R EV I E W T E ST- 7

Class : XIII(XYZ & CC) PAPER-2

Time : 3 hour PAPER CODE : A Max. Marks : 210
INSTRUCTIONS
1. The question paper contain 24 pages and 3-parts. Part-B contains 6 questions of "Match the Column" type , Part-C
contains 17 and Part-D contains 2 questions. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and Pages. If you found some
mistake like missing questions or pages then contact immediately to the Invigilator.
PART-B
(i) Q.1 to Q.6 are "Match the Column" type which may have one or more than one matching options and carry 8 marks
for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match. Marks will be awarded only if all the
correct alternatives are selected.
PART-C
(ii) Q.1 to Q.17 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded only if all the correct
bubbles are filled in your OMR sheet.
PART-D
(iii) Q.1 to Q.2 are "Subjective" questions. There is NO NEGATIVE marking. Marks will be awarded only if all the correct
bubbles are filled in your OMR sheet.
2. Indicate the correct answer for each question by filling appropriate bubble(s) in your answer sheet.
3. Use only HB pencil for darkening the bubble(s).
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.

PART-B PART-C PART-D

For example if Correct match Ensure that all columns Ensure that all columns
for (A) is P, Q; for (B) is P, R; (4 before decimal and 2 after {1 before decimal and 2 after
for (C) is P and for (D) is S decimal) are filled. Answer decimal with proper sign (+)
then the correct method for having blank column will be or (–)} are filled and columns
filling the bubble is treated as incorrect. Insert after 'E' used for filling power
P Q R S leading zero(s) if required after of 10 with proper sign (+) or
(A) rounding the result to (–). Answer having blank
2 decimal places. column will be treated as
(B) e.g. 86 should be filled as incorrect.
0086.00 e.g. – 4.19 × 1027 should be
(C) . filled as – 4.19 E + 27
.
(D) .
.
.
.
.
.
.
.
USEFUL DATA: Atomic Mass: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31,
Ag = 108, N = 14, Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40,
Zn = 65.4, Ba = 137, Co = 59, Hg = 200, Pb = 207, He = 4, F=19.
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1.
Take g = 10 m/s2 where ever required.
 PART- B
MATCH THE COLUMN [6 × 8 = 48]
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match.
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.
Q.1 On a capacitor of capacitance C0 following steps are performed in the order as given in column I.
(a) Capacitor is charged by connecting it across a battery of EMF V0.
(b) Dielectric of dielectric constant k and thickness d is inserted
(c) Capacitor is disconnected from battery
(d) Separation between plates is doubled
Column I Column II
(Steps performed) Final value of Quantity (Symbols have usual meaning)
C 0 V0
(A) (a) (d) (c) (b) (P) Q=
2
kC 0 V0
(B) (d) (a) (c) (b) (Q) Q=
k 1
kC 0
(C) (b) (a) (c) (d) (R) C=
k 1
V0 (k  1)
(D) (a) (b) (d) (c) (S) V=
2k

ROUGH WORK
Q.2 Column I has some conductor accross which battery is connected as shown. Variation of resisitivity  is
also indicated. Which of the quantities in column II remain constant throughout the volume of conductor.
Column I Column II

(A) (P) Magnitude of electric field

(B) (Q) Magnitude of current density

(C) (R) Power dissipated per unit volume

(D) (S) Drift speed of free electron

ROUGH WORK
Q.3 Column I Column II
(A) (A) CH3–Cl do not give ppt. with aqueous AgNO3 (P) both (A) and (R) are true and (R)
but it gives ppt. with alcoholic AgNO3 is the correct explanation of (A)
(R) In water NO 3 is more solvated so it is less reactive (Q) both (A) and (R) are true but (R)
than alcoholic NO 3 . is not correct explanation of (A)
(B) (A) HCHO has sp2-hybridised carbon and the following (R) (A) is true but (R) is false

geometry: (S) (A) is false and (R) is true

(R) The bond angles are changed due to greater multiple

bond-single bond repulsion, then single bond- single
bond repulsion.
(C) (A) p-amino benzoic acid do not exists as zwittor ion
(R) Acidic and basic groups in this compound are too far from
each other to react, so they can't form salt.
(D) (A) The Friedel-Crafts alkylation of nitro-benzene gives meta
alkylated nitrobenzene
(R) Nitro group is meta directing during aromatic
electrophilic substitution as it decreases electron density
at o & p position

ROUGH WORK
Q.4 Column I Column II
(A) Precipitate with KCN, which is soluble (P) Fe2+
in excess of reagent.
(B) Precipitate with NaOH & NH4OH, (Q) Hg2+
which is insoluble in both excess of reagent
(C) Coloured ppt. with KI, which is soluble in (R) Pb2+
excess of reagent
(D) Black ppt. with H2S, which is soluble in (S) Ag+
hot & dil. HNO3

Q.5 Column-I Column-II

(A) The inhabitants of an island tell truth one third of the time. They lie (P) 1
with the probability of 2/3. On an occasion, after one of them made
a statement, another fellow stepped forward and declared the (Q) 2
p
statement true. If the probability that it was indeed true is (R) 3
q
where p and q are relatively prime then the value of (q – p) equals (S) 4
2
( 1)[ x ]
if x  0

(B) The function f (x) is defined as f (x) =  1
 Lim if x  0
n 1 xn
where [x] denotes the greatest integer function. Number of integral
values of x for which f (x) is continuous is
(C) Let ABCD be a square of side unity and P be a point on the circle
inscribed in it. The value of (PA)2 + (PB)2 + (PC)2 + (PD)2 equals
(D) Number of pair(s) (a, b) of positive integer is the solution of the
equation a2 – b2 = 105, is
ROUGH WORK
Q.6 Column-I Column-II
n
k
(A) Lim
n 
n  sin 2n is equal to (P) –1
k 1

(B) In a convex quadrilateral ABCD if cos A + cos C = 0 (Q) 0

tan B 1
then the value of equals (R)
tan D 2
(C) If n is an odd integer then (1 + i)6n + (1 – i)6n is equal to (S) 1
dx
(D) If  1 = ax + b x + c  x  1 dx
x 1  x x
then (a + b + c) equals

ROUGH WORK
 P A RT- C
SUBJECTIVE
There is NO NEGATIVE marking.

Q.1 Find the kinetic energy of pulse travelling in a taut string. Given T = 10 N &  = 0.1 kg/m. [Give answer
in millijoules]. [9]
Q.2 A sample of ideal gas is taken through the cyclic process shown in the
figure. The temperature of the gas at state A is TA=200 K. At states B
and C the temperature of the gas is the same.
What is the greatest temperature of the gas in kelvins during the cyclic process?
[9]
Q.3 Two objects of equal volume V=1m3 and different densities d1= 500 kg/m3 and
d2 = 1000 kg/m3 are glued to each other so that their contact surface is flat and
has an area A = 0.1 m2. When the objects are submerged in a certain liquid,
they float in stable equilibrium, the contact surface being parallel to the surface
of the liquid (see the diagram). How deep (H in meters) can the contact surface
be in the liquid so that the objects are not torn apart? The maximum force that
the glue can withstand is F=250 N. [9]
Q.4 An inclined plane is placed on a horizontal smooth surface. The plane is
struck by an elastic ball whose velocity is horizontal just before the impact.
The ball bounces off the inclined plane and then lands on it again at the
point of first impact. Find the ratio of the masses of the ball and the inclined
plane. (Angle  = 30°) [9]
Q.5 A radio receiver is set up on a mast in the middle of a calm lake to track the radio signal from a satellite
orbiting the earth. As the satellite rises above the horizon, the intensity of the signal varies periodically.
The intensity is at a maximum when the satellite is 1 = 0.01 radian above the horizon and then again at
2 = 0.03 radian above the horizon. What is the wavelength  (in meters) of the satellite signal? The
receiver is h = 4.0 m above the lake surface. [9]
Q.6 Initially switch S was closed for long time. Switch is opened at t = 0. Find the current (in amperes)
through battery at time RC ln2. Take V = 12 V, R = 4 ohm, C = 1.0 F. [9]
Q.7 Three ideal gases A, B & D were taken in a vessel of constant volume in molar ratio of 1 : 2 : 3
respectively causing the reaction : A (g) + 2B (g) l C (g). After a long time when the equilibrium (1st) is
5
established the total pressure was th of the initial total pressure. At this point volume was reduced to
6
half and a catalyst was added starting the reaction.
2C (g) + D(g) l 2 F (g).
If at equilibrium (2nd) moles of A & C are equal then find the ratio of equilibrium total pressure at 2nd
equilibrium to equilibrium total pressure at 1st equilibrium [9]
Q.8 There are two part of this question (a) & (b). If Answer question (a) is X and question (b) Y present
answer of this question as X + Y.

(a) CH2 = CH– O + CH2 = CH – CH2 – Br acetone
 (A) 
 
(B). Product (B)
Molecular weight of compound (B) is X.

(b) An alcohol (A) on treatment with conc. H2SO4 gave an alkene (B). The compound (B), on reacting with
Br2 water and subsequent dehydrobomination with NaNH2 produced a compound (C). The compound
(C) with dil. H2SO4 in presence of HgSO4 gave a compound 'D'. The compound D can also be obtained
by oxidation of A by acidified KMnO4 or from dry heating of calcium acetate. Calculate molecular
weight of 'C' (Y).
Find the value of X + Y. [9]
Q.9 An inorganic compound (A) reacts with water to form two acids (B) and (C). Compound (A) also
reacts with NaOH to form (D) and (E) two salt solutions. (B) and (D) gives yellow ppt with BaCl2
solution and (C) and (E) gives white ppt, insoluble in dil HNO3, with AgNO3 solution. Calculate the
molecular weight of compound (A). [5]

Q.10

(a) Gas (C) is passed through water first and then gas (D) is passed, white turbidity is obtained.
(b) The aq. solution of compound (B) + (NH4)2SO4 cool
 pale green crystalline solid, calculate the
molecular mass of pale green compound. [4]
Q.11 The reaction
CH 4 (g) + 2O2 (g) l CO2 (g) + 2H2O (g) ...(1)
comes to equilibrium at 2.7 × 105 K under standard state condition. Assuming H° and S° to be
independent of temperature and using given data, find maximum electrical work obtained from reaction
(2) (in kJ/mol).
CH4 (g) + 2O2 (g) l CO2 (g) + 2H2O (l) ...(2)
at 300 K.
Given : H ocombustion (CH4(g)) = –890 kJ/mole at 300 K
H ovap. (H2O (l) ) = 40 kJ/mole at 300 K
Sovap. (H2O (l) ) = 118.5 J/Kmole at 300 K [9]
 x3 if x  1

Q.12 Suppose f (x) =  . If f '' (1) exist then find the value of a2 + b2 + c2. [9]
 ax 2  bx  c if x  1
Q.13 An equilateral triangle is inscribed in an ellipse whose equation is x2 + 4y2 = 4. One vertex of the triangle
m
is (0, 1), one altitude is contained in the y-axis, and the length of each side is , where m and n are
n
relatively prime positive integers. Find the value of (m + n). [9]
Q.14 A circle of radius t is tangent to the hypotenuse, the incircle, and one leg of an isosceles right triangle with
 a a
inradius r = 1 + sin . If the value of r t = where a is a surd find (a2 + b2). [9]
8 b
 tan 3x
Q.15 Find the sum of the local maximum and local minimum values of the function f (x) = on interval
tan 3 x
0,  2 . [9]
Q.16 Let f (x) = x3 + 3x2 – 6x + 11 and g (x) = ln | x |.
1 t2
d
If A = f  g ' (1)  ; B = g  f ' ( 1)  ; C =  f ' ( x ) · g '  f ( x )  dx ; D =  g ( x) dx evaluated at t = 3
2
dt 1
and A(B + C) – D = ln K, find the value of K. [9]
Q.17 Three biased coins C1, C2 and C3 lie on a table. Their respective probabilities of falling heads when
tossed once are 1/3, 2/3 and 1. A coin is picked up randomly, tossed twice and observed to fall heads
on both the ocassions.
Now given that a coin has been tossed twice and observed to fall heads both times. If the probability that
a
a 3rd throw of the same coin will also produce heads is where a and b are relatively prime, find the
b
value of (a2 + b2). [9]
 PART-D

Q.1 500 ml of 0.01 AgNO3 is mixed with 250 ml each of NaBr and NaCl, each having molarity 0.02 M
each. Find equilibrium concentration of Br– (moles/L).
Given: KSP (AgBr) = 5 × 10–13; KSP (AgCl) = 10–10 [9]
Q.2 Two beakers A and B contains AgNO3 solutions of concentrations 0.1 M and 0.01 M respectively as
shown in figures. Pure silver electrodes are now lowered in each beaker. Now NH3 is added in each
beaker till conc. of NH3 in beaker A and B become 0.1 M and 0.2 M respectively. If two beakers are
now connected in Galvanic cell arrangement, find the EMF (in Volts) of the resulting cell at 298 K.
RT
[Use log102 = 0.3, (2.303) = 0.06 at 298 K]
F

Given: E º  = 0.8 Volt , k f [Ag( NH3 ) 2 ] = 108 [9]
Ag / Ag