XI (J-BATCH) CHEMISTRY REVIEW TEST-4

Select the correct alternative. (Only one is correct) [15 × 3 = 45]

There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.16 A closed container having fixed mass of an ideal gas is heated from initial temperature of 300 K
to final temperature of 1200 K. Which of the options must be true? [All symbols have their usual meaining]
(A) Z1 will become four times the original value.
(B*) Z1 & Z11 increases by same factor.
(C)  decreases
(D) Density of the gas in the container decreases.
p P
[Sol: Z1 = 2 2uavg N * N* = N* 
KT T
P 8 RT
Z1 = T uavg =
T M
P
Z1  uavg  T v  const
T
T
Z1   T P  T By gay lussac’s law
T
1
Z11 = ps2uavg(N*)2
2

P2
Z11  T × P  T
T2

Z11  T T 2

Z11  T T 2

1
=
2 2 N *
T
  T  P
P
  (constant) ]

Q.17 A large number of oil drop samples in Milikan’s oil drop experiment gave the following values of charges
q = 2×10–19 coulomb, 3×10–18 coulomb, 4 ×10–19 coulomb, 5 ×10–18 coulomb & no other values.
What could be concluded as the charge of e– from above information.
(A) 2 × 10–18 coulomb (B*) 2 × 10–19 coulomb
(C) 1 × 10–19 coulomb (D) 5 × 10–20 coulomb
[Sol: (B) q = 2 × 10 , 3 × 10 , 4 × 10 & 5 × 10–18 coulombs. So the highest common factor
–19 –8 –19

= 2 × 10–19 ]

Q.18 Certain amount of phosphorus (P4) was made to react with certain amount of oxygen to give a mixture
of P4O6 & P4O10 in the molar ratio of 2 : 1 (P4O6 : P4O10). If none of the reactants remained after
the reaction(s) then what was the ratio of mass of P4 : O2 taken initially.
(A*) 93 : 88 (B) 88 : 93 (C) 3 : 11 (D) 11 : 3
[Sol: (A)
 P4  3O2  P4O6
a 3a a

P4  5O2  P4O10
b 5b b

a 2
here 
b 1
 moles of P4 reacted = a + b
& moles of O2 reacted = 3a + 5b
(a  b)124 3 124 93
 mass ratio of P4 : O2 = = = ]
3a  5b 32 11 32 88

Q.19 For a closed (not rigid) container containing n = 10 moles of an ideal gas, fitted with movable, frictionless,
weightless piston operating such that pressure of gas remains constant at 0.821 atm, which graph
represents correct variation of log V vs log T where V is in lit. & T in Kelvin.

(A*) (B) (C) (D)

[Sol: (A) PV = nRT

 nR 
V =   T
 p 
 10  0.0821 
 V=  T = T
 0.821 
log V = log T

so the curve is ]

Q.20 Calculate total maximum mass (kg) which can be lifted by 10 identical balloon (each having volume
82.1 lit. and mass of balloon & gas = 3 kg) at a height 83.14 m at Mars where g = 5 m/s2 &
atmosphere contains only Ar (At. wt.40). At Mars temperature is 10 K and density of atmosphere
2
at ground level is k gm/lit. [Given : e–0.1 = 0.9] (Assume dH = d0 e Mgh RT to be applicable).
0.821
(A*) 2000 × 0.81–30 (B) 1970 (C) 2000 × 0.9 –30 (D) 2000 × 0.81 – 3
Mgh

[Sol: (A) d = d0 e RT

4010 3 5  83.14
2 
8.31410
e
d = 0.821
2 2
= 0.821 e–0.2 =  ( 0 .9 ) 2
0.821
 Now at height h = 83.14 m
V × d = mass of balloons  mass of gas filled  mass of load
               

82.110
  (0.9) 2 = (3 × 10) + m
0.821
 m = (2000 × 0.81) – 30 Kg ]

Q.21 Following are the nuclear reactions in which both neutrons as well as protons on both sides are conserved.
From this identify the correct options.
A  B + 4
2 He
B  C + 4 10 n
(A*) A & B are isodiaphers
(B) B & C are isotones
(C) A & C are isotopes
(D) If B & A are neutral then B+3 is isoelectronic with A.
[Sol: A  B + 4
2 He
B  C + 4 10 n
Let atomic no. of A = Z
& mass no. of A = M
Z A M  Z 2 B M 4  2
He 4
n=M–Z n =(M – 4) – (Z – 2) = M – Z – 2
p=Z p=Z–2
n – p = M – 2Z n – p = (M – Z – 2) – (Z – 2)
= M – 2Z
so A & B are isodiaphers
M 4
 Z  2 C M 8  4 O n
1

Z 2 B
n=M–4–Z+2 n = M – 8– Z + 2
=M–Z–2 =M–Z–6
Atomic no of A = Z
Atomic no. of C = Z – 2 so these are not isotopes
Total no. of electrons in B+3 = Z –2–3 = Z–5
total no. of electrons in A = Z not isoelectronic ]

Q.22 40 miligram diatomic volatile substance (X2) is converted to vapour that displaced 4.926 ml of air
at 1 atm & 300 K. Atomic weight of element X is
(A) 400 (B) 40 (C) 200 (D*) 100
[Sol: (D) PV = nRT
40  10 3
1 × 4.92 × 10–3 = × 0.0821 × 300
M
M = 200
200
 Atomic mass of A = = 100 ]
2
Q.23 Electromagnetic radiations having  = 310.5 Å are subjected to a metal sheet having work
function = 12.7 eV. What will be the velocity of photoelectrons with maximum Kinetic Energy..
(A) 0, no emission will occur (B) 2.18 × 106 m/sec
(C) 3.1 × 107 m/sec (D*) 3.1 × 106 m/sec
[Sol: (D)
1242
(KE)max = – 12.7 = 27.3 eV
31.05
 ½ mv2 = 27.3 × 1.6 × 0–19

27.3 1.6 1019  2

 v=
9.11031
 v = 3.1 × 106 m/sec. ]

Q.24 An U tube containing ideal gas closed at both ends having infinite long columns consists of mercury
having initial height difference of 76 cm as shown. Both left column & right column have a hole
from which gas is coming out according to rate law as given. [Assume outside the U-tube to be a
perfect vaccum at all the instant] Given: ln2 = 0.693
dP
Left Column = –K1P ; K1 = 0.693 × 10–2 sec–1
dt
dP
Right Column = –K2P ; K2 = 1.386 × 10–2 sec–1
dt
where P = Pressure in the respective column
If at t = 0 pressure in Left Column = 1atm then what will be the height difference in the two levels
after 200 sec.
(A*) 0 (B) 76 (C) 38 (D) 19
[Sol: (A)
At t = 0, pressure in left column = 1 atm = 76 cm of Hg
 pressure in right column = 76 + 76 = 152 cm of Hg

In left column In the right column

P t P t
dP dP
P = –K1  dt  P = –  K 2 dt
P0 0 P0 0

P P
 ln P = –K1 × t  ln P = –K2 × t
0 0

P P
ln = –0.693 ×10–2 × 200 ln = –1.386 × 10–2 × 200
76 152
P 152
ln = 0.693 × 2 ln = 1.386 × 2
76 P
76 152
 ln = 2 × 0.693 = 2 ln2 = 4ln 2 = ln24
P P
76 152
 = 22  P=
P 16
 76
P= = 19 cm P = 9.5 cm of Hg
4
Thus before 200 sec, pressure in both columns become equal so height difference in the two columns
are equal. ]

Q.25 A very long rectangular box is divided into n equal compartments with
(n–1) fixed SPM (semi permeable membrane) numbered from 1 to
(n–1) [n is unknown] as shown. The gases are initially present in only
I compartment & can pass through only those SPM whose number
is less than or equal to their subscript (like A1 can pass through 1st
SPM only, A2 through 1st & 2nd & so on).
If initially all gases have same moles & after substantial time ratio of
PA in 3rd compartment to PA in 1st compartment is 5 then what
6 n 1

would be the value of n (where PA 6 & PA represents partial pressure of A6 & A n 1 respectively)
n 1

is
(A) 10 (B) 15 (C*) 35 (D) 30
[Sol: (C)
Let initially moles of A6 & An – 1 = x
x
finally moles of A6 =
7
x
& moles of An – 1 =
n
PA6 x/7
 PAn1 = =5
x/n
n = 35 ]

Q.26 A mixture of CH4 (15 ml), CO (10 ml) is mixed with just sufficient O2 gas in an eudiometry tube(operating
at 1 atm & 500 K) is subjected to sparking and then cooled back to the original temperature of 500K.
If Vc1 be volume contraction due to the above process and V c2 be the contraction after passing the
resultant gas(es) through CaCl2 (anhydrous), then Vc1,Vc2 will be
(A) 30, 0 (B) 30, 30 (C*) 5, 30 (D) 5, 0
[Sol: (C)
CH4(g) + 2O2(g)  CO2(g) + 2H2O(g)
15 30 15 30

CO(g) + ½ O2(g)  CO2(g)

10 5 10

 VC1 = [(15 + 10) + (35)] – [30 + 15+10] = 5ml

& VC2 = 30 ml ]
Q.27 If in Bohr’s model, for unielectronic atom, time period of revolution is represented as Tn,z where n
represents shell no. and Z represents atomic number then the value of T1,2 : T2,1 will be
(A) 8 : 1 (B) 1 : 8 (C) 1 : 1 (D*) None of these
n3
[Sol: (D) Tn, z 
z2
13 23
T1, 2  & T2, 1 
22 12
T1, 2 1 1 1
 =   ]
T2,1 4 8 32

Q.28 Assuming Heisenberg Uncertainity Principle to be true what could be the minimum uncertainty in de-broglie
wavelength of a moving electron accelerated by Potential Difference of 6 V whose uncertainty in position
7
is n.m.
22
(A) 6.29 Å (B) 6 Å (C*) 0.629 Å (D) 0.3125 Å
h
[Sol: p=

h
p = 
2
h
So x × p =
4
h h
 x ×  =

2
4

2 h2 1
  = = ×
4x 2mev 4x

6.63 10   22
39 2
=

2 9.1 10 31 1.6 10 4  22  7 10 
19 9

= 6.29 × 10–11 m = 0.629 Å. ]

Questions No. 29 to 30 (2 questions)

Read the following comprehension and answer the question that follow.
One of the concerns of various chemists is of selecting an appropriate equation of state which can
relate the four parameters (P, V, T and n) & give results close to experimental values at critical conditions.
Although Vander Waal equation is easy to use, the experimental value of 'Z' (compressibility factor)
at critical condition does not match with the predicted value [Experimental :  0.27, Predicted (Vander
Waal)  0.375] For this reason, another equation of state is being used known as
 RT  a V RT
P =  V  b  e
m
Dieterici Equation
 m 
 where a, b are dieterici constant, Vm = Molar volume, P = Pressure & T = Temperature
which gives better results at Critical Condition. ( ZCritical Condition = 2/e2).

 dP   d 2P 
 
Also at Critical condition   =0&  dV 2  = 0.
 dV  T  T
If PC, VC, TC are critical pressure, volume & temperature and
VC & TC are related as 2a × (VC–b)2 = VC3 RTC .

Q.29 PC, VC, TC in terms of dieterici constant will be respectively

a a a 8a a a a a
(A*) , 2 b, (B) 2
, 3b , (C) , 3b , (D) 2 2 , 2b ,
2 2
4b e 4bR 27 b 27 Rb 2
4b e 2
4bR b e 4bR

V T P
Q.30 If Vr = V (reduced volume), Tr = T (reduced temperature) & Pr = P (reduced pressure) then
C C C
which of the following represents reduced equation of state for dieterici equation.
[All equation dimensionally correct]
 2  2
  2
VT  1  e Tr e 2Tr
(A*) Pr e r r  V
 r  = (B) Pr e Vr Tr
(Vr  b) 
 2 2 2
2a 2 2 2
Vr Tr  1  e Tr Vr Tr  1  e Tr TC
(C) Pr e  r
V    (D) Pr e  r
V   
 2 2  2 2

PCVC 2 2 RTC
[Sol: ZC = RT = 2  PC = V e 2 ..........(1)
C e C
2 3
Now 2a(VC – b) = VC RTC ...........(2)
a
If we put VC = 2b & TC =
4bR
then from (2)
Ra
2a(2b – b)2 = (2b)3
4bR
8b 3a
 2a × b2 =
4b
 2ab2 = 2ab2
And from (1)
2R a a
PC = 2 =
4bR 2be 4b 2e 2
a a
29. PC = 2 2 , VC = 2b, TC =
4b e 4bR
RT RTr TC
30. P = V  b  e  a / Vn RT  PrPC = e a / VrVC RTrTC 
m VrVC  b
  a 
Pr a RTr a  a /  2bVr RTr 
 4bR 
 e
4b 2e 2 4bR 2Vr b  b 

Pr Tr
 = 2Vr  1 e 2 / VrTr
e2
 2 
 V T 
 r r
 Pr = e (2Vr – 1) = e2Tr
 2 
 
 VrTr  e 2Tr
 Pr = e (Vr – ½) = ]
2

Select the correct alternative. (One or more than one is/are correct) [3 × 5 = 15]

Q.4 Following represents the Maxwell distribution curve for an ideal gas at two temperatures T 1 & T2.
3/2
dN  M   Mv 2 
Which of the following option(s) are true? [Given : N = 4π 2ππR  v exp 
2 dv ]

   2RT 

(A*) Total area under the two curves is independent of moles of gas
(B*) If dU1= a Umps1 & dU2 = a Umps2 then A1 = A2 (where a is a constant)
(C) Here T1 > T2 and hence higher the temperature, sharper the curve.
(D*) The fraction of molecules having speed = Umps decreases as temperature increases.
1 dN dN
[Sol: Differential area under the curve =du 
N du N
So total area = 1 (independent of moles)
(B) At T = T1
3/ 2
 dN   M 
aUmp s 
 
aUmps 
2
M aU mps1
A1 =   = 4   2
– 
 2RT1 
2RT1
 N 1 1 e 1

3/ 2 3/ 2
 M 
1
A1 = 4      
a 3 U mp s1 3 e  a
2

   2 RT1

3/ 2 3/ 2
4 3 a 2  M   2 RT1 
A1 = ae    
  2 RT1   M 
4 2

A1 = a3ea

 Now at T = T2
3/ 2
 dN   M 
aUmps 
2

aUmps 
 MaUmps2 
A2 =   = 4   2  
 2RT2 
 N 2  2 RT2 
2
e 2

4 2

A2 = a 3e  a

 A1 = A2
(C) T1 < T2
(D) The fraction of molecules having speed = Umps decreases as temperature increases.]

Q.5 In the following six electronic configuration (remaining inner orbitals are completely filled). Mark the
correct option(s).

C–I C–II

C–III C–IV

C–V C–VI
(A*) Stability order : C–II > C–I & C–IV > C–III
(B*) Order of spin multiplicity : C–IV > C–III = C–I > C–II
(C*) C–V violates all the three rules of electronic configuration
(D) If C–VI represents A then A2+ when kept near a magnet faces weak repulsions (acts as dimagnetic).
[Sol: (A), (B), (C)
(A) C – II is more stable than C–I since C–I is excited state of C – II
C–IV is more stable than C–III due to high spin multiplicity
(B) spin multiplicity in C–IV = 7 spin multiplicity in C–III = 5
spin mjultiplicity in C–I = 5 spin multiplicity in C–II = 3
so C–IV > C–III = C–I > C–II
(C) C–V violates all the three rules of electronic configuration i.e. Hund’s rule, Pauli’e exclusion principle
& Aufbau rule.
(D) C–IV is A then configuration of A 2+ is so it is highly paramagnetic. ]

Q.6 A sample of H2O2 solution labelled as 33.6 volume has density of 264 gm/lit. Mark the correct option(s)
representing concentration of same solution in other units.[Solution contains only H 2O & H2O2]
(A*) Mole fraction of H2O2 in the solution = 0.25
(B) % w/v = 102%
(C) M H 2O 2 = 6 M
1000
(D*) m H 2O 2 = m
54
[Sol: (A, D)
33.6
Molarity = = 3M
11.2
Consider 1 litre solution
wH 2O2 + wH 2O = 264 gm
moles of H2O2 = 3
  wH 2O2 = 3 × 34 102 gm
& wH 2O = 264 – 102 = 162 gm
162
 n H 2O = =9
18
3
(A) mole fraction of H2O2 = = 0.25
39
102
(B) % w/v =  100 = 10.2 %
1000
(C) M H 2O2 = 3M
3 1000 1000
(D) mH 2O2 =  m ]
162 54
MATCH THE COLUMN [2 × 8 = 16]
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One entry of column-I may have one or more than one matching with entries of
column-II.
Q.3 Match the following quantum numbers in Column I with respective atomic orbitals in Column II (Type
of orbital)
Column I Column II (Type of orbital)
(A) n = 3, l = 2 (P) 3dyz
(B) l=2 (Q) 4d xy
(C) m = –1 (R) 5px
(D) m = –2 (S) 6 d x2  y 2
[Ans. (A) P, (B) P,Q,S, (C) P, R (D) Q, S]

Q.4 If in Bohr’s model, for unielectronic atom following symbols are used
rn,z  Radius of nth orbit with atomic number z ;
Un,zPotential energy ; Kn,zKinetic energy of e– ;
Vn,zVelocity ; Tn,zTime period of revolution
Column I Column II
(A) U1,2 : K1,1 (P) 1 : 8
(B) r1,2 : r2,1 (Q) –8:1
(C) V1,3 : V3,1 (R) 9:1
(D) T1,2 : T2,1 (S) None of these
[Ans. (A) Q, (B) P, (C) R, (D) S ]

Ze 2 1 Ze 2
[Sol: (A) U =  K=
r 2 r

 Ze 2 Z 1  Ze 2 Z
= K=
n2 2 n2
 Z2 1 Z2
U K=
n2 2 n2

22 1 12
U12 =  K11 =
12 2 12
U 12 4 2
K11 =   = –8:1
1 1

n2 4
(B) r  r21 =
Z 1
1
r12 =
2
1 1
r1, 2 : r2, 1 =  =1: 8
2 4

Z
(C) V
n
3 3 3
V13  V13 : V31 =  = 9:1
1 1 1
1
V3, 1 
3
2r n2 n n3
(D) T= T · T 
V 2 z z2
13 1 1 1
T12 =  T1, 2 : T2, 1 =  1 : 32
22 4 4 8

23 8
T2, 1 =  ]
12 1