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*RAN-1160*
* R A N - 1 1 6 0 *

RAN-1160
T.Y.B.Sc. (Sem.-VI) Examination
March / April - 2019
Chemistry Paper-X (Analytical Chemistry)

[ Total Marks: 50

k|Q“p : / Instructions
“uQ¡ v$ip®h¡g  r“ip“uhpmu rhNsp¡ DÑfhlu ‘f Ahíe gMhu. Seat No.:
Fill up strictly the details of  signs on your answer book
Name of the Examination:
 T.Y.B.Sc. (Sem.-VI)
Name of the Subject :
 Chemistry Paper-X (Analytical Chemistry)
Subject Code No.: 1 1 6 0 Student’s Signature

(1) As per the instruction No.1 of page no.1

(f) S>dZu bpSy>“p A„L$ âï““p„ ‘|fp NyZ v$ip®h¡ R>¡.
(2) Figures to the right indicate full marks of the question.
(3) S>hpbp¡ V|$„L$dp„ A“¡ dyØpkf gMp¡.
(3) Write the answers briefly and to the point

1. “uQ¡“p âï“p¡“p„ V|$„L$dp„ S>hpb gMp¡. (5)

(1) N°¡qV»$N Üpfp ’sy„ âL$pi“y„ rhcpS>“ L$ep rkÝ^p„s ‘f L$pe® L$f¡ R>¡?
(f) õ‘¡L$V²$p¡ap¡V$p¡duV$f“p k„v$c®dp„ A„^L$pf âhpl A¡V$g¡ iy„?
(3) hpey âhplu hZ®g¡M“dp„ [õ’fL$gp sfuL¡$ h‘fpsp b¡ âhplu“p “pd Ap‘p¡.
(4) êqY$Ns âhplu hZ®g¡M““u dep®v$p S>Zphp¡.
(‘) ap¡d®g ‘p¡V$¢rieg“u ìep¿ep Ap‘p¡.

2. “uQ¡“p âï“p¡dp„’u ÓZ“p S>hpb gMp¡. (15)

(1) õ‘¡L$V²$p¡ap¡V$p¡duV$fdp„ h‘fpsp ap¡V$p¡dëV$uàgpef V$eyb k„k|QL$“u L$pe® ‘Ý^rs
kdÅhp¡. s¡d“u k„h¡v$“iugsp“u kfMpdZu ap¡V$p¡V$eyb kp’¡ L$fp¡.
(f) g¡çbV$®-rbef r“ed“p ‘pep“y„ kduL$fZ Ap‘p¡ A“¡ “uQ¡“p ‘v$p¡ ìep¿epres L$fp¡:
(1) ‘pfNçesp (f) Ahip¡jZp„L$ (3) Ahip¡jZsp (4) dp¡gf Ahip¡jZsp

RAN-1160 ] [ 1 ] [ P.T.O. ]
 (3) rbef“p r“ed’u rhQg“ A¡V$g¡ iy„? fpkperZL$ rhQg“ Dv$plfZ Ap‘u kdÅhp¡.
(4) rÜqL$fZhpmp õ‘¡L$V²$p¡ap¡V$p¡duV$f“y„ f¡MprQÓ Ap‘p¡ A“¡ s¡“u L$pdNufu hZ®hp¡.
(‘) õV$ug“p 0.5 N°pd “d|“p“¡ HNO3, dp„ Ap¡Npmu s¡dp„“p Mn “y„ KMnO4 dp„
KIO3 hX¡$ Ap¡qL$kX¡$i“ L$fu s¡“¡ 50.0 rd.gu. ky^u d„v$ L$fhpdp„ Aph¡ R>¡,
Ap ÖphZdp„’u 5.0 rd.gu. ÖphZ gC s¡“p¡ Ahip¡jZp„L$ dp‘sp 0.658 dpg|d
‘X$ep¡. Ap “d|“p“p„ ÖphZdp„’u 5.0 rd.gu. âdprZs 1.5 × 10– 4M KMnO4
Dd¡fu ‘qfZpdu ÖphZ“p¡ Ahip¡jZp„L$ 0.450 dþep¡, sp¡ Ap ÖphZ“u dp¡gf
kp„Ösp ip¡^p¡.

3.
“uQ¡“p âï“p¡dp„’u ÓZ“p S>hpb gMp¡. (15)
(1) hpey hZ®g¡M“dp„ h‘fpsp ""hplL$ hpey'' ‘f V|$„L$“p¢^ gMp¡.
(f) Dódp hplL$sp k„k|QL$“u fQ“p A“¡ L$pe®‘^¹^rs kdÅhp¡. s¡“p apev$p A“¡
N¡fapev$p Ap‘p¡.
(3) hpey hZ®g¡M““u ‘fudpZdp‘L$ ‘©Õ’L$fZdp„ D‘ep¡rNsp kdÅhp¡.
(4) (1) hZ®g¡M““y„ rhõs©s hN}L$fZ L$fp¡.
(f) s“y õsf hZ®g¡M“dp„ h‘fpsp O“ Ar^ip¡jL$ rhi¡ dprlsu Ap‘p¡.
(5) DÃQ r“ó‘pv$“ âhplu hZ®g¡M““p„ kp^““y„ f¡MprQÓ Ap‘p¡ A“¡ s¡dp„ h‘fpsp
k„k|QL$p¡ ‘f “p¢^ gMp¡.

4.
“uQ¡“p âï“p¡dp„’u ÓZ“p S>hpb gMp¡. (15)
(1) f¡X$p¡n A“ydp‘“dp„ h‘fpsp k|QL$p¡“p âL$pf Dv$plfZ Ap‘u kdÅhp¡.
(f) ApS>£ÞV$p¡d¡V²$uL$ A“ydp‘“ A¡V$g¡ iy„? Aphp A“ydp‘““u aÅÞk ‘Ý^rsdp„ k|QL$“u
‘k„v$Nu dpV$¡ L$C bpbsp¡ Ýep“dp„ fpMhu Å¡CA¡?
(3) f¡X$p¡n A“ydp‘“dp„ Ap¡qL$kX¡$i“L$sp® sfuL¡$ KMnO4 “p¡ D‘ep¡N krhõspf kdÅhp¡.
(4) Ahn¡‘“ A“ydp‘“ dpV$¡“u çlp¡f ‘Ý^rs hZ®hp¡. Ap A“ydp‘“ v$fçep“ dpÝed“u
pH L¡$V$gu fpMhu Å¡BA¡? ip dpV$¡?
(‘) “uQ¡“p rdî îphZ dpV$¡ PCl “y„ d|ëe NZp¡.
(1) 50.0 ml. 0.080 M AgNO3 + 50.0 ml. 0.100 M NaCl
(2) 40.0 ml. 0.200 M AgNO3 + 80.0 ml. 0.1 M NaCl,
        (AgCl “p¡ Ksp = 1.0 × 10– 10)

RAN-1160 ] [ 2 ] [ Contd.
 ENGLISH VERSION

1. Answer the following questions in brief : (5)

(1) Dispersion of light by grating is working on which principle?
(2) What is dark current with respect spectrophotometer?
(3) Name two liquids used as stationary phase in gas liquid chromatography.
(4) State limitations of conventional liquid chromatography.
(5) Give definition of formal potential.

2. Write any three answers of the following. (15)
(1) Explain the working of photomultiplier tube detector used in
spectrophotometer. Compare its sensitivity with phototube.
(2) Give basic equation of Lambert-Beer's law and define the following
terms:
(1)Transmittance (2)Absorbance (3) Absorptivity (4) Molar absoptivity
(3) What is deviation from Beer's law? Explain chemical deviation with
example.
(4) Give block diagram of double beam spectrophotometer and describe its
working.
(5) A 0.5 gm. sample of steel is dissolved in HNO3. Mn from the sample is
oxidized to KMnO4 by KIO3 and diluted to 50.0ml. From this 5.0 ml.
solution is taken and its measured absorbance is 0.658. To this sample
solution 5.0 ml. 1.5 ×10– 4 M standard KMnO4 solution is added and
absorbance of resulting solution is 0.450. So, find out molar
concentration of this solution.

3. Write any three answers of the following. (15)

(1) Write a brief note on 'carrier gas' used in gas chromatography.
(2) Explain construction and working of thermal conductivity detector.
Give its merits and demerits.
(3) Explain the application of gas chromatography in quantitative analysis.
(4) (i) Give detail classification of chromatography.
(ii) Give information regarding solid adsorbents used in thin layer
chromatography.
(5) Give schematic diagram of high performance liquid chromatography
and write note on detectors used in it.

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4.
Write any three answers of the following. (15)
(1) Explain types of indicator used in redox titration giving suitable examples.
(2) What are argentometric titrations? Which factors need to be considered
while selecting indicator in Fajan's method of such titration?
(3) Explain the use of KMnO4 as oxidizing agent in redox titrations.
(4) Describe Mohr's method of precipitation titration. What will be the
pH kept of the medium in this method? Why?
(5) Calculate the value of PCl of the following mixed solutions.
(1) 50.0 ml. 0.080 M AgNO3 + 50.0 ml 0.100 M NaCl
(2) 40.0 ml. 0.200 M AgNO3 + 80.0 ml 0.100 M NaCl
    (Ksp of AgCl = 1.0 × 10 –10)

RAN-1160 ] [ 4 ] [ 4360 ]