z

Q1. In the reaction: x MnO + y PbO2 + z H+  x MnO2 + y Pb2+ + H O, then x, y, z are:

2 2
(A) 2, 5, 8 (B) 2, 5, 6 (C) 1, 5, 6 (D) None

Q2. The oxidation states of the most electronegative elements in the products when BaO 2 reacts with
H2SO4 are
(A) 0, 1 (B) 1, 2 (C) 2, 0 (D) 2, +1

Q3. If equal volumes of 1 M KMnO4 and 1 M K2Cr2O7 solutions are allowed to oxidise Fe (II) to Fe
(III) in acidic medium, then Fe (II) oxidised will be :
(A) equal in both cases (B) can’t be determined (C) more by KMnO4 (D) more by K2Cr2O7

Q4. The ratio of amount of H2S needed to precipitate all the metal ions from 100 mL of 1M AgNO 3
and 100 mL of 1M – CuSO4 is –
(A) 1 : 2 (B) 2 : 1 (C) 1 : 4 (D) 4 : 1

Q5. A certain compound has the molecular formula X4O6. If 10 gm of X4O6 has 5.72 gm of X, atomic
mass of X is –
(A) 32 amu (B) 37 amu (C) 42 amu (D) 98 amu

Q6. One mole of a mixture of CO and CO2 requires exactly 20 gm of NaOH in solution for complete
conversion of all the CO2 in Na2CO3. How many grams more of NaOH would it require for
conversion into Na2CO3 if the mixture is completely oxidised to CO2 ?
(A) 60 gm (B) 80 gm (C) 40 gm (D) 20 gm

Q7. A sample of pure Cu(3.18 grams) heated in a steam of oxygen for some time gains in weight with
the formation of black oxide of copper (CuO). The final weight is 3.92 gm. What percent of
copper remains unoxidised?
(A) ~6.5 (B) ~6.9 (C) ~7.6 (D) ~7.9

Q8. One gram of variable alloy of lead and tin yielded on treatment of conc. HNO 3 filtration and
heating 0.42 gm of SnO2. If all the lead in one gram of alloy is converted into PbSO4., what will
be the weight of PbSO4 obtained?
(A) 0.98 gm (B) 1.00 gm (C) 1.07 gm (D) 0.95 gm

Q9. 1 litre of 0.250 M NaSO solution Na2SO4 solution is added to an aqueous solution of 30 g of
BaCl2 resulting in the formation of white precipitate of insoluble BaSO 4?
Na2SO4 + BaCl2  BaSO4 + 2NaCl
How many moles & how many grams of BaSO4 are formed? (Atomic mass of Na = 23, S = 32, O
= 16, Ba = 137.3, Cl = 35.5)

Q10. 1g sample of H2O2 solution containing x% H2O2 by weight requires x ml of KMnO4 solution for
complete oxidation under acidic conditions. Calculate N of KMnO 4.

Q11. 2.013g of commercial sample of NaOH containing Na 2CO3 as an impurity was dissolved to give
250ml solution. A 10ml portion of this solution required 20ml of 0.1N H2SO4 for complete
neutralisation. Calculate %age weight of Na2CO3 in the sample.
Q12. A small amount of limestone completely neutralises 500ml of centinormal HCl and no acid is left
1
at the end. After converting all CaCl2 to CaSO4, how much plaster of paris (CaSO4. H O) can be
2 2
 obtained.

Q13. A solution contains a mixture of Na2CO3 and NaOH. Using phenolphthalein as indicator, 25ml.
of mixture required 19.5ml of 0.995N HCl for end point. With methyl orange 25ml of solution
required 25.9ml of the same HCl for the endpoint. Calculate in g/L of each substance in the
mixture.

Q14. A solution contains a mixture of Na2CO3 and NaHCO3 . 10ml of solution required 2.5ml of 0.1M
H2SO4 for neutralisation using phenolphthalein as indicator. Methyl orange is then added when a
further 2.5ml of 0.2M H2SO4 was required. Calculate amount of Na2CO3 and NaHCO3 in g/L.

Q15. A 1.984g of crystalline Na2S2O3 . xH2O was dissolved in water and solution required 40ml of N/
5 I2 solution for complete reaction. Calculate the number of molecules of water of crystallisation
i n
1 molecule of Na2S2O3.

Q16. 6g of a mixture of NH4Cl and NaCl are treated with 110ml of NaOH solution containing 25.2g
per litre. The solution boiled to remove NH3. The resulting solution required 48.1ml of a solution
of 0.1N HCl acid. What is %age composition of the mixture.

Q17. A solution of KMnO4 containing 3g/L is used to titrate a solution of H2O2 containing 2g/L. What
volume of KMnO4 solution is required to react with 20ml of H2O2 solution ? What is strength of
H2O2 solution in terms of available O2 ?

Q18. A 0.5g sample containing MnO2 is treated with HCl liberating Cl2. The Cl2 is passed into a solution
of KI and 30.0cm3 of 0.1M Na2S2O3 are required to titrate the liberate I2. Calculate %age of MnO2
in the sample (atomic weight of Mn = 55, Cl = 35.5, O = 16).

Q19. In an ore the only oxidisable material is Sn2+. This ore is titrated with a dichromate solution
containing 2.5g of K2Cr2O7 in 0.50L. A 0.40g of sample of the ore required 10cm3 of titrant to
reach equivalent point. Calculate the %age of Tin in ore. (K = 39, Cr = 52, Sn = 118.7)

Q20. 50ml of an aqueous solution of H2O2 was treated with an excess of KI solution and dilute H2SO4,
the liberated I2 required 20ml of 0.1N Na2S2O3 solution for complete interaction. Calculate conc.
of H2O2 in g/L.

Q21. 1.387g of KCl and NH4Cl is heated until constant weight is obtained. The solid residue is then
dissolved in water and a solution is made up to 250ml. 50ml of this solution requires 20ml of
decinormal AgNO3 solution. Calculate %age of KCl in the mixture.

Q22. 1.0g of a mixture of Anhydrous Na2CO3 and K2CO3 was made up to 250ml in aqueous solution.
25ml of this solution was neutralised by 20ml of HCl acid of unknown concentration. The normal
solution required 16.24ml of 0.1N AgNO3 for precipitation. Calculate :
(a) %age of K2CO3 in the mixture
(b) conc. of HCl in g/L

Q1. 10 L of hard water required 0.56 gm of lime (CaO) for removing hardness. Hence temporary
hardness in ppm of CaCO3 is:-
(A) 100 (B) 200 (C) 10 (D) 20
Q2. 2H2O2 (l)  2H2O (l) + O2(g)
100 ml of x molar H2O2 gives 3 L of O2 gas under the condition when 1 mol of O2 occupies 24 L,
values of x is:-
(A) 2.5 (B) 1.0 (C) 0.5 (D) 0.25

N
Q3. 10 mL of H2O2 solution (volume strength = x) required 10 mL of MnO4- solution in aicdic
0.56
medium. Hence, x is:-
(A) 0.56 (B) 5.6 (C) 0.1 (D) 10

Q4. 0.56g of limestone is dissolved in an acid solution and calcium precipitated as Calcium oxalate
CaC2O4. After filtering and washing the ppt., it requires 45ml of 0.04M KMnO 4 solution for
titration in acidic solution. Calculate %age of CaO in limestone (CaCO 3).

Q5. Cr2O72 in acid solution oxidises SnCl2 according to the reaction :

3Sn2+ + 14H+ + Cr2O72  3Sn4+ + 2Cr3+ + 7H2O
If SnCl2 is source of Sn2+, how many grams of SnCl2 would be contained in 2L of 0.1N solution
? If K2Cr2O7 is the source of Cr2O72, what is normality of the solution containing 4.9g of K2Cr2O7
on 0.1L of solution ? (atomic weight of Sn = 118.7, Molecular weight of K 2Cr2O7 = 294)

Q6. Cr2O72 ion in acid solution oxidises stannous ion (Sn 2+) according to reaction given below :
3Sn2+ + 14H+ + Cr2O72  3Sn4+ + 2Cr3+ + 7H2O
If SnCl2 is the source of Sn2+, how many grams of SnCl2 would be contained in 2.00L of 0.1N
solution ? If K2Cr2O7 is the source of Cr2O72, what is the normality of the solution containing
4.9g of K2Cr2O7 in 0.1L of solution ? (atomic weight of Sn = 118.7)

Q7. 25ml of a solution containing Ferrous and Ferric Sulphate acidified with H 2SO4 is reduced by 3g
of Zinc. The solution required 34.25ml of 1.015 N/10 solution of K 2Cr2O7 for oxidation. Before
reduction with Zinc, 25ml of same solution required 22.45ml of same K2Cr2O7 solution. Calculate
weights of FeSO4 and Fe2(SO4)3 per litre of solution.

Q8. 3.3504g of hydrated Na2CO3 were dissolved in 200ml of water. 50ml of the solution required
58.5ml of N/10 H2SO4 for neutralisation. Calculate number of molecules of water of crystallisation
in one molecule of hydrated salt. (atomic weight of Na = 23, C = 12, O = 16)

Q9. 1g sample of Manganese ore containing MnO 2, SiO2, 5% moisture was treated with 25ml of
approx. 1N oxalic acid and 25ml of 2N H2SO4 and was heated so that oxidation of oxalic acid to
CO2 was complete. Contents were cooled diluted to 250ml. 25ml of stock oxalic acid required
7.2ml of 0.1N KMnO4. When 25ml of stock oxalic acid was diluted to 250ml and 25ml were
titrated with same KMnO4 it required 24.8ml of 0.1N KMnO4. What is the %age of MnO2 in
sample. (atomic weight of Mn = 55, O = 16, C = 12)

Q10. 1.0g of a mixture consisting of equal number of moles of carbonate of two alkali metals required
44.4ml of 0.5N HCl acid for complete reaction. If atomic weight of one metal is 7.0, find atomic
weight of other metal. What will be total amount of sulphate formed on quantitative conversion
of 1.0g of mixture into sulphates ?

Q11. Hydroxyl amine (NH4OH) reduces Iron (III) according to equation :

2NH2OH + 4Fe3+  N2O(g) + H2O + Fe2+ + 4H+
Iron (II) thus produced is estimated by standard KMnO4 solution. The reaction is :
 MnO4 + 5Fe2+ + 8H+  Mn2+ + 5Fe3+ + 4H2O
A 10ml sample of NH2OH was diluted to 1L. 50ml of this diluted solution was boiled with an
excess of Iron (III) solution. The resulting solution required 12ml of 0.02M KMnO 4 for complete
oxidation of Iron (II). Calculate weight of hydroxyl amine in 1L of original solution.

Q12. 0.5g of Fuming H2SO4 (Oleum) is diluted with H2O. This solution is completely neutralised by
26.7ml of 0.4N NaOH. Find %age of free SO 3 in the sample solution.

Q13. 0.5g of a mixture of K2CO3 and Li2CO3 requires 30ml of a 0.25N HCl solution for neutralisation.
What is %age composition of mixture ? (atomic weight of Li = 7, K = 39, C = 12, O = 16)

Q14. When a mixture of NaBr and NaCl is digested with H2SO4 acid, all the halogens are expelled and
Na2SO4 is formed quantitatively. With a particular mixture it was found that weight of Na 2SO4
obtained was the same as the weight of NaCl and NaBr mixture taken. Calculate the ratio of NaCl
and NaBr in the mixture. (atomic weight of Na = 23, K = 39, Br = 80, Cl = 35.5, S = 32)

Q15. 12.5g sample of Arsenous oxide (As2O3) was dissolved in water containing 7.5g of NaHCO3 and
resulting solution diluted to 250ml. 25ml of this solution was completely oxidised by 22.4ml of a
solution of Iodine, 25ml of which reacted with 24.5ml of a solution of Sodium thiosulphate
(Na2S2O3 . 5H2O) containing 27.7g of this salt in Litre. Calculate %age of As2O3 in the sample.
(molecular weight of
As2O3 = 198)

Q16. 100ml of a dichromate solution containing 10g of K 2Cr2O7/L and 75ml of a Ferrous salt solution
containing 80g of FeSO4 . 7H2O/L are mixed in presence of excess of dil. H2SO4 and resulting
solution titrated with 0.2121N KMnO4 solution. What will be volume of KMnO4 solution required?

Q17. 356mg of an alloy of Zn and Cd is precipitated as ZnS and CdS by H 2S. The mixed precipitate is
dissolved in 5 millimoles of Ferric Sulphate, precipitating Sulphur. The filtrate is acidified and
divalent iron required 1.6 millimoles of KMnO4. Find %age of Cadmium in the sample. (atomic
weight of Cd = 112, Zn = 65.5, Iron = 56)

Q18. 6g of a mixture of (NH4)2SO4 and NH4Cl was made up to 1000ml with water. 25ml of this
solution was boiled with 50ml of N/10 NaOH until no more NH 3 was liberated and then it was
found that 24.3ml of N/10 HCl was required to neutralise excess of NaOH. Find %age of NH 4Cl
and (NH4)2SO4 in the mixture.