Product Safety Data Sheet

Document D0203810 Versio 3.0

Code: n:
Description: NATURGARD AIK DPHEN AE Status: Published
Project WICKLOW AIK - dPHEN Project
Name: Numbe
r:
Category: Pest Control Segme Aerosols (AIK)
nt:
Formula FILL FORMULA
Type:

PSDS
PSDS

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name NaturGard All Insect Killer Aerosol (D-Phenothrin)

Product Type All insect killer

Product Code To be advised

Use Household insecticide aerosol spray

Appearance Aerosol can

Supplier Reckitt Benckiser East Asia

200 Newton Road, #05-01
Newton 200
Singapore
Tel: +65 6572 8900

Reckitt Benckiser (Malaysia) Sdn Bhd

Level 5, Menara UAC,No. 12, Jalan PJU 7/5
Mutiara Damansara, 47800 Petaling Jaya,
Selangor Darul Ehsan,
Malaysia
Tel: +603 7719 1000

Technical Services Reckitt Benckiser (Australia) Pty Limited

44 Wharf Road West Ryde NSW 2114
Tel: + 61 (02) 9857 2000
AFTER HOURS EMERGENCY TELEPHONE (5pm to 8am EST Australia): (02) 9857 2444

2. HAZARDS IDENTIFICATION

The product is classified as not dangerous in accordance with Directive 1999/45/EC.

Most important hazards

R-phrase(s) R12 - Extremely flammable
R51/53 - Toxic to aquatic organisms. May cause long- term adverse effects in the aquatic env

3. COMPOSITION

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 The product contains the following components

Chemical CAS No EC# Proportion (%w/w) Classification

Deionised Water 7732-18-5 231-791-2 30 - 60 Not applicable

Hydrocarbon 106-97-8/ 203-448-7/ 30 - 60 F+; R12

1
propellant 74-98-6 200-827-9
Hydrocarbon solvent 64771-72-8 265-233-4 <10 Xn;R65 - 66

Polyglycerol oleate 9007-48-1 Not applicable <10 Not applicable

ester
Lauryl 2687-96-9 403-730-1 <1 C;R34 - 43,
pyrrolidone N;R50/53
D-Limonene 5989-27-5 227-813-5 <1 R10, Xi;R38 - 43,
N;R50/53
Perfume Mixture Not available <1 Xi;R38 - 43,
N;R51/53
Esbiothrin 84030-86-4 Not applicable <1 Xn; R20/22,
N;R50/53
<1 N;R50/53
d-Phenothrin / 188023-86-1 Not applicable /
Phenothrin /26002-80-2 247-404-5
Imiprothrin 72963-72-5 Not applicable <1 Xn; R20;
N; R50/53
Butylated hydroxy 128-37-0 204-881-4 <1 Xn;R22,- 36,
toluene N;R51/53

1
Our supplier of butane has provided documentation stating that the butane component contains less than 0.1%w/w 1,3 butadiene.

Key to R phrases :
R66: Repeated exposure may cause skin dryness or cracking
R65: Harmful: may cause lung damage if swallowed
R51/53: Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R50/53: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R43: May cause sensitisation by skin contact
R38: Irritating to skin
R36: Irritating to eyes
R34: Causes burns
R20/22: Harmful by inhalation and if swallowed
R20: Harmful by inhalation
R22: Harmful if swallowed
R12: Extremely flammable
R10: Flammable

4. FIRST- AID MEASURES

Eye Contact Wash eyes with a large amount of water. If irritation occurs and persists seek medical attentio
Skin Contact Wash off skin with warm water and soap. If irritation occurs and persists, seek medical attenti
Inhalation Remove to fresh air. If breathing difficulties are experienced seek medical attention.
Ingestion Not an anticipated route of exposure.

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 5. FIRE- FIGHTING MEASURES

Specific Dangers Aerosol cans may explode with extreme heat and become projectiles.
Extinguisher Type Water, foam, carbon dioxide.

6. ACCIDENTAL RELEASE MEASURES

Spills Keep area well ventilated. Remove ignition sources.

Minor Spills Wipe up spills with a clean dry cloth. Wash away residues with water.

Major Spills Contain spill and collect using a suitable absorbent material such as vermiculite. Shovel into l
Wash residues away with water and detergent. Do not allow material to enter waterways.

See also Sections 8 and 13

7. HANDLING AND STORAGE

Handling Avoid all direct contact with the product. The product should not be used in restricted areas, e
Do not spray on a naked flame, onto or near fire, or any incandescent material such as an elec
Keep away from all sources of ignition - No smoking.
Storage Store in a cool, dry, frost free place out of the reach of children.
Protect from sunlight and do not expose to temperatures exceeding 50°C
Keep away from sources of ignition.
Warehouse and stores containing aerosols should be fire-separated from other areas by fire-re
The store should be well ventilated, particularly at low-levels.
Avoid the storage of aerosols in basements wherever practical.

8. EXPOSURE CONTROL AND PERSONAL PROTECTION

See also Section 7

Occupational Exposure Limits

CAS No. TWA*

3
n-Butane 106-97-8 1900mg/m ; 800 ppm

Propane 74-98-6 asphyxiant

3
Butylated hydroxy toluene 128-37-0 10mg/m

* Worksafe Australia Exposure Standards for Atmospheric Contaminants in the Occupational Environment (NOHSC: 1003 1995). Also applicable

Engineering Controls Keep areas well ventilated. Maintain air concentration below exposure standards.

Personal Protective Equipment When handling bulk quantities wear suitable protective gloves, clothing and eye wear should b
should be worn.

Flammability Propellant gases are extremely flammable.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Aerosol

Appearance Fine Mist
Colour Colourless
pH Not determined

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 Vapour pressure 240kPa at 16 °C (butane)
Boiling Point 0 °C (butane)
Melting Point Not determined
Flash Point of Contents -60 °C (butane)
Solubility Immiscible in water
Density 0.95 - 0.96 g/ml at 25°C (Concentrate)
Viscosity Not determined

10. STABILITY AND REACTIVITY

Stability Stable under normal conditions. Cans may explode when subjected to extreme heat.
Dangerous Reactions Avoid extreme heat and pressures. Do not incinerate or puncture cans.
Hazardous Decomposition Products Products may include oxides of carbon.

11. TOXICOLOGICAL INFORMATION

Product Toxicity The classification is based on toxicity testing of a similar product and known toxicity of the acti
Other hazard identifications in Section 2 were derived from the known effects of the individual
Acute Effect(s)
Eye Contact May cause transient irritation to the eyes.
Skin Contact May cause irritation to the skin with prolonged/repeated contact.
Inhalation Mists/vapours may cause irritation to the upper respiratory tract
Ingestion Not an anticipated route of exposure
Sensitisation Not a skin sensitiser.
Chronic Effect(s) The chronic toxicity of this product has not been determined.
Specific Effect(s)
Carcinogenic Effects No information available.
Mutagenic Effects No information available.
Reproductive Toxicity No information available.
Toxicity Information Information is based on available component data and toxicity result of similar products.

12. ECOLOGICAL INFORMATION

See also Sections 6,7,13 and 15

Product Ecotoxicity The classification is based on ecotoxicity testing of the concentrate of a similar product and kn

Component Ecotoxicity The following data was considered to determined the overall ecotoxicity of the product:
Esbiothrin:
Fish (Rainbow trout) LC50 (96h): 0.013mg/L
Aquatic invertebrates (Daphnia magna) EC50 (48h) : 0.0089 mg/L

D-Phenothrin/Phenothrin:
Aquatic invertebrates (Daphnia magna) EC50 (48h): 0.0043mg/L
Fish (Rainbow trout) LC50 (96h): 0.0027mg/L

Imiprothrin:
Aquatic invertebrates (Daphnia pulex) EC50 (48h): 0.051 mg/L
Fish (Bluegill sunfish) LC50 (96h): 0.007mg/L
Fish (Rainbow trout) LC50 (96h): 0.038 mg/L

Summary of Product Ecotoxicity

Ecotoxicity It was found to be toxic to aquatic organisms. May cause long-term adverse effects in the aqua
Mobility No information available.
Persistence and degradability No information available.

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 13. DISPOSAL CONSIDERATIONS

Consumer Instructions Containers may be disposed of by consumers in the normal household waste stream.
Do not pierce of burn after use.
Protect from sunlight and do not expose to temperatures exceeding 50°C.
Bulk Quantities Dispose of according to Local, State and National regulations. For future information contact y

14. TRANSPORT INFORMATION

UN Number: UN 1950
Description: AEROSOLS

International Transport
Sea: IMDG
UN-Number UN 1950
Proper shipping name AEROSOLS
Class 2
Subsidiary Risk Not applicable
Marine Pollutant Yes
Special Provisions 63, 190, 277
Limited Quantity 1L
EmS F-D, S-U

Air: ICAO/IATA
Classification: UN 1950, Aerosols, Flammable 2.1, Limited Quantity
Proper Shipping Name: AEROSOLS, FLAMMABLE
Class: 2.1
Subsidiary Risk: Not applicable
Packing group: Not applicable
Maximum quantity: See DG List

Road & Rail: ADG (Australia)

UN number: UN 1950
Proper shipping name: AEROSOLS
DG class: 2.1
Subsidiary risk: None allocated
Packing group: None allocated
Hazchem code: 2YE

National transport regulations may apply.

15. REGULATORY INFORMATION

According to EU directives this product is classified as:

F+; R12 - Extremely Flammable

N; R51/53 - Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

The label must contain the following symbols:

Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C.
Do not pierce or burn after use.
Do not spray onto a naked flame or any incandescent material.
S2 Keep out of reach of children.
S16 Keep away from sources of ignition - No smoking.
S23 Do not breathe vapour
S46 If swallowed, seek medical advice immediately and show this container or label
S51 Use only in well-ventilated areas

The following directives are relevant to the above classification and labelling of these products:

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 Council Directive 1999/45/EEC on the approximation of the laws, regulations and administrative provisions of the Member States relating to the c
packaging and labelling of dangerous preparations.

16. OTHER INFORMATION

Data sources used in the preparation of this Safety Data Sheet :

Raw material supplier's Safety Data Sheets.

This document complements the technical usage instructions but does not replace them. The information contained herein is based on our best c
of the product concerned, and is given in good faith. The attention of recipients is drawn to (amongst other things) the element of risk consequent
for a purpose other than that for which it was intended.

In no way does this document remove the need of the recipient of the product to fully understand and apply statutory requirements. It is the recipi
take due precautions relative to the use made of the product.

All information contained herein is included only to assist the recipient in fulfilling his or her statutory duty connected with the use of hazardous ma

This list of information must not be considered as exhaustive, and does not exonerate the recipient from taking other precautions described in doc
mentioned, concerning the storage and use of the product, for which he or she remains the sole person responsible.

Where Used
Where Used

Customer Product Bill of Material Formulation Bill of Material

0203073 : FIL,PESTC,NATURGARD AIK (D-PH)

History

Document History (Ver. 3.0)

Author: Mimi Cruz/AANZ/R_B

Creation Date: 21 Jul 2010 01:28 GMT

Creation Reason: New Document
Password Validated Signatures
Approved By Regulatory: Arun Prakash/AANZ/R_B
Published Date: 02 Aug 2010 01:30 GMT
Revision Reason: Update PSDS including additional information on D-Phen

Revision History Published Revision Reason

2.0 7 Apr 10 Update ecotoxicity information.
1.0 11 Feb 10 New Document

This document is only current on the day of viewing. Printed copies are UNCONTROLLED unless they are part of a Quality/Technical Manual or atta

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