il'<I' 'lj_(li � C>J' <Jlmll � \3\3 I � �9Rrn �t.\\ill<ltc.'1li >lt-.rJI � C<l'A <Jlmll '♦lli'I'� �
f.!<fll <liil'f 'llfll I �-
(i) �911 li'>Jll'lil>J / ll'>J!iPf.l'I• <Jlffi
0
+l I
H,P02
H - P - 0 - H (<JI� '♦lli�U <Jlffi)
A
(ii) � <llffi / li'>JCli'lH<ii <JIFl'i.,
+3
H3 P03

(iii) <.Wl li'>Jli'lll>J <Jlffi

+3
HP02 0 = Ii - 0 - H (<Jl<I' - "♦lli�U <llffi)
(iv) �I li'>Jli'lll>J lllffi
College Dorpon Concept Book C-02
0 0
+3 1 t
H4 PzOs HO - P - 0 - P - 0 - H (N-'1>iil4ltj <Jlffi)
� A
(v) \>/�4J<l''l<l'fii<II <Jlffi / <l''l<l'flt<II (V) <Jlffi
0
1
H - 0 - P - 0-H {f.li-'lf'lil�tj <Jlffi)
0I
H

(vi) CW! <l''l<l'Rt<il <Jlffi

+s I
HP03 H - 0 - P = 0 (<Jl"<II 'lf'lil��)
(vii) �'111 <l''l<l'Ri<II <Jlffi
0 0
+S t t
H4P207 HO-P-0-P-0-H (m-�)
I I
0 0
I I
H H

(viii) 'lii1N'�ill'I <llfis>I

H 2S03 ; H-0-S-0 -H (N-'lf'lil�tj <Jlffi)
A
(ix) 'lli1N"�Rl'I' <llffi
0
I
H,so.; H - 0 - S - 0 - H (N-'4'1il4ltj <Jlffi)
A

0 0
I 1
H-0-S-0-0-S-0-H
I J
0 0
:. � �. <Jlili!i!•R!-lflr 'Marshall's acid'.
0 0
* '1�C'iii'lli1f<l'�fii<II <Jlffi l!il�ii1N'�Rl'I' '-'lffi Glfo'rnrlf H,s,o, ;
1 1
H-0-S-O-S-0-H
J J
0 0
0
1
• -.,1?1>11i1�Rl<11 <J1A11, -.,1ll\o/MP11o1�fii'I' "'PIIS '11'11 \o/Ml•r.'l1S11o1f,J,�fii<1> "'ffi H,so,; H - o - � - o - o - H
0
:. � �. <Jlil15!'1il-!1'11 'Caro's acid'
0
t
• '<IICWlii1f<l'�Rl'I' <!IP!\,, H,s,o,; H-0-S-0-H
I
0

Group-16(VIA)
-2 +2 +4 +6 +4 +6 +6
40. Sol•: Hz S, SCI2 , SCI4 , SF6 , S0 2, S03 , H2 S04
41. Soi•: 2H2S+S02➔ 3S+2H20 (iilfiil'fiiiC'1) [<JI� <Jl��WIJ�'G qWj
CI,+S02+2H20➔2HCI+H 2S0• (Miilfiil<llllC'1)
College Dorpon Concept Book C-02

S02+2H20 ➔H,S0.+2IHI
IHl+ffl�➔q��I

42. Sol": f-1""1 � Wl!f.! ffl f.!<fi3 <uJ>! q'l 'f <uJ>! (Ouega.<) � 'ffi<l'lil'I' SO, 'IWITT' '♦lil$19 '11iiC<1C·1
C"IPl''f 'l'llfll'lll I <ll'C<I' Flue Ga< Desulphurization q'l FGD Plant q'il!�I FGD plant <ll �� '<l � 9f1Rll
� 'f<uJ>I WAI <litil -♦�lil'I' S02 C"IPl''f <RI� I

�: CaCO.,+S02(g)➔CaS0 3+CO, (g)

CaO+SO,(g)➔CaS03
180°C
2CaS03+02 (g)+ 4H20(1)➔2(CaS04 .2H20) __. 2CaS04.H20
�"1"!Tl! 'fJmi>I m>trlr
43. Sol": Fe,0,+8HCI- FeCI, +2FeCI,+ 4H,O Gr4!'., Fe,o. <ll Fe <!I'll ClITT!Rt 2 '8 3 1

(t'l'ilT>I)�
44. Sol": Pb304 + 4HN03 ➔ 2Pb(N03),+ Pb02 +2H20 Gf�. Pb3 04 <ll Pb <!I'll ClITT!Rt 2 '<l 4 1

(ffiil'!) (ffi<i')

Group -17(\ II.\)

45. Sol": 2NnX+3H2 S0,+Mn02 _. 2NaHSO,+ MnSO,+ 2H20 +X2; X = Cl, Br,I
46. Sol": Gl'lfiir.'iil �<!, IS<!.>! � � q'l NaCl <!I'll � � :!i'l'f1 � �'I o!l'li�C\5 NaCl � NaOH
o!IS!i5C� IS�� � � Gl'lm' 911'8'!1'1 'llllf1
47. Sol": Cll'mfi! <ll� >!'Tif'tf'I' •l�•lr-il �1 '1115'11 r.li'kl�l5 � � � Cll'mfi! o!ISl5 '<l'il1il 'lll5 (<l'l'I T§f1il<I'
�I <ll� 'Im Cli'lil�C\Sli �<!, �'f<litil Cli'1fir-l o!!S\5<Rl�I
48. Sol": <l'Mkl'lil � 40°c 151� Gl'1fiR � <litil 'l'lli1PI-OI� Gl'1'Cil1 �,'1I�Ilil� Gf4re. f:iwz 9111S\S"R1 IS<!."1l!
40"C
� 1 Ca (OH), + Cl,- Ca(OCl)CI + H2 0
zs�c
f<ii<J 25 C 151� 'l'Jli1Prnl� � 1S<!."1l!�1
°
2Ca(OH)2 + 2Cl2 -+ Ca(CI0)2 + CaCl 2 + 2H 2 0
49. Sol": Ca(OCl)CI + H2 0 -+ Ca(OH), + Cl2
H2 0 + Cl 2 _. HOCI + HCI
HOCI ➔HCI + [OJ
[OJ + ffi � ➔ mf� � <!lqz (OJ + �'.{Cffl ➔ 1J:15 �'.{Cffl
50. Sol": ll)ICi1ICiet•PI'{� HCietC'iil 11'CIIJ � '<l'l:il f<iil "11'11Sl!."1l!<l'l:lPl'l �!lllICi1ICli!tii i:wt 'lfCll '1fiif5151
�- ClF3 , BrF3, BrF5, IC15, IF7 � I
51. Sol": F "1ifll'l'J.il� '®f"tfilokl"1TC"f 5 �� I "1ifll'l'l "fm� 1 � F1 5, FI 7 � 1
52. Sol": Gi'Jm' 9IIHl:l5 >!TllT'li :!i'lqhi I <.$1Ifiil'lll Ill � � :!i'l'IC<I' Gi'Jm' 91TH qC'1 I Gi'Jm' 9f1Rll � �
�,'1I�Iill>i lllffi $1 � I <ll� "1l:'l! � llJ�Cl'al�lfii'I' <llffi <S Gl�Cietii lS<!.'1!! '<l'l:il I lll'C<I' � Gf"ll'lliW!T<l'il'f

(acidic disporportionation) �qli11

Cl,(g) +H,0(1 )➔H•(aq) +c1-(aq) + HCIO(aq)
College Dorpon Concept Book C-02

2HCJ0 (aq) ➔ 2W (aq) + 2c1- (aq) + O2 (g)

911f.!c\o�t ��<l'tll '-'1il1!00 HCI Clll't<l'tll � ?f1F!�<l'ilf �I «11:'r � ?f1F! �� �I
Ca(OCl)Clcs>+2HC l( aq) _. Caf;q)+ 2Cl(aq) +H2 0(1)+Cl 2caq)
53. Sol•: 15 °C �9flml'fll � C'l1l51il ��:!Mt<! (ll'mR Wl'ill 'R'C'i' c>IIN>•I• Gf'lil�lli"' t.>IIN>filll ��'1I4i'lil�
\'S�'11!�1 � 70°C �'1'llralrn C'1INi9111 Gf'lil� <S t.>IIN>filll �\'S�'11!� 1
2Na0H+Cl,_. NaCl+NaOCJ+H2 0(15°C)
o -1 +1

6Na0H+3CJ2 -+ SNaCI + NaCJ03 +3H 2 0(70 °C)

0 -t{mllm) +5�

'-'1� �� Gl'tflr-l "fil'll'I'.( '-'1� "1'1t"f � '<S M\!ltlHI"' �1 � � �W!J (Disproportionation)

��I
c1, � c1- � '1Ri'<113 �'!!Ill'� 1ilffi!'1 � o � -1 «1 !f>I '1fll I �. c1i 11-.r-l c10- � '1Ri'<113
� � � lSffi!'I � 0 � + 1 '-'1 � '11'll I '-'1 <l'lilt'I Cl, '\!ltRl<I' '<l � �'1 � <ml I
54. Sol•: (ll'mR '-'l�Rl!� 1 � 911Rl1'"1'1t"f �<ml� '\!lflll'l!R '3/�C¾'1 \'S�'1l!<m!�ilf!A 'ffll<li�<m!
<l�<mfl
9l1Rll' "llt"f Gl'IHIC'lil �1i'lllt'1 �1 Cll"'R: CI,+H,O➔HCJ+H0CJ
HOCI ➔HCl+IOI
ilf!A� + 101 ➔<I� lll<IZ�� + 101 ➔ '!'3ifi<ll'-.(Cffl
55. Sol 0: 9ih<f1Cll � li''lli'illC'lil "1Vf � <11 <:IIICfilNil'lil �'1 9f1R Clll't<l'tlllf� HBr, HI l\3Hi'-l'ilf �1
li''lli'lllc>lil '1V! Cillfill'lil f.itf.i!.filll ,:iQll;ll PBr3 � � 'lll 9fCil 9l1Rll'��<ml HBr� <l'tllI
2P+3Br2=2PBr3 PBr3+3H20: H3 P03+3HBr
"l<il�IC<I I' '-'l<lt 12 '-'lil"l(CllfC'I "'Qll;ll Pl, \'S�'11! � 'lll ?f1F! �� MC:ifii-,, �HI�<ml1
56. Sol0 : '1�""1'1fCil <11Jli1Pl•III Cli'li1I'8;1& <S '1W H,SO, '-'lil MM-fill! HF�TIT '!!Tl! 1
CaF, + 2H,SO, = 2HF + Ca (HSO,h
57. Sol0: HF< HCJ< HBr< HI
58. Sol0: � <f1C11"ff'I �131 HF �ljilTIT'!!Tl!1 "l "IM-filC<II '-'lWZ � 1
SiO,+4HF-+ SiF. +2H,O '-'l<IZSiF4+2HF-+ H,SiF. �'1fi'Cilli,Pl,f.M
"'"'X
Pl<II 1J1ffi)
<II, Si02 +6HF-+ H 2SiF6+2H2 0
59 Sol•:�'11"! HF'-'1il��<m!'11'11�'!!Tl!����'1fiiC<IC"lf.ifui;lr�1
Cli"'R, Si02+6HF _. H2 SiF6+2H20
60. Sol": (H,O+HCJ = H,o+ + c1-)HCI lllil�:!Mt<I ��U\ilf.@11 � '<l Gf'lil� <51fl1'1��'lll �
� <l'tlf I
61. Sol 0: ajlf.i1IC\!lt'1'11J.C�ll 'llt'IJ '-'1� F2 '!J: '<il"A'<l Gl"ll'l!WIJ � "l'1"A <ml "111 � � F '-'lil 1Sffi!'1 '11A
C<ll<li11ilili (-1) 1 F � '3l'IJR'J ajICi11Cist'1 Cl, Br, I 151>!1'l1WIT � C'f!f1
8Hl'i·tA4H
62. Sol•: Xe� <?'Ii'� 'lJ.'11 e- '11flfi"l'CII Sd snfo'I Orbital Ill� <l'tll 2, 4, 6 � ""'lJ.'11 e-ll3RI' <l'tlll �.Xe�
XeF2 , XeF4 , XeF6 � � 1 He, Ne,Ar '-'lil �� � f.l\'Sf¾filc>lil <l'laj<lllf\ �'!Ill! 131 � \'Swf<ir-,, � ll3Hi'
<mi ""'lJ.'11 e- ��om 1 "11lflil'il3, M'l'G<I� ·IRl'l! Orbital �t'i'lil 'llt'IJ e- "l,'1f.t.ul>I �
1 f.l\'SB,ui'l � �
1!13 � '11'll, Orbital �t'i'lil "fRlill''114""J "'"' � � I � Xe � � '<llilf.i1'<3 He, Ne,Ar� '1TCil "111 Kr�
C'IT'f � <l'ilC\o '1fCil I
63. soi•:
(i) �:
College Dorpon Concept Book C-02

<I'. � '6 'iro o!lf �He Cqif! '6 '1"11;> �l\l>i<ltill)l'etll ilrn1til ��I
..r.���--Jl'l�'!!i'!IHe�<l'tll'�I
'I. � � ill•iiC�lli <i>ll'et ��I
'II. � � '31"f'llral'm 'lm'llll '3ilil He�� I
(ii) f.m.!:
<I'. 41Fl�)<II 1511Cill'l"l••il� ��I
..r. f.m.!��'IIC'!I'<l 'f'1)"l!R, '-'l�-1) R�IC�ll 911�·-M �>i�W5llit9f f.m.! ��� 1
(iii) \'511.f.!:
<I'. �4'i.JN><II � �9f UT��� 1l'lr,;!, 41..ojl 'l?"' "!I�� Ar�� 1
..r. Weldin9��151ml'6'!!1���1
'I.� "66if3i.�"'i RC"tli <l'Cli •fl�'lliPJ.illiPIG!"ll.f.! ��I
(iv)��:
<I'. � �I/ Z4'i.)Ri'I'� Ar «ill' � Kr�� 1
(v) Clll"!'l: lii>@H'I' �'ll'll liiiSIC'iill Pim! "IC<lt�r.'iili f<i�� Xe ��1
(vi) c;r,s;{; @A� <I'll!� '<IIJl"l1,I �>illl '-'l<I� � �'RGI
'-'l� 1RUI-Uffl ?l'T'l � �� � �'I � � '-'l<I� �4'i.JRi<II <lr:JI ll'1>1<114� � � R'!R �'I
��I

f.lf.1>1 (Miscellaneous)
64. Sol•: ffl >i1ilm r:<l'l'I � lf1f '3lll � � � .!l't9fll («l� >!<I�""') � � �· 151�<1'GI
""'f'IJ9!-f l'-'l� >1"'14C<II <l'<'f ��I
Cll'IR: 9f 1 (IA) 2(11A) 13(1UA) 14(1VA)
ffl�
2 Li--. Be--. 8--. C
3 Na � Mg � Al � Si

65. Soi•:
ffl )11'o'na'i' � o'na'I'
)11' ffl H (I) He(2)
�ll ffl Li (3) Ne(10)
-:>ll ffl Na (11) Ar(l8)
S�ffl K (19) Kr(36)
,rlf ffl Rb(37) Xe (54)
�"3"fl!m c.� (55) Rn (86)
�11'9fllfll Fr(87) Lv (116) ['-'l� ,�;, ••,v"'IC� 1511R,i!i]
66. Soi•: r:<l'l'I 151 t "' "fll'lll 11Cl!J ,., mil i!i le-rt,! 'lilC'I' '-'l� "fll'lll �m�cr<l'illil
sj,�i!ilC'I' \O�,e. "ll•ii\/ij'l'i!ii 'Ii!!� I
67. Soi•: � � I mo! � "fll'lll'lll � �&l/ ffil � 1 it <l'tll' C1l'1U I mo! <l'tll' � 151"f>llll'I <l'tll'
� � >mic'!I f.irn I mol t:R1l1l<il 15IT1!C'! 9ffii'll3 TI'Cl3 ClJ "IRl'l! � � .g � 15ijtj�'l',l•1 "fR!i � I
68. Soi•: sj,f,I �: Cs > Rb> K > Na> Li 1J:'.'!ffil �: Ba> Sr> Ca> Mg > Be
69. Soi•: SiC/4 + 4H2 0 -+ Si(OH)4 + 4HCI
PC/3 + 3H2 0-+ H3 P03 + 3HCI
PC/ 5 + 4H2 0-+ H3 P04 + SHCI
2S2Cl2 + 2H2 0 -+ 3S + S04 + 4HCI
Engineering Admission Program Concept Book C-02

70. Sol": 13 'IZ 21C':llPf111'!R � �. AICI, � l'i<l't'I <5lIB AC:lN"' W-1 H,o +
<II ��Ulilf.@11 ���9!l!<l'Cl! 1 <ll�
� l'i<l't'I HCI Clll'I 'I'll'!� HCI � � H <llil � '11 Common ion effect <llil <lllilC'I H,o• ��'91!1 �m
+

'l'tlf �'11��� ��. AICl 3 <llil'5lra�'I !r>1 '!ITT' '11���1

�t, AICl3 <llil <5lIB �'I� 'l'll'lil � <llil � l'i<l't'I HCI Clll'l 'l'll'I � 1
71 . Sol": Si, P, S �Ci1(JIC'1C'� OOii' 1 � 9f1Rll' H 91ilm'J."C<l' �'R <llill:5 9f1Cil 'II1 151� 0 91ll'lll'.(il C5Cll �
�C"l�IC'!C'•1iil"' <ICi1' <ll'C<l"<l �'R <llill:5 9f1Cil '111 � Si, P, S 9f1Rll' '>fltQf � 'l'Cll '111
72. Sol": Si <llil � � 151'! fli�JIIH 11'1 -Si - Si - � 111'1J'Cll MIIIM'I' � � • , <ll � �
'fii'Rl3 W'[ 15l'C'l'I' Si - Si �� �. 'll1tl3 � "!Rli �, � Si <llil 'l"l'IIZ'I' 'l(q C'lfil 1
151� P Ill� <lll�ICIIIC\6 'l,� "'Jl'1i1illi '6'!11"1'>1 �'I 'Ii'! Qf1C'I' 1l'lil <ll1ilC<f P, 151'1, � QffC'I' � P <!Iii' 'fi1'11Z'<II
'<il'Sl � I
73. Sol": Mg(12)-+ 1s 2 2s 2 2p6 3s2 ; Al(13)-+ 1s 2 2s 2 2p6 3s2 3p 1
<ll-.rlC'l Mg <llil �1.: •tRJ.<tCliil 3s 151ilf.iilli1 � � "I,<f I � Mg <llil � '<ll1MC'll'I �,lft., I Gl'1i;IMC'I' Al
91ll'lll'.(il �!� ?lCli <ll'411il 1511J.<fi! � �I � <ll� 151C� <:11�.lft"I I <ll <lllilC�, Al, Mg 151C� i5IC'1
Qlf<ll'f � Al 151C� Mg <llil )'I <:111-0�'l'il•l "IRliil 111'1 C'lfil I
74. Sol": �'1�'1 �: r:'<111'1 0000! 1 mol � � 91ll'lll',{li' � �!� ?lCli � � 1� � C111t
1 mo, �C"l41]'1 � '<IICli 1 mol <llTI' "il'f11:l'<11 l5lf!!C'1 9ffii'll6 'l'ilCl6 Cl! "IRliil � � l6TC<I' �Ci1�-i "'11>1Rl­
<l'C'i' I
Cl <llil e-151f>1Rl- F 151C� �I <llil '<lllil'I F <llil mf � I F 91ll'lll',{li' l5ll'<lllll' �I �. l61il �� �'!l ·tRli<tCll 7
� e- QfT<IITu 61$1'1� � �, � � 1511'116 e- '<l �!� ?lCliil � "il'fll:i"I' � � � �-, �Z.
e- 'lj_(li TI'C\6 � "IRli � TI'Cl6 �, <ll 'lllilC'I F <llil f.l� �Ci1<11IH loll >tRJ.il 111-i '<IIC'll Cl 151C'1"FI � � '
75. Sol": ?(,Jlc.i'll!)l!f'1: F >Cl> Br> I; /i.lli11�: ,-> Br- > c1- > p-
76. Sol": H 20: 15f'J.t'3 Oxygen '1il'111'.(C\6 sp3 "!Z'<llillll'I fli�Jlll'l 1 � <llt\6 2 � lone pair e- QffC'I', <ll<ft Ip - l.p �
> Ip - bpm'I > bp - bpm'I, �. <llil LHOH ��� Ip <llilmt'lil<lllilC<f ��11'1-0I
77. Sol": SF 6 -+ sp3d2; Xe0F2 -+ sp 3d; BeF2 -+ sp; So�--+ sp3; NHt-+ sp3
H H
• H-9. +_......,◊.....e-... ..-H __ i;io_ .,.. .o
,.,...cu2 "-....,o,H•':,o,H
78. Sol: H :.....,. ---o/ s--..0
'o I
a
H /... II
<ll"lfC'1, "lffi'wt � H2 0:-+ Cu2+ <ll<ftS-+ O; >tllr.41� � 0 - H <ll<fZS - o- ; H � [H2 0 '6 Soi- <llil
1[�
79. Sol": � ?lCliil Cl! >,q �i1�'1 <:11"1J 91ll'lll',{li' � �151Z"1 c-!ll 16'1C'i'il � � ��'1 / bond pair electron
'<l 1l'lill � ?lCli � <f'til � � � 151t"1 c-rn 'II "'11.'iliC<II � � / RP!"'f llll!l11;> �Ci1�'1 / lone pair
electron WI 1 'llt<R'I � 1J:'ll loli:Jf4i;Ji1>i'1,� M� � 'llt<iiil'I, '1,iai'6tli!i <!lilt '1�-lr.efli!i ��tfli:J '11i:J""1fii<II
151<l�C'lil �'1il � '<IICli, <ll� Valence Shell Electron Pair Repulsion theory ii"!�� �9f,
80. Sol": AgCI <llil ilJ11il>I "IRliil 1!1'1161il �Clli•M "IRli 151C� 151\6Jf'tt<II � �m-0 16T 9flF!Cl6 151!i<f<fur 1 <ll� �
AgCl <ll� >tllC�I� l.'<fM!J <ll<f� �'1ii11ill!f'1 NaCl 15191C"A C'lfil �m-016T 9flF!C\6151!i<f<fur 1
81 . Sol": H - bond: <ll'411il <oiftt<II � 'l/"f1l1l<II 91ll'lll'.(ll (F, 0, N) '>fltQf >tIIC�I� 4'<iC'l 151mi H <ll<fZ 151i!J 151".(il "'�"­
"1/'fll:i"I' 0000! 1[� � �"""' H - bond <ICi1' I
H 2 0151�1.i'IRI 'll'C'fJ H - Bond�� I
82. Sol":151<l!(li3il �: Cl! >r'<ili! d block OOOOl'�'IC"F <ll'<llft �.1ft.i lolt!!C'lil e- R-iJrc>I d Orbital 1511� "1,4 QffC'l'1
Co-+ 151<l!(li3il, Zn -+ 151<1!(1@ �!!. Fe-+ 151<1!i'.J@ 1
83. Sol": ffl: NaCl <llil �'11 � :!i<f'IC'I' � <ICi1' 1 ffl� �� �'lil 111'1J'Cll NaOH t�9!l!'l'll'I � 1
Engineering Admission Program Concept Book C-02

ISIJit'1ir.lli�: 2c1- - ze--+ Cl2

"'lit� (Hg)�: Na+ + e- -+ Na
Na+ Hg-+ Na - Hg
2NaHg+ 2H2 0 -+ 2Na0H + H2 + 2Hg
84. Sol": HCIO, HP03, IAg (NH3l,ICI, lfe (CN),t, N3H
85. Sol": (i); n = 3 �.
2 3
C-+ 3s 3p :. c'!l<fit <l'>t<l'lll>t (P)
D-+ 3s2 3p5 :. c'!l<fit Gl'ITTR (CI)
PCl 3 <!Ill <:111:.�f.k:1ll''f:

...-Cl
-1·1Cl+H- 0- P--...,
CI
j 2H,O
H
H-0 - P,.. .o......-
<--v-H + 2HCI

(H3P03)
:. PCl3 + 3H2O -+ H3 PO3 + 3HCI and PC/5 + 4H2 O -+ H3PO4 + SHCI
(ii); A '8 B <ll� .m91ll C'ITi'f <ll<fZ B <!Ill� A �"f"FI �I�. <l'Jft@.'1ll � 1511<1'ltllll <ll"!l A02 Ill "11'1illi9•t
Cq'f-f � <ll<f� � �<p 'IIIC<II� 'f:.f � � 1 �- A � 'llJ1'•1C'1Pl9111 <ll<fZ B � <l'Jl'1Pl9111, D �
Gl'ITTR I
86. Sol": (i); c'!li'f 'l)t Be '<l Mg 1 <ffi!'f, ��� �-gm e- <:<I' il';tt,•1Rl;'iJJtll �<RI '<Ill! '111
(ii); Mg(OH) 2 �� 1 <ffil'f: MgO+ H2 0-+ Mg(OH) 2 <l1ll � :!i<f'I fi'filiii'IC<I' � <ml 1
87. Sol": C'IINi91Cllll C6tll <:IIJlij)'llH91Cllil '1i'l'1llJ Cq'f-f, ffl'f � Al <!Ill t!1G<f � Na <!Ill t!1G<f � am! Cq'f-f
-�•rr-11,
Na 91ll'IIT'.[il <5119'119C'1 "l<i>fil �C'1<11]'1 � � <ll<ft � lfi!l'i1;i<i> brisff.lfiil Na• '5lfll"I i'.!';�9f!i � 1
Na➔ Na•+e-
<51�, Al 9\il'llT'l � � 3 f& �C'1<11]'1 � � <ll<f� ffir� ffl � Al l+ '5lfll"I "3fil �I
Al➔ Al,.+3e-
� Ar'•� � '6TCl!RI 9®11'1 Cq'f-f� <!Ill ffl � <ll't'<I' � Na• <5l1ll'C'1ll' � Cq'f-f� I �

Al·<llll 'lfi3",q C'MIC'lll � M�Jlll'1 Ar'• '5lfll"I '8 91fli� � �t'1<11]C'1il �'I C'IINi91Cllll � C<l'iiTc>I
M�JII1'1 Na• '<l �C'1<1'Jit'1ll �'Ill Cbtll 151C'1<1' C<1M �, � Al <!Ill -mfi;>t 14cm<lt'1 <ll'i!Qfl'1M'<l 151C'1<1' C<1M �, c>!
'<lt'1J <:IIJlij)'llH91Cllil ,� (660°C) C'IINi91Cllll (98 °C) Cbtll 151C'1<1'� Cq'f-f�,
88. Sol":

0 fR >tklit -ni'f
0 'fH !F°""" �
'fflll'll'"ll'lmf'l3'f
Engineering Admission Program Concept Book C-02

���Cl!,� H2 0Gl<J. 15191il � H2 0151<J,il151Zffl � �Cl\ill'et'i � 'l!IIIJ'C'1I � �1 <JI�

<JI�� �151'1 � �I <JI ffi 'lill:lR � � vm Wl!<fl � 1i'lll1 �t � <51R� �� q'!
�?f!Ril�<li'll�I �. ���I
<Jlq'flf, � � 'fCii1 <:13T, 4°C 1!>1'1lliilll� -.,!f.rn Gflt� �� � C'A?
89. Sol": NH, , � (PH,) 151'l9f"l'l'Cl � "l'll!<I', ffl<f, (i) N <Jlil "'fiii"-
41'11\li'l'l!il \3.0J, iji>i<fi110lil "'� "ll•iillj<ll\61
(2.1) <Jlil C5tll � � I <JI� '<lllilt'I, P - H <Jlil � � N - H <Jlil ��li1<il]'i ,.JN,1 � N 91il'l!f'lll
1'it'I' Gff"''f'I' � �I (ii) 'i�ailliiltl'iil "fTll'l!l'lm' 'IJl'llli' (0.075nm), lji>jljiilil>til '1flrlll'!m' 'IJl'llli' (0.11nm)
151'l'1'11'1 ���em�� �,.,�'i cmr <J1<1� f.i:""" �Ci'l�'i ,'IIN,l' f.w � N 91il'l!l'.[l\!i �i1'illJ.i1<1115tl<I ,41"1
�1 �. PH 3 <Jlil P 91il'l!l'J,ilWi1'!1lf NH3 <Jlil N 91il'l!l'l� ��q'!�Ci1�'1 "1>'il'!"f'll\3! ��1
<JI�, NH,,� (PH,)151'l9f"l'l'Cl�"'l'!il'l'I
C\ f"' /Cl
90. Sol": AICl3 '>t'l'llil<f �9fl!lilll'll � 151'1 � �1 Al )Al
c1/ \c1 \c1
�� � Gf'l � GfT'l'Tlll' (g;j'� <ll'lll' � "'Ji'ii51il'<Sffli1"! �<f <fif � C'l'ii'f>I'� '<l'tll' I $.l, I 80°C
�'1"1Til1'1il '1Sc� � Al 2Cl6 151� "'Jl'iililil'<S!lfii"j' � <fli1ll' $1<1 � W-1 ��<JI� <IIY,il'i1ii1 �191
(latm) <Jlil151flf<l'"519f�'<l'tll'I �. R<lfo'!G�'!llil � (� 423°C) A1,c1. �� �"1il!>ITTI <11�'1>"'
�151�e_, 'l!;�'(ffi� I
91. Sol": I 91il'l!l'J,il Gflffl CI 91il'l!l'.(ll' C5tll � � 1 �. P 91il'l!l'.(ll' olil '1ll"I � CI 91il'l!l'.(ll' 1SITTl'11 �'<l, � I
91il'l!l'.(ll' lil!rn<fl �'!II� -Ill I <JI� � q'!'llil '<llfilt'f Pi 5 �� -111
92. Sol": ��'1fl'5 HN03 : HCI = 1: 3 ��1
(i) 3HN03c,onc.) + 9HC1c,oncl-+ 6H2 0(t) + 3NOC1cg) + 6[Cl](aq)
2Auc,> + 6[Cllcaq ) -+ 2AuCl3(aqJ
2AuCl3 CaqJ + 2HC1c,onc.) -+ 2HAuCl 4caqJ
Clll<I '<l'tll', 3HNO,cconc) + llHClcconc) + 2Aucs) -+ 2HAuCl<(a q) + 6H 2 0(I) + 3NOCl(g)
t:t,V.'lil::.ifi'i<t-�Pfii
(ii) 2HN03c ,onc.) + 6HC1c,onc.) -+ 4H 2 0(t) + 2NOCl( g) + 4[Cl lcaq)
Ptcs> + 4[Cl]caq) -+ PtCl•(aq)
PtCl4 {a ) + 2HC1c,oncl-+ H2 PtCl6(aq)
q
Clll<l'<l'tll', 2HN03ccon c) + 8HC1c,onc) + Ptc ,>-+ H2 PtCl6(aqJ + 4H2 0(t) + 2NOC1cg)
t:t,l!'.'lilti18"f.i♦ <!!Pfii
93. Sol": .!l-'1 IA q'! .!F'1 I <Jlil 'li�'l'l,rk� llt'IJ u,co, � 151'i)C<iil'l � ffl9f f<lc�11%t"' � -IT I �z Na,co,
<:'I'�� TI'Ci1 l!iJ f<lrnlf€!"'� �-II�'., � � C<f'l'I CO 2 9fl'<l'!ll 111'C<f -1! 1 lll�il<I, .!F9f I <Jlil �l\li'l'l_C'lli >1C'IJ

•
C<f'<li1111ill LiNO, f<lrn11%i"' W-1 NO, <fJT>I �9fl! <ll'lll', 151'1) C<ll'R .!F'1 I � � ffi'1 f<lc�11%t"' W-1 NO, <fJT>I
tt.9fl!'<lltil-ll, <Iii�, 2KN03 -+ 2KN02 + 02 ; 'li'l:i'f, KN03 C<f'��TI'Ci'I C<f'l'I N02 <fJT>i 9fl'<l'lll'lll'l<f-ll 1
94. Sol": (i); F-151'l'1'11'1 c1-, ar-, ,- • 151Jl•@l'iil 'o/l<l'1il � � �'!llll c1-, er-•, 1- Ill� l.'1ii11ill�'i f-151'l'1'11'1
� �� 1 'IR"f, AgCI, AgBr <Jl<fZ Agl lllil >tlll<li$1 C:� AgF 151'l9f"l'l �. <lR!R'J, AgF � � �'<l
AgCI, AgBr, Agl � � � � 1
II);��
111-�
95. Sol": F2 <Jlil ffl 91il'l!l'.fll' � 151itlibil 1l,fi; 2p 151ilMGlli1il M:'>t'!f �Ci1<11'iil'iil 9fiil"'1fii<II M<IIWril 9ffifll'T<f CJ, lllil
ffl 91il'l!l'.fll' 3p Glilf<itlli1'ii R:� �Ci1�C'iil mt<fil 9ffifll'T'1 � � 1 �. F - f >tlll<ll� �
\lii1'illl,i1<11"'1l<I '1:f.,r � <Jl<f� Clf"ITTi'1 Gf'l >r<flml' <I'll� '<l >r<flml' � "1W1I 1151�. Cl2 Gl'lil � f<lt�liilt'1
� ajili11liilt'1>tlj_�il >!C'IJ>r<flm! ��'.Cl - Cl�� >r<flml' �1
96. Sol": [Cu(NH 3)4 )S04 c:iitc<f Cu <Jlil � '>t�'<llil<f � sp 2d 1 <Jlt'll'lul, dsp2 '>t�'<llil<f 151C<nRJ.'I' lll<f� � �<fJ
�'UI

)oo
Engineering Admission Program Concept Book C-02

[Cu(NH3 )4 ] z+ � 91Jml!JT� � Cuz+ � � � � lll<rt <r� � 1Rl3 >IIIGii!�

<r<frffl 1 � llll:5 f.miT@ �C'1<11]'1 K'll1>1 >l<l_C�IC'•1 � fof'1J1"5 (: NH 3) � mft �Cii<ll]'l <J_<fti'f sp 2 d >it<l'il'l
w,�.
3d 4s 4p 4d
CII I I I I I H3N:�:NH3

[DI: I: I I I: I
Cu2�

c'ltijAJl'lfit"I
H3N: :NH,
�(II)� (Cu(NH3),)'•
spld"""" "l•��'w-1
>III"'�� <r<frffl '1tr-Rf � dsp >it<l'il'l � sp d ffl � >!�TI''l � 1 � [Cu(NH3)4 J z+ � �
2 2

sp2 d >!�TI''l 1!� W, � � �'. dsp2 >IZ<l'il'l � 1 lll"l! ��.,!

(i) � Cuz+ � 3d 151il!4il1Ciiil � �Cii<ll]'lfi:;r.4 \S11>•1Rl,;;;i "/1f.r 4p 151il!4il1Ci1 ISl.'<liM"' TI'l:5�1 '3'>R
f.mlre, �Ci'i<ll]'l � �'1 � f.i''!Tr,o (: NH3 ) � mft �Cii<ll]'l <J.<ft"f dsp 2>!t<l'il'1 WC'G 9fITT I
3d 4s 4p
Cu 2 +
Ii J.liJ.liJ.I i I D I I 1
["I� 4P,'"'l:t"".,,.;<ifis.-,fflliJ JJW1illilil'1t'lf'1J�)
[Cu(NH3)4)2+ IiJ.li J.li J.I : I IJJ I : I : I i I
NH3 NH3 NH3 NH3

dsp2 'l�'l'if'I
(ii) IS� �'!! � dsp >!�TI'C'l<r v,c-., >1�4�/l'. 4P� 151ilf4CIC'1 � � �<11]'1 Ill!'! � Cuz+
2

� � � � 151f't!<li �Cul+ � <l'il1il � � � 1 � � Cuz+ � 151("'� �; Cu3+

l5ITll'C'lll' C<l'l'I � �I llll:5 � � (Cu(NH3) 4 ] 2+ � � dsp2 >IZTI''l W "'11 <rll'I! �� �
� �'- sp2d >it<l'il'1 W; '3'>R � �Cii<ll]'lfi:; 151-,,J-:iCil 3d 151ilf4CIC'1 � • .,fiiC4C"1 >it� �
Glrn'lfi:;{.<11 "'fJ1il1 � 11-.f � TI'1:5 >r"f'll <l'Cil I

97. Sol": all<l'�C6il 151-,,J-:ic.'!i <!lil>I IJ.C:81 ll'C'O' � Wlil lil!rn<JI "IIC'I', 151fflt<l', � 'll'C'O' <liR'I 9ffl'lil'l�Ci1l
.,'il'"1Cilil M<l'W � QflC<I' I '<l'Ci1, � 1511t� �� (3.51) all<l'�C6il "1TC� � � (2.25) 151C91"ff l5IC'!<I'
ffll
� � � �'.( 15191<r � � �'.('ii'� 'f\' <r'<i"C'1 Gimi Qff{.<111 '<l'Ci1, Ill<!' ll!<!'fi:; � � Ill<!' ll!<!'fi:;
l5lfi'5 �� 151''.( I � � � � <l'il1:5 � Gl>!�'>JJ "IWlr-il C - C <r'<i"I � <l'il1:5 � I Ill <ffi!C'l, � l5iGJ"3
� lll<!Z >!<l'i'f � 'll'C�J <l'fli'l"'li I

98. Sol": Br- lll<rt ,- lll<r 1511<i'll1 c,- lll<rt F- lll<r cml Glt'l'<i' � 1 '<l'Ci1, Br- Ill<!� ,- lll"l! ,.,iiili:@'l c,- lll<!Z F- 151'C9f"l'l
l5lt'l'<i' � � 1 '<l'Ci1, HgCl 2 ,AgF, AgCI <r� �'Cl Hgl2 ,AgBr lll<!ZAgl <r��1

99. Sol": Bez+ lll"l! l5lmll' Mg z+ lll"l! C5Clf l5IC'!<!' � �'llfll Bez+ � CJ- lll"l! C911'1ii@'l C4fil � �.
BeCl2 , MgeCl2 151'C9f"l'l 15if'� >IIIC�leil �>!"'Ill. Ill�, MgeCl2 (aq), BeCl2 (aq) 151'C9f"l'l151N<i' � � 1

100. Sol": lflG<r <i'i�C'lC6il � l5llll'C'lll' l5lmll' 11G ��. �il Gl)l'lmt'lil ,.,iiiii:@'l � C4fil� Ill<!� '<l'Ci1, lflG<r
<i'l�cAf;f{; "'�ffl"l 151�:it,, � 1151'4!'., ,.,iiilill-OC'lil '1flrlir'1 � 'liG'1I <i'l�l.'1C6il � <i'"Cli 1 �. al'., 2
lll<r � <i'i�C'ii:>IIJ.�il �� <l!'1I R!flli.,: BeCO, < MgCO, < CaCO, < sreo, < BaCO,
100°c 350°( S47°C 778"'C 998°(

101. Sol": ���l•if.l<i' �CQiiCll!f'l <i1i'I! Ill� <rT � � 9!Qf<i' 9!� 151'.(<r 'll'C'IJ � H-� � �. "lC<i' 151T<J'!1511ffl
aj�OlilCiilt'l <r'<i"I <rCi'i, �! HF, H2 0, CH3 COOH � 151'�,
Engineering Admission Program Concept Book C-02

��i'iM.,S ��tl'iiCIM q�g Ill� lol� � 1o1zm 'll'ClfJ • H � ��cm H � � W-1 Qflt<l' 1
Ill�'! H� � �'!!lt'I' �(Chelation)�� 1 fbti1'ir.'1g <1>lll'C'i �. � 1 Cll"'R (i) �1'1�ciilC¥'1'1;
C6 H4 (0H)N02 , (ii) l!iftqJ �f� r.<1'1<lfli1Ni:ift:15 C6 H4(0H)CHO, (ii1/ >iJIM>i�M<I' lllffi C6 H4(0H)COOH <oi'.li!
��cm
'll'CIIJ H-� � I
O-H
�= 6
'i'
rA-('0- rA('
�N➔O
II I
H
ISlt4i'1�1C..'1C'I ISlt4i�i,il� ,.,.,..,,,��"'
"RJ!ISl!'fm' H-� "RJ!ISl!'fm' H-'IW!
102. Sol": Cl ll!qz N ll!;l � 'il'il\ill'l>"'I (3.0) � �m � Cl llli! 91Wi!cm qjf>II� (9.9x10-2 nm) > N ll!;l
91Wil'ffl qjf>II� (7x10-2nm) �WI 'ffl'C'i, Cl :ll�tl'iiCiet'i � � <RCl3 91ml -II Fl''lt '1�1C<et'i '11ti'l I Cll"'R!
lol)ICIIIM-0I (NH,) 1
103. Sol": NH, , Hz0, HF lll<lz �Cqj'1(.i1g � Rl!i 1o1•.r�rCi11l! 'll'CIIJ loll<l�'ffl :ift:!lli1Cei'1 � ffiTl!A � 1 ,J)jf 11'"C"f,
Ill� <ll"9f <RCl3 WI �"r.'11 :ift:!lliiCiet'i � �c'\o � �. � C<IM °'1Rli i1rt<I I '5191iWit<I',
PH3, H2 S, HCI lll<Jz 15�fileq� � � Rl!i 151�1:iiTl! 'll'ClfJ C'l>R H-� �. 1l'"C"f l!if"""'f \OIC� <1141�"' <!'ill
11'lli 1
104. Sol": CuS04 . SH2 0 lll;l <IF-I
R!/lli91!
H H
I I
H-O-..,. ,.....--O-H ·.. H····Ot<-..... /o-
/
Cu2+
·o S
H-0_.,.;, <'-.....0-H···· ......_H····OV ......_0_
I I
H H
Cl!� 9!00 11ll'l cu z+ llli! >iTCQI � � �. %l11so 0c ;;,,,,,11,ili,� '51� � �- '1'l31il <11 �
9!00 lol'l
ClJji; mm >ittlll<r "llllffl! � <l'l<et � C>f1ms 11ll91>!1l!<i <l'l!l m�
IJlqt 260°c \OJ'f"IITim
��I
0 0
1 1
105. Sol": H 2 S20 8 ; H -0 - S -0 -0 - S -0 -H
J J
0 0
1l_ft <51f�C<et'i "1l11114l '1911i"'g<51"''!1:an'!I�"""'<l'<ir.'1 � �. H2 S2 08 � S llli! 1S!ll!'i 111'1 x WI,
2x(+l) + 2x + 6x(-1) + 2x(-1) = 0 :. x = (+6) �TZ H 2 S2 08 � S llli!�'i 111'1 (+6)
0
II
Cr05; ,..,..er,
O'C{ b:.O
� \:Sl�C<et'i 9li!1ll'J. '1lgi51'91�15 qffl � �. Cr0 5 � Cr llli! "eill!'I 111'1 x WI,
x + 4x(-1) + lx(-2) = 0 :. x = (+6) �t Cr05 � Cr llli!"eill!'i 111'1 (+6) I
106. Sol": (i) [Cu(NH,).Jso. ➔ �i'51Jlllfil'1 <P911il (II) >ili1Cll''il
(ii) [Co(NH3)6)Cl3 ➔ Cil_'!li'51Jlllfil'1 ,� (lll) C;!jllgi�
(iii) [Zn(NH3)4)S04 ➔ �l\51Jlllfil'1 �Z<l' (II) >ili1Cl!'il
(iv) [Ag(NH3)2 )CI ➔ � lol)lllfil'1 � (I) C;!jligi�
(v) [Co(NH3)3Cl3) ➔.ii�ICg(ii� '51Jlllfil'1 ,� (Ill) C;!lllg�
(vi) [Cr(H2 0)4 Cl 2 )CI ➔ �I<51ll1�I15�(JIICill C;!lllfil-OIII lilf) C;!lllg�
(vii) [Cr(H 20)3Cl3) ➔ � '51)1<]?-0(ii�ICill ()l)'lfil-0I11 (lll/ C;!lllg�
(viii) K3 [Fe(CN)6) ➔ 91'illf3rnlll C�'!li>ilMr.'1I ,<i'Cil'il (Ill)
Eng Rahul Sir Concept Book C-02

107. Sol": Nz 151'.{l! 11C�� N 9Rflll'l 91il"'91il � >IIIC<li� q'.fiOI��� f<ii¥, Oz� 11C�� 0 9Rflll'l 91il"'91il
� >IIIC�ie!J ����I 'fl"llffl, Oz 151'.{l! "1'til! � '<>lf$C<lt'1 9Rflll'JP5 � � � � e- �
'<>I� Nz '<>l'.{l! � N 9Rflll'.tt'311Tili 1 C'!!fll!il 'J:eiC<ltli(; e- � I 1Ri'f, Oz � � 0 9Rflll'.{l! 11C� m'f, Nz 151'.{l!
� N 9Rflll'.{l! 11C� m'f '<>It� GIC'1<I' Cq'f-f �I �. Nz 15!'J. Oz '<>l'l '<>1t91"1'1 '<>if���<mlI
108. Sol": p - p a� "1'til! '>I�� '<>lilf<itli1 � � �� '<>lfi\iili'IIC•ll! � GlC'1<1'6I � � '<>if'fili'll �.
'<>I'� '<>If� � (area of over lapping) Wffil Cq'f-f � 1 � tvm p - p a q'.fiOI � 'i1I '<l � � 1
s - p a� C"R<ll, s '<>lilMGICi1il � -II Qff<ll1il � p '<>lilMGICi1il C'IR)ll �� s - p � � � 1
<!lt"Ral '<>If� "1'til!il (area of overlapping) Wffil � 1 � s - p a�� '<l � � � 1
s -s a� C"R<ll, s GlilMGICi1il C<l'TC'1l � -II � 1Sf-!J' '<>If� � Wffil � <l"I! � 1 �
S-S a���I
109. Sol":� T§ffil'f �: (<l'lC'!f Rr"f1I Cllli100'1 � '>l'lf!f � q'! �t!<I' T§ffil'f 11A �<ml��
T§ffil'f '>it-.0, � � � � 'i<<li(IJ<i>\6iil 'IT'!'<l � 9fll!I Clfll'I-
Cllli1 q'! '<>ITlT'1 T§ffil'I '>IZSIJI � '1!•1111,i<l>'Oi
Fe 0 1.80
feZ +
+2 1.83
+3 1.96
- -
fel+
•
'<J�ll>��"l f'U CH3 CH3, CHz - CHz '<l CH - CH <!I � "11c'lil 11C� <!l<l'fi; >il'lll!'I 9Rflll'l <!'WI 1 "1lc'lil
11C� 'llA'I 'fllm'.{l! � '<lt•li(IJ<l>'OI f.i"m 'Rtl6 � C<l>T'l '51'.tt'3 'llA'I 9Rflll'.{l! C<i>T'I �� ��i1i�C<lt"1'1 �
161 '<ltf'11 QfT<i>I � I �Ctl�'O 00'1 fi\i'1ff;c-,, � �il,�•M lf� sp3 , spZ '<l sp I <!IOOl 11C,o' s-$
lf� 25%, 33.33% '<l 50% 1 sp 3, sp z , sp � GlllMGICi1 s-<!l;l $ � � � <!'WI 9llrlll'.{l! "'�"'
'1!'1111,l'<!' 'IIA'G � 9fll! I ClflR-
<!'WI 'fllm'.(l! 00'1 'llA'l 'fllm'.(l! �ili�·M "'�� 'i!'II1/J<l>\61
CH3 - CH3 sp' 2.48
(Hz= (H z s p - 2.75
CH= CH Sp 3.24
110. Sol": Be(4)-+ fill fill; 2s Orbital 'ITTl'l_<f

1W !WITgJI] ; 2p Orbital '<>l�'l_<f

ts2 zs2
N (7)-+
ts Zs Zp

Mg(12)-+ITI] fill�l1��1-H�!,��llill; 3s0rbital 'ITTl'l_<f

ts 2 zs2 z p6 3s2

P(lS)-+ ITI] [TIU1q1q1

ts 2 zs2 Zp6
�IITIJ!Igp] ;
3s2 3p
3p Orbital �'l.<f

� Be, N, Mg, P <!I� �Ci1'1\1i'1 �!'11 GIC'1<I' Cq'f-f �"11-,, �. B,0,Al, S lf� Be, N, Mg, P <!l;l l51r'1
� <l'ilf �(; <1Jfi;;Jj.il\1SIC<i Be, N, Mg, P <!Iii '<>lm�<i>il•I � lf� 8,0,AI, S '<>lt'f"ff Cq'f-f � 1
111. Sol": Na•<!iqz Ne <!Jg �Ci141]'1 W!Jl>I <!I� �'G, Na• <!I � '>it-.0, 1 llt IJ!qt Ne <!I C� '>IZsfJI 1off; 1
1Ri'f, Na• <!l;l , ,it�� iofl; �i1«G'1. qCi1 ��I �, Na• � '<>llil'G <!I� e- C'fl! 'Rtl6
Ne� llt e- C<lilTI'lil CoC!l'51C'1<1> Cq'f-f "1fui fi\t\6� I '<>I'�, Na+ <!Jg Gll9�<i>il•1� Ne '<>It�� Cq'f-fI
112. Sol": �'1Ii1IilmC'1ll <l>lil'C'I Cd <!l<i� lig '<>l<l!ll-:iil Clll'1-!I �m �(; CdS � <!l<i� HgO '<l HgS i'fli! qec.fjj � 1
3d :
I: I: I: I:;! C'f-.rp11�'<>lm-1ff;c-,, 1lt�e-i�1
4s
I:
4p �
113. Sol": [Fe(CN).J3- -+!1�11�111: 11I]
;acor or �Ot"""CN
dlop3 'l<'Hil'i
:. [Fe(CN)6 ]3 - '<>lrn'$ '1JilllllJl'tC'1ff;<I> I
Engineering Admission Program Concept Book C-02

:. [Fe(CN)6 ]4 - ���I
-�
114. Sol": 25mg H "Rflll'.l = - -mole H atom= 25 x 10-3 x6.023x1023 H atom= 1.50575x1022 atom
,
�t, �--lfu; �= 1.50575x1022 x13.6xl.6x10-' 9J = 32765.12 Joule= 32.76512 KJ (Ans.)
115. Sol": o!IC�i"l�� ff E �' E= 0.75x6.023x1023 x5.14043xl.6x10-19 J
= 371529.7187) = 371.5297187 KJ (Ans.)
116. Sol": He+ "Rflll'.('11 loll��<lliM� KJ mo1e-1 s!I��. 3.9387x10-'8 x6.023x1023 x10-3 KJ mole-•
= 2372.27901 KJ mole-'
. �=-,..,.,.7298
:. L1+ �'111511U�'I'll'!'"""'
=... He �'111511� i'l'li'I •�""-��
2372.2790,
�<f = 3 �<f (o!lfll) (Ans.)

,er,,
117. Sol":
3d 4s 4p
11�11�11�11 111RO I I I
Ni(iS)➔
,�Ni�,
3d 4s 4p �,---- 1:---<;0
Ni(C0),➔ 11�11�11�11�11�1 IT] I: I: I: I
cffilt�
',, \ ,'
si>3� ',co'
ffil"I' (0)
�4HI '1R
� � C'IT<f Ni(C0)4 � �mil 'ill s!itG C<ll'FI � �Cii<II]� ,�1 1R"f Ni(C0)4 s!iil Cffi4 tnf �
\Sl�IIIJl•t�lil'l' 1
118. Sol": >tlii<l'/8:15 (s2 -) � � � (0 2 -) � � GIC"'f"l'I � �mil >jjijljl� '5!flll'f'll ,111'11llm�
��I s!lil<R"I >tiii<l'i�>t'!_� 151')1�\S>t'!_� "'11:�� >tllt.41� �I

119. Sol": Crs!ill loli'l'Hf<n l•J Ci!l'illi'® q1 Gll'flr�C'tr-1 ➔ Fe0.Cr2 03

(ii) Ci!l'l'll'8!41il (t.ili'IN'I' �) ➔ Cr2 03
(iii) Ci!l'l'I'� (til\S �) ➔ PbCr04

(i) IIJl'l�'il� ➔ Fe,o,

(ii) � �iGi�'il ➔ Fe2 03
(iii) MCiii�1'9:'il q'f �'I �iGi�'il ➔ 2Fe2 0,. 3H2 0
(iv)� <11 >tl�C\Sili® ➔ FeC03
(v) �'I 91�il�1:>t ➔ FeS2

(i) >!1'16� q'f� or;rot ➔ (Co,Ni,Fe)As2

(ii) r.41<11-ti® <l1 c<mlit UJl"I ➔ (Co, As)S
(iii) M�l>t� ➔ (Fe, Co, Ni)3 S4

Ni s!lll 1511'1'M<11¥ (i) C1-i:'1Jl�i51'8:i; ➔ (Ni, Cu, Fe)S

(ii) >tiiiitli'® <l'I� � ➔ (Ni, Co, Fe)As2
(iii) filfollli® ➔ NiS
(iv) MC41'11'8:i; ➔ NiAs
(v) f.lC<lli'f UJl"I ➔ NiAsS
(vi) •iiilMfiill/® ➔ (Ni. Mg)Si03 . xH2 0
)08
 Concept Book C-02

(i) <l'"fll! UJl'>I ➔ Cu 2S

(ii) <l'"fll! "11�1�'! ➔ CuFeS 2 q'f Cu2 S. Fe2 S3
(iii) i1Jli1I<1'f® ➔ CuC0 3 . Cu(OH)2
(iv) 151Jlf)ll�_il ➔ 2CuC0 3 . Cu(OH)2
(v) i1Jli1IC<l'l'1� ➔ CuO
(vi) "l'�otlc.<1'I'1I ➔ CuSi03 . 2H 2 0

Zn cl-,:i 151I<1'Ri<l'i (i)ffl � ➔ ZnS

(ii) <l'Jli1I• �'1 ➔ ZnC0 3
(iii) fet-1>tf® ➔ ZnO
120. Sol": S8 1151'.(il � >ri'ffil'!G IJ:t'illtlibil o!<rt � f.wlli9fg
$\ /$
/ $ \
s
s� / '-s
105' $
clt'3 � C<l'T'I 105° o!<rt � S-S <rlfi'I MCfii<lt'1 � 264 KJmole-1 1 "11'1 � � �� S-S <N'1
i51W3 � 11'lil � l5IC'1<I' � � �O,olil' C"Ral ol�O = 0�(498KJmole- 1)� �I
�. S8 <oi"J. � 11llTi1T'il � S C9lt'3 1511:'!<ji C'lfil � �. �. >tli1<l'l!.llil >tPi-fil!il <!llf�CietC'1il >tlJ!.fil!il
C"IC<li <l'S! � I
121. Sol 0 : � 11lf1ib <fW q1 'f'lmJ'6 � c1Pft15il '>lt""IM � clil t9fil Fe 3 0 4 clil cl� �9f � 111 cl'C<I'
Passive q'f RW!I <jiCll Cll"C"f �t.. 11ll'!J' C<l'ft-1114Pi-m.<l'il >1t""IM � <.'f!I "!I 1
:. olil'9fil � HCI olil'� cl� Passive � <.<l'l'1 MPi-fi� <P� "!1151�. C<l'T'1 � l;�'fl!� � "!11
Na•[-0
122. Sol": _ 's(:] � Na 2S04
Na+ of

>J.<6ill�. '1""11"'�· Na,so. "11<$cl6fw-! lfll'C'1l!�-1 M'i)iil'1, �� (S ➔ 0), 11.it >tiiCql� ls- o-) c1<rz11.it
�(=::soi-). >J.'6il11., C1lfil 3 lfll'C'1il o!<rt (2 + 2 + 2) = 6� �., M'iliil-11
H3 N N� ll+
3

\, NH3
[ ( ✓
,m,I' r°'NH 3
NH,

cl>/TC'1, NH, olil' 1/Ct(J (H - !- H) � (N- H) >tiiCql&\ <rlfi'I M'iliil'1, (H,N ➔Co)� <r'<i'1 cl<!t

([Co(NH3 )6 ) 3+, 3CI-) clil 1/Ct(J ��-, M'iliil-11 'J.13ilf1.. C1llil 3 lfll'C'1il �� cl<rt C1llil (3x6 + 6 + 3) =
27���1
123. Sol 0 CH 2 = CH - C = CH dil<$cl6 7 � Pl<flll <rlfi'I (C - H 4� cl<rt C - C 3 jtJ o!<rt 3 � � � ffiJlfA
:

� I � � C "Rfl!f'J. � '>lt<l'il'f sp 2 cl<rt � � C "Rfl!f'J. � '>IZ<l'il'I sp I

Solution to Practice Problems C:\ICQ)

124. Ans. (b) 125.Ans.(a) 126. Ans.(d) 127. Ans. (b)
128. Ans. (a) 129.Ans.(c) 130. Ans.(a) 131.Ans. (c)
132. Ans. (a) 133.Ans.(d) 134. Ans.(c) 135.Ans. (a)
136.Ans. (d) 137.Ans.(d) 138. Ans. (d) 139.Ans. (c)
140. Ans. (b) 141.Ans.(a) 142. Ans. (d) 143.Ans. (d)
Eng Rahul Sir. Concept Book C-02

144. Ans. (b) 145.Ans. (b) 146. Ans. (c) 147.Ans. (c)
148. Ans. (c) 149.Ans. (b) 150. Ans. (b) 151.Ans. (c)
152. Ans. (b) 153.Ans. (b) 154. Ans. (d) 155.Ans. (b)
156. Ans. (a) 157. Ans. (a) 158. Ans. (d) 159. Ans. (a)
160. Ans. (a) 161. Ans. (a) 162. Ans. (a) 163. Ans. (d)
164. Ans. (d) 165. Ans. (b) 166. Ans. (d) 167.Ans. (b)
168. Ans. (c) 169. Ans. (b) 170. Ans. (b) 171.Ans. (a)
172. Ans. (a) 173. Ans. (c) 174. Ans. (c) 175. Ans. (b)
176. Ans. (a) 177. Ans. (a) 178. Ans. (a) 179. Ans. (d)
180. Ans. (b) 181. Ans. (d) 182. Ans. (b) 183. Ans. (a)
184. Ans. (c) 185.Ans. (a) 186. Ans. (b) 187.Ans. (a)
188. Ans. (d) 189.Ans. (c) 190. Ans. (a) 191.Ans. (b)
192. Ans. (d) 193.Ans. (c) 194. Ans. (a) 195. Ans. (c)
196. Ans. (a) 197.Ans. (c) 198. Ans. (a) 199.Ans. (d)
200. Ans. (a) 201.Ans. (c) 202. Ans. (a) 203.Ans. (b)
204. Ans. (d) 205. Ans. (c) 206. Ans. (a) 207. s01•: (c); ◊�-N.,.o
'O
208. Ans. (d) 209. Ans. (c) 210. Ans. (d) 211. Ans. (b)
212. Ans. (d) 213. Ans. (b) 214. Ans. (b) 215.Ans. (c)
216. Ans. (b) 217.Ans. (c) 218. Ans. (c) 219. Ans. (b)
220. Ans. (b) 221. Ans. (a) 222. Ans. (b) 223. Ans. (c)
224. Ans. (c) 225.Ans. (c) 226. Ans. (a) 227. Ans. (c)
228. Ans. (d) 229. Ans. (b) 230. Ans. (a) 231.Ans. (b)
232.Ans. (c) 233.Ans. (d) 234. Ans. (d) 235. Ans. (a)
236. Ans. (d) 237. Ans. (d) 238. Ans. (b) 239.Ans. (a)
240.Ans. (a) 241.Ans. (b) 242. Ans. (c) 243.Ans. (b)
244. Ans. (a) 245. Ans. (a) 246. Ans. (b) 247.Ans. (a)
248. Ans. (c) 249. Ans. (c) 250. Ans. (d) 251.Ans. (c)
252. Ans. (b) 253. Ans. (b) 254. Ans. (a) 255. Ans. (c)
256. Ans. (b) 257. Ans. (b) 258. Ans. (a) 259. Ans. (a)
260.Ans. (b) 261.Ans. (d) 262. Ans. (b) 263.Ans. (b)
264. Ans. (c) 265. Ans. (a) 266. Ans. (d) 267. Ans. (c)
268. Ans. (c) 269. Ans. (d) 270. Ans. (a) 271.Ans. (b)
272. Ans. (c) 273. Ans. (a) 274. Ans. (b) 275. Ans. (b)
276.Ans. (b) 277. Ans. (a) 278. Ans. (c) 279. Ans. (b)
280.Ans. (a) 281. Ans. (a) 282. Ans. (b) 283. Ans. (a)
284. Ans. (b) 285. Ans. (a) 286. Ans. (c) 287.Ans. (c)
288. Ans. (c) 289.Ans. (d) 290. Ans. (c) 291.Ans. (c)
292. Ans. (a) 293. Ans. (b) 294. Ans. (a) 295. Ans. (c)
296. Ans. (c) 297. Ans. (d) 298. Ans. (d) 299.Ans. (d)
300. Ans. (b) 301. Ans. (b) 302. Ans. (c) 303. Ans. (b)
304. Ans. (a)
Eng Rahul Sir. Mobile-01965687679 )o� 91f\lq<5t.'l� ,:fG)t11 � "1'io"II...
 Concept Book C-02

SMS Exam
>!<I""��
IExam Code: EC1602I
01. elf "1W!l-
(i) NaBr, BaF2 , CsCI, KCI (ii) NaCl, HCJ, JCI, BeF, (iii) NF3, BaF,. F20, H2S
f.rmr�·?
(a) i (b) ii (c) i, ii (d) ii,iii
02. NH, 151<J:tl3 LHNH = 107.8 � ?fm151<J:tl3 LHOH = 104.4 <l'lil'1-
° °

(i) 151HIIC'St'i "1�1:yIc¾C'lil ,mr� � (ii) 1o1Rilc'at'l 'lf�1:yIC'StC'iil C5Cll "Ii!;� 'II�
(iii) 151HIIC'StC'ili � � f.t>f'! �Ci'l<l\ii'i � l5llil 'i�CijiC6tC'lil � <JI�
f.rmr�·?
(a) i, iii (b) ii, iii (c) i (d) iii
03. POC'3 <Jlil11C>j)'Clf lfll'C'iil��
(i)��� (ii)<Jl.$�� (iii)� >tllC<ll� q'<i'l
f.rmr�·?

IAl•l 1�1 1
E
(a) i, ii (b) ii, iii (c) i, iii (d) i, ii, iii
f.rmr � 151IC"IIC<II 04 '<l 05 "I�� ffl 'ff'G:

04. � 91WIT'!W<!' 1511<l'liPR'cml �?

(a) A (b) B (c) C (d) D
05. A '<l D � c:'!lc'lil C'lvli-
(i) R!! 'lil'llt<I' ��� �
(iii) <Jl'l'RI 1fC>j)' electrostatic force <l'l'at <l'Cil
f.rmr�·?
(a) i, ii (b) ii, iii (c) i, iii (d) i, ii, iii
f.rmr� Gill"IIC.,S 06 '<l 07 'it �fflll'l'S:
c>lta, omrsllcfm! 'fto/JT
A 11
B 12
C 17
D 9
06. r:<l'f'I � c•rnIiltl!i �C"l<l\ii'l � f.iC'Stil � <-UC'! C'll!RI � �?
OOA OOB ooc (d) D
07. r:<!'A c:'!1<$151f'll<li >tllC<li� tnf C'i-.rro?
(a) AC (b) AD (c) BC2 (d) 802
08. Na, [Co (NOz)•J <Jlil IUPAC "ITl!-
(a) Sodium cobaltinitrite (b) Sodium hexanitritcobaltate (111)
(c) Sodium hexanitrocobalt (111) (d) Sodium hexanitrocobaltate (111)
f.rmr� ISIIC'IIW 09 '<l 10 "I��ffl1"'S:
Engineering Admission Program Concept Book C-02

-
09. �9fCifll' � .\St •l�IC'!�Pl�<i>g \olilMCii1 � -ml?
(a)sp (b)spz (c)sp' (d) sp'd
10. �'IC<l' Cl! '>!�<Rm'! �\OlilT§f-!/ C<l'f'! � �� �?
(a) >!fflWI (b) >t�C�i.s!l (c) cr - � (d) re-�

�=
�: C>iis�C>tg message opcion-"1 f'mr UDV EC 1602: f.lN l5R!'lll m
=m
1519M'!Gf.r �'I 'l't1I � 'il'6 03598359835 '!'ffi! I
ffl 'Rre-ll � C>t"1t'! "1� space 'il'61 l'I'!'!: UDV EC1602:ab dcacb c (3 "1<!� 9 '!� l'rnT �) 1)