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Eqms India Pvt. LTD.: Environmental Impact Assessment Report For Expansion of Chemicals and Apis Production Unit. by
Eqms India Pvt. LTD.: Environmental Impact Assessment Report For Expansion of Chemicals and Apis Production Unit. by
Eqms India Pvt. LTD.: Environmental Impact Assessment Report For Expansion of Chemicals and Apis Production Unit. by
Unit.
By
December, 2018
Table of Contents
Chapter 1. INTRODUCTION ...................................................................................... 12
1.1. IMPORTANCE AND NEED OF AN EIA ................................................................... 12
1.2. PROJECT & PROJECT PROPONENT ................................................................... 12
1.3. IMPORTANCE AND BENEFIT OF THE PROJECT ................................................. 13
1.4. PURPOSE OF THE EIA STUDY ............................................................................. 14
1.5. PROJECT LOCATION ............................................................................................ 14
1.6. REGULATORY FRAMEWORK ............................................................................... 17
1.7. PUBLIC HEARING .................................................................................................. 17
1.8. SCOPE & METHODOLOGY OF THE STUDY......................................................... 22
1.9. APPROVED TERMS OF REFERENCE FOR EIA STUDY BY EAC ........................ 23
1.8.1 TOR Compliance Status ........................................................................... 23
1.10. STRUCTURE OF THE REPORT............................................................................. 31
Chapter 2. Project Description .................................................................................... 33
2.1. NEED AND JUSTIFICATION OF THE PROJECT ................................................... 34
2.2. SITE DETAILS AND LOCATION ............................................................................. 34
i. Site Location ............................................................................................. 34
2.3. Approach to Site ...................................................................................................... 36
2.4. LAND REQUIREMENT ........................................................................................... 36
2.5. PRODUCTS WITH CAPACITIES FOR THE PROPOSED PROJECTS ................... 38
2.6. MANUFACTURING PROCESS ............................................................................... 40
2.7. DETAILS OF RAW MATERIALS, CONSUMPTION AND SOURCE ...................... 109
2.7.2. Raw Material Storage (Liquids) ............................................................... 119
2.8. INFRASTRUCTURE & UTILITIES REQUIRED FOR THE EXPANSION PROJECT
119
2.8.1. Land ........................................................................................................ 119
2.8.2. Water ...................................................................................................... 119
2.8.3. Power ..................................................................................................... 121
2.8.4. Boiler ...................................................................................................... 121
2.8.5. Fuel ......................................................................................................... 121
2.8.6. Man Power .............................................................................................. 122
2.8.7. Facilities for worker ................................................................................. 122
2.8.8. Wastewater treatment: ............................................................................ 122
List of Tables
Table 1.1 : Details of permits and clearance applicable....................................................... 17
Table 1.2 : Compliance Status of Terms of Reference ........................................................ 24
Table 2.1 : Salient features ................................................................................................. 34
Table 2.2 : Land Distribution at site ..................................................................................... 36
Table 2.3 : List of Products.................................................................................................. 38
Table 2.4 : List of Raw materials, consumption and its source .......................................... 109
Table 2.5 : Area Breakup .................................................................................................. 119
Table 2.6 : Water Breakup ................................................................................................ 119
Table 2.7 Stacks in the API Plant with emission details ..................................................... 131
Table 2.8 : Hazardous waste details ................................................................................. 134
Table 3.1 : Salient Environmental Features of Proposed Site............................................ 140
Table 3.2 : Summary of Methodology for Primary/Secondary Baseline Data Collection .... 144
Table 3.3 : Land use of the Study Area ............................................................................. 150
Table 3.4 Long Term Meteorological Data of Ludiana (30 years average) ........................ 152
Table 3.5 Site Specific Meteorological Data ...................................................................... 153
Table 3.6 : Ambient Air Quality Monitoring Locations ........................................................ 155
Table 3.7 : Ambient Air Quality Monitoring Results for PM2.5 and PM10(24-hour average)
.................................................................................................................................. 156
Table 3.7 Conti... Ambient Air Quality Monitoring Results for SOx and NOx (24-hrs avg.) 156
Table 3.7 Conti... Ambient Air Quality Monitoring Results for SOx and NOx (24-hrs avg.) 156
Table 3.8 Month wise AAQ Data (Jan to May 2018) .......................................................... 158
Table 3.9 Ambient Noise Quality Monitoring Locations ..................................................... 158
Table 3.10 Ambient Noise Quality in the Study Area ......................................................... 159
Table 3.11 Ground Water Sampling Locations .................................................................. 160
Table 3.12 Ground Water Quality in the Study Area .......................................................... 161
Table 3.15 Continued..........Ground Water Quality in the Study Area ............................... 162
Observation on Water Quality ........................................................................................... 164
Ground water .................................................................................................................... 164
Table 3.13 CPCB Best Designated Use Standard (Source-CPCB) ................................... 164
Table 3.14 Sampling Location Surface Water ................................................................... 165
Table 3.15 Surface Water Quality in the Study Area ......................................................... 166
Table 3.16 : Soil Sampling Locations ................................................................................ 169
Table 3.17 Physiochemical Characteristics of Soil ............................................................ 169
Table 3.18 Type of Forest in Barnala District .................................................................... 171
Table 3.19 List of Common Plant Species Present in Study Area ..................................... 172
Table 3.20 List of Medicinal Plants and their Medicinal Value ........................................... 174
Table 3.21 : Mammalian Fauna reported in study area ..................................................... 176
*Conservation status is LC (Least Concerned species) ..................................................... 176
Table 3.22 : Reptiles and Amphibian observed in Study Area ........................................... 176
Table 3.23 : Avifauna Sighted during the primary survey .................................................. 177
Table 3.24 : Caste-wise Population Distribution of 2.0-km Radial Study Zone................... 179
Table 3.25 : Caste wise Population Distribution of 10-km Radial Study Area .................... 180
Table 3.26 : Male-female wise Literates & Illiterates ......................................................... 182
Table 3.27 Distribution of Work Participation Rate ............................................................ 184
Table 3.28 Village wise Occupational Pattern in the Study Area ....................................... 185
Table 3.29 : Composition of Non-Workers......................................................................... 187
Table 3.30 Village wise Basic Amenities Availability ......................................................... 191
Table 4.1 : Stack emissions .............................................................................................. 197
Table 4.2 : Summary of Maximum 24-hour Incremental GLC due to the Proposed Project
Stacks ........................................................................................................................ 198
Table 4.3 Ambient Air Quality Monitoring Results (24-hour average) ................................ 198
Table 4.4 Ambient Air Quality Monitoring Results (24-hour average) ................................ 198
Table 5.1 : Design Features for Minimization of Fugitive Emissions .................................. 214
Table 5.2 : Ambient air environment impact and management plan................................... 214
Table 5.3 : Ambient noise environment impact and management plan .............................. 216
Table 5.4 : Water environment impact and management plan ........................................... 218
Table 5.5 : Impact and management plan ......................................................................... 222
Table 5.6 : Budget for environmental management plan ................................................... 229
List of Figures
Figure 1.1 : Plant coordinates ............................................................................................. 15
Figure 1.2 : Project Location (on Toposheet) ...................................................................... 16
Figure 2.1 : Project Location Map ....................................................................................... 35
Figure 2.2 : Site Layout ....................................................................................................... 37
Figure 2.3 : Process flow diagram ....................................................................................... 42
Figure 2.4 : Process flow diagram of Acetic Anhydride........................................................ 44
Figure 2.5 : Process flow diagram ....................................................................................... 46
Figure 2.6 : Process flow diagram of Iso Butyl benzene ...................................................... 48
Figure 2.7 :Process flow diagram of Diclofenac Sodium ...................................................... 49
Figure 2.8 : Process flow diagram of Metformin Hydrochloride ............................................ 51
Figure 2.9 : Process flow diagram of Fenofibrate ................................................................ 52
Figure 2.10 : Process flow diagram of Clopidogrel Bisulphate ............................................. 55
Figure 2.11 : Process flow diagram of Amlodipine ............................................................... 59
Figure 2.12 : Process Flow diagram of Ibuprofen ................................................................ 63
Figure 2.13 : Process Flow Diagram ................................................................................... 65
Figure 2.14 : Process flow diagram ..................................................................................... 67
Figure 2.15 : Process flow diagram ..................................................................................... 68
Figure 2.16 Process flow diagram Ursodeoxycholic acid ..................................................... 71
Figure 2.17 : Process flow diagram ..................................................................................... 74
Figure 2.18 : Process flow diagram ..................................................................................... 76
Figure 2.19 Process flow diagram ....................................................................................... 78
Figure 2.20 : Process flow diagram ..................................................................................... 82
Material balance of of Pentaprozole .................................................................................... 82
Figure 2.21 : Process flow diagram ..................................................................................... 86
Figure 2.22 : Process flow diagram ..................................................................................... 89
Figure 2.23 : Process flow diagram ..................................................................................... 90
Figure 2.24 : Process flow diagram ..................................................................................... 91
Figure 2.25 : Process flow diagram ..................................................................................... 94
Figure 2.26 : Process flow diagram ..................................................................................... 97
Figure 2.27 : Process flow diagram ..................................................................................... 99
Figure 2.28 : Process flow diagram ..................................................................................... 99
Figure 2.29 : Process flow diagram ................................................................................... 100
Figure 2.30 :Process flow diagram .................................................................................... 101
Figure 2.31 : Process flow diagram ................................................................................... 102
Figure 2.32 : Process flow diagram ................................................................................... 103
Figure 2.33 : Process flow diagram ................................................................................... 104
EQMS India Pvt. Ltd. 9
EIA/EMP Report for Expansion of Chemicals and APIs production unit by IOLCP
List of Annexure
Annexure I : Nabet Certificate
Annexure VIII : Surface water permission and Letter for Ground water abstraction
permission
EXECUTIVE SUMMARY
PUBLIC HEARING
As per Ministry of Environment and Forest, GOI, New Delhi vide its Notification No. S.O.1533
dated September 14, 2006 and subsequent amendment thereof. A draft EIA report has
submitted (Prepared as per prescribe TOR) at Punjab Pollution Control Board report. Further an
advertisement was published in three prominent newspapers, ‘The Tribune’, ‘Ajit’ and
‘Spokesman’ dated 25 Sep 2018. In the presence of ADC-Barnala, Representative of Punjab
Pollution Control Board, Patiala & Regional office PPCB, Sangrur with near by public, Public
Hearing was conducted on 26th Oct 2018 at Village Fatehgarh Channa, Mansa Road, Barnala,
Punjab for the Proposed Expansion of Chemicals and APIs production unit, from capacity of
543.45 TPD to 671.95 TPD by M/s IOL Chemicals & Pharmaceuticals Limited. which is covered
under Category-A. Most of the issue raised during public hearing were related to employment,
CSR and clarity oriented related to environmental aspects and the proceeding are addressed
Project Description:
The present EIA study covers enhancement of existing capacity and addition of new products
hence the capacity increases from 543.45 TPD to 671.95 TPD for the manufacturing of bulk
drug and API drugs production unit. IOLCP has applied for TOR in 19 April 2018 and Standard
TOR has been issued on 1st June 2018.
All the products are not manufactured at a time. The likely production capacities of the products
will depend upon market demand but limited to the sanctioned capacity as mentioned above.
Description of Environment:
Primary baseline data has been collected as per the TOR prescribed by MOEF during 15th
March 2018 to 15th June 2018 for one complete season Baseline Data was generated by
following the standard procedures of the Ministry of Environment & Forests and the Central
Pollution Control Board.
Air Environment: Ambient air quality was monitored at eight locations in the study area. The
locations were selected as per CPCB guidelines. The mean concentration of PM2.5 in all location
ranges between 42 to 48 µg/m3.. The mean concentration of PM10 in all location ranges between
85 to 93 µg/m3 This may be due to the dust generated from thrashing of Wheat crop in the
agricultural field, presence of industries in addition to plying of heavy traffic such as trucks and
other combustion engine vehicles in nearby roads. Mean value are found well within National
Ambient Air Quality standards. SO2 level in all the location ranges between 6.2-20.5 µg/m3,
NOx level in all the location ranges between 14.0-41.2 µg/m3, which was found well within
National Ambient Air Quality standards i.e. NAAQMS (80µg/m3). The NH3 level in all monitoring
locations ranges between 9 to 23 µg/m3. The NH3 level in all monitoring location is under
permissible limit i.e. NAAQMS 400 µg /m³.The 8 hrs. CO level in all monitoring locations ranges
between 0.14 to 0.81 mg/m³.
Noise Environment:The ambient noise level of all the monitoring locations were found well
within the National Ambient Noise Quality Standards prescribed for industrial (Standards - 75
dBA during day time and 70 dBA during night time) residential area (Standards - 55 dBA during
day time and 45 dBA during night time) and commercial area (Standards - 65 dBA during day
time and 55 dBA during night time)
Water Quality: Six surface water samples and eight groundwater samples were collected from
the area for chemical and biological analysis. Overall the ground water quality of the study area
is found well within the permissible limits. No metallic and bacterial contaminations were
observed in ground water samples.
Surface water quality is determined by the help of water quality criteria defined in CPCB best
designated uses criteria. Surface water monitoring is performed for nalla near project site at 100
upstream and downstream point of the project site high bacterial contamination were observed
in Nala water quality meeting the BDU criteria Class D which is fit for propagation of wildlife and
fisheries.
Canal Water quality: The canal water quality is good for Drinking water source after
conventional treatment and disinfection and meeting the class C of Best designated uses of
CPCB.
Pond Water Quality: Bacterial contaminations were observed in pond water samples. Dissolve
oxygen is found within the range while BOD was found slightly high than the Class C of Best
designated uses. Hence the pond water is fit for Propagation of Wild life and Fisheries and
meeting the criteria D of Best designated uses of CPCB.
Soil Quality: The soil quality of study area is sandy loam. The pH and conductivity of the soil is
within acceptable range. The soil analysis describes that the soil of the study area is moderately
fertile.
For the proposed project, computations of 24-hour average ground level concentrations were carried out
using ISCST3 model, which is a recommended model by USEPA for prediction of air quality from point
area.
Table: Summary of Maximum 24-hour Incremental GLC due to the Proposed Expansion
Project Stacks
The nearest settlement in downwind direction is Fatehgarh channa village (towards SE) at a distance of
1.68 km. As per baseline data of mean AAQ for PM at Fatehgarh channa village is 92 µg/m³ and with this
proposed project, 0.95 µg/m³ rise in GLCs so PM level will be 92.95 µg/m³. The Particulate Matter in the
study area is contributed mainly by commercial activities and traffic movement (vehicular emissions), re-
suspended dust from paved and unpaved roads and open uncovered areas as well as from industrial
activities.
Maximum baseline GLC for SO2 (Process and utilities) at downwind direction (SE) was as 11.8 µg/m³
observed at Fatehgarh Channa village. With this proposed expansion project SOx level may increase by
0.61 µg/m³ so post project level of SOx is 12.41µg/m³. Maximum baseline GLC for NOx was as 22.70
µg/m³ observed at Fatehgarh channa village . With this proposed project NOx concentration is 3.1 µg/m³
so rise in GLC of NOx concentration is 25.80 µg/m³. It can be concluded that with the proposed project
all the AAQ parameters will remain within the NAAQ norms.
As is evident from the table and discussion above, there will be no adverse impacts on the surrounding
area (all pollutants post project GLC will be well within NAAQ norms). Highly efficient air pollution control
systems have been adopted to mitigate particulate matter as well as gaseous emissions in the ambient
environment.
Noise Quality:
The main source of noise generation during operation stages are mainly from pumps, blowers,
compressors, DG sets, vehicle movement for transportation of raw materials, finished goods
etc. DG sets will be provided with acoustics enclosures. Mufflers, silencers, acoustics treatment
of room will be done wherever required. Equipment will be maintained so that noise level does
not increase due to improper maintenance. Material handling operations and movement of
vehicles will be properly scheduled to minimize construction noise. Workers working in noisy
areas will be given ear plugs. The noise level will be restricted within the plant boundary to meet
the standards. Existing greenbelt developed within the plant premises will also act as a barrier
to the propagation of noise from the factory premises. This shall further reduce the noise levels
appreciably. Hence, no significant impact is envisaged.
Water Quality: Total water requirement–1800 KLD (Fresh water 1456 KLD and Recycle water
344 KLD).Water requirement will be made available through ground water and surface water.
Low TDS Effluent Treated in To ETP. ETP comprises of Four Stage , Two Stage Anaerobic ,
One Stage Aerobic and One Stage Tertiary. After treatment treated effluents discharge in to
plantation area within premises. High TDS effluent Treated in to MEE. Condensate recovery will
be reused in plant. Concentrated stream will be sent to ATFD for further treatment. MEE salt will
be sold out to end users.
Solid and Hazardous Wastes Disposal:
All the solid and hazardous waste generated from the proposed unit shall be disposed as per
the norm. Minor quantities of construction waste will be generated in the form of packaging
material and construction waste. Proper care will be taken for handling and reduction of the
solid waste generated during construction phase. ETP sludge/ process residue generated
during operation phase shall be disposed as per the hazardous wastes management, handling
and Trans-boundary movement Rule 2016 and amendment thereof.
Impact on Ecology: No national park, wildlife sanctuary, biosphere reserve exists within 10 km
area of the project. No endangered or rare or threatened plant or animal species was observed
within 10 km area of the project site. The impact on the surrounding ecology during the
operation of the project will mainly occur from the deposition of air pollutants. Air pollution
affects the biotic and abiotic components of the ecosystem individually and synergistically with
other pollutants. Chronic and acute effects on plants and animals may be induced when the
concentration of air pollutants exceeds threshold limits. Particulate emission and other gaseous
emissions from the proposed plant are the major pollutant that may affect the ecology of the
area. However the AAQ modeling proves that in worst condition the concentration of the PM
and other gaseous emission will not exceeds the AAQ standards. Further the mitigation
measures have been suggested for the same. By adopting the mitigation measures suggested
the impact due to operation of the proposed expansion will be negligible.
Risk Assessment and Disaster Management Plan: The hazard potential of chemicals and
estimation of consequences in case of their accidental release during storage, transportation
and handling has been identified and risk assessment has been carried out to quantify the
extent of damage and suggest recommendations for safety improvement for the proposed
facilities. Risk mitigation measures based on MCA analysis and engineering judgments are
incorporated in order to improve overall system safety and mitigate the effects of major
accidents.
An effective Disaster Management Plan (DMP) to mitigate the risks involved has been prepared.
This plan defines the responsibilities and resources available to respond to the different types of
emergencies envisaged. Training exercises will be held to ensure that all personnel are familiar
with their responsibilities and that communication links are functioning effectively.
Green belt development: IOLCP has planted approx 26000 tree/shrubs and herbs in existing
greenbelt. The tree species like Eucalyptus, neem, Daikan, sadabahar, Ficus spp., Champa,
kadam gulmohar along with shrubs and herbs has been planted under existing greenbelt.
Further maintenance of the existing greenbelt shall be done on regular basis for which IOL
Chemical has already kept a budget for Rs. 50 lakhs as a capital cost.
CSR Plan: Unit has committed to spend about Rs. 1.53 crores (0.75% of the capital investment)
towards CER. But the Approved TOR is for 2.5 % of the project cost and IOLCP follow the OM
issued on dated 1st May 2018, hence earmarked the fund of Rs 1.53 crores. The amount will be
spending in next 3 years for infrastructure development of surrounding area.
Project Benefits
Proposed expansion project will result in considerable growth of stimulating the industrial
and commercial activities in the state. Small and medium scale industries may be further
developed as a consequence.
The project will be beneficial in govt’s target of increase the production capacity and yield in
the field of pharmaceuticals.
Overall Growth of the neighbouring area viz. Health and family welfare; Watershed
development; Sustainable livelihood and strengthening of village Self Help Groups; and
Infrastructure development.
In operation phase, the proposed plant would require significant workforce of non-technical
and technical persons.
Migration of persons with better education and professional experience will result in increase
of population and literacy in the surrounding villages.
Civic amenities will be substantial after the commencement of project activities. The basic
requirement of the community needs will be strengthened by extending healthcare,
educational facilities to the community, building/strengthening of existing roads in the area.
The local population will be given preference to employment on the basis of their eligibility
and company requirement. The employment potential will ameliorate economic conditions of
these families directly and provide employment to many other families indirectly who are
involved in business and service oriented activities. The employment of local people in
primary and secondary sectors of project shall upgrade the prosperity of the region. This in-
turn will improve the socio-economic conditions of the area.
CHAPTER 1. INTRODUCTION
This chapter provides background information of the project, need of the project,
need of the EIA study, scope and EIA methodology adopted and structure of the
report.
By incorporating these & other business strengths, IOLCP have boosted our
capabilities and planned for expansion of existing unit by addition some new products
and increasing the capacity of exiting product. IOLCP applied in MOEF&CC and
received TOR on 1st June 2018 (Letter No. J-11011/976/2008-IA-II(I)) for proposes
expansion of existing products and addition of new products from the capacity of
543.45 TPD to 671.95 TPD at Village Fatehgarh Channa, Mansa Road District
Barnala – 148101, Punjab.
No National Parks, Wildlife Sanctuaries, Tiger/ Elephant Reserves, Wildlife Corridors
etc. falls within 10 km radius from the plant site.
1.3. IMPORTANCE AND BENEFIT OF THE PROJECT
India is witnessing a steady rise in healthcare expenditure from US$ 76.1 per head in
2012 to US$ 118 per head in 2016. Still, India remains among the bottom five
countries with the lowest public health expenditure globally. A major chunk of the
population (nearly 40% of Indians) lives on less than US$ 1 per day, and most of them
have to pay out of their own pockets for medical services2. Out-of-pocket spending in
India is over four times higher than public spending on healthcare. Therefore, there is
a rising need for advanced drugs that will help people to recover quickly at lower
cost.The need of APIs is increasing every year due to continual growth of
pharmaceutical industry. IOLCP products cater to the key industrial sectors of
chemicals, Pharmaceutical & Packaging. Efficient teamwork & strong associations
showed the success. Through an unwavering focus on Quality, Commitment &
Delivery, IOLCP have charted the way to success in operations and have won the
admiration of the customers. This project is expected to partially fulfill the demand of
bulk drugs and APIs of pharmaceutical industries.
Market demand for chemicals and its intermediates is growing at a Compounded
Annual Growth Rate (CAGR) of 4-5% globally. The proposed project will contribute in
bridging this demand and supply gap by expansion of its chemicals production unit.
‗The Tribune‘, ‗Ajit‘ and ‗Spokesman‘ dated 25 Sep 2018. In the presence of ADC-
Barnala, Representative of Punjab Pollution Control Board, Patiala & Regional office
PPCB, Sangrur with near by public, Public Hearing was conducted on 26th Oct 2018
at Village Fatehgarh Channa, Mansa Road, Barnala, Punjab for the Proposed
Expansion of Chemicals and APIs production unit, from capacity of 543.45 TPD to
671.95 TPD by M/s IOL Chemicals & Pharmaceuticals Limited. which is coverd under
Category-A. Most of the issue raised during public hearing were related to
employment, CSR and clarity oriented related to environmental aspects and the
procedding are addressed in below Table The issues raised during the public hearing
with reply and public hearing minutes enclosed as Annexure VII.
Table 1.2 : Public hearing Queries with Complaince
1. Sh. Narinder Pal He stated that whatever explained The representative of the
Singh : about the project, pollution control company informed that as
Dhanaula, devices and other activities to be explained in the EIA report,
District Barnala carried out for the proposed 30,000 trees will be planted
expansion project are seems to be and the care of the same will
good. He further stated that be carried out for three years.
whatever explained and He also informed that they will
commitment/promised made by the discuss the matter with
industry should be fulfilled. He also representatives of clubs and
stated that the industry should plant village panchayats to provide
26,000 trees as explained and common land for planting trees
committed by it and the trees and the industry will care these
should be planted in their village trees for 3 years. He also
also. He requested that a water informed that the employment
cooler be provided in the school of will be given the local people.
their village. He also stated that He further informed that the
there is unemployment in the State company requires M. Sc. & B.
and it is not possible for the Govt. Sc candidates. The company
to provide Govt. jobs to has recruited 300-400 persons
unemployed, as such, he requested from different institutions. He
the company to provide committed that the first
employment to the local people. He preference will be given to the
also stated the company is giving applicants of District Barnala.
good salary in comparison to other
industries to its workers/staff. He
reiterated that whatever
commitments are made, the
industry should fulfill. He again said
that the employment should be
3. Sh. Gurmit He stated that M/s Trident & IOL The representative of the
Singh, are caring the environment. He company informed that the
Councilor, further stated that care of trees medical camps have been
Handaya, should be done. The company organized by the company in
District Barnala should care the health of the people village Dhanaula, Fatehgarh
and they are expecting the same Chhanna and other villages.
from the company. He also informed that the
medical camps will also be
organized in future under the
CSR activities. He further
informed that now, the
company is profit making and
3% of the profit will be spent on
the CSR activities in the
nearby area.
6. Sh. Multi Singh, He stated that he is a small farmer The representative of the
R/o Kahne Ke, and has very small land holding industry informed that they
District Barnala and he is working as milkman. He have taken 10 acres of land
further stated that he is selling the only for parking the vehicles
milk@ Rs. 50/- per liter to the staff which comes to the industry for
/workers of the industry due to any purpose. The parked
which he is getting more profit and vehicles are allowed to enter
his living standard has been one by one so as to avoid
upgraded. The nearby area has traffic congestion on the main
developed due to this factory. He entrance gate of the industry.
requested that there is a heavy He further informed that the
traffic at the main gate of the point raised by him has also
industry due to the parking of trucks been noted down and more
and tractor-trolleys, due to which precautions/steps will be taken
there are chances of accident. He to set right the said point.
further stated that if any accident
took place near the industry, the
industry ambulance has helped the
victim to admit in the hospital. He
demanded that the employment
should be given to the local people.
8. Sh. Ram Singh, How much of increase in the The environmental consultant
R/o Village pollution from the proposed of the industry informed that
Kureke Kalan, expansion and how the pollution the pollution control devices of
District Barnala from the industry will be controlled? latest technology will be
provided to control the pollution
He stated that thieves/anti social
from the industry. There is
elements are snatching money and
insignificant increase in the
other valuable ornaments from the
pollution from the proposed
workers who come back their
expansion (increased level of
homes from the industry at night.
PM 2.5 by 0.95 µg/Nm3, SOx
He demanded from the district
level by 0.61 µg/Nm3, NOx
Administration that proper
level by 3.1 µg/Nm3). Regular
arrangements may be made in this
monitoring of the pollution
regards.
control devices will be done.
No wastewater will be
discharged outside the
premises of the industry and
the unit will be zero liquid
discharge.
The TOR compliance status of the project has been presented in Table 1.2
ii. A toposheet of the study area of radius Toposheet map of the study area of 10
of 10km and site location on km radius is given in Figure 1.2
1:50,000/1:25,000 scale on an A3/A2
sheet. (including all eco-sensitive areas and
environmentally sensitive places)
iii. Details w.r.t. option analysis for The expansion is done within existing
selection of site premises and justification of the project
because of availability of facilities
please refer Section 2.1
iv. Co-ordinates (lat-long) of all four The boundary coordinates of the
corners of the site. project site is given in Figure 1.1
v. Google map-Earth downloaded of the Google map of the project site is given
project site. in Figure 3.3.
vi.Layout maps indicating existing unit as The layout map indicating existing and
well as proposed unit indicating storage proposed expansion is given in Figure
area, plant area, greenbelt area, utilities 2.2. and Table 2.2
etc. If located within an Industrial
area/Estate/Complex, layout of Industrial
Area indicating location of unit within the
Industrial area/Estate.
vii. Photographs of the proposed and Existing green belt photograph is given
ix. Action plan for the green belt Action plan for the green belt
development plan in 33 % area i.e. land development plan is given in Section
with not less than 1,500 trees per ha. 5.9.
Giving details of species, width of
plantation, planning schedule etc. shall be
included. The green belt shall be around
the project boundary and a scheme for
greening of the roads used for the project
shall also be incorporated.
x. Action plan for rainwater harvesting It‘s a chemical unit Rainwater
measures at plant site shall be submitted to harvesting in not possible within
harvest rainwater from the roof tops and premises to avoid the ground water
storm water drains to recharge the ground contamination, IOLCP already adopted
water and to use for the various activities at 9 villages ponds for RWH in nearby
the project site to conserve fresh water and areas.
reduce the water requirement from other
sources.
xi. Total capital cost and recurring The total investment is ~ Rs 205
cost/annum for environmental pollution crores. The capital investment towards
control measures shall be included. environment management is estimated
to be Rs.690 lacs and recurring cost
will be Rs. 483 lacs.
xii. Action plan for post-project Post-project environmental monitoring
environmental monitoring shall be is given in Section 5.13.1.
submitted.
xiii. Onsite and Offsite Disaster (Natural an A detailed risk assessment was carried
Man-made) Preparedness and Emergency -out, refer Chapter 6 of EIA report.
Management Plan including Risk
Assessment and damage control. Disaster
management plan should be linked with
District disaster management plan.
8. Occupational health
i. Plan and fund allocation to ensure the Adequate fund allocated for OHS, the
occupational health & safety of all contract detail given in Section 5.13.2. Facility
and casual workers for worker is given in Section 2.8.7.
ii. Details of exposure specific health status The health checkup of all employees
evaluation of worker. If the workers' health was carried out on annual basis same
is being evaluated by pre-designed format, will be followed for proposed expansion
chest x rays, Audiometry, Spirometry, project. The health report of the
Vision testing (Far & Near vision, color workers for existing unit are enclosed
vision and any other ocular defect) ECG, as Annexure X.
during pre-placement and periodical
examinations give the details of the same.
Details regarding last month analyzed data
of above-mentioned parameters as per age,
This EIA report has been prepared on the basis of available on-site primary data
(survey/ monitoring) and secondary/literature data. The EIA report contains project
features, baseline environmental setup, assessment of environmental impacts, and
formulation of mitigation measures, environmental management and monitoring plan
with risk & disaster management plan.
The report would include 9 Chapters excluding Executive Summary, which is included
at the beginning of the report. The structure of the EIA Report with necessary tables,
drawings and annexure is as follows:
Chapter 1:Introduction
This chapter provides background information on need of project, need of EIA study
and brief of the project. The scope and EIA methodology adopted in preparation of EIA
report have also been described in this Chapter. It also covers the identification of
project & project proponent, brief description of nature, size, location of the project and
its importance to the country and the region. Scope of the study details about the
regulatory scoping carried out as per the generic structure given in the EIA
Notification, 2006.
Chapter 2: Project Description
This chapter deals with the project details of the proposed Chemicals
(Pharmaceuticals) Manufacturing Plant, with type of project, need for the project,
location, size & magnitude of operation including associated activities required by and
for the project, proposed schedule for approval and implementation, including
technical details of raw material, quality and quantity etc.
Chapter 3: Description of Environment
This chapter presents the existing environmental status of the study area around the
proposed project including topography, drainage pattern, water environment,
geological, climate, transport system, land use, flora & fauna, socio-economic aspects,
basic amenities etc. Environmental assessment of the proposed project site in regard
to its capability to receive the proposed new development is also discussed in this
Chapter.
Chapter 4: Anticipated Environmental Impacts and Mitigation Measures
This chapter describes the overall impacts of the proposed project activities and
underscores the areas of concern, which need mitigation measures. It predicts the
overall impact of the proposed project on different components of the environment viz.
air, water, land, noise, biological, and socio-economic.
Chapter 5: Environmental Management Plan
This chapter details the inferences drawn from the environmental impact assessment
exercise. It describes the overall impacts of the proposed activities during construction
and operation phases and underscores the areas of concern, which need mitigation
measures. It also provides mitigation and control measures for environmental
management plan (EMP) for minimizing the negative environmental impacts and to
strengthening the positive environmental impacts of the proposed project. Technical
aspects of monitoring the effectiveness of mitigation measures have been given in this
Chapter also.
This chapter deals with the brief details of the establishment of new proposed bulk drug
project; Location Consideration, Technology Description, Raw material Requirement and
its source, Process flow diagram, Environmental aspects etc.
EQMS India Pvt. Ltd. Document No. IOL/EIA/01 Issue No. 01 R 00 Page 35 of 357
EIA/EMP Report for expansion of APIs and Bulk drug production unit
(Sq.mtr) (Sq.mtr)
(Source: IOLCP)
Figure 2.2 : Site Layout
The Ethyl Alcohol & Acetic Acid are mixed in the Reaction Kettle. In the kettle, temperature of
102 to 1050 C and pressure of 0.1 to 0.15 kg/cm2 is maintained. The reaction is endothermic and
in order to provide required heat of reaction, heat is supplied by means of the reboilers attached
to the reaction kettle. The vapors from the top of the Reaction Kettle are sent to Ethyl Column
No. 1. The vapors coming from the top of the column are condensed in condenser No. 1 and 2
with the help of cooling water and then passed through another cooler. The condensed material
is then sent to the Decanter-1. Here two layers get formed in which the top layer is of Crude Ethyl
Acetate and the bottom layer consists of Alcohol, Water & Ester. A portion of the top layer is
recycled back to the Reaction column and the rest is fed to the Ethyl Column No. 2 where again
same procedure is repeated.
Now, the top layer of decanter of Column No. 1 and 2 are sent to Distillation Column, which has
an inbuilt Reboiler so as to provide proper heat for distillation. In the Distillation Column Ethyl
Acetate vapors are generated which are condensed and cooled and the finished Ethyl Acetate is
then diverted to the Daily Storage Tanks (DST) .
The vapors from the top of the Distillation Column are condensed in Condenser 1 and 2 and then
cooled in a Cooler. The cooled material is then taken in the Decanter – 2. Here also the two
layers get formed. The top layer is of Crude Ethyl Acetate and the bottom is of Alcohol, Water &
Ester. The top layer is recycled back to the Distillation Column and some part of it is send to the
Reaction Kettle. The bottom layers of the Decanters of Column No. 1 and 2 along with decanter
of distillation column are fed to the Recovery Column where Ester and Alcohol are recovered and
the water is drained out after recovering its heat in a Plate Type heat Exchanger installed at the
drain point of the recovery column.
Acetic Anhydride plant uses the Acetic Acid. Acetic Acid after preheating is fed into the
vaporizer where Acetic Acid is vaporized and the vapors of Acetic Acid are fed in the the
Ketene furnace where Acetic Acid is dehydrated into ketene at around 700-750 deg C. The
following reaction takes place in the furnace:
700-750 deg. C
CH3COOH ------------------------------------------------->CH2CO + H2O
AceticAcid Ketene Watervapors
The outlet of ketene goes to the gas coolers where Acetic Acid vapors and water are
condensed. The condensate is then fed to the pump vessel. The ketene gas is absorbed by
the Acetic Acid to form Acetic Anhydride by the following reaction:
CH2C0* + CH3COOH ------------------------------------>C4H6O3
Ketene AceticAcid Acetic AnhydrideGas
Scrubbers are four in numbers and their relative Equipment numbering is Scrubber – 110 ,
114 , 117 , 118. Packing are provided in all the Scrubbers as that of 20 mm O.D Rasching
Rings. The first Scrubber is 110 in which the feed is of the Ketene Gas from the top of the
K.O.P.-1. From the top, in the Scrubber – 110, the Liquid stream from the bottom overflow of
Scrubber – 114 is fed as the Absorbent. The reaction takes place between the Ketene Gas &
the Acetic Acid so as to form the Product Acetic Anhydride. 70 – 75 % of the total Ketene
Gas gets reacted & the rest comes out from the top of the Scrubber – 110 & becomes feed
for the Scrubber – 114. In Scrubber – 110 the liquid keeps on collecting at the bottom, which
contains the Acetic Anhydride that has formed. This liquid always remains in circulation at
the Scrubber through the Inter Cooler – 112 the Centrifugal Circulation Pump 221 & 222.
When the Liquid level reaches certain specified mark, it gets automatically transferred to the
Scrubber – 117 through the Inter Cooler – 132 by the Centrifugal Circulation Pumps 221 &
222 & acts as the Absorption media there. In Scrubber – 114 the remaining of the reaction
between the Ketene Gas & the Acetic Acid is completed. The Absorbent is the fresh feed of
the Acetic Acid that is supplied from the Acetic Acid Tanks by means of Centrifugal Pumps
231&232 through the Inter Cooler – 116. Here also in the same manner there is a collection
of the liquid at the bottom of the Scrubber. When the required level is achieved, the material
gets transferred to the Scrubber – 110 & is the Absorption media of that. After first two
Scrubbers i.e 110 & 114 the reaction gets completed between the Ketene Gas & Acetic Acid.
Now the gas, which escapes the top of the Scrubber – 114, comes to the Scrubber – 117.
Here the main purpose is to improve the color of the product Acetic Anhydride. The
unabsorbed gases are then send to the Scrubber – 118 from the top of the Scrubber – 117.
Also from the bottom of the Scrubber – 117 one stream is fed to the Distillation Column- 120
Of Acetic Anhydride. This stream contains the entire Acetic Anhydride that has formed in the
Scrubbers.In Scrubber–118 there is the feed of the D.A (Dilute Acetic Acid) from the bottom
of the K.O.P – 2 by the centrifugal circulation pump, which is the Absorption media of that. At
the top of the Scrubber - 118 we have the connection of The System which provides the
vacuum & hence the means for the conveying of gases through the packing. In Scrubber –
118 no Chemical reaction takes place. Now in the Distilation Column 120 the purpose is of to
recover the product Acetic Anhydride. The column is a Bubble Cap Tray Column and the top
product is Acetic anhydride, which is then sent to DST for daily storage.
2.6.3. Manufacturing process of Mono Chloro Acetic acid & acetyl chloride
Mono Chloro Acetic acid & acetyl chloride are manufactured together in a single reaction
column.
Acetic anhydride is fed on the top of reaction column. Chlorine gas purged from the bottom
of the column through sparger. Acetic anhydride reacts with HCL gas & produce acetic acid &
acetyl chloride. This acetic acid further reacts with chlorine gas in the presence of acetyl
chloride & gives Mono Chloro Acetic acid & Hcl gas which reacts with acetic anhydride as
mentioned above. The reaction mixture circulated in the reaction column so that above
reactions takes place,circulation in reaction column done by means of the centrifugal
pumps. . The Hcl gas generated from the reaction reacts with the acetic anhydride &
produce acetyl chloride & acetic acid. This acetic acid produce in the reaction reacts with
chlorine & produce Mono Chloro Acetic acid & HCL gas. Acetyl chloride produce by reaction
of acetic anhydride & Hcl gas acts as a catalyst for the Mono Chloro Acetic acid reaction.
The acetyl chloride molecule attaches with the chlorine atom & produces the chloroacetyl ion
which reacts with acetic acid & produces the Mono Chloro Acetic acid. Acetyl chloride
remainsunreacted.
Room temp.
(CH3COO)2+HCL CH3COOH +CH3COCl Δ H = -IVE
(SLIGHTLY)
95 deg c
CH3COOH+Cl2 ClCH2COOH +Hcl Δ H = +IVE
As given above, for both reactions the temperature & pressure conditions are different.
In first reaction the acetic anhydride reacts with HCL gas at room temperature & this
reaction is slightly exothermic in nature. Whereas the second reaction of acetic acid with
chlorine occurs at high temperature of 95-100 deg c & this reaction is slightly endothermic
in nature.
Input Output
Name of Material Unit Qty Name of Unit Qty
Material
Acetic Anhydride MT 41.57 Acetic Acid MT 24.45
HCL MT 14.88 Acetyl MT 32.0
Chloride
Water MT 10.0 Water MT 10.0
Total 66.45 66.45
.The Nitrogen required for blanking purpose is generated in our own Nitrogen generation plant.
This Nitrogen is also used for purging of vessels as and when required. Recovered Potassium
carbonate sold out.
The process involves firstly, preparation of Mono methyl chloro acetate in GL reactor by reaction
between methanol & monochloroacetic acid, Then in SS reactor, 2,6-Dichlorophenol, potassium
carbonate & toluene is charged and then Mono methyl chloro acetate is added slowly at controlled
temp. and then the reaction mass is worked up to give 2,6 -dichloro-N-phenylbenzeneamine as
Intermediate which is separated & then reacted with Chloro acetyl chloride in a GL reactor & then
worked up to give 2- chloro-N-(2,6-dichlorophenol)-N-phenylacetamide as Intermediate, which is
separated & dried. This is then further reacted with Aluminium chloride, anhydrous in a GL reactor &
worked up to give 1-(2-6-dichlorophenyl) indolin-2-one as Intermediate, which is separated & then
hydrolysed in alkaline medium to give Diclofenac Sodium, which is suitably purified to give Diclofenac
sodium. Poly Aluminium chloride to be sale to paper industries for paper sizing
Material
Mono Methyl Chloro MT 2.41 Methyl 2-(2,6- MT 5.17
Acetate dichloropheno
xy) acetate
2,6-dichlorophenol MT 3.62 HCL MT 0.803
Water MT 10 Water MT 10.057
Total 16.03 16.03
Stage-2
Name of Material Unit Qty Name of Unit Qty
Material
Aniline MT 2.07 2,6 dichloro- MT 5.2371
N-
Phenylbenzen
e
Methyl 2-(2,6- MT 5.17 Methanol MT 0.7050
dichlorophenoxy)
acetate
Water MT 10.0 Carbon MT 0.9680
Dioxide
Sodium Methoxide MT 1.20 Sodium MT 1.4960
Ethoxide
Water MT 10.0339
Total MT 18.44 Total MT 18.44
Stage-3
Name of Material Unit Qty Name of Unit Qty
Material
2,6 dichloro-N- MT 5.2371 (2-Chloro-N- MT 6.9201
Phenylbenzene (2,6dichloroph
enylacetamide
)
Chloro Acetyl MT 2.51 HCL MT 0.803
Chloride
Water MT 10.0 Water MT 10.024
Total 17.7471 17.7471
Stage-4
Name of Material Unit Qty Name of Unit Qty
Material
(2-Chloro-N- MT 6.9201 (1-(2,6- MT 6.12
(2,6dichlorophenyla dichlorophenyl
cetamide) )indolin-2-one)
Aluminium Chloride MT 2.96 Hydrochloric MT 3.212
Acid
Water MT 21.20 Aluminium MT 1.716
Hydroxide
Water MT 20.0321
Total MT 31.0801 Total MT 31.0801
Stage 5
N-Butanol is charged to a reaction vessel at room temperature followed by addition of Dimethyl amine
Hydrochloride. Reaction mass is heated & followed by addition of Dicyanodiamide under heating.
Reaction mass is refluxed till completion. Reaction mass is cooled & extracted with water. Layers are
separated, from which organic layer i.e O-xylene layer is reused as such in next batch & Aq. layer is
distilled off under vacuum. Reaction mass is cooled & solid is filtered & dried as Metformin
Hydrochloride.
methylpropan
oic acid
Sodium Hydroxide MT 0.252 Sodium MT 0.3651
Chloride
Chloroform MT 0.247 Rxn Water MT 0.075
Acetone MT 0.120 Water MT 6.000
Water MT 6.000
Total MT 7.1029 Total MT 7.1029
Stage-2
Name of Material Unit Qty Name of Unit Qty
Material
2-(4-[4- MT 0.6630 Propan-2-yl 2- MT 0.7500
chlorophenyl)carbo (4-[(4-
nyl]phenoxy]-2- chlorophenyl)
methylpropanoic carbonyl]phen
acid oxy)-2-
methylpropan
oate (
Fenofibrate)
IPA MT 0.1260
water MT 6.0000 water MT 6.039
Total MT 6.789 Total MT 6.789
Tartrate salt was converted into chiral base by adjusting pH with ammonia solution. Base was
extracted with Toluene and used as such in next step.
Stage-IVB: Couple Amine Hydrochloride
Organic layer of chiral base and tosylate was coupled by using DPHOP as base in presence of
phase transfer catalyst at high temperature. After completion of reaction was worked up and
free base formed. Base converted to hydrochloride salt with IPA.HCl. Hydrochloride salt was
centrifuged and washed with toluene and dried.
Stage-V: Clopidogrel Bisulphate
Reaction of couple amine hydrochloride with paraformaldehyde followed by cyclization in acidic
medium to give Clopidogrel base thus obtained free base treated with sulfuric acid in acetone to
afford Clopidogrel bisulphate.
Stage-3
Name of Material Unit Qty Name of Material Unit Qty
2-(thiophen-2-yl)ethanol MT 0.3050 2-(thiophen-2-yl)ethyl 4- MT 0.6722
methylbenzenesulfonate
4-methylbenzene-1- MT 0.4586 Sodium Chloride MT 0.1394
sulfonyl chloride
Sodium Hydroxide MT 0.096 water MT 2.0480
water MT 2.0000
Total MT 2.8596 Total MT 2.8596
Stage-IVA
(R)-methyl 2-amino-2-(2- MT 0.8331 (R)-methyl 2-amino-2-(2- MT 0.4755
chlorophenyl)acetate chlorophenyl)acetate
(2R,3R)-2,3-dihydroxy
succinate
Ammonium Hydroxide MT 0.1685 Tartaric Acid Ammonium MT 0.4386
Salt
water MT 1.0000 water MT 1.0875
Total MT 2.0016 Total MT 2.0016
Stage-IVB
(R)-methyl 2-amino-2-(2- MT 0.4755 (S)-methyl 2-(2- MT 0.8247
chlorophenyl)acetate chlorophenyl)-2-((2-
(thiophene-2-
yl)ethyl)amino)acetate
hydrochloride
2-(thiophen-2-yl)ethyl 4- MT 0.6722 Iso propyl Alcohol MT 0.1430
methylbenzenesulfonateH
ydroxide
Isopropyl alcohol MT 0.2323 p-Toluenesulfonic acid MT 0.4100
hydrochloride
water MT 2.0420 Water MT 2.0430
Total MT 3.4220 Total MT 3.4220
Stage-V
(S)-methyl 2-(2- MT 0.8247 Clopidogrel Bisulphate MT 1.0000
chlorophenyl)-2-((2-
(thiophene-2-
yl)ethyl)amino)acetate
hydrochloride
Paraformaldehyde MT 0.072
Sulphuric Acid MT 0.2359 Hydrochloric Acid MT 0.087
Water MT 2.000 Water MT 2.0456
Total MT 3.1326 Total MT 3.1326
Centrifuge the reaction mass at 25-30o C. Wash the cake with toluene, spin dry for 1hr. Unload the
material into double polythene bag weigh the product & label. Record the weight of product. Send
sample to Q.C for completeanalysis
Step – II :PHEEMA
Procedure:
Ensure the cleanliness of reactor (R-102). Charge toluene, Start flushing the reactor with nitrogen.
Draw toluene from the bottom valve of the reactor & send the sample to QC for moisture content
(moisture content < 0.05%). Meanwhile check the moisture content of the THF it should be < 0.1%.
Charge THF stir for 10 Minutes. Send an aliquot to QC for moisture content. It should be < 0.1%. Add
Sodium Hydride, in two lots (under N2 blanket). Cool the reaction mass from 25°C to 10°C. Add ethyl -
4 – chloroacetoacetate, in portions over a period of 9 – 11h at 10 – 15oC. Record addition time and
temperature for every 30min. slowly raise temperature from 15°C to 20°C. Add of HEP over a period of
10 to 12 h at 20°C-25°C. Maintain reaction mass for 12 – 16 h at 20°C-25°C. After 12 h maintenance
send sample to QC for TLC (absence of HEP). If TLC does not comply continue the reaction until TLC
complies. Add acetic acid slowly at 25°-30°C in 1 h and stir the mass for 1hr. Ensure that sodium
hydride is decomposed.
Meanwhile charge water in reactor (R-108) for quenching. Transfer the reaction mass from Reactor (R-
102) to R-108. Rinse the reactor R-102 with methanol. Stir the reaction mass in reactor (R-108) for 1hr
and settle for 1hr at 30°C – 35°C. Separate the bottom aqueous layer and discard. Give water washing
to the organic layer with water, stir for 30 min. and settle for 30 min. Separate the bottom aqueous layer
and discard. Repeat two washings with water separate the aqueous layer and discard. Collect the
organic layer. Transfer total organic layer from R-108 to R-103. Distill out toluene under 680 mm/Hg
vacuum and up to about 50°C. Cool the reaction mass to 30°-35°C at 680 mm/Hg. Add n-hexane, to
the reaction mass. Stir for 1 h and settle for 1 h. Separate the layers and collect bottom organic layer in
carboys.
Step – III : Procedure to Convert PHEEMA to phthaloylamlodipine.
Procedure:
Ensure the cleanliness of Reactor R-107. Charge IPA, PHEEMA and piperidine at 25°C-30°C followed
by acetic acid. At 25°C-30°C. Cool the mass to 15°C – 20°C and add slowly OCB at 15°C – 20°C over
a period of 3 – 4 h. raise the temperature from 20°C to 30°C. Maintain at 25°C -30°C for 36 to 40 h
under stirring. Send the sample to QC for TLC (absence of PHEEMA) if TLC does not comply maintain
till TLC complies. Transfer the reaction mass from R-107 to R-106 Apply vacuum to the Reactor R-106
Distill out IPA under vacuum 680 mm/Hg up to 50°C + 2°C. Ensure that reaction mass thick slurry.
(Record vacuum and temperature for every 1h). Cool the mass to 25°C -30°C. Transfer the organic
layer to R-107. If the mass is very thick charge acetic Acid. Stir for 30-40 minutes. Charge methyl
aminocrotonate at 25°C-30°C and stir for 30-40 min. Heat the mass 40°C – 45°C, maintain for 18 – 22
h at 40 – 45oC. (Record time and temperature for every 1h). Send the sample to QC for TLC (Absence
of OCB) If TLC does not comply maintain at 40°C-45°C till TLC complies. Slowly cool the mass to
20°C. Centrifuge the reaction mass in CF 101, spin dry and unload the crude cake into double poly
bags. Record weight of the product . Meanwhile charge water & acetic Acid in R-103. Charge the crude
cake. Stir for ½ h, Centrifuge the mass and wash the cake with water Spin dry for ½ h and unload the
wet cake. Send the sample to QC for HPLC analysis.
STEP – IV (Purification in toluene)
Procedure:
Ensure the cleanliness and dryness of reactor R-0 103. Charge toluene at room temperature. Charge
crude phthaloyl amlodipine under stirring at room temperature . Heat the reaction mass to 70°C-75°C.
Check for the dissolution if dissolution is OK separate the water layer and remove the particles from
bottom then Maintain for 1h at 70°C-75°C. Cool the mass to 0-5°C Maintain for 2h Centrifuge the
mass, spin dry for 30min and unload the wet cake into double polythene bags. Record the weight of
the product Collect toluene mother liquor in clean drums Send the sample to QC for HPLC analysis.
The product of this stage is the IBAP (Iso Butyl Aceto Phenone), which is formed by the chemical
reaction
Where Iso Butyl Benzene & Acetyl Chloride is the reactants and the reaction solvent is TCE (Tri Chloro
Ethylene). Hydrogen Chloride is generated as the reaction side product which comes in the vapor form and is
then Scrubbed with Water to form Hydrochloric Acid and reused in the DM plant.
STAGE 1 (b) ISO PROPYL CHLORO ACETATE STAGE.
This stage produces Iso Propyl Chloro Acetate from the reaction of the following
IPA (Iso Propyl Alcohol) & MCA (Monochloro Acetic Acid) are the reactants and IPCA (Iso Propyl Chloro
Acetate) is the reaction product whereas the water formed during the reaction is the side product. IPA is the
excess reactant and so MCA charged is always completely reacted.
2 .ALDEHYDE STAGE.
In this stage IBAP, IPCA, SPO & NaOH reacted together & form 2,4- Iso Butyl Phenyl Propanaldehyde, Iso
Propyl Alcohol, Sodium hydroxide, sodium chloride and carbon dioxide. The iso propyl alcohol is recovered by
distillation. The chemical reaction is as follows
3. IBUPROFEN STAGE
The aldehyde which has already been formed is now to be oxidized to get the required Product i.e. IBU–
PROFEN Salt chemically known as 2,4 – Iso Butyl Phenyl Propionic Acid. The chemical reaction for the
synthesis is as follows
Where the oxidizing Agent is Sodium Di Chromate. The chromic acid & water are the reaction
side products and Sulphuric Acid is the excess reactant. After the reaction is over, the formed
IBUPROFEN Salt is then extracted from the reaction mass by n – Hexane solvent extraction.
Rest of the reaction mass that contains Chromic Acid, Water & Sulphuric Acid is called as Green
Acid, which is used as a byproduct for manufacture of Basic Chrome Sulphate. Crystallization is
done to get the product in the solid stage and that is later on separated from the n – Hexane by
Centrifugation.
Process water is charged in to the reactor & cooled to 5oC. Slowly sulfuric acid is added maintaining
temperature. Aminoguadine bicarbonate is added to above solution followed by 2,3-
dichlorocenzoylnitrile. Acetonitrile is added to reaction which acts as catalyst. Reaction mass is stirred
for 20 hrs at 45-50oC. After completion of reaction solid is filtered & washed with plenty of water, solid
is again suspended to aq. sodium hydroxide solution and filtered followed by washing with water, solid
is dried as LAM-0.1. Sodium sulphate (as a by-product) will be selling to authorize dealer.
Stage-02:
Ethanol is added to a reactor followed by Stage-01 material & reaction mass is refluxed for 8 hrs. After
completion of reaction, mass is distilled to half volume followed by cooling & solid is filtered & dried as
Lamotrigine
sulphate
Toluene is charged to a clean reaction vessel at 25-35oC followed by charging of 2-Benzyl pyridine
under nitrogen atmosphere. Cool the reaction mass to 5-10oC & Charge sodium amide under
Nitrogen atmosphere. Stir the reaction mass for some time at same temperature & slowly raise the
temperature of reaction mass to 30-35oC. Meanwhile in another reaction vessel charge purified water
at 25-35oC & caustic lye solution at 25-35oC. Charge toluene & Cool the mass to 0-5oC. Charge 2-
chloro-N,N-dimethyl ethylamine Hydrochloride & Stir the reaction mass for 30 minutes at same
temperature. Stop agitation & allow to settle the mass for 15 minutes. Separated the organic layer to
a dry vessel. Add anhydrous potassium carbonate to organic layer to remove the moisture. Decant off
organic layer & slowly add to above reaction mass at 30-35oC in approx. 1hr. Maintain the reaction
mass monitor the reaction progress by HPLC till reaction complies (2-Benzyl pyridine <10%).
After reaction completion cool the reaction mass to 20-25oC. Slowly add methanol & stir for 10- 15
minutes & then add slowly water to quench the reaction mass at 20-25oC. Stir the mass for 30
minutes. Adjust the pH of reaction mass to 4-4.5 using dil. HCl at 20-30oC & stir for 10 minutes.
Separate the layer & collected the toluene layer for recovery of unreacted 2-Benzyl pyridine.
Charge aq. Layer back to reaction vessel at 25-30oC. Charge toluene to reaction vessel at 25- 30oC,
Stir the mass for 10-15 minutes. Settle & separate the toluene layer for recovery of unreacted 2-
Benzyl pyridine. Charge aq. Layer back to reaction vessel at 25-30oC. Adjust the pH of reaction mass
to 10-11 using aq. NaOH solution & Charge Hexane, stir for 30 minutes. Settle & separate the organic
layer & collected in dedicated container. Again charge aq. Layer back to reactor. Charge Hexane to
reactor & stir for 30 minutes at 25-30oC. Settle & separate the organic layer & collected in dedicated
container. Charge the combine Hexane to reactor & heat to 40- 45oC. Charge activated carbon & stir
for 20-30 minutes at same temperature. Filter Hexane layer through hyflo & wash the hyflo bed with
Hexane, Distill off Hexane under vacuum below 60oC Unload the oil & check the wt. & quality of oil.
Distill of oil using short path distillation assembly to get pure oil.
Ibuprofen solution was obtained by dissolving ibuprofen in acetone, treated with activated carbon and
filtered. Similarly, DL-Lysine solution was prepared by dissolving DL-lysine in water, treated with
activated carbon and followed by filtration. Add drop wise lysine solution in Ibuprofen solution drop
wise. Obtained solid filtered to give Ibuprofen Lysinate.
Toluene is charged to reactor followed by charging of Cholic acid. Reaction mass is heated slowly
followed by Azeotropic reflux to remove water. After that cool the mass to 25-35, further cool to 5-10 &
maintain for 1 hr at same temperature. Filter the material & washed with chilled toluene. Charged the
wet cake back to reaction vessel followed by addition of methanol. Slowly added sulfuric acid & raise
the temperature of reaction mass to reflux. Stir the mass for 8-10 hrs & after completion of reaction
cool the mass to room temperature. Further cool the mass to zero degree & filter the material &
washed with chilled methanol, dry the wet cake in oven under vacuum till LOD came less than 1%.
Unload the dry material as UDCA-01.
Stage-02
Charge MDC into reaction at 25-30oC. Charged UDCA-01 & Dimethyl amino pyridine at same
temperature under stirring. Charge TEA & cool the mass to zero degree. Slowly added acetic
anhydride & stir at same temperature to for reaction completion. After reaction completion slowly add
water to reaction mass for reaction termination. Distill water azeotropically to remove MDC. Add ethyl
acetate & Heptane at 50-55 & stir. Cool the mass up to 20-22 & filter the solid. Wash the wet cake with
water followed by heptanes. Unload the wet cake & dry in air dryer at 500C till LOD came less than 1%.
Unload dry material as UDCA-02
Stage-03
Charge Ethyl acetate to reaction vessel. Charge UDCA-02 at 25-30oC & stir the mass. Charge
Sodium bromide & acetic acid at same temperature & cool the reaction mass to zero degree. Slowly
added sodium hypochlorite solution & stir the reaction mass at same temperature. Check the reaction
progress using HPLC. After reaction completion charge 10% aq. Sodium sulfite solution. Separate
the layer & wash the organic layer with aq.
Sodium bicarbonate solution. Charge DM water to organic layer & distill of ethyl acetate
azeotropically, cool the mass & filter the solid. Wash the wet cake with water & dry the solid in oven
under vacuum till LOD came NMT 0.5%. Unload the dry solid as UDCA- 03
Stage-04
Charge triethylene glycol to a reaction vessel. Charge UDCA-03 at 25-30oC & stir the mass. Slowly
added aq. Hydrazine hydrate solution. Charge 1-octanol in catalytic quantity & raise the temperature
of reaction to get clear solution. Slowly added aq. KOH solution under heating & start azetropic
distillation to remove water. After reaction completion cool the mass & add dil HCl to reaction vessel
to quench the reaction mass. Extract the reaction mass using ethyl acetate. Separate the organic
layer & again extract aq. Layer using ethyl acetate. To combined organic layer wash with aq. Sodium
bicarbonate. Wash the organic layer with aq. Sodium chloride & then distil of ethyl acetate completely
under vacuum below 45 to give UDCA-04.
Stage-05
Charge n-propanol & UDCA-04 to reaction vessel & stir to get a clear solution. Charge sodium
bromide & acetic acid followed by addition of DM water. Cool the reaction mass & slowly add
sodium hypochlorite solution. Maintain the reaction & after reaction completion slowly charge
aq. Sodium sulfite. Distill off water & n-propanol azeotropically. Cool the reaction mass & add
water. Slowly adjust the pH using Dil HCl & filter the solid. Wash the wet cake with Water & re
crystallize the solid in methanol, dry the solid in oven under vacuum till LOD came below
0.5%. Unload the solid as UDCA-05
UDCA-06
Charge IPA & tert-butoxide to a reaction vessel & stir to get a clear solution. Charge UDCA-05
& stir. Charge the reaction mass to pressure vessel. Slowly apply Hydrogen gas up to 3 bar &
raise the temperature of reaction mass up to 90 degree. Monitor the reaction Progress by
HPLC & after completion of reaction, release the pressure & filter the mass. Distill off IPA &
add water to residue. Slowly added sulfuric acid to adjust the pH 7-8 & again distill water &
traces of IPA. Charge water & heat the mass, adjust the pH to 2-2.5. Cool the mass & filter the
solid. Dry the wet cake in oven under vacuum till LOD came less than 0.5%. Unload the solid
as UDCA-06
UDCA-07
Charge Methyl ethyl ketone & UDCA-06 to reaction vessel. Heat the mass to 75-80 degree
& slowly add TEA. Stir the reaction mass & slowly cool to 20-25 degree. Filter the mass & re
crystallize the solid using methyl ethyl ketone. Dry the solid in oven till LOD came less than
0.5%. Unload the dry solid as UDCA-07
UDCA
Charge purified water & UDCA-07 to reaction vessel at 25-30oC. Heat the reaction mass
slowly added aq. NaOH solution to get a clear solution. Further heat the reaction mass to 80-
85oC & adjust the pH of reaction mass to 2.4 using dil. Sulfuric acid. Cool the reaction mass
to 35-40oC & filter the mass. Wash the wet cake with purified water & dry the solid in oven
under vacuum below 85 degree till LOD came below 0.5%. Unload the dry solid as UDCA &
submit the sample in QC for complete analysis.
Input Output
Water is charged to a reaction vessel at room temperature followed by stage- 01 material. Aq.
Solution of KOH is added slowly & reaction mass is stirred for 2 hrs at same temperature. Solid
is filtered to give N-octyl-D Glucamine, which is dried, tested & reused in next batch. Mother
liquor is charged to another reaction vessel & pH is adjusted with acetic acid. Solid is filtered to
give Dex Ibuprofen. Material is dried & submitted for complete analysis.
Stage-I
cyclohexane & cyclohexanone is charged to a reaction vessel followed by methyl
cyanoacetate & ammonium acetate, reaction mass is heated to reflux temperature and
remove water azeotropically. Cool & Filter the reaction mass. Filtrate ML is diluted water
followed by layer separation. Organic phase transfer for recovery to give stage-01.
Stage-II
Methanol & water is charge at atmospheric temperature followed by sodium cyanide.
Then stage-1 is added in 20-30 min. Heat the reaction mass to reflux temperature and
maintain. Allow RM to cool to & Add water slowly over period. Distill out methanol.
Filtered off the reaction mass, unload the wet cake. Dry the wet material.
Stage-III&IV
Charge ethanol & stage-2 material to reaction vessel. Cool the reaction mass & Purge the
dry HCl gas to reaction mass. Stir the reaction mass till completion, apply vacuum and
distilled out ethanol. Allow Reaction mass to cool to 25-30°C. Add slowly water & toluene.
Adjust the pH of reaction mixture by using 1N NaOH solution. Settle and separate out
layers. Distilled out toluene under vacuum & then cool to Room temperature. Unload the
stage-3.
Arrange clean and dry autoclave. Charge Stage-4 at room temperature. Charge Raney
Nickel at room temperature. Charge potable water & apply the nitrogen pressure to
autoclave and start agitation then release the nitrogen pressure. Apply the hydrogen
pressure and start heating. Heat the reaction mass to till reaction completion. Filter the
reaction mass through hyflo bed & Distilled out water under vacuum to get thick oily mass
to semi solid. Charge conc. HCl at room temperature. Heat the reaction mass to &
Distilled out hydrochloric acid under vacuum, precipitated gabapentin hydrochloride
filtered through Buckner funnel & Dry the material.
Stage-VII:
Charge Stage-6 at room temperature. Charge DM water & Charge Methylethylketone at
room temperature. Heat the reaction mass & Adjust the pH by using Liq. NH3 solution.
Gradually cool the reaction mass & Maintain. Filtered the solid through Buckner funnel &
Charge Methanol & wet cake at room temperature. Heat the reaction mass to reflux
temperature. Maintain the reaction mass at reflux temperature. Cool the reaction mass,
Filter the precipitated solid and dry the material.By-Product Ammonium chloride sell to
authorized dealer.
Stage-01:
Maltol is reacted with DMS in presence of potassium carbonate using acetone as solvent under
reflux, reaction mass is distilled under vacuum, aq. Ammonia is charged and reaction mass is
further heated, after distillation 3-Methoxy-2-methyl-pyridine-4-one is crystallized & filtered with
acetone.
Stage-02:
Stage 01 is reacted with phosphorusoxychloride, reaction mass is distilled and further reacted
under heating with hydrogen peroxide in presence of acetic acid, oil obtained from distillation of
reaction mass is allowed to react with sodium hydroxide in presence of methanol under reflux,
after reaction completion reaction mass is distilled and reacted with acetic anhydride under
heating, distillation gave crude oil, alkaline pH of reaction mass is maintained by caustic lye and
product is extracted in MDC, which is further reacted with thionyl chloride to give 3,4- dimethoxy-
2-chloromethylpyridine. Hydrochloride.Trisodium phosphate is generated as by product which
shall be converted in calcium phosphate by reaction with CaCl2, The final byproduct i.e. Calcium
Phosphate shall be sell to authorized dealer.
Stage-03:
3,4-dimethoxy- 2- chloromethyl pyridine Hydrochloride is dissolved in water & aq. Layer is
reacted with 5-difluoromethoxy-2- mercaptobenzimidazole in presence Sodium hydroxide. After
reaction completion material is extracted with MDC as solvent to give 5- difluromethoxy-2-
[[(3,4-dimethoxypyridin-2-yl]methyl]thio]- benzimidazole. MDC layer undergoes oxidation
reaction with hypo solution under cooling, after completion of reaction, MDC is distilled off & aq.
sodium hydroxide solution in acetone is added & precipitated material is filtered under cooling to
give Sodium-5-difluromethoxy-2- [[(3,4-dimethoxypyridin-2-yl]methyl]sulfinyl]- benzimidazole.
Sesquihydrate (Pantoprazole Sodium sesquihydrate).
Water MT 1.0000
TOTAL MT 1.405 TOTAL MT 1.405
STAGE 3
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
3-Methoxy-2-methyl- MT 0.3217 4-Chloro-3-methoxy-2- MT 0.3645
pyridine-4-(1-H)-one methyl-pyridine
Phosphoryl Chloride MT 0.3585 Trisodium phosphate MT 0.3794
Sodium Hydroxide MT 0.2777 Hydrochloric Acid MT 0.1689
Water MT 1.0000 Water MT 1.0451
TOTAL MT 1.9579 TOTAL MT 1.9579
STAGE 4
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
4-Chloro-3-methoxy-2- MT 0.3645 4-Chloro-3-methoxy-2- MT 0.4016
methyl-pyridine methylpyridine-1-oxide
Acetic Acid MT 0.1388 Acetic Acid MT 0.1388
Hydrogen Peroxide MT 0.0795 Water MT 1.0424
Water MT 1.0000
TOTAL MT 1.5828 TOTAL MT 1.5828
STAGE 5
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
4-Chloro-3-methoxy-2- MT 0.4016 3,4-dimethoxy-2- MT 0.3912
methylpyridine-1-oxide methylpyridine-1-oxide
Sodium Methoxide MT 0.1266 Sodium Chloride MT 0.1250
Water MT 1.0000 Water MT 1.0120
TOTAL MT 1.5282 TOTAL MT 1.5282
STAGE 6
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
3,4-dimethoxy-2- MT 0.3912 (3,4- MT 0.4884
methylpyridine-1-oxide dimethoxypyridine-2-
yl) methyl acetate
Acetic anhydride MT 0.2384 Acetic Acid MT 0.1388
Water MT 1.0000 Water MT 1.0024
TOTAL MT 1.6296 TOTAL MT 1.6296
STAGE 7
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
(3,4-dimethoxypyridine- MT 0.4884 (3,4- MT 0.3912
2-yl) methyl acetate dimethoxypyridine-2-
yl) Methanol
Sodium hydroxide MT 0.0935 Sodium acetate MT 0.1898
Water MT 1.0410 Water MT 1.0419
TOTAL MT 1.6229 TOTAL MT 1.6229
STAGE 8
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
(3,4-dimethoxypyridine- MT 0.3912 2-(Chloromethyl)-3,4- MT 0.5185
2-yl) Methanol dimethoxypyridine
hydrochloride
Thionyl chloride MT 0.2782 Sulphur dioxide MT 0.0148
Water MT 1.0000 Water MT 1.1361
TOTAL MT 1.6694 TOTAL MT 1.6694
STAGE 9
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
2-(Chloromethyl)-3,4- MT 0.5185 5-(Difluoromethoxy)-2- MT 0.8495
dimethoxypyridine {[(3,4-dimethoxy
hydrochloride pyridine-2-yl
)methyl]sulfonyl}-1H-
benzimidazole
5-(difluromethoxy)-1H- MT 0.5000 Sodium Chloride MT 0.2708
benzimidazole-2-thiol
Sodium Hydroxide MT 0.187 Water MT 1.0852
Water MT 1.0000
TOTAL MT 2.2055 TOTAL MT 2.2055
STAGE 10
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
5-(Difluoromethoxy)-2- MT 0.8495 Pantaprazole Sodium MT 1.0000
{[(3,4-dimethoxy
pyridine-2-yl
)methyl]sulfonyl}-1H-
benzimidazole
Sodium Hypochlorite MT 0.1741 Sodium Chloride MT 0.1354
Sodium Hydroxide MT 0.0925 Water MT 1.0432
Water MT 1.0625
TOTAL MT 2.1786 TOTAL MT 2.1786
Stage-01:
Chloroform is charged to a reaction vessel at room temperature. O- tolylbenzonitrile is charged
and reaction mass is stirred. Bromination is done under heating using Dibromo Hydrantoin &
benzoyl peroxide. Reaction mass is quenched using water & organic layer is distilled. Toluene is
charged to reaction vessel, followed by water and CS flakes. 2-Butyl-4-chloro-5-formylimidazole
is added and reaction mass is stirred at room temperature, followed by addition of TBAB,
reaction mass is stirred till reaction completion, layer is separated and organic layer is charged to
reaction vessel, methanolic solution of sodium boro-hydride is added to reaction mass under
stirring, after reaction completion solid is filtered and dried as stage-01 material. By product
Sodium borotrihydrate will be sell to authorized dealer (Ansh Chem Tech).
Stage-02:
Toluene & stage-01 material is charged to reaction vessel followed by TEA hydrochloride,
reaction mass is stirred and sodium azide is added, reaction mass is refluxed and reaction
completion temperature is brought to room temperature, pH of reaction mass is adjusted to 7
using acetic acid, solid thus formed is filtered and dried as stage-02 compound.
Stage-03:
IPA is charged to reaction vessel followed by KOH, reaction mass is stirred to get a clear
solution. Stage02 material is charged and stirred to get dissolved. Reaction mass is distilled and
1.5 Volume IPA is charged, reaction mass is cooled and stirred for 2 hrs. Solid is filtered and
dried to give Losartan potassium
STAGE 2
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
4'- MT 0.5900 4'-{[2-butyl-4-chloro- MT 0.8199
(bromomethyl)biphen 5-(carbaldehyde)-
yl-2 -carbonitrile 1H-imidazol-1-
yl]methyl}biphenyl-2-
carbonitrile
2-butyl-4-chloro-1H- MT 0.4088 Sodium Bromide MT 0.2222
imidazole-5-
carbaldehyde
Sodium Hydroxide MT 0.0876 Water MT 5.0443
Water MT 5.0000
TOTAL MT 6.0864 TOTAL MT 6.0864
STAGE 3
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
4'-{[2-butyl-4-chloro- MT 0.8199 4'-{[2-butyl-4-chloro- MT 0.8242
5-(carbaldehyde)-1H- 5-(hydroxymethyl)-
imidazol-1- 1H-imidazol-1-
yl]methyl}biphenyl-2- yl]methyl}biphenyl-2-
carbonitrile carbonitrile
Sodium Borohydride MT 0.0828 Sodium Borate MT 0.1817
Water MT 5.1171 Water MT 5.0009
Hydrogen MT 0.0130
TOTAL MT 6.0198 TOTAL MT 6.0198
STAGE 4
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
STAGE 5
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
Losartan MT 0.9175 Losartan Potassium MT 1.0000
Potassium Hydroxide MT 0.1426 Water MT 5.0601
Water MT 5.0000
TOTAL MT 6.0601 TOTAL MT 6.0601
CMIC acid
Methanol and OCB are heated. HAS dissolved in water is added to the reaction mixture.
The oxime formed is brought in contact with chlorine. After chlorination is completed,
nitrogen gas is passed &methanol distillation is carried out The chloro-oxime is subjected to
neutralization by adding soda ash and recovered sodium sulphate sale to paper and glass
industries.. The pH of the reaction is adjusted between 1.0-1.2. In another flask sodium
hydroxide flakes and methanol are mixed together charged to methylacetoacetate to form
sodium salt of MAA. The sodium salt of MAA is added to chloro-oxime mass; the reaction
mass is heated & after reaction completion, cooled product is then subjected to
acidification with 20% sulphuric acid solution. The pH is maintained,after acidification the
reaction mass is filtered.
CMIC Chloride
Toluene and DMF are charged to CMIC Acid and reaction mixture is heated. Meanwhile
prepare solution of triphosgene in toluene. Slowly add the solution to reaction mixture.
Then maintain the reaction mixture, after maintaining cool the reaction mass to room temp.
Settle and separate the organic layer. Distill out toluene under vacuum. Charge n-Hexane
to oily residue.Heat to get clear reaction mass, further cool & maintain. Filter the solid under
nitrogen to give CMIC chloride.Sodium sulphate as a by-product will sell to authorized
dealer.
Methanol and DCB are heated. HAS dissolved in water is added to the reaction mixture.
The oxime formed is brought in contact with chlorine, methanol distillation is carried out.
The chloro-oxime is subjected to neutralization by adding soda ash and recovered sodium
sulphate sale to paper and glass industries. In another flask sodium hydroxide flakes and
methanol are mixed together and charged to methyl aceto acetate to form sodium salt of
MAA. The sodium salt of MAA is added to chloro- oxime mass; the reaction mass
temperature is maintained under cooling. The cooled product is then subjected to
acidification with 20% sulphuric acid solution. The pH is maintained,the reaction mass is
filtered to give DCMIC acid
DCMIC Chloride
Toluene and DMF are charged to DCMIC Acid and reaction mixture is heated. Meanwhile
prepare solution of triphosgene in toluene. Slowly add the solution to reaction mixture. After
maintaining cool the reaction mass to room temp. Settle and separate the oily layer. Distill
out toluene under vacuum. Charge n-Hexane .Heat to get clear reaction mass. Cool to RT.
and filter the solid under nitrogen. Sodium sulphate as a by-product will sell to authorized
dealer.
FCMIC Acid
FCMIC Chloride
Toluene and DMF are charged to FCMIC Acid and reaction mixture is heated. Meanwhile
prepare solution of triphosgene in toluene. Slowly add the solution to reaction mixture.
Then maintain the reaction mixture. After maintaining cool the reaction mass to room
temp. Settle and separate the oily layer. Distill out toluene under vacuum. Charge n-Hexane
.Heat to get clear reaction mass. cool and filter the solid under nitrogen. Sodium sulphate as
a by-product will be sell to authorized dealer.
STAGE 1
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
FlouroBenzaldehyde MT 0.2892 Oxime MT 0.3166
Hydroxylamine MT 0.1517 Sulphuric Acid MT 0.089
Sulphate
Water MT 1.0000 Water MT 1.0353
TOTAL MT 1.4409 TOTAL MT 1.4409
STAGE 2
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
Oxime MT 0.3166 Chloroxime MT 0.3794
Sulphuric Acid MT 0.089 Sodium Chloride MT 0.1066
Chlorine MT 0.1306 Carbondioxide MT 0.08
Sodium Carbonate MT 0.1933 Sodium Sulphate MT 0.1295
Water MT 2.0000 Water MT 2.0340
TOTAL MT 2.7295 TOTAL MT 2.7295
STAGE 3
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
Chloroxime MT 0.3794 FCMIC Ester MT 0.4919
Methyl Acetoacetate MT 0.2139 Sodium Chloride MT 0.1066
Sodium Hydroxide MT 0.0729 Water MT 1.0677
Water MT 1.0000
TOTAL MT 1.6662 TOTAL MT 1.6662
STAGE 4
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
FCMIC Ester MT 0.4919 FCMIC Acid MT 0.4663
Sodium Hydroxide MT 0.073 Sodium Sulphate MT 0.1295
Sulphuric Acid MT 0.089 Methanol MT 0.058
Water MT 1.0000 Water MT 1.0001
TOTAL MT 1.6539 TOTAL MT 1.6539
STAGE 5
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
FCMIC Acid MT 0.4663 FCMIC Chloride MT 0.5000
Triphosgene MT 0.1822 Hydrochloric Acid MT 0.0660
Water MT 1.000 Carbon Dioxide MT 0.080
Water MT 1.0025
TOTAL MT 1.6485 TOTAL MT 1.6485
Stage-I.
m – Xylene is charged in reaction vessel. Charged sodium metal and potassium carbonate
into it, oleic acid used as a emulsifying agent in above reaction,Raise the temperature of
reaction mass and apply pressure of propylene. Maintain the reaction mass at elevated
temperature under pressure. After reaction completion the reaction mass quenched with
methanol and water. Separate organic layer and aqueous layer. Distilled out MIBT using
fractional column.
STAGE 1
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
Propyl Alcohol MT 11.76 Propyl Acetate MT 20.00
Acetic Acid MT 11.88 Water MT 13.64
Water MT 10.00
TOTAL MT 33.64 TOTAL MT 33.64
Stage-II.
Charged chloroform in reaction vessel. Charged D-Serine methyl ester hydro chloride into it
followed by addition of thionyl chloride. Heat the reaction mass for 24 hours. After reaction
completion filtered the reaction mass to give crude 2-Methyl-2-amino-3-chloropropanoate
hydrochloride. The crude is crystallized in methanol. Filtered it and dried it to give white solid 2-
Methyl-2-amino-3-chloropropanoate hydrochloride.
Stage-I.
STAGE 2
INPUT OUTPUT
Name of Material Unit Qty Name of Material Unit Qty
Di-ester MT 0.2712 ATTBA MT 0.2500
Sodium Hydroxide MT 0.0306 Methanol MT 0.0240
Methanol MT 0.0240 Sodium Chloride MT 0.0440
Hydrochloric Acid MT 0.0270 Iso Propyl Alcohol MT 0.0450
Iso Propyl Alcohol MT 0.0450 Ethanol MT 0.0340
Water MT 5.0130 Water MT 5.0138
TOTAL MT 5.4108 TOTAL MT 5.4108
Stage-01: Methanol is charged in reaction vessel. Charged 3-cyano pyridine to it. Slowly add
acetic acid followed by addition of hydrogen peroxide. Reaction mass is stirred and refluxed for
few hours. After reaction completion distill off methanol & acetic acid, unload oily residue as
stage-01 material i.e. 3-Cyano pyridine-N-oxide.
Stage-02: Chloroform & stage-01 material is charged to reaction vessel followed by addition of
phosphorous oxy chloride under stirring. Reaction mass is refluxed and after reaction completion
temperature is brought to room temperature, solvent along with unreacted POCl3 is distilled off &
pH of reaction mass is adjusted to 9-10 using aqueous sodium hydroxide. Solid thus formed is
filtered. 2-Chloro-3-cyano pyridine is purified using crystallization with MDC and dried it.
Metaphophoryl chloride shall be generated as a by product and sell to authorized dealer.
Stage-01: A solution of p-tolyl magnesium chloride in THF is charged reaction vessel under
nitrogen atmosphere at room temperature followed by o-bromobenzonitrile. After stirring reaction
mixture is hydrolyzed 1N hydrochloride solution. After extracting with ethyl ether, the organic
phase is dried over potassium carbonate, filtered and then evaporated under vacuum. Purified
OTBN using ethyl acetate Filtered it and dried it. White colour dry powder obtained. Mangesium
chloride bromide shall be generated as a by product and sell to authorized dealer.
Stage-I.
Benzaldehyde reacted with bromine and chlorine in presence of Aluminum Chloride, Ethylene di
chloride as a solvent in above reaction, the Brominated mass quenched in water and washed.
After washing organics mass is distilled and recovered ethylene di chloride is reused in
bromination. Distilled metabromo benzaldehyde taken for second stage. Distilled metabromo
benzaldehyde taken for second stage and Poly Aluminium Chloride to sale to paper industries for
paper sizing.
Stage-II.
Metabromo benzaldehyde reacted with Mono Ethyl Glycol and produce Meta bromobenzalacetal,
This metabromobenzalacetal react with KOH and phenol in presence of Toluene Solvent and
produce meta phenoxy benzalacetal which on hydrolysis with Sulphuric acid and water give meta
phenoxy Benzaldehyde and MEG water is neutralized with caustic lye and recovered water and
mono ethylene Glycol is recycle in next batch. Potassium bromide, hydrobromide are generated
as a by product and sell to authorized dealer. HCL is also generated as a byproduct which shall
be use in other products.
Stage-01: MDC is charged to the reaction vessel. Then 4-amino benzoic acid is charged to it
followed by addition of thionyl chloride at room temperature. After this quenched the reaction
mixture with water. Separate organic layer and aqueous layer.
Stage-02: transfer organic layer of stage-01 into reaction vessel. Add ammonia solution slowly.
Distill off solvent completely, solid thus formed is filtered. 4-amino benzamide is purified by
crystallization using methanol and dried as stage-02 i.e. 4-amino benzamide. HCL is also
generated as a byproduct which shall be use in other products.
chloride chloride
Water MT 5.0000 Hydrochloric acid MT 0.5897
Water MT 5.0332
TOTAL MT 11.1018 TOTAL MT 11.1018
Stage-I.
4-Hydroxybenzaldehyde reacted with bromine in presence of Aluminum Chloride, methane di
chloride as a solvent in above reaction, the Brominated mass quenched in water and washed.
Distill methane di chloride. 3-bromo-4-hydroxybenzaldehyde used in next stage and Poly
Aluminium Chloride to sale to paper industries for paper sizing.
Stage-II.
3-Bromo-4-hydroxy benzaldehyde reacted with sodium methoxide in presence of copper
bromide, ethyl acetate used as a solvent. Heat the reaction mass until reaction complies. Slowly
cool the reaction mass and filtered it. Vanillin is purified using chloroform. Sodium bromide and
hydrogen bromide are generated as by product which shall be sell to authorize dealer. HCL is
also generated as a byproduct which shall be use in inhouse DM plant.
henol
19. 62-53-3 ORAL (LD50): Acute:
Aniline 2.07 Liquid In ,Drums
250 mg/kg [Rat.].
stored in ware
house
20. 79-04-9 Rat LD50 (oral)
Chloro 2.51 Liquid In ,Drums
208mg/kg
acetyl stored in ware
Chloride house
21. 124-41-4 ORAL (LD50): Acute:
Sodium 1.917 Solid In Bags ,Stored
2037 mg/kg [Rat]
Methoxide in ware house
22. 1310-73- LC50 = 1200
Sodium 3.8566 Solid In Bags ,Stored
2 mg/m3/2H; Inhalation,
Hydroxide in ware house
rat, LD50 = 6600
mg/kg; Oral, rat
23. 461-58-5 Mouse LD50 (oral) 10
Dicyandimi 20.30 Solid In Bags ,Stored
g/kg
de in ware house
24. 506-59-2 Acute oral toxicity
Dimethyla 19.89 Solid In Bags ,Stored
(LD50): 1070 mg/kg
mine in ware house
[Rat
Hydrochlor
ide
25. 42019-
4- 0.4839 Solid In Bags ,Stored
78-3
chlorophen in ware house
yl (4-
hydroxyph
enyl)-
methanone
26. 67-66-3 Acute oral toxicity
Chloroform 5.56 Liquid 20
(LD50): 36 mg/kg
[Mouse].Acute toxicity
of the vapor (LC50):
47702 mg/m 4 hours
[Rat]. 3
27. 67-66-3 Acute oral toxicity
Acetone 15.06 Liquid 55
(LD50): 36 mg/kg
[Mouse].Acute toxicity
of the vapor (LC50):
47702 mg/m 4 hours
[Rat]. 3
28. 67-64-1 Acute oral
2- 0.4421 Solid In Bags ,Stored
toxicity (LD50): 3000
chlorophen in ware house
mg/kg [Mouse]. Acute
yl glycine
toxicity of the vapor
(LC50): 44000 mg/m3
4 hours [Mouse]
29. 67-56-1 Acute toxicity of the
Methanol 7.236 Liquid 35
vapor (LC50):
64000 4 hours
[Rat].Acute oral
toxicity (LD50): 5628
mg/kg [Rat]
30. 1336- Acute oral toxicity
Ammoniu 0.337 Liquid In ,Drums
aldehyde
45. 110-89-4 LD50 = 337 mg/kg (
Piperidine 0.0769 Liquid In Bags ,Stored
Rat )
in ware house
46. 14205- Oral rat LD50 : 1760
Methyl-3 0.0534 Solid In Bags ,Stored
39-1 mg/kg.
amine in ware house
crotonate
47. 6574-97-
2-3 0.0781 Solid In Bags ,Stored
6
dichloro in ware house
benzonitril
e
48. 2582-30- Rat LD50.
Amino 0.0536 Solid In Bags ,Stored
1 (intraperitoneal).
Guanidine 1160mg/kg in ware house
bicarbonat
e
49. 101-82-6
2 Benzyl 0.0700 Liquid In Bags ,Stored
Pyridine in ware house
50. 6574-97-
2 chloro - 0.0600 Solid In Bags ,Stored
6
N-N in ware house
dimethyl
ethyamine
hydrochlori
de
51. 2582-30- Rat LD50.
Sodium 0.0163 Solid In Bags ,Stored
1 (intraperitoneal).
Amide 1160mg/kg in ware house
52. 101-82-6
Ibuprofen 2.35 Solid In carboys,
Stored in BSR
53. 6574-97-
DL-Lysine 0.2092 Solid In Bags ,Stored
6
in ware house
54. 81-25-4 Oral LD50 (mouse):
Cholic Acid 0.2601 Solid In Bags ,Stored
4950 mg/kg
in ware house
55. 7681-52- Acute oral toxicity
Sodium 0.0948 Liquid In ,Drums
9 (LD50): 5800 mg/kg
Hypochlorit [Mouse]. stored in ware
e house
56.
Hydrazine 302-01-2 0.0205 Liquid In ,Drums
stored in ware
house
57. 1310-58- Acute oral toxicity
Potassium 1.183 Solid In Bags ,Stored
3 (LD50): 273 mg/kg
Hydroxide [Rat] in ware house
58.
Hydrogen 1333-74- LC50 inhalation rat 0.0012 Gas In 7m3 /10 M3
gas 0 (ppm) > 15000 cylinders store
ppm/1h in separate
yard
59. 865-47-4 LD50 Oral 1650
Potassium 0.1442 Solid In Bags ,Stored
mg/kg ( Rat )
Tert in ware house
Butoxide
60. 121-44-8 Acute oral toxicity
Triethylami 0.8769 Liquid In ,Drums
(LD50): 460 mg/kg
ne [Rat.] stored in ware
house
61. 3159-07-
Dibenzo[b, 0.7721 Solid In Bags ,Stored
7
f][1,4]thiaz in ware house
epin-
11(10H)-
one
62. 10025- ORAL (LD50):. Acute:
Phosphoru 0.8207 Liquid In ,Drums
87-3 380 mg/kg [Rat]
s Oxy- stored in ware
chloride house
63. 13349-
Piperazinyl 0.5979 Liquid In ,Drums
82-1
ethoxy stored in ware
ethanol house
64.
Fumaric 110-17-8 Acute oral toxicity 0.3983 Solid In ,Drums
Acid (LD50): 10700 mg/kg stored in ware
[Rat] house
65. 23323-
N-Octyl D 0.7207 Solid In ,Drums
37-7
Glucamine stored in ware
house
66. 108-94-1 ORAL (LD50): Acute:
Cyclohexa 2.8655 Liquid 10.00
1516 mg/kg [Rat]
none
67. 105-34-0
Methylcya 2.8933 Liquid 10.00
noacetate
68. 631-61-8 Oral Rat LD50mg/kg:
Ammoniu 2.2733 Solid In ,Drums
736.
m acetate stored in ware
house
69. 110-82-7 ORAL (LD50): Acute:
Cyclohexa 2.4573 Liquid 10.00
12705 mg/kg [Rat]
ne
70. 7647-01- Acute toxicity of
Dry HCl 3.1972 Gas In 50 kg
0 the vapor (LC50):
Cylinders,
3124 ppm, 1 hours
Store in
[Rat]
separate yard
71. 12635- LD50: Not available.
Raney-Ni 1.7136 Solid In ,Drums
27-7 LC50: Not available
stored in ware
house
72. 78-93-3 ORAL (LD50): Acute:
Methylethy 5.0657 Liquid 20.00
2737 mg/kg [Rat].
lketone
73.
Liq. 7664-41- LC50 inhalation rat 0.9085 Liquid In ,Drums
Ammonia 7 (ppm) 7338 ppm/1h stored in ware
house
74. 77-78-1 Acute oral
Di methyl 0.3231 Liquid In ,Drums
toxicity (LD50): 140
sulphate stored in ware
mg/kg [Mouse]. Acute
house
toxicity of the vapor
(LC50): 45 ppm 4
hour(s) [Rat]
75.
Di chloro 75-09-02 Acute oral toxicity 6.6056 Liquid 20.00
methane (LD50): 1600 mg/kg
[Rat]. Acute toxicity of
the vapor (LC50):
52000 1 hours [Rat].
76. 7722-84- Acute OralLD50 Rat:
Hydrogen 0.1414 Liquid In ,Drums
1 1253 mg/kg.
peroxide stored in ware
house
77. 7719-09- LD50 Oral - rat - 324
Thionyl 2.7336 Liquid In ,Drums
7 mg/kg
chloride stored in ware
house
78. 97963-
5- di fluoro 0.5000 Solid In ,Drums
62-7
methoxy-2- stored in ware
mercapto house
benzimida
zole
79. 114772-
4-Methyl- 0.4186 Solid In ,Drums
53-1
2- stored in ware
cyanobiph house
enyl
(OTBN)
80. 77-48-5 Oral, rat: LD50 = 250
Dibromo 0.6264 Solid In ,Drums
mg/kg;
Hydrantoin stored in ware
house
81.
hyflo 0.022 Solid In Bags ,Stored
in ware house
82. 83857- LD50 = 980 mg/kg
2-Butyl-4- 0.4088 Solid In ,Drums
96-9
chloro-5- stored in ware
formyl- house
Imidazole
83. 16940- ORAL (LD50): Acute:
Sodium 0.1205 Solid In, Drums
66-2 160 mg/kg [Rat]
borohydrid stored in ware
e (NaBH4) house
84.
Sodium 26628- Acute oral toxicity 0.1426 Solid In, Drums
Azide 22-8 (LD50): 27 mg/kg stored in ware
[Mouse] house
85. 7440-44- Acute inhalation is
Activated 0.081 Solid In, Drums
0 LC50 (RAT) is 64.4
Carbon stored in ware
mg/l house
86. 115-46-8 Acute Oral, mouse:
Diphenyl(pi 0.2668 Solid In Bags, Stored
LD50 = 650 mg/kg.
peridin-4- in ware house
yl)methano
l
87. 154477-
Methyl-2- 0.2850 Liquid In, Drums
54-0
(4-(4- stored in ware
chlorobuta house
noyl)pheny
l)-2-
methylprop
anoate
88. 68-12-2 ORAL (LD50): Acute:
Dimethylfo 1.3946 Liquid In, Drums
2800 mg/kg [Rat]
rmamide stored in ware
house
89.
Ethyl 141-78-6 Acute oral 3.7295 Liquid 1265.00
acetate
toxicity (LD50): 4100
mg/kg [Mouse]. Acute
toxicity of the vapor
(LC50): 45000 mg/m3
3 hours [Mouse]
90. 16940- ORAL (LD50): Acute:
Sodium 0.0377 Solid In Bags ,Stored
66-2 160 mg/kg [Rat]
borohydrid in ware house
e
91. 89-98-5
2- 1.0978 Liquid In, Drums
Chloroben stored in ware
zaldehyde house
92. 10039- LD50 = 842 mg/kg (
Hydroxyla 1.8825 Solid In Bags, Stored
54-0 Rat ).
mine in ware house
sulphate
93. 105-45-3 LD50 Rat oral 3.0
Methylacet 1.337 Liquid In, Drums
g/kg
oacetate stored in ware
LC50 Rat inhalation
house
>26.4 mg/L/1 hr
94.
Triphosgen 32315- 3.400 Solid In Bags, Stored
e 10-9 in ware house
95.
EDTA 10378- Acute oral toxicity 0.275 Solid In Bags, Stored
23-1 (LD50): >2000 mg/kg in ware house
[Rat].
96. 83-38-5
2,6 – 0.2419 Solid In Bags, Stored
Dichlorobe in ware house
nza
aldehyde
97. 387-45-1
2-cholro-6- 0.2564 Solid In Bags, Stored
fluorobenz in ware house
aldehyde
house
112.
Aluminium 21645- 2.0180 Solid In Bags ,Stored
Hydroxide 51-2 in ware house
113. 7726-95- ORAL (LD50): Acute:
Bromine 4.565 Liquid In ,Drums
6 3100 mg/kg [Mouse]
stored in ware
house
114. 108-95-2 ORAL (LD50): Acute:
Phenol 1.4387 Liquid In ,Drums
317 mg/kg [Rat]
stored in ware
house
115. 150-13-0 LD50 Oral - Mouse -
4-Amino 2.0145 Solid In Bags ,Stored
2,850 mg/kg
benzoic in ware house
acid
116. 1336- Acute oral toxicity
Ammonia 0.2522 Gas 120 Nos of
21-6 (LD50): 350 mg/kg
Cylinder in
[Rat].
Ammonia yard
117. 62-23-7 ATEmix (oral) 1960
p-Nitro 2.7018 Solid In Bags ,Stored
mg/kg
benzoic in ware house
acid
118. 10026- ORAL (LD50): Acute:
Phosphoro 3.4000 Solid In Bags ,Stored
13-8 660 mg/kg [Rat]
us penta in ware house
chloride
119. 123-08-0 LD50 Oral - Rat
4-Hydroxy 1.6055 Solid In Bags ,Stored
2,250 mg/kg
benzaldeh in ware house
yde
120. 75-05-8 Acute toxicity of the
Acetonitrile 0.007 Liquid In ,Drums
vapor (LC50):
stored in ware
7551 8 hours [Rat.]
house
121. 112-27-6 ORAL (LD50): Acute:
Triethylene 0.270 Liquid In ,Drums
17000 mg/kg [Rat].
glycol stored in ware
house
122. 109-99-9 ORAL (LD50): Acute:
THF 0.650 Liquid In ,Drums
1650 mg/kg [Rat].
stored in ware
VAPOR (LC50):
house
Acute: 21000
mg/m 3 hours [Rat]
123. 71-36-3 ORAL (LD50): Acute:
N-butanol 6.40 Liquid 30
790 mg/kg [Rat.]
All solid / powder / granular raw materials will come in bags / drums and will be
transported through road transport. Liquid raw materials will come in road tankers (bulk) or
in drums through road. Most of the raw materials are indigenously available.
Products are changed as per market demand. The solid raw materials in bags will be
stored in Godown with adequate safety measures.
{148 (from
MEE
condensate)
54 (from
UFRO)}
Washing 50 0 0 50 (To ETP)
Domestic 85 0 12 73 (To ETP)
Total 1800 344 502 954
(Source: IOLCP)
Figure 2.1: Proposed Water Balance (After expansion)
EQMS India Pvt. Ltd. Document No. IOL/EIA/01 Issue No. 01 R 00 Page 121 of 248
EIA/EMP Report for Expansion of Chemicals and APIs production unit by IOLCP
LTDS / 6-10 < 2000 <3000 - < 5000 Collection Equalization Tank
Neutralization Tank Two stage
LCOD
Anaerobic tank Aerobic tank
Secondary clarifierPressure
Sand Filter Activated Carbon Filter
For plantation.
Domestic 6-9 < 3000 < 3000 ETP/STP
Effluent Characteristics
Effluent generated from process, utilities and sewage which will be treated through
ETP of capacity 1000 KLD.proposed expansion will be carried out in existing unit and
online monitoring system is also installed, Punjab pollution control board has done the
sampling and monitoring, the copy of result is enclosed as Annexure XII. The inlet &
outlet characteristics of effluent are shown below
S.No Parameters Inlet of ETP Outlet of ETP Aeration
1. pH 6.9 7.9
2. Total Suspended 98 32
Solids (mg/l)
EQMS India Pvt. Ltd. Document No. IOL/EIA/01 Issue No. 01 R 00 Page 122 of 248
EIA/EMP Report for Expansion of Chemicals and APIs production unit by IOLCP
EQMS India Pvt. Ltd. Document No. IOL/EIA/01 Issue No. 01 R 00 Page 125 of 248
EIA/EMP Report for Expansion of Chemicals and APIs production unit by IOLCP
EQMS India Pvt. Ltd. Document No. IOL/EIA/01 Issue No. 01 R 00 Page 126 of 248
EIA/EMP Report for Expansion of Chemicals and APIs production unit by IOLCP
EQMS India Pvt. Ltd. Document No. IOL/EIA/01 Issue No. 01 R 00 Page 127 of 248
EIA/EMP Report for Expansion of Chemicals and APIs production unit by IOLCP
(Source:IOLCP)
2.13. AUXILIARY & GENERAL WELFARE FACILITIES
The following facilities have been considered under this head.
2.13.1. Fire and Safety System:
Site has full-fledged fire and safety system. Site has on-site emergency plan to get the
direction in case of emergency.
The fire and safety system shall be including:
Fire pumps (with emergency power from DG set) – 1 no. including 1 nos. jockey
pump, 1 nos. diesel driven, 1 no‘s electric pumps.
Water reservoir available for firefighting controlling
Full-fledged Emergency control centre
Fire hydrants
Other firefighting equipment including:
2.14. OHS System
IOLCP has well-organized Safety Management system with well defined ―Safety Health
& Environment Policy‖, ―Quality Policy‖. For the proposed expansion project, IOLCP is
committed to the principles of sustainable development. As a part of this commitment,
IOLCP protects the environment in which they operate and ensure the health and safety
of our employees, contractors, visitors and communities. All employees are responsible
for being aware about safety, health and environment needs in their area of work. The
proposed plant will also have these policies in place. The significance of safety & health
in chemical industries has been a vital issue in achieving productivity and an edge in
competitive world. Hence, all the pollution control measures envisaged at feasibility stage
will be implemented with due care.
The proposed plant will be designed as per guidelines comprising of separate entry &exit
for workers and material. The layout of plants will be under purview of various statutory
regulations and these regulations will be reviewed regularly. All reaction vessels will
relate to scrubber so that any toxic fumes/ vapor generated during reaction gets
neutralized.
The proposed plant will have Air Handling Units to keep temperature <25 deg in powder
processing area and filtered air will be supplied in other areas. Dust collector will be
provided in powder processing area to remove dust generated during sifting/ milling of
product. Workers engaged in powder processing work will be provided personal
protective equipment‘s like dust masks, respirators etc.
The proposed plant will be provided with sophisticated instrumentation for continuously
monitoring of operating parameters.
The plant premises will be strictly maintained as a ―NO SMOKING ―area. Firefighting
facility will be provided at site consisting of underground fire hydrant system and various
fire extinguishers.
For electrical instrumentation and installations, the entire plant will be sub divided into
hazardous and nonhazardous zone. In the hazardous zone, flameproof fittings &fixtures
will be provided. Arrangements will be made in each equipment to avoid static spark.
All reaction vessels will be provided safety valve, rupture disc, pressure gauges etc to
avoid any explosion. Provision for inert gas purging will be there in each reactor to avoid
possibility of developing any hazardous mixture.
The company will have On Site Emergency Plan to handle any emergencies e.g. fire,
chemical spillage and medical arising from any unforeseen reason.
Workers will be trained & make them aware regarding safety and proper hygiene in plant.
All workers will undergo periodic medical examination and will be provided personal
protective equipment‘s for their safety.
Major hazards can be avoided by proper implementation of Maintenance and Inspection
Schedule, Periodic maintenance will be in place to check the various types of
compressors, pumps, fan, and blowers and monitor the vibration level. Compliance of
Statuary Regulations related to Factory act and IBR in which all boilers will be hydro
tested all pressure vessels will be tested for ultrasonic thickness measurement and weld
joint by radiography. All hot/cold surfaces will be insulated. Waste generated during
process will be removed regularly. Proper housekeeping in maintenance block, utility
block will be done to ensure that spillage of oil, litters of maintenance material are
cleared off.
2.15. PROJECT COST ESTIMATES & IMPLEMENTATION SCHEDULE
This is a tentative schedule in which flexibility can be exercised depending upon the
market demand. Estimated project cost along with analysis in terms of economic viability
of the project.
Cost of Estimates of the Proposed Project is 205 crores. Project work will be start after
getting the environmental clearance.
2.16. CSR Activities
Unit has committed to spend about Rs. 1.53 crores (0.75% of the capital investment)
towards CER. But the Approved TOR is for 2.5 % of the project cost and IOLCP follow
the OM issued on dated 1st May 2018, hence earmarked the fund of Rs 1.53 crores. The
amount will be spending in next 3 years for infrastructure development of surrounding
area. Need based survey has been conducted in surrounding villages of the study area
and following facilities will be carried out and it will be continued for proposed expansion
project.
Allocation of funds for Public Development
Providing Bags of sugar to Jangham
Sponsor a child at CRY
Provide education expenditures for the physically disable persons i.e. deaf and
dumb ―Ek Prayas‖ and ―Govind Dham‖
Donation to schools such as Sacred Heart Convent School
Distribution of free medicines to the poor in nearby villages.
This Chapter describes the baseline environmental conditions around the project site for
various environmental attributes, i.e. physical, biological and socio-economic conditions,
within the 10 km radial zone of the proposed project site, which is termed as the study area.
Topography, drainage, meteorology, air, noise, water, soil and land constitute the physical
environment, where as flora and fauna constitute the biological environment. Demographic
details and occupational pattern in the study area constitute socio-economic environment.
Secondary data from literature search were also obtained from the Govt. sources i.e. Meteorological
Department, CPCB publications; Forest Department and other Govt. Sources. The baseline
th th
environmental data generation has been done for the period of 15 March 2018 to 15 Jun 2018. M/s JP
Test & Research Centre, Sahibabad, Uttar Pradesh with EQMS Team, carried out sampling and testing.
The study area within a 10 km radius around the proposed plant site has been considered as impact
zone for EIA study. Primary and secondary data has been collected for 10 Km radius of the project site.
3.1.1 Environmental Setting and Salient Environmental Features of the Project Area
The proposed project is an expansion project of existing unit situated at village Fatehgarh
Channa on Mansa road, Tehsil & District Barnala Punjab. As per the EIA notification dated 14th
September 2006, as amended till date, the proposed project falls under category 5(f), Synthetic
Organic chemical and site is not located in notified industrial area, hence proposed expansion
project shall be appraised as Category ―A‖ by MOEF&CC. The proposed project is expanding in
an area of 62 acres with a dense green belt of 30 acres (50% of the total plot area).
The proposed site is at a distance of about 1.45 km,SE from village Fatehgarh Channa. State Highway
13 is at a distance of .81 km NW in Direction. Nearest Railway station is Barnala railway station 8.69 km
from the project site and Chandigarh airport is approx. 130 km away in NE direction from project site
(aerial distance). The rail and road connectivity map of the site is provided in Figure 3.1. Nearest
settlement to the site is Fatehgarh Channa 1.47 km. There is no river present within the study area.
Location map showing site and surrounding environment features within the 10 km area is provided in
Figure 3.3 and Google map of 10 km radius of the site is provided in Figure 3.4. The Salient
Environmental Features of plant site within 500m, 2 Km and 10 Km radius is summarised at Table 3.1.
3.1.2 Primary Data Collection: Monitoring Plan and Quality Assurance Procedures
th
Primary baseline data has been collected as per the TOR prescribed by MOEF during 15 March 2018 to
th
15 June 2018 for one complete season. The study period and methodology for primary data collection is
summarized in Table 3.2.
Soil
Texture, bulk density, pH,
6 locations in Soil samples were collected at six
conductivity, cation exchange Once in a
study area locations within the study area and
capacity, organic matter, Total season
(Fig 3.5) analyzed as per IARI method
N,P,K, and Heavy metals etc
Noise
No. Of
Frequency/
Parameters sampling Remark
season
locations
Noise monitoring was conducted
8 locations in within the 10 km area of project site
Once in
Noise profiling for 24 hrs study area for noise profiling for 24 hrs using
season
(Fig 3.6) integrated sound level meter, as per
CPCB guidelines.
Ecology (Flora & Fauna)
Primary survey and Secondary
Flora & Fauna Once sources
Standard methods and procedures have been strictly adhered to in the course of this study. QA/QC
procedures were strictly followed which covers all aspects of the study, and includes sample collection,
handling, laboratory analyses, data coding, statistical analyses, presentation and communication of
results. All analysis was carried out in MoEF accredited/recognized laboratory. Environment sampling
Map is provided in Figure 3.5.
3.2.2 Drainage
According to the Watershed Atlas of India, the study area forms part of Lower Sutlej Sub-Basin
below Bhakra Dam. There is no well-defined material drainage system in the area. Two main
drains pass through the area – Upper Lisarna Nala in the northwest and Dhanaula Drain in the
central part. Large network of canals belonging to Bhakra main canal runs through core and
buffer zones
(http://www.barnalaonline.in/city-guide/geography-of-barnala)
Figure 3.8 Area statistics for Land Use / Land Cover Categories in the Study Area
3.4 Meteorology
Historical meteorological data was obtained from nearest IMD station located at Ludiana. The
predominant wind direction is from west and northwest direction during winter season. Details
provided in Table 3.4.
Table 3.4 Long Term Meteorological Data of Ludiana (30 years average)
Temperature Relative Predominant Wind Wind
o Rainfall
Month ( C) daily Humidity (%) Direction Speed
(mm) (From)
Max Min Max Min Km/hr
January 18.6 5.2 91 63 23.2 NW, W 4.8
February 20.9 6.9 87 59 29.7 NW, W 5.8
March 25.6 11.4 79 54 32.0 NW, W 6.5
April 33.7 16.9 55 32 28.3 NW 6.7
May 38.4 21.9 45 26 27.3 NW 7.1
June 39.2 25.6 54 35 56.1 NW 8.8
July 34.2 25.6 79 64 235.5 SE, NW 7.1
August 33.6 25.2 82 69 195.4 SE, NW 5.5
September 33.7 22.5 78 59 109.1 SE, NW 4.5
October 31.8 16.3 73 47 6.0 NW, W 3.6
November 26.6 10.9 81 53 11.1 NW, W 3.4
December 21.0 6.5 89 61 21.5 NW, W 3.9
Annual Total or
29.8 16.2 74 52 775.2 NW 5.6
Mean
Source: IMD
Temperature– December, January and February constitute winter months with daily mean
minimum temperature around 6.40C and daily mean maximum temperature around 28.9 0C. May
and June is the hottest month with daily mean maximum temperature at 39.2 0C and daily mean
minimum temperature at 23.7 0C.
Relative Humidity–April, May and June are driest with average relative humidity ranges
between 43-60%. The maximum humidity during monsoon season is 84%.
Rainfall– The annual total rainfall is 893 mm. Over 76% of the total annual rainfall is received
during the monsoon period between July to September.
Cloud Cover – In the study area, clear weather prevails in most of the time during post
monsoon, winter and summer seasons. Only during monsoon months of July, August and
September, moderate to heavy clouds are observed.
Wind Speed– The mean wind speed ranges from 4.4 to 5.0 kmph during post-monsoon, 6.6 to
9.3 kmph during monsoon and 7.9 to 8.2 kmph in pre-monsoon season.
Wind Direction– The predominant wind direction is from west and northwest direction in most of
the year except monsoon season where wind blows from east and west direction.
The wind directions, wind speed, temperature, rainfall and humidity recorded at site during study
period are presented in Table 3.6. Site specific wind rose diagram for study period is presented
in Figure 3.11.
Figure 3.10 Wind Rose Diagram of Study Area (Pre Monsoon Season)
Table 3.7 : Ambient Air Quality Monitoring Results for PM2.5 and PM10(24-hour average)
Location PM2.5 (µg/m³) PM10 (µg/m³)
Min Max Mean 98 Percentile Min Max Mean 98 Percentile
Project Site 38 56 45 54 74 97 88 97
Fatehgarh
Chhanna 40 62 48 60 77 112 92 111
Kaleke 33 66 47 63 68 110 89 109
Dhanaula 31 69 44 63 58 107 85 106
Dhaula 35 62 44 60 69 112 87 110
Ghunas 32 57 42 54 67 104 85 103
Handiaya 33 59 47 57 70 109 90 106
Barnala 37 57 48 56 76 115 93 114
Table 3.7 Conti... Ambient Air Quality Monitoring Results for SOx and NOx (24-hrs avg.)
Location SO₂ (µg/m³) NO₂ (µg/m³)
Min Max Mean 98 Percentile Min Max Mean 98 Percentile
Project Site 7.2 19.8 12.7 18.6 14.2 41.2 26.4 38.6
Fatehgarh
Chhanna 6.8 17.5 11.8 16.1 14.0 39.3 22.7 37.4
Kaleke 6.2 16.3 10.9 16.0 15.8 35.0 23.2 33.4
Dhanaula 6.5 17.0 11.4 16.4 15.3 32.2 21.1 30.7
Dhaula 7.0 18.8 12.5 18.1 16.5 35.5 23.8 34.0
Ghunas 6.6 16.0 11.0 15.4 14.3 30.2 21.6 29.7
Handiaya 7.4 20.5 12.7 19.3 16.5 31.1 23.0 30.7
Barnala 6.9 18.4 12.2 18.4 19.3 36.9 27.4 36.0
Table 3.7 Conti... Ambient Air Quality Monitoring Results for SOx and NOx (24-hrs avg.)
Location NH3 (µg/m³) CO (mg/m³)
Min Max Mean 98 Percentile Min Max Mean 98 Percentile
Project Site 11 20 15 20 0.28 0.46 0.36 0.45
Fatehgarh
Chhanna 9 15 12 15 0.37 0.81 0.64 0.80
Kaleke 10 16 12 16 0.22 0.56 0.33 0.49
Dhanaula 12 17 14 17 0.28 0.53 0.38 0.51
Dhaula 10 16 13 16 0.14 0.28 0.19 0.27
Ghunas 10 15 12 15 0.23 0.42 0.33 0.42
Handiaya 9 15 11 15 0.15 0.32 0.25 0.32
Barnala 13 23 17 22 0.43 0.76 0.64 0.76
except plant site. However the mean concentrations of PM10 levels are well within specified limits
(100 g/m ) as per NAAQS. This may be due to the dust generated from thrashing of Wheat crop
3
in the agricultural field, presence of industries in addition to plying of heavy traffic such as trucks
and other combustion engine vehicles in nearby roads.
3
Particulate Matter (PM 2.5): PM2.5 levels were found ranging from 31 to 69 µg/m . The mean
3.
concentration of PM2.5 in all location ranges between 42 to 48 µg/m The maximum PM2.5 levels
in all location are exceeding the specified limits (60 g/m ) as per NAAQS except project site ,
3
Ghunas, Handiaya and Barnala. While the mean concentration of PM2.5 levels is well within the
specified limit of 60 g/m . This may be due to the dust generated from thrashing of Wheat crop in
3
the agricultural field, presence of industries in addition to plying of heavy traffic such as trucks and
other combustion engine vehicles in nearby roads.
Sulphur Dioxide (SO2): The SO2 level in all the location ranges between 6.2-20.5 µg/m3, which
3
was found well within National Ambient Air Quality standards i.e. NAAQMS ( 80µg/m ). The
highest SO2 level were found at Handiaya (20.5 µg/m3) and lowest SO2 level were observed also
at Kaleke (6.2 µg/m3).
Oxides of Nitrogen (NOx): The NOx level in all the location ranges between 14.0-41.2 µg/m3,
3
which was found well within National Ambient Air Quality standards i.e. NAAQMS (80µg/m ). The
highest NOx level were found at Project site (41.2 µg/m3) and lowest NO x level were observed
also at Fatehgarh Channa (14.0 µg/m3).
3
Ammonia (NH3): The NH3 level in all monitoring locations ranges between 9 to 23 µg/m . The
NH3 level in all monitoring location is under permissible limit i.e. NAAQMS 400 µg /m³.
Carboon Monoxide (CO): The 8 hrs. CO level in all monitoring locations ranges between 0.14 to
0.81 mg/m³. The CO level in all monitoring location are under permissible limit i.e. NAAQMS level
2 mg/m³.
Other Parmeters: VOC, HBr and HCL were not detected in the study area.
Overall the mean PM level in the study area are within the prescribed National Ambient Air
Quality Standard, 2009 (CPCB) at all locations.
3.5.4. Comparison of Ambient Air Quality Data with Available Secondary Data
Secondary air quality data for project area is referred from SPCB, Punjab is given in Table 3.8.
SPCB has established an on-line monitoring station at vill, Aspal Khurad (Kahneke), Tehsil-Tapa,
Distt-Barnal which is located about 10 km from the proposed site. The Month wise AAQ results
are given below:
The monitored levels were compared against the Noise Pollution (Regulation and Control) Rules
2000, as amended through the Noise Pollution (Regulation and Control) Amendment Rules
2010 dated 11th January 2010. The project site falls in designated industrial area and the noise
levels at all the locations were found within the ambient noise standards.
45 dBA during night time) and commercial area (Standards - 65 dBA during day time and 55
dBA during night time). The Ambient noise are well within the limit as per prescribe standard.
3.7. Traffic Study
The site is in planned industrial area of trident group having a good network of internal roads.
Further the site is located close to State Highway-13 which is passing about 800 m of the project
site.
As the site is located close to SH-13 and all the material movement shall be done through this
highway. The SH - 13 is two lanes (2-lane) of very good design (1.5 m hard shoulders and 3 m
central verge) and its capacity is 40000 PCU per day as per IRC specification (IRC64-1990).
Considering total material transport from IOLCP i.e. 10-15 truck/month, the existing highway is
adequate to bear the additional load without any issue.
Ground water
The pH value of drinking water is an important index of acidity or alkalinity. pH
value was found within desired and permissible limit, neutral to alkaline in nature.
Total dissolve solids was found in the range of 358 to 728 mg/l which found
slightly above the desired limit but well within permissible range of IS 10500:2012.
Chloride was found in the range of 56 to 138 mg/l which found well within desired
range (250 mg/l) of IS 10500:2012
Total hardness values ranges between 182 to 356 mg/l which is higher than the
desired limit at in few locations but within the permissible limits.
Ca values and sodium values are also found in higher side. Fluoride contents in
traces were also found in the ground water sample but it was well within the
permissible limits.
Overall the ground water quality of the study area is found well within the
permissible limits. No metallic and bacterial contaminations were observed in
ground water samples.
.
3.8.2. Surface Water Quality
There is no perennial river within the study area. Irrigation canal (Uppli Canal) and ponds are
the source of surface water. There is a waste water drain flowing close to the site. it is
contaminated due to direct discharge of waste water from industries. Six surface water
samples were collected and examined for major physico-chemical parameters and
bacteriological parameters. CPCB best designated Use standards are shown in Table 3.13.
Surface water sampling locations are presented in Table 3.14. Surface water results
provided in Table 3.15.
Surface water quality is determined by the help of water quality criteria defined in CPCB best
designated uses criteria. Surface water monitoring is performed for nalla near project site at 100
upstream and downstream point of the project site high bacterial contamination were observed in
Nala water quality meeting the BDU criteria Class D which is fit for propagation of wildlife and
fisheries.
Canal Water quality: The canal water quality is good for Drinking water source after conventional
treatment and disinfection and meeting the class C of Best designated uses of CPCB.
Pond Water Quality: Bacterial contamination were observed in pond water samples. Dissolve
oxygen is found within the range while BOD was found slightly on slightly high than the Class C of
Best designated uses. Hence the pond water is fit for Propagation of Wild life and Fisheries and
meeting the criteria D of Best designated uses of CPCB.
3.9. Soil Quality
Soils may be defined as a thin layer of earth's crust that serves as a natural medium for the growth
of plants. It is the unconsolidated mineral matter that has been subjected to and influenced by
genetic and environmental factors. Soils serve as a reservoir of nutrients for plants and crops and
also provide mechanical anchorage and favorable tilts. Soil is our most important natural resource
and a natural resource is anything that comes from the earth and is used by us. We depend on the
soil for food, clothing, shelter, minerals, clay & water. Soil is the seat of many macro & micro flora
like algae, fungi, earthworms, bacteria etc. These are very beneficial in promoting soil reactions
and decomposing the organic matter by which essential nutrients for plants are liberated. Most of
the soils are made-up of two main parts:
Tiny bits of mineral particles which come from larger rocks, and humus, which is dark
brown in color and consists of decaying remains of plants and animals.
Soil also contains water, air and living organisms, such as fungi, bacteria, earthworms,
roundworms, insects, etc. Actually, more living organisms live in the soil than above it.
For general characterization of soil a few random samples from the study area to the depth of
about 15-cm may be sufficient. Deeper soil samples may be needed only for the study of soil
profile.
3.8.1. Methodology
The soil samples were collected from Six (06) selected locations during the Pre-monsoon season
(15th March-15th June 2018). The samples collected from all the locations were homogeneous
representative of each sampling location. At random five sub-locations were identified at each
location and soil samples were collected from 5 to15-cm below the surface of soil. It was uniformly
mixed before homogenizing the soil sample. The samples about 500-gms were packed in
polythene bags labelled in the field with the name of sampling location & number and sent to the
laboratory for the analysis of physicochemical parameters. The samples were dried and passed
through a 2.0 mm sieve to prepare them for testing.
thereby is indicating that soils are medium in available phosphorus content. Available potassium
content in these soils ranges between 156.2 & 185.6 kg/ha thereby is indicating that the soils are
medium in potassium content.
The available manganese content in surface soils was recorded as 4.46 to 5.94 mg/kg as the
critical limit of available manganese is 2.0 mg/kg. The available Zinc in surface soils of the study
area ranges from 1.45 to 1.82 mg/kg. As per the critical limit of available Zinc as 0.5 mg/kg, most
of the study area soils are with sufficient available Zinc level in the vicinity of the project. Above
description of study area soils reveals that the soils in the study area are having moderate fertility
index.
3.10. Ecology
The Botanical and wildlife species in an area depend on the availability of suitable habitat for
survival. Habitat loss and increasing habitat fragmentation are the primary causes of species
decline in these environments. This section provides an overview of flora and fauna observed in
study area during site visit.
Forest Cover in Barnala District: As per the India State of Forest Report, ISFR 2017 there is
only 8 sqkm forest in the Barnala district. Most of the land in Barnala district is under agriculture.
The details of the forest type present in the Barnala district is given in Table 3.18.
2 Dense Forest 01
3 Open Forest 07
Most of the land around the study area (10 km radius around the project site) is under agriculture
and residential uses. No national parks, wild life sanctuary, biosphere reserve is present within 10
km area of the project site. No Reserve Forest and protected forests are present within the study
area. Because there is no forest in the study area and the vegetation is restricted along road side
and other open areas. The vegetation is meager in spite of the favorable environmental conditions.
At some places, area is covered with thick vegetation. The plants are a significant characteristic
tress comprises of mainly Eucalyptus etc. Some trees of Kikar, subabul, Toot, are also found in
the area. Around village roads, Pipal (Ficus religiosa), Bargad (Ficus benghalensis), Neem
(Azadirachta indica), Babul (Acacia niotica), Dhak (Butea monosperma), Jamun (Syzygium
cumini), Nilgiri (Eucalyptus globulus) and Amaltash (Cassia fistula) were commonly observed.
Among the fruit trees, the important ones were Ziziphus mauritiana (Ber), Syzgium cumini (jamun)
and Psidium guajava (Amrud). Dischanthum annuatum, a fodder grass wa s growing on normal
soils while Cenchrus celaris another fodder species grows on sandy soil patches. Other grasse s
found in the study area are Diplachne fusca, Heteropogon controutus, Sporobolous maraginatus,
Aristida hixtrix, Dactylon centicem, etc. Weeds like Calotropis gigantea, Ricinus communis,
Alternanthera sessilis and Achyranthes aspera were commonly observed on the banks of fields.
The list of the plant species observed in the study area is given Table 3.19
Medicinal Plants : The study area shows many medicinal plants. Many medicinal plants are also
observed in which Azadirachta indica; Aegle marmelos, Emblica officinalis, Ocimum are the
important one. List of medicinally important trees, shrubs and herbs and their uses with their
natural orders are presented in Table 3.20
Sr.
Name of Species Family Medicinal Use
No.
Trees
1.
Aegle marmelos Rutaceae Antidiuratic, antithetmintic, antipyretic,
Sr.
Name of Species Family Medicinal Use
No.
carminative tonic
Furit used in chronic diarrhoea & dysentery
2.
Azadirachta indica Meliaceae Oil extracted from seed as local stimulant,
insecticide and antiseptic
3.
Cassia fistula Caesalpiniaceae Control fever and gas trouble
Laxative
4.
Emblica offcinalis Euphorbiaceae Fruit powder coolent and laxative
Rich source of vitamin C
5.
Ficus religiosa Moraceae Quenches thirst
6.
Mangifera indica Anacardiaceae Controls stomach pain, diarrhoea, urine
sugar
7.
Syzygium cumini Mystaceae Stem bark is used to treat sore throat,
bronchitis, ulcer, dysentery
Seed powder for diabetes
8.
Acacia nilotica Mimosaceae In pharmacy, used in preparing emulsions,
tablets, pills etc.
9.
Calatropis procera Asclepiadaceae Root bark used for leprosy
10.
Argemone Papaveraceae Latex is laxative and used in cataract
mexicana Seed oil used in asthma
Rare and Endangered Plant Species in the Study Area: In the study area, no rare and endangered
plant species was observed (Source: Red Data Book of Indian Plants, N.P Nayar and A. P. K.
Sastry, B.S.I. 1988).
3.10.2 Fauna
Most of the land around the study area (10 km radius around the project site) is under agriculture
and residential uses. No national parks, wild life sanctuary, biosphere reserve is present within 10
km area of the project site. No Reserve Forest and protected forests are present with in the study
area.
The information on fauna was collected by visual observations, random survey at different
locations and discussion with the local people. The secondary data from different Govt. Sources
and available literature was also referred in this study. The fauna study is carried for core zone as
well as for buffer zone i.e. 10 km area around the project site, which is describes in following
sections.
A. Fauna in Core zone: Proposed plant unit is already existing unit. No tree cutting is required. No major
vegetation is present within the core zone except Eucalytus plantation hence no wildlife exists within the
core zone. However, the presence of reptiles and amphibian species has been reported by the local
people. Common avifaunal species has also been observed in the core zone.
B. Fauana in Buffer Zone: List of fauna found in buffer zone (10 km study area) is provided in Table 3.3.
The listed fauna found in study area has been cross-checked with Red Data Book of Indian Animals
(Zoological Survey of India). There is no endangered or critical faunal species in the study area.
Mammals:
No significant carnivorous and herbivorous wild animals are found in the area. commonly found
mammals like Langurs (Semnopithecus entellus), Mongoose (Herpestes edwards) and Jungle Cat
(Felis chaus) are observed in the area. However, the presence of fox and hare has also been
reported in the area by the villager during public consultation. List of mammals observed in the
study area is provided in Table 3.22.
Amphibian & Reptiles (Herpetofauna)
Frog, Indian bull frog, snake like Indian cobra (Naja naja); Dhaman (Lycodon aulicus), and \lizard
is encountered at various places in study area (refer Table 3.22).
Avifauna
Avifauna is an important part of the ecosystem playing the various roles as scavengers,
pollinators, predators of insect, pest, etc. They are also one of the bio indicators of different status
of environment and affected by urbanization, industrialization and human interference. They can
be used as sensitive indicators of pollution and malfunction of ecosystem.
Due to presence of the canal and other water bodies and favorable habitats for avifauna, wide
range of avifauna observed in the study area. The study area is inhabited by forty species of birds.
Among the birds recorded in this study, were insectivores and other dominating types included
omnivores, predators and granivores. The list of avifauna observed in the study area is given in
Table 3.23.
In order to assess the Demography & Socio-economic features of the study area, field surveys
through questionnaire filling and public consultations undertaken during the baseline field study
period. Village/Town wise census records 2011, for the study area falling mainly in Barnala District
of Punjab State was compiled and placed in the form of tabulation and graphical representation.
Purpose of the Study
As per provision of the EIA Notification, 2006, under the Environmental (Protection) Act, 1986,
expansion projects can be undertaken only after obtaining an Environmental Clearance (EC). Any
project seeking an environmental clearance requires an EIA report, prepared in accordance with
guidelines of Ministry of Environment & Forests (MoEF & CC), Government of India.
The construction phase of the project could lead to unplanned and haphazard development of
slums of various size and description with little or rudimentary. Socio-economic study was
conducted to establish the baseline demographic features and impacts due to upcoming
expansion project, as construction of any major industrial project invariably leads to Socio-
economic changes in its vicinity.
There are only three towns named Barnala (MC), Handiaya (NP) and Dhanaula (MC) in the study
area comes under 2 tehsils namely Barnala and Tapa of Barnala district in Punjab. Caste wise
male-female population break-up of the entire study area villages/towns is shown in Table 3.25 as
follows;
Table 3.25 : Caste wise Population Distribution of 10-km Radial Study Area
Name of the Village No of Total Population Scheduled Tribes
Households Scheduled Castes
Persons Male Female Male Female Male Female
A-0-2km
Fatehgarh Chhanna 438 2405 1231 1174 299 291 0 0
B-2-10KM
Kaleke 1277 6804 3615 3189 1029 913 0 0
Dhanaula 1042 5593 3049 2544 512 477 0 0
Dangarh 486 2371 1265 1106 413 358 0 0
Rajgarh 207 1174 626 548 195 162 0 0
Pharwahi 955 5047 2700 2347 1175 1054 0 0
Rasulpur ……………………..Un-Inhabited Village……………
Dhanaula Khurd 1028 5406 2939 2467 732 650 0 0
Bhaini Jassa 536 2905 1587 1318 409 335 0 0
Jodhpur 640 3409 1785 1624 579 565 0 0
Khudi Kalan 961 5142 2784 2358 866 760 0 0
Patti Sohlan 101 523 282 241 147 135 0 0
Barnala (Rural) 1152 6077 3651 2426 1181 966 0 0
Dhaula 2008 10819 5772 5047 1843 1725 0 0
Barnala (MCl) 24490 116449 62554 53895 16096 14501 0 0
Handiaya (NP) 2702 12507 6810 5697 2592 2295 0 0
Dhanaula (MCl) 3878 19920 10521 9399 3662 3349 0 0
Rura Kalan 1162 6154 3249 2905 905 833 0 0
Dhurkot 1018 5473 2855 2618 900 755 0 0
Badra 513 2766 1481 1285 305 248 0 0
Kahneke 536 2655 1408 1247 243 199 0 0
Mehta 420 2304 1223 1081 513 412 0 0
Ghunas 550 2836 1537 1299 634 499 0 0
Khudi Khurd 256 1406 736 670 289 285 0 0
TOTAL (0-10km) 45918 227740 122429 105311 35220 31476 0 0
Source: Census Records 2011
Sex Ratio
The ‗Sex Ratio‘ is a numeric relationship between females and males of an area and bears
paramount importance in the present-day scenario where the un-ethnic pre-determination of sex
and killing of female foetus during pregnancy is practiced by unscrupulous medical practitioners
against the rule of the law of the country. It is evident that by contrast the practice of female
foeticide is not prevalent in the study area. There are 876 females for every 1,000 males in
Barnala district. The sex ratio for the children of 0-6 years of age is 843 female children per 1000
male children in the district. As per the census records 2011, the data reveals the sex ratio as 860
females for every 1000 males in the study area. The child sex ratio in the study area was observed
as 832 female children per 1000 male children (0-6years).
The male-female wise population distribution of the study area is shown by graphical
representation in Figure 3.12 as follows;
Figure 3.12 Figure: Male-Female wise Population Distribution in the Study Area
Scheduled Caste & Scheduled Tribe Population
On the basis of the village/town wise SC & ST population distribution for the study area during
2011, the ‗Scheduled Castes‘ population was observed as 66696 consisting of 35220 males and
31476 females respectively which accounts as 29.3% to the total population (227740) in the study
area. No ‗Scheduled Tribes‘ population was observed in the study area. It implies that the rest
population out of the total population (about 70.7%) belongs to the General category.
Male-female wise SC & ST population distribution of the study area is graphically shown in Figure
3.13 as follows.
Literacy Rate
Literacy level is quantifiable indicator to assess the development status of an area or region. Male-
Female wise literates and illiterate‘s population is represented in Table 3.26 Total literates‘
population was recorded as 144370 (63.4%) in the study area. Data reveals that Male-Female
wise literates are observed as 81364 & 63006 respectively, implies that the ‗Literacy Rate‘ is
recorded as 63.4% with male-female wise percentages being 35.7% & 22.7% respectively. The
total illiterate‘s population was recorded as 83370 (36.6%) in the study area. Male-Female wise
illiterates were observed as 41065 (18.0%) and 42305 (18.6%) respectively. The Male-Female
wise graphical representation of literates & illiterates‘ population in study area villages/town is
shown in Figure 3.14.
Literates Illiterates
Total
Name of the Village Population Persons Males Females Persons Males Females
A-0-2km
Fatehgarh Chhanna 2405 1296 691 605 1109 540 569
B-2-10km
Kaleke 6804 3619 1980 1639 3185 1635 1550
Economic Structure
The majority of people in rural sector are cultivators & agricultural labors which indicates dominant
agricultural economy. A small section of people are engaged as workers in household industries.
But in urban sector the existing scenario is completely reversed as most of the people there are
engaged in non-agricultural activity especially in local hotels/restaurants and as drivers some
people also operates their vans/jeeps/cars as tourist vehicle.
Annual income helps in identifying families below poverty line. During the field survey, income of a
household through all possible sources was recorded. Agriculture and allied activities was
reported to be the major source of income followed by non-farm wage labor, business, Govt. &
Pvt. Service etc. The other important sources of income include government pension and income
from selling of fodder.
Economy of the District
As per the district census handbook of 2011, the economy of the district is mainly based on the
agriculture & allied activities. Industry plays a key role in increasing the economy of the state and
further to districts and village levels. The district has also made a significant contribution in the
productivity of Cotton & Sugarcane. Forestry, Fisheries & Mining and Quarrying are also major
aspects contributing in the major economy of the district.
Workers Scenario (Occupation Pattern)
Occupational pattern was studied to assess the skills of people in the study area. Occupational
pattern helps in identifying major economic activities of the area. The main and marginal workers
population with further classification as casual, agricultural, households and other workers is
shown in Table 3.27. In the study area the Main and Marginal Workers population was observed
as 74644 (32.8%) and 6612 (2.9%) respectively to the total population (227740) while the
remaining 146484 (64.3%) were recorded as non-workers. Thus, it implies that the semi-skilled
and non-skilled work-force required in study area for the project is available in aplenty.
MAIN MAIN_CL MAIN_AL MAIN_HH MAIN_OT MARG MARG_CL MARG_AL MARG_HH MARG_OT
Name of Village WORK_P _P _P _P _P WORK_P _P _P _P _P
A-0-2km
Fatehgarh
Chhanna 711 394 129 10 178 25 5 4 1 15
B-2-10km
Kaleke 2319 973 495 145 706 221 37 76 6 102
Dhanaula 2299 1109 91 25 1074 45 4 2 0 39
Dangarh 576 287 144 24 121 197 10 95 6 86
Rajgarh 373 177 118 25 53 9 1 5 2 1
Pharwahi 1438 497 399 14 528 127 9 40 9 69
Rasulpur …………Uninhabited Village……………….
Dhanaula Khurd 1633 813 132 17 671 310 13 29 0 268
Bhaini Jassa 958 454 290 8 206 25 1 3 3 18
Jodhpur 1069 445 182 25 417 304 15 39 3 247
Khudi Kalan 1516 704 220 16 576 148 22 43 2 81
Patti Sohlan 105 33 14 23 35 87 5 7 10 65
Barnala(Rural) 2461 639 181 45 1596 134 22 18 3 91
Dhaula 4118 1338 691 59 2030 113 11 22 12 68
Barnala (M Cl) 37806 1858 1374 801 33773 2963 84 279 109 2491
Handiaya (NP) 3981 247 607 48 3079 234 3 111 6 114
Dhanaula (M Cl) 6184 1012 958 232 3982 487 22 160 42 263
Rura Kalan 2250 862 490 390 508 468 15 122 120 211
Dhurkot 1796 818 481 15 482 452 28 299 3 122
Badra 764 516 91 4 153 136 3 62 0 71
Kahneke 984 553 156 26 249 23 7 2 0 14
Mehta 572 319 112 11 130 105 9 29 2 65
Ghunas 1013 380 120 1 512 11 1 1 0 9
Khudi Khurd 429 274 17 3 135 13 0 1 0 12
TOTAL
(0-10km) 74644 14308 7363 1957 51016 6612 322 1445 338 4507
Source-Census Records 2011
List of Abbreviations
MAIN WORKERS POPULATION:
MAIN WORK_P : Main workers total population
Non-Workers Population
Persons Males Females
146484 53247 (36.4%) 93237 (63.6%)
rural and 2 dispensaries in the urban area. In addition, there are also 12 Ayurvedic institutions in
the district.
Potable Water Facilities
Potable water facility is available in most of the villages/towns of the study area. Tube well water
facility was commonly observed in 15 (62.5%) villages of the study area. Hand pump facility for
drinking water was observed only in 8 villages of the study area. Out of the total twenty-four (24)
revenue villages/towns, no village was served with River/Canal water for drinking purpose in the
study area. As per the census records of 2011, no village was observed with Tank/Pond/Lake
water facility in the rural part of the study area. Adequate potable water facilities are available in
the study area.
Regarding, the position of villages covered under the rural drinking water supply scheme up to
3/2010 is concerned, in the district there are 124 inhabited villages, and all have been identified as
water scarcity villages, out of which in 117 village‘s water supply scheme have been
commissioned and in the remaining 7 villages scheme is still to be initiated. Thus, the percentage
of villages in this regard has been 94.4%.
Communication, Road, Transport and Banking Facilities
Apart from Post &Telegraph (P & T) services, transport is the main communication linkage in the
study area. As per the census records 2011, only one village named Dhanaula Khurd village of
Barnala district was observed with Post Office facility in the study area. Most of the villages are
depending upon those villages being served with such facility. The study area has good road
network, passes from the area.
Transport and Communication facilities are necessary for administrative purposes as well as
public convenience. Moreover; a well-knit public transportation system is a prerequisite for social
and economic development of the district. The linking of one place with other by road is very
essential to provide good transport system. Mainly four (04) towns named Dhanaula, Barnala,
Handiaya and Tapa are available within the distance range of 0 to 10kms from the villages of the
study area. More than >50% villages/towns are served with Pucca road facility in the study area.
As per the compiled information on basic infrastructure facility, about 33% villages in the study
area are being served with Public Bus services. Only two villages named Barnala (Rural) and
Ghunas were observed with railway station facility in the study area and remaining villages are
depending upon towns and concerned district HQ for such facility. Nearest State/National Highway
are as SH-13 (1.01km, West) & NH-64, 3.47km, North respectively from the project site. There is
no airport facility in this district. The nearest airport is Sahnewal Airport (LUH/VILD), located at
85km away from the district HQ in Punjab. The study area has almost all the schedule commercial
banks with ATM facility in urban areas and the district HQ.
Power Supply
It is revealed from the compiled information on amenities availability as per the census record of
2011; almost all villages and towns (about 92%) are electrified for all purpose in the study area.
Electricity is one of the chief importance necessities for the economic development of the district.
Village/town wise ‗Basic Infrastructure and Amenities’ availability data for the entire study area is
represented in Table 3.30 as follows;
Name of the Village Educational Medical Drinking Water Communication Approach to the Power Supply Nearest Town
Village
& Transport
P M SS SS P P M Al. D F T W H TW P Mo BS RS P KR NW F E E E EA
S H H C H W P O b. R P D A C
C S W C g.
C C
Kaleke 1 1 1 1 0 0 1 1 1 1 2 2 1 1 2 1 1 2 2 1 2 1 1 1 1 1 DHANAULA
Dhanaula 1 1 0 0 0 0 0 0 0 0 1 2 2 1 2 2 1 2 1 1 2 1 1 1 1 1 BARNALA
Dangarh 1 1 1 1 1 0 0 1 1 0 1 2 1 1 2 1 2 2 2 1 2 1 1 1 2 1 DHANAULA
Rajgarh 1 1 0 0 0 0 0 0 0 0 2 2 2 2 2 1 2 2 2 1 2 1 1 1 1 1 BARNALA
Pharwahi 1 1 1 1 0 1 0 0 0 0 2 1 1 1 2 1 2 2 2 1 2 1 1 1 1 1 BARNALA
Rasulpur BARNALA
Dhanaula Khurd 1 2 0 0 0 0 0 0 0 0 2 2 1 1 1 1 1 2 2 1 2 1 1 1 1 1 HANDIAYA
Bhaini Jassa 1 1 1 0 0 0 0 0 0 0 2 2 1 1 2 1 2 2 2 1 2 1 1 1 1 1 HANDIAYA
Fatehgarh Chhanna 1 1 1 0 0 1 0 0 1 0 2 2 2 1 2 1 2 2 1 1 2 1 1 1 1 1 HANDIAYA
Jodhpur 1 1 1 1 0 0 0 0 1 0 2 2 2 1 2 1 2 2 1 1 2 1 1 1 1 1 HANDIAYA
Khudi Kalan 1 1 1 1 0 1 0 0 0 0 1 2 2 2 2 2 1 2 1 1 2 1 1 1 1 1 HANDIAYA
Patti Sohlan 1 0 0 0 0 0 0 0 0 0 2 2 2 2 2 2 2 2 1 1 2 1 1 1 1 1 BARNALA
Barnala(Rural) 1 0 0 0 0 0 0 0 0 0 1 2 2 2 2 1 2 1 2 1 2 1 1 1 2 1 BARNALA
Dhaula 2 1 1 1 0 0 0 0 1 0 1 2 2 1 2 1 1 2 1 1 2 1 1 1 1 1 BARNALA
Rura Kalan 1 1 1 1 1 1 1 0 1 0 1 2 2 1 2 1 1 2 1 1 2 1 1 1 1 2 TAPA
Dhurkot 1 1 1 0 0 1 1 0 1 1 1 2 2 2 2 1 2 2 1 1 2 1 1 1 1 1 TAPA
Badra 1 1 1 0 0 0 0 0 1 1 1 2 1 1 2 1 2 2 1 1 2 1 1 1 2 1 TAPA
Kahneke 1 1 1 0 0 0 0 0 0 0 1 2 2 1 2 2 2 2 2 1 2 1 1 1 1 1 TAPA
Mehta 1 1 0 0 0 0 0 0 0 0 1 2 2 1 2 2 2 2 1 1 2 1 1 1 1 2 TAPA
Ghunas 1 1 0 0 0 1 1 0 0 1 2 2 1 1 2 1 1 1 1 1 2 1 1 1 1 1 TAPA
Khudi Khurd 1 1 1 0 0 1 0 0 1 0 1 2 1 1 2 1 1 2 1 1 1 1 1 1 1 1 TAPA
4.1. General
In this chapter, we:
Identify project activities that could beneficially or adversely impact the environment
Predict and assess the environmental impacts of the such activities
Identify possible mitigation measures for these project activities and select the most
appropriate mitigation measure, based on the reduction in significance achieved and
practically in implementation
These pollutants can affect the surrounding vegetation and nearby agricultural crops. It‘s an
expansion project within existing premises and construction activity is limited only to the project
site and hence unlikely to cause any change in the ambient air quality around the proposed
project. As the emission level is very low and intermittent, quantitative predictions are not
possible due to limitations of the dispersion model. Therefore, considering all the air pollutants, it
is not expected that air emissions due to construction will exceed air quality standards
(NAAQMS).
There might be some impact on air quality that may take place during construction, which would
be caused by emission of dust during excavation as well as from the earth material stored at the
site. The potential for dust in the form of particulate matter to be emitted during construction
strongly depends on the type of activities taking place, such as the movements of vehicles,
speed, soil stripping, excavation, back filling and reinstatement. Sprinkling water on the
deposited earth material shall minimize emissions of particulate. The rate of emission of dust, its
predicted rates of deposition and the temporary nature of the dust generating activities is
expected to be well within acceptable limits. Also, vehicles transporting earth and other
construction material to the site will be covered to ensure their dust particles do not escape into
the air. During construction all earth material will be kept covered to minimize impact on the
ambient air quality.
Traffic to the site during construction will be slightly more intensive than at present. However,
well connectivity State Highway 13 will not have any significant stress on the traffic. The present
road conditions are good for the proposed additional movement of vehicular traffic.
Hence the impacts on the ambient air quality during construction phase will be temporarily for
short duration and reversible in nature and restricted to small area.
4.2.2. Operation Phase
Prediction of ground level concentration (GLCs) due to proposed project has been made by
using air dispersion model as per CPCB Guideline.
1. The pre-project (baseline) ambient air quality status in the study area indicates that all the
criteria pollutants except PM (due to local phenomenon) are well within the prescribed
National Ambient Air Quality Standards (NAAQS) for industrial, residential, rural and other
areas.
2. The ambient air quality with respect to air pollutants will change during the operation phase of
the proposed project. However, adequate stack height will be provided for better dispersion of
flue gas as per the guidelines of CPCB. In addition to that, adequate greenbelt will be
developed for further control of air pollution.
3. To assess the impact of air emissions from various continuous point sources, air dispersion
modelling study has been conducted with the help of Industrial Source Complex Short Term
Model (ISCST3) View 6.2 model of Lakes Environmental. Detailed description has been given
in the following sub-sections:
4.2.3. Model Details
2. In the proposed project, prediction of impacts on air environment has been carried out
employing mathematical model based on a Steady State Gaussian Plume Dispersion Model
designed for multiple point sources for short term. In the present case, Industrial Source
Complex Short-term [ISCST3] dispersion model based on steady state Gaussian Plume
Dispersion, designed for multiple point sources for short term and developed by United States
Environmental Protection Agency (USEPA) has been used for simulations from point sources.
3. The predictions for air quality during operation phase were carried out for particulate matter
less than 10 microns (PM10), particulate matter less than 2.5 microns (PM2.5) and Hydrogen
Bromide (HBr), Hydrochloric acid (HCl), Chlorine (Cl2) and many more concentrations using
ISCST3.
The main sources of air pollution due to the operation of the plant are the Boiler and Process
stack. The contribution to GLCs for the pollutants i.e. particulate matter, SOx, NOx, HCl, etc.
were predicted over the study area proposed project considering the worst scenario. The
emission load from proposed project is given in Table below. The prediction (maximum) is based
on the expected total emission rate from each stack and are given in isopleths Figure 4.1 (A, B,
C and D) for proposed project. The additional contribution to GLC is also given below in Table
4.1.
Table 4.1 : Stack emissions
Ht. Dia. Vel. Tem Flow Emission rate
S. Description
(m (m) (m/s p Rate (g/s)
n 0
) ) ( C) nM³/hr SP NO HCL
M x
1 boiler 14 tph 52 1.3 5.73 75 25271.5 1.05 2.11 -
5 2
2 boiler 32 tph 60 1.5 12.2 80 65487.1 2.73 5.46 -
5
3 boiler 80 tph 60 1.7 6.7 85 48267.6 2.01 4.02 -
5 7
4 Furnace 1500000 Kcal/hr 28 0.5 5 200 2225.55 0.03 - -
5 2 X Furnace 2000000 Kcal/hr 24 0.5 2 200 890.22 0.01 - -
6 5 X Furnace 200000 Kcal/hr 16 0.2 4.3 200 478.49 0.01 - -
5
7 IBAP Scrubber 16 0.2 4.3 35 478.49 0.01 - 0.00
5
8 Acetyl Scrubber 16 0.2 4.3 35 478.49 0.01 - 0.00
5 1
9 PAC Scrubber 16 0.2 4.3 35 478.49 0.01 - 0.00
5 1
10 M- 16 0.2 4.3 35 478.49 0.01 - 0.00
phenoxybenzaldhyde/Vanillin/ATTBA/Losat 5 1
an potassium/ Methyl – 2- amino- 3 – chloro
propionate HCL/ 4 amino benzamide/P-
nitrobenzyl chloride
The summary of maximum ground level concentrations (GLC) for the proposed project is listed in Table
4.2.
Table 4.2 : Summary of Maximum 24-hour Incremental GLC due to the Proposed Project
Stacks
Maximum incremental GLC Distance
Parameters Direction
(µg/m³) (Km)
PM 0.95 1.6 SE
SO2 0.64 1.6 SE
NOx 3.1 1.6 SE
HCL 0.23 1.6 SE
(Source: Modelling output results)
Maximum 24 hourly average incremental in GLCs of PM, SO2, NOx and HCl due to proposed expansion
project during operation phase are predicted and given in Table 4.2. The isopleths of the pollutant
concentration due to the impacts associated with the operation of the proposed project are shown in
Figures 4.1 through 4.4 for PM, HCl, SO2 and NOx respectively. Contours of the incremental GLCs depict
that the travel of emissions from the proposed project would be mainly in SE, quadrant.
Besides the worst GLC (maximum) predictions the GLC incremental at the sensitive receptors (where the
ambient air monitoring was carried out) was also predicted. The predicted incremental GLC for pollutants
are given in underneath Table 4.4.
The main source of noise generation during operation stages are mainly from pumps, blowers,
compressors, DG sets, vehicle movement for transportation of raw materials, finished goods etc.
Noise level contributed from light medium and heavy vehicles on the roads can be considerable
depending upon the traffic density. The heavy commercial vehicles traffic is limited depending
upon the material receipt and dispatch of synthetic organics through road transport. But this
noise will be intermittent and temporary. It is expected that noise level at the plant boundary and
other 8 locations will be within the prescribed norms of CPCB due to operation of the proposed
project and no significant impact on noise environment is expected. Also, the noise will not be
audible beyond its boundary limit, particularly due to natural green belt and other attenuators.
4.4. Water Environment
4.4.1. Construction Phase
During construction, water will be needed mainly for construction and domestic purpose i.e. for
drinking and sanitation. Drinking and sanitation facilities shall be provided to workers during
construction. Water will also be needed for sprinkling to reduce dust emission, if any.
The water required in the above activities will be only a fraction of total water required.
Moreover, this requirement will be irregular and limited to construction phase only and hence no
impact is envisaged during construction phase. The domestic wastewater generated will be
send to existing ETP and hence no impact is envisaged.
4.4.2. Operation Phase
Water requirement will be made available through Borewell/surface water. Wastewater will be
segregated into two streams as High TDS / High COD (HTDS) and Low TDS / Low COD
(LTDS). The HTDS Effluent stream after neutralization, filtration will be sent to Multi Effect
Evaporator (MEE). The distillate water will be treated in ETP along with LTDS effluent. The
concentrate will be sent to ATFD for drying. The dried salt will be sent to approved TSDF for
final disposal. The ETP treated effluent will be send for plantation. The RO reject (from blow
down of boiler and cooling tower) will be send to MEE. No process effluent will be discharged
outside the plant premises. The provision of stripper for recovery of solvent (VOC) from HTDS
effluent before MEE. The inorganic hazardous residues will be sent to TSDF.
There will not be any discharge of wastewater on the land. Besides, there will be separate storm
water and industrial wastewater drains to eliminate chances of mixing of rainwater
withwastewater. Hazardous wastes will be stored, managed and handles as per hazardous
wastes rules. All bulk chemicals and fuel storage areas will be provided with dyke wall / bunds to
eliminate chances of any spillages/ leakages entering into the storm water drain.
No significant adverse impact on the surface and ground water or soil quality is envisaged in
viewof the proposed mitigative measures.
4.5. Land Environment
Proposed expansion project will generate employment opportunities some through direct employment and
more so indirectly through services for the plant.
Infrastructure development i.e. road & commercial building construction in the area
due to proposed expansion activities.
The project will be beneficial to local people as the company progress and expands its
activity gradually.
More revenue will be generated to the Government.
Negative Impacts due to Proposed Expansion Project
During construction and operational phase noise will be generated due to traffic influx
in the company premises due to material and personal transport. But it will be minimal
and for a short term only.
Dust and other emissions are expected during construction phase and local people
may be affected.
Improper management of waste material from the proposed activities may affect the
local peoples.
Due to Noise generation during the operation phase of the proposed project, local
people may be adversely affected.
Mitigation Measures for Negative Impacts due to Proposed Expansion Project
Increase in population density in core zone study area due to workforce involvement
during construction phase is only for short term impact.
Adequate Pollution controlling equipments with higher efficiancy shall be attached with
proposed stacks.
The project proponent/contractors shall ensure that most of the workforce shall be
engaged from the nearby villages/town.
The transportation of raw materials will be done by trucks as per MSIHC rule.
Suitable dust suppression techniques will be adopted, such as water sprinkling will be
taken.
The inorganic hazardous residues will be sent to TSDF.
The impact is likely to be for short duration and confined locally to the construction site
itself.
The overall project will have a long term benefit and hence no mitigation measure is
required.
4.8. Infrastructure
The raw material (solid, liquid and also gaseous etc.) will be transported from suppliers
approximately 3 to 5 trucks/ day will come to the plant. The final product (APIs/intermediate) will
be dispatched from plant to various parts of the country through the State and National high way
and railways, for which nearly 14 to 15 small vehicles will be used for the same. Based on the
estimation, approximately 2-3 vehicles per day will remain at the project site. Hence, due to the
project activities the increase in the vehicular traffic density in the study area will be negligible.
However, adequate parking facility provided the project site along with rest room and canteen
facilities within the premises of the factory for drivers will be provided. The project site is only
about 0.81 km away from State Highway (SH – 13), Hence, this marginal increase in the traffic,
will not affect the road infrastructure of the study area.
5.1. Introduction
Prediction of the potential adverse environmental and social impacts arising from
development interventions is at the technical heart of EIA process. An equally
essential element of this process is to develop measures to eliminate, offset, or
reduce impacts to acceptable levels during implementation and operation of projects.
The integration of such measures into project implementation and operation is
supported by clearly defining the environmental requirements within an Environmental
Management Plan (EMP).
Normally, potential impacts are identified early during the initiation of project, and
measures to avoid or minimize impacts are incorporated into the alternatives being
considered. In this respect, some of the most important measures to protect the
environment and local communities become integral to the project design, and may
not be reflected in a formal EMP.
For the proposed expansion of IOCLP, by way of EIA study propose to identify all the
likely potential impacts, collect data information and incorporate all the measures
necessary to avoid or minimize impacts on surrounding environment due to proposed
expansion unit. Many of the mitigation measures are already taken up in the
engineering design itself.
5.2. Objectives of EMP
Overall objective of EMP:
Prevention: Measures aimed at impeding the occurrence of negative environmental
impacts and/or preventing such an occurrence having harmful environmental impacts.
Preservation: Preventing any future actions that might adversely affect an
environmental resource or attribute.
Minimization: Limiting or reducing the degree, extent, magnitude, or duration of
adverse impacts.
5.3. Components of EMP
EMP for IOLCP to set up manufacturing unit of APIs intermediates considers the
following aspects:
Description of mitigation measures
Description of monitoring program
Institutional arrangements
Implementation schedule and reporting procedures
Institutional framework includes the responsibilities for environmental management as
well as responsibilities for implementing environmental measures.
5.4. Air Environment
Construction Phase:
Excavators shall be used for construction . The excavated material shall be stacked at
safe places for backfill at a later stage of construction .
To control the fugitive emission during construction phase adequate water sprinkling
system will be developed
All process drains/ equipment washing should be collected in closed pit (to avoid
fouling of work area through odour etc.) and taken to ETP.
Regular maintenance of valves, pumps and other equipment to prevent leakage and
thus minimizing the fugitive emissions of VOCs.
Inlet and outlet mufflers shall be provided which are easy to design and construct.
The green belt in and around the plant periphery will attenuate the noise level .
Provision of
protective devices
like ear muff/plugs to
the workers.
Greenbelt
development in and
around the plant
periphery
5.7. Water Environment
5.7.1. Construction Phase:
The water environment is susceptible to change during construction because
of the effluents from sanitary facilities for the construction workers, washing of
vehicles and spillage of fuels. Following mitigation measures shall be
adopted:
Suitable treatment measures already place at construction site for the
expansion project;
The vehicle maintenance area shall be in such a manner as to prevent
contamination of surface and ground water sources by accidental spillage
of oil;
The washing effluents from the vehicle maintenance area are likely to
contain suspended solids and oil & grease. Hence, an oil trap followed by
settling tank shall be provided for the treatment of these effluents; and
The waste oil collected in the oil trap shall be sold to authorized re-
refiners for off-site recycling.
Sanitation
The construction site shall be provided with enough and suitable toilet facilities for
workers to meet the proper standards of hygiene. Existing ETP have been used
during construction phase.
Operation Phase:
All the process effluent generated from the proposed project will be treated in
ETP & recycled back in the process and Treated water will be send for greenbelt
development. Domestic effluent which will be treated in existing ETP. No impact
on ground or surface water is envisaged due to the project. However, rainwater
harvesting and recycle & reuse of all the industrial effluent have been adopted in
the project to conserve the water resources.
Based on the ecological baseline study following mitigation measures have been
suggested:
Regeneration / restoration of rare plants and animals: No rare plants and wildlife
species exists in the core and buffer zone, hence protection and conservation plan is
not required.
Being an existing unit dense greenbelt havin 10-15 m width has been already
developed all around the plant premises except few places. Beside boundary
plantation there are there 10 patches in which mixed plantation has been done by
IOLCP. Greenbelt is already developed in 30 acres (more than 33%) of the land. The
photographs of the existing greenery are given below:
It has been proposed by IOLCP that additional 9000 trees shall be planted in the area
of existing eucalyptus plantation which shall be replaced with native species
plantation like gulmohar, shisham, siris, jamun, Kadam, daikan, neem, kaner etc. for
this plantation IOLCP has earmarked a budget of Rs. 30 lakhs including maintenance
cost for 5 year.
Beside this maintenance of the existing greenbelt shall be done on regular basis for
which IOL Chemical has already kept a budget for Rs. 20 lakhs as a capital cost.
IOLCP has planted approx. 26000 tree/shrubs and herbs in existing greenbelt. The
tree species like Eucalyptus, neem, Daikan, sadabahar, Ficus spp., jamun, Champa,
kadam gulmohar along with shrubs and herbs has been planted under existing
greenbelt.
There will be no major source of hazardous waste generation due to the proposed
project that would be causing harm to the environment, as major solid waste is
gypsum which will be sold to cement industries and hazardous wastes are ETP
Sludge & used oil which will be disposed as per Hazardous Waste (Management,
Handling & Transboundary Movement) Rules, 2016 and its amendments.
Hazardous wastes will be stored at earmarked area with impervious flooring and with shed to
eliminate chances of contamination of land and ground water.
Maintain records of hazardous waste generation and disposal as per HWM rules
2016.
Ensure all necessary precautions are taken during handling, loading and unloading of
hazardous wastes.
Ensure training to persons involved in handling/ transportation of hazardous
chemicals/ wastes.
Ensure availability of MSDS of hazardous materials, whenever required.
Ensure required PPE’s are provided to the persons involved in handling/
transportation of hazardous chemicals/ wastes
Energy consumption norms per unit production for all products manufactured in the
organization are monitored and compared with the targeted value by the MIS division
and reported to top management on daily basis, which directly impacts the product
cost and generates the scope for further improvement initiatives.
President
1 No
Officer
1 No
Operator Helper
5 Nos 3 Nos
Responsibilities of Environment Management Cell (EMC)
6.1. Introduction
Industrial plants deal with materials, which are generally hazardous in nature by virtue of
their intrinsic chemical properties or their operating temperatures or pressures or a
combination of these. Fire, explosion, toxic release or combinations of these are the hazards
associated with industrial plants using hazardous chemicals. More comprehensive,
systematic and sophisticated methods of Safety Engineering, such as, Hazard Analysis and
Quantitative Risk Assessment have now been developed to improve upon the integrity,
reliability and safety of industrial plants.
The primary emphasis in safety engineering is to reduce risk to human life, property and
environment. Some of the more important methods used to achieve this are:
Quantitative Risk Analysis: Provides a relative measure of the
likelihood and severity of various possible hazardous events by
critically examining the plant process and design.
Work Safety Analysis: The technique discerns whether the plant
layout and operating procedures in practice have any inherent
infirmities.
Safety Audit: Takes a careful look at plant operating conditions, work
practices and work environments to detect unsafe conditions.
Together, these three broad tools attempt to minimize the chances of accidents occurring.
Yet, there always exists, no matter how remote, probability of occurrence of a major
accident. If the accident involves highly hazardous chemicals in sufficiently large quantities,
the consequences may be serious to the plant, to surrounding areas and the populations
residing therein.
6.2. Risk Assessment
A three ‗levels‘ risk assessment approach has been adopted for them/s IOL Chemicals &
Pharmaceuticals Limited (hence forth IOLCP) proposed expansion project to be set up at
Village Fatehgarh Channa on Mansa Road, Tehsil & District Barnala Punjab. The risk
assessment levels are generally consistent with the practices encountered through various
assignments for medium and large chemical complexes. The brief outline of the three-tier
approach is given below:
Level 1 – Risk Screening
This is top-down review of worst- case potential hazards/risks, aimed primarily at identifying
plant sites or areas within plant, which pose the highest risk. Various screening factors
considered include:
Inventory of hazardous materials;
Hazardous Materials properties;
Storage conditions (e.g. temperature and pressure);
Location sensitivity (distance to residential areas / populace).
The data / information is obtained from plant. The results provide a relative indication of the
extent of hazards and potential for risk exposure.
Level 2 – Major Risk Survey (Semi - Quantitative)
The survey approach combines the site inspection with established risk assessment
techniques applied both qualitative as well quantitative mode. The primary objective is to
identify and select major risks at a specific location in the plant considering possible soft
spots / weak links during operation / maintenance. Aspects covered in the risk usually
include:
Process Hazards;
Process Safety Management Systems;
Fire Protection and Emergency response equipment and
programs.
Security Vulnerability;
Impact of hazards consequences (equipment damage, business
interruption, injury, fatalities);
Qualitative risk identification of scenarios involving hazardous
materials;
Risk reduction measures.
Selection of critical scenarios and their potential of damage provide means of prioritising
mitigative measures and allocate the resources to the areas with highest risks.
Level 3 – Quantitative Risk Assessment (Deterministic)
This is the stage of assessment of risks associated with all credible hazards (scenarios) with
potential to cause an undesirable outcome such as human injury, fatality or destruction of
property. The four basic elements include:
i. Hazards identification utilizing formal approach (Level 2, HAZOP
etc.);
ii. Frequency Analysis. Based on past safety data (incidents /
accidents); Identifying likely pathway of failures and quantifying
the toxic / inflammable material release;
iii. Hazards analysis to quantify the consequences of various
hazards scenarios (fire, explosion, BLEVE, toxic vapor release
etc.). Establish minimum value for damage (e.g. IDLH, over
pressure, radiation flux) to assess the impact on environment.
iv. Risk Quantification: Quantitative techniques are used considering
effect / impact due to weather data, population data, and
frequency of occurrences and likely hood of ignition / toxic
release. Data are analyzed considering likely damage (in terms of
injury / fatality, property damage) each scenario is likely to cause.
QRA provides a means to determine the relative significance of several undesired events,
allowing analyst and the team to focus their risk reduction efforts where they will be beneficial
most.
IOLCP shall manufacture pharmaceutical chemicals at the proposed site.Table2.4 inChapter
2 gives the list of raw materials. Solid raw materials are stored in ware house while liquid and
gaseous raw materials are stored in tank farms and covered area. The list of bulk liquid
storages of raw materials is as given below:
Tank-8 30
24 Propanol Liquid 40 Tank-1,40 KL
25 Ammonia Gas in Cylinders 120 Nos
Flammable chemicals:
Flammable gases gases which at 20oC and at standard pressure of
101.3KPa are:-
Ignitable when in a mixture of 13% or less by volume with air, or;
Have a flammable range with air of at least 12% points regardless
of the lower flammable limits.
(i) Extremely flammable liquids: chemicals which have a flash point lower than
or equal to 230C and the boiling point less than 350C;
(ii) Very Highly flammable liquids: chemicals which have a flash point lower
than or equal to 230C and the boiling point higher than 35 0C;
(iii) Highly Flammable Liquid: Chemicals, which have a flash point lower
than or equal to 60 0C but higher than 23 0C.
(iv) Flammable liquids: chemicals, which have a flash point higher than 60
0
C but lower than 90 0C.
Explosives: Explosive means a solid or liquid or pyrotechnics substance (or a mixture of
substances) or an article.
hrs. Swallowing
may cause death
or eye damage.
Hydrochloric acid (Gas) CAS No: 313 --- --- Not Flammable; ERPG-1: 3.0 ppm Plant uses liquid
7647-01-0 UN No: 1789 Inhalation of fumes ERPG-2: 20 ppm and emits HCl gas
results in coughing and ERPG-3: 150
choking sensation, and ppm
irritation of nose and IDLH: ---- ppm
lungs. Liquid causes
burns
n-Hexane 306 --- --- Clear colorless liquids TEEL-1: 400 ppm Health Hazards:
CAS No:110-54-3 with a petrol -like odor. TEEL-2: 3300 Inhalation causes
UN No:1208 Flash points -9°F ppm irritation of
Highly flammable; TEEL-3: 8600 respiratory tract,
Vapors may explode; ppm cough, mild
IDLH 1100 ppm depression,
arrhythmias.
Aspiration causes
severe lung
irritation,
coughing,
pulmonary
edema;
Hydrogen 247 --- --- Hazardous in case of ORAL (LD50): Highly
ingestion, of inhalation. Acute: 5620 Flammable/
Slightly hazardous in mg/kg [Rat]. 4100 Explosive
case of skin contact mg/kg [Mouse].
(irritant, permeator), of 4935 mg/kg
eye contact [Rabbit]. VAPOR
(irritant). (LC50): Acute:
45000 mg/m 3 -3
hours [Mouse].
16000 ppm 6
hours [Rat].
162 --- --- Flammable; OT (LD50):
Cyclohexanone
Hazardous in case of Acute: 1516
C6H10O
ingestion, of inhalation. mg/kg [Rat]. DT
CAS No:108-94-1
Slightly hazardous in (LD50)
Oily Liquid with acetone like odor BP:155.6
case of skin contact 948 mg/kg
0C
(irritant, permeator). [Rabbit].
MethylcyanoacetateC4H5NO2 --- --- --- No Data available No Data available
CAS No:105-34-0
Clear colorless liquid BP: 204—207 0C
Cyclo Hexane 161 --- --- Slightly hazardous in ORAL (LD50): Flammable
CAS No: 110-82-7 case of skin contact Acute: 12705
(irritant, permeator), of mg/kg [Rat]. 813
Liquid. With: eye contact (irritant), of mg/kg [Mouse].
Chloroform-like odor; ingestion, of inhalation DERMAL
LFL: 1.3% (LD): Acute:
UFL:8.4% >18000 mg/kg
BP: 80.70C [Rabbit].
FP: -18 0C
--- --- --- Hazardous in case of OT(LD50): Acute:
Methylethylketone skin contact (irritant, 2737 mg/kg [Rat].
C4H8O permeator), of eye DT (LD50) 6480
CAS No:78-93-3 contact (irritant), of mg/kg [Rabbit].
Liquid with Pleasant Sweetish odor ingestion, of inhalation (LC50): 23500
BP:79.6 0C (lung irritant). mg/M3 8 hours
[Rat].
Di chloro methane --- --- --- Very hazardous in DT->---mg/Kg;
C-H2-Cl2 case of eye contact OT----1600
CAS No:75-09-2 (irritant), of ingestion, mg/Kg;
TQ-I: Threshold quantity (for application of rules 4,5,7 to 9 and 13 to 15) TQ-II: Threshold quantity (for application of rules 10 to 12)
1. Note:
1. Oral Toxicity (OT) in LD50 (mg/kg)
2. Dermal Toxicity (DT) in LD50 (mg/kg)
3. Inhalation Toxicity in LC50 (mg/l) [4 hrs.]
IOLCP is using 122 raw materials (Table 2.4). Out of 122 raw materials 59 are solids (being
stored in bags / drums), 37 are liquids (being stored in drums), 22 are liquids being stored in
tanks and four are gases being stored in cylinders and bullet (Propylene.)
Hazards analysis has been carried out for gaseous raw materials and liquid raw materials
stored in bulk (tanks). Six raw materials are having not been mentioned in MSIHC Schedule
1Part II (List of Hazardous and Toxic Chemicals). Three gaseous raw materials namely
Chlorine, Ammonia and Propylene have been mentioned in MSIHC List both in Schedule 1
Part II and Schedule 2. Other raw materials have been mentioned in Schedule 1 Part II only.
Stage Description
High A failure which could reasonably be expected to occur within the
expected life time of the plant.
(> 10-2/yr.)
Examples of high failure likelihood are process leaks or single instrument
or valve failures or a human error which could result in releases of
hazardous materials.
Moderate A failure or sequence of failures which has a low probability of
occurrence within the expected lifetime of the plant.
(10-2 --10-
4
/yr.) Examples of moderate likelihood are dual instrument or valve failures,
combination of instrument failures and human errors, or single failures of
small process lines or fittings.
Low A failure or series of failures which have a very low probability of
occurrence within the expected lifetime of plant.
Stage Description
(<10-4) Examples of ‗low‘ likelihood are multiple instruments or valve failures or
multiple human errors, or single spontaneous failures of tanks or process
vessels.
Minor Impact limited to the local area of the event with potent for ‗knock – on-
Incidents events‘
Serious One that could cause:
Incident Any serious injury or fatality on/off site;
Property damage of $ 1 million offsite or $ 5 million onsite.
Extensive One that is five or more times worse than a serious incident.
Incident
Assigning a relative risk to each scenario provides a means of prioritising associated risk
mitigation measures and planned actions.
6.6. Thermal Hazards
To understand the damages produced by various scenarios, it is appropriate to understand
the physiological/physical effects of thermal radiation intensities. The thermal radiation due to
tank fire usually results in burn on the human body. Furthermore, inanimate objects like
equipment, piping, cables, etc. may also be affected and need to be evaluated for damages.
Table 6.4, Table 6.5and Table 6.6(below), respectively give tolerable intensities of various
objects and desirable escape time for thermal radiation.
Thermal hazards could be from fires or explosion. Fire releases energy slowly while
explosion release energy very rapidly (typically in micro seconds). Explosion is rapid
combustion of gases resulting in rapidly moving shock wave. Explosion can be confined
(within a vessel or building) or unconfined (due to release of flammable gases).
BLEVE (boiling liquid expanding vapour explosion) occurs if a vessel containing a liquid at a
temperature above its atmospheric boiling point ruptures. The subsequent BLEVE is the
vaporisation and subsequent explosion of large fraction of its vapour contents; possibly
followed by combustion or explosion of the vaporised cloud if it is in combustible range.
Thermal hazards have been considered for various scenarios including:
Fire in inflammable chemicals storage tanks.
Table 6.4. Effects due to Incident Radiation Intensity
Incident Radiation
Damage Type
kW/m2
0.7 Equivalent to Solar Radiation
1.6 No discomfort on long duration
Sufficient to cause pain within 20 sec. Blistering of
4.0
skin (first degree burn is likely).
Pain threshold reached after 8 sec. Second degree
9.5
burn after 20 sec.
Minimum energy required for piloted ignition of wood,
12.5
melting of plastic tubing etc.
2.
0.15 Typical pressure for glass failure
3.
0.5 - 1 Large and small windows usually shattered
4.
0.7 Minor damage to house structure
5.
1 Partial demolition of houses made
uninhabitable.
6.
2.3 Lower limit of serious structure damage
7.
5–7 Nearly complete destruction of houses
8.
9 Loaded train box wagons demolished
9.
10 Probable destruction of houses
10.
200 Limits of crater lip
In IOLCP case explosion are likely due to Propylene and other inflammable chemicals.
The effect of ambient conditions on the impact of fire / heat radiation and GLC of hazardous /
toxic material can be beneficial as well as harmful. A high wind (turbulence) can dilute the
toxic material while stable environment can extend the reach of IDLH or IT (inhalation LC50
rats for products) concentration to long distance. Any inflammable gas / vapour release in
turbulent weather will soon dilute the hazardous gases below LEL and thus save the
disaster.
6.11. Incidents Impacts
The identified failure scenarios (Table 6.8) have been analysed (Using ALOHA and EFFECT
Modules) for the impact zones considering damage due to thermal and toxic impacts. Each
incident will have Impact on the surrounding environment which in extreme case may cross
plant boundary. The impact zones for various scenarios are given in Table 6.9.
3.
Template 2. Chlorine pipe leakage: Toxic Impact Zone Stability Class ―D‖
Template 3. Chlorine pipe leakage: Toxic Impact Zone Stability Class ―F‖
Template 8. Ethyl Acetate heavy Leakage & Fire —Thermal Impact Zone
Template 10. Heavy HCl Leakage-Toxic Impact Zone; Stability Class ―D‖
Spray more quantity of water /fog to suppress the air born vapours or to avoid
the formation of vapor cloud of ammonia gas, because ammonia vapor cloud
may explode vigorously at its LEL and convert in to flash fire.
Emergency kit and two sets of breathing apparatus provided to meet any
emergency.
4. Water sprinkler system provided for propylene gas bullet to handle any
leakage.
6.15. Other Hazards
The other hazards in the plant include (but not limited to):
Other toxic hazards due to acids / other toxic spillages (mainly limited to
spillage area only.).
Mechanical hazards due to machines / equipment.
Hazards due to individual soft spots like walking casually and noticing a pit
and falling or colliding/ stumbling or slipping (not noticing a wet place etc.).
6.16. Other Toxic Hazards
Other hazardous chemicals including products their impact will be limited to spillage area.
The acid spillage if comes in contact with metal parts will produce hydrogen which is highly
flammable gas. Any person moving in area and getting splash will get the injury. In addition,
the spillage will cause pollution problem. The spillage is to be collected and neutralized for
toxic contents before disposal.
6.17. General Control Measures
Since some of the substances in use at IOLCP are hazardous with fire potential and also
toxic in nature, it is necessary to use appropriate control measures recommended for such
substances:
6.18. Flammable Gas Fires
Fire control generally consists of directing, diluting and dispersing the inflammable gas/vapor
to prevent contact with persons, to prevent it from infiltrating structures if the leak is out door,
and to avoid its contact with ignition sources while, if possible, simultaneously stopping the
flow of gas. Water in the form of spray, applied from hoses or monitor nozzles or by fixed
water spray system cools the burning vapours / gas.
6.19. Process Safety System to be Developed at IOLCP
Process & Plant Safety:
Conducting Preliminary Safety Analysis (A1), Basic Safety Review (A2), Detailed Safety
Review (A3), Pre-Start-Up Safety Review (A4) & Pre Start-Up Safety audit according to PPS
(Process & Plant Safety) directive (details mentioned in following flow diagram)
Every change in the process, procedure, equipment, etc. will be done through robust
management of change (MOC) procedure
Pre-Start up Safety Reviews for all modification
Pressure testing of pipelines and replacement of fragile pipelines and tanks by
prevention project
Hazardous area classification
Internal safety rounds for P&PS
Control P&IDs, and Lock opened (LO)/ Lock closed (LC) procedures are in place
TOPPS (Top Performance in Process & Plant Safety) training to all employees
Root Cause Analysis of all incidents
Occupational Safety:
Permit to Work procedure and Monthly monitoring of all filled permit for continual
improvement
Mobilized Near- Miss Reporting and award scheme
HSE rounds: PMT (Plant Management Team) of one plant takes HSE round of
another plant. Exchange of best practices among plants
MSDS Management
Tool Box talk with contractors
Central Safety Committee
Departmental Safety Committees
HSE Coordinator and Monitor program: Shop floor employees‘ participation in Safety
activities
Celebration of theme-based Safety days/ weeks at site
Safety Induction program for new joiners (both company & contract employees)
Emergency Preparedness:
On-Site Emergency Plan for the site
Training on On-Site Emergency Action Plan
Regular Site level Mock drills and Plant specific Fire Drills and Leak, spill drills
Availability of First aiders, Fire Fighters and Rescue members in each shift
Maintenance of Fire hydrant system, sprinkler system and portable fire extinguishers
Periodic testing of fire hydrant and sprinkler systems
Three Fire Tenders and Two Ambulances
Occupational Health:
Pre-employment & Annual Medical Examination
Quarterly/Periodical Physical Examinations
Canteen Employees Examination
Fork lift operators Examination
Recall services & Follow-Up
Return to work assessment
Exit Examination
Training on Counselling, Hearing Conservation Program, Hazardous Chemical
Awareness Program, Shop floor training, First-aid (138Nos. Certified First Aiders),
etc.
Legal records: All medical records of employees to be maintained.
Emergency Medical services: Ambulance services, First-aid boxes, Decontamination
facility etc.
Health Promotional Activities: Awareness on Medical issues, Ergonomics awareness
programs, Stress management, De-addiction program, etc.
corrective actions are decided by Plant Manager, General Manager - works and
Engineering Manager and they are implemented. After implementation again,
monitoring is carried out.
The sampling for gaseous pollutants and air pollutants are done by Air sampling
pump. A sample report of work area monitoring is attached as Annexure V.
• Use water spray to reduce vapors; do not put water directly on leak,
Fire,& explosion, spill area or inside container.
• Keep combustibles (wood, paper, oil, etc.) away from spilled
material.
• Use water spray to reduce vapors; do not put water directly on leak,
Fire, & explosion, spill area or inside container.
• Keep combustibles (wood, paper, oil, etc.) away from spilled
material.
• Use water spray to reduce vapors; do not put water directly on leak,
spill area or inside container.
• Keep combustibles (wood, paper, oil, etc.) away from spilled
material.
Noise Environment:The ambient noise level of all the monitoring locations were found well
within the National Ambient Noise Quality Standards prescribed for industrial (Standards - 75
dBA during day time and 70 dBA during night time) residential area (Standards - 55 dBA during
day time and 45 dBA during night time) and commercial area (Standards - 65 dBA during day
time and 55 dBA during night time) The Ambient noise are well within the limit as per prescribe
standard.
Water Quality: Six surface water samples and eight groundwater samples were collected from
the area for chemical and biological analysis. Overall the ground water quality of the study area
is found well within the permissible limits. No metallic and bacterial contaminations were
observed in ground water samples.
Surface water quality is determined by the help of water quality criteria defined in CPCB best
designated uses criteria. Surface water monitoring is performed for nalla near project site at 100
upstream and downstream point of the project site high bacterial contamination were observed in
Nala water quality meeting the BDU criteria Class D which is fit for propagation of wildlife and
fisheries.
Canal Water quality: The canal water quality is good for Drinking water source after conventional
treatment and disinfection and meeting the class C of Best designated uses of CPCB.
Pond Water Quality: Bacterial contamination were observed in pond water samples. Dissolve
oxygen is found within the range while BOD was found slightly on slightly high than the Class C
of Best designated uses. Hence the pond water is fit for Propagation of Wild life and Fisheries
and meeting the criteria D of Best designated uses of CPCB.
Soil Quality: The soil quality of study area is sandy loam. The pH and conductivity of the soil is
within acceptable range. The soil analysis describes that the soil of the study area is moderately
fertile.
Sensitive Ecosystem: There are no environmentally sensitive components such as National
Park, Wildlife Sanctuary, Elephant / Tiger Reserve, migratory routes of fauna and wet land
present within 10 Km radius of plant site.
Socio economic environment: As per Census of India- 2011, Barnala district had a total
population of 5, 95,527 out of which 3, 17,522 are males and 2, 78005 are females. Males
constitute the 53.31% and female constitutes 46.68 % of total population. Barnala has an
average literacy rate 67.8% which is 7.5% more than the 2001 Census data. The percentage of
decadal growth in population has been 13.0% during 2001-11 and sex ratio (number of females
per 1000) has been 876 in 2011 as compared to 872 in 2001. In the district 0-6 years of
population in the district has been 10.9 which is on the decreasing trend in comparison of 2001
when it was 13.3% . As per the census records 2011, in Barnala district there are 78.5% Sikhs,
19.0% Hindus, 2.2% Muslims, 0.1% Christians, Jains and Buddhists are negligible.
PM 0.95 1.6 SE
SO2 0.64 1.6 SE
NOx 3.1 1.6 SE
HCL 0.23 1.6 SE
The nearest settlement in downwind direction is Fatehgarh channa village (towards SE)
at 1.68 km. As per baseline data of mean AAQ for PM at Fatehgarh channa village is 92
µg/m³ and with this proposed project, 0.95 µg/m³ rise in GLCs so PM level will be 92.95
µg/m³. The Particulate Matter in the study area is contributed mainly by commercial
activities and traffic movement (vehicular emissions), re-suspended dust from paved and
unpaved roads and open uncovered areas as well as from industrial activities.
Maximum baseline GLC for SO2 (Process and utilities) at downwind direction (SE) was
as 11.8 µg/m³ observed at Fatehgarh Channa village. With this proposed expansion
project SOx level may increase by 0.61 µg/m³ so post project level of SOx is 12.41µg/m³.
Maximum baseline GLC for NOx was as 22.70 µg/m³ observed at Fatehgarh channa
village. With this proposed project NOx concentration is 3.1 µg/m³ so rise in GLC of NOx
concentration is 25.80 µg/m³. It can be concluded that with the proposed project all the
AAQ parameters will remain within the NAAQ norms.
As is evident from the table and discussion above, there will be no adverse impacts on
the surrounding area (all pollutants post project GLC will be well within NAAQ norms
except PM which is already high due to natural and other commercial and traffic causes).
Highly efficient air pollution control systems have been adopted to mitigate particulate
matter as well as gaseous emissions in the ambient environment.
Noise Quality:
The main source of noise generation during operation stages are mainly from pumps, blowers,
compressors, DG sets, vehicle movement for transportation of raw materials, finished goods etc.
DG sets will be provided with acoustics enclosures. Mufflers, silencers, acoustics treatment of
room will be done wherever required. Equipment will be maintained so that noise level does not
increase due to improper maintenance. Material handling operations and movement of vehicles
will be properly scheduled to minimize construction noise. Workers working in noisy areas will be
given ear plugs. The noise level will be restricted within the plant boundary to meet the
standards. Existing greenbelt developed within the plant premises will also act as a barrier to the
propagation of noise from the factory premises. This shall further reduce the noise levels
appreciably. Hence, no significant impact is envisaged.
Water Quality: Total water requirement–1800 KLD (Fresh water 1456 KLD and Recycle water 344 KLD).
Water requirement will be made available through ground water and surface water. Low TDS Effluent
Treated in To ETP. ETP comprises of Four Stage, Two Stage Anaerobic, One Stage Aerobic and One
Stage Tertiary. After treatment treated effluents discharge in to plantation area within premises. High TDS
effluent Treated in to MEE. Condensate recovery will be reused in plant. Concentrated stream will be sent
to ATFD for further treatment. MEE salt will be sold out to end users.
Solid and Hazardous Wastes Disposal:
All the solid and hazardous waste generated from the proposed unit shall be disposed as per the
norm. Minor quantities of construction waste will be generated in the form of packaging material
and construction waste. Proper care will be taken for handling and reduction of the solid waste
generated during construction phase. ETP sludge/ process residue generated during operation
phase shall be disposed as per the hazardous waste‘s management, handling and Trans-
boundary movement Rule 2016 and amendment thereof.
Impact on Ecology: No national park, wildlife sanctuary, biosphere reserve exists within 10 km
area of the project. No endangered or rare or threatened plant or animal species was observed
within 10 km area of the project site. The impact on the surrounding ecology during the operation
of the project will mainly occur from the deposition of air pollutants. Air pollution affects the biotic
and abiotic components of the ecosystem individually and synergistically with other pollutants.
Chronic and acute effects on plants and animals may be induced when the concentration of air
pollutants exceeds threshold limits. Particulate emission and other gaseous emissions from the
proposed plant are the major pollutant that may affect the ecology of the area. However, the
AAQ modeling proves that in worst condition the concentration of the PM and other gaseous
emission will not exceeds the AAQ standards. Further the mitigation measures have been
suggested for the same. By adopting the mitigation measures suggested the impact due to
operation of the proposed expansion will be negligible.
Risk Assessment and Disaster Management Plan: The hazard potential of chemicals and
estimation of consequences in case of their accidental release during storage, transportation and
handling has been identified and risk assessment has been carried out to quantify the extent of
damage and suggest recommendations for safety improvement for the proposed facilities. Risk
mitigation measures based on MCA analysis and engineering judgments are incorporated in
order to improve overall system safety and mitigate the effects of major accidents.
An effective Disaster Management Plan (DMP) to mitigate the risks involved has been prepared.
This plan defines the responsibilities and resources available to respond to the different types of
emergencies envisaged. Training exercises will be held to ensure that all personnel are familiar
with their responsibilities and that communication links are functioning effectively.
Green belt development:IOLCP has planted approx 26000 tree/shrubs and herbs in existing
greenbelt. The tree species like Eucalyptus, neem, Daikan, sadabahar, Ficus spp., jamun,
Champa, kadam gulmohar along with shrubs and herbs has been planted under existing
greenbelt. Further maintenance of the existing greenbelt shall be done on regular basis for which
IOL Chemical has already kept a budget for Rs. 20 lakhs as a capital cost.
CSR Plan: IOLCP has allocated 2.5% of the total project cost towards the Enterprise Social
Commitment (ESC) and item-wise details along with time bound action plan will be prepared and
incorporated after public hearing.
Project Benefits
Proposed expansion project will result in considerable growth of stimulating the industrial
and commercial activities in the state. Small and medium scale industries may be further
developed therefore.
The project will be beneficial in govt‘s target of increase the production capacity and yield
in the field of pharmaceuticals.
Increased revenue to the state by way of royalty, taxes and duties;
Overall Growth of the neighboring area viz. Health and family welfare; Watershed
development; Sustainable livelihood and strengthening of village Self Help Groups; and
Infrastructure development.
In operation phase, the proposed plant would require significant workforce of non-
technical and technical persons.
Migration of persons with better education and professional experience will result in
increase of population and literacy in the surrounding villages.
Civic amenities will be substantial after the commencement of project activities. The
basic requirement of the community needs will be strengthened by extending healthcare,
educational facilities to the community, building/strengthening of existing roads in the
area.
The local population will be given preference to employment on the basis of their
eligibility and company requirement. The employment potential will ameliorate economic
conditions of these families directly and provide employment to many other families
indirectly who are involved in business and service-oriented activities. The employment
of local people in primary and secondary sectors of project shall upgrade the prosperity
of the region. This in-turn will improve the socio-economic conditions of the area.
Involvement Signature
Functional Name of the
(Period and Task**)
Areas Expert
Feb 2018 to finalization of report
Monitoring of water quality.
Water Balance
Identification & assessment of
quantum of water pollution and its
Mitigation measures.
ETP Suggestion.
Conducted Ecological survey &
preparation of status report.
Ecology and Ratnesh Application of taxonomy in resource
Bio-diversity Kotiyal inventory (Flora & Fauna)
Conservation List of species animals and plants
(EB) report.
Identification & assessment of
ecological impact due to proposed
project and its Mitigation measures.
Identification of hazardous and non
Solid and hazardous wastes.
Hazardous
Reuse and recycling of solid wastes .
Waste Y Bordia
Management Handling and disposal of Non-
Hazardous solid waste & Hazardous
(SHW)
waste.
Identification of hazards due to
proposed project.
Risk and P K Identification of hazardous
Hazards Srivastava
substances in the proposed project.
(RH)
Preparation of risk assessment report
and onsite emergency plan.
Declaration by the Head of the Accredited Consultant Organization /authorized person
I, S.K.Jain, hereby confirm that the above-mentioned experts the EIA/EMP Report for expansion of APIs
and Bulk drug production unit by M/s IOL Chemical and Pharmaceutical Limited . I also confirm that the
consultant organization shall be fully accountable for any mis -leading information mentioned in this
statement.
Name: S.K.Jain
Signature