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Material II Assignment 3
Material II Assignment 3
Engineering Materials II
Assignment 3
Group members
Dawit wonduante………..ugr/3751/13
Mailaf tewodros…………..ugr/6268/13
Elias jemal……………………ugr/7443/13
Zerubabel tadiyos………..ugr/7066/13
2)
(a) to calculate the Ff /Fm ratio
3)
m = 2(AC) + 4(AF)
= (2)(12.01 g/mol) + (4)(19.00 g/mol) = 100.02 g/mol
4)
(a) Compute the densities of totally crystalline and totally amorphous polypropylene.
(b) Determine the density of a specimen having 74.6% crystallinity.
= 0.917 g/cm3
5)
to specify possible crystal structures for an AX type of ceramic material given its density
(2.10 g/cm3), that the unit cell has cubic symmetry with edge length of 0.57 nm, and the atomic weights of the A and
X elements (28.5 and 30.0 g/mol, respectively)
6)
(a) Under these conditions, name one crystalline defect that you would expect to form in order to maintain
charge neutrality.
For a Cu2+O2− compound in which a small fraction of the copper ions exist as Cu+, for each Cu+
formed there is one less positive charge introduced (or one more negative charge). In order to maintain charge
neutrality, we must either add an additional positive charge or subtract a negative charge. This may be
accomplished be either creating Cu2+ interstitials or O2− vacancies.
(b) How many Cu+ ions are required for the creation of each defect?
There will be two Cu+ ions required for each of these defects.
(c) How would you express the chemical formula for this nonstoichiometric material?
7)
For every Al3+ ion that substitutes for Mg2+ in MgO, a single positive charge is added. Thus, in order to
maintain charge neutrality, either a positive charge must be removed or a negative charge must be added.
Negative charges are added by creating O2− interstitials, which are not likely to form.
Positive charges may be removed by forming Mg2+ vacancies, and one magnesium vacancy would be
formed for every two Al3+ ions added.
8)