REVIEW TEST-5

C
H E
M I
STR
Y
Class : XI
Time : 100 min Max. Marks : 100
INSTRUCTIONS
General Remarks:
1. The question paper contain 20 questions and 24 pages. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
2. Each question should be done only in the space provided for it, otherwise the solution will not be
checked.
3. Use of Calculator, Log table and Mobile is not permitted.
4. Legibility and clarity in answering the question will be appreciated.
5. Put a cross ( × ) on the rough work done by you.
6. Last two pages are Extra pages. You may use them for any unfinished question(s) mentioning the page
number with remark "continued on page........"

Name ________________________________ Father's Name ____________________________

Class : __________ Batch : B.C. Roll No. ___________

Invigilator's Full Name __________________________________________________

USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Pt = 195,
Useful constant : h = 6.62 × 10–34 J sec.

For Office Use ……………………………. Total Marks Obtained…………………

Q.No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Marks
Q.1
(a) The first ionisation energy of Mg is higher than that of Na, but on the other hand the second ionisation
energy of Na is very much higher than that of Mg. Explain (limit your explanation within 40 words).
[2]
(b) Select the one having lower first ionisation energy in each given pair with explanation (limit your explanation
within 20 words)
(i) I and I– (ii) Ba and Sr (iii) Be and B [3]
Q.2
(a) Arrange the following in
(i) order of increasing IE1 Mg, F, Na, Al
(ii) order of decreasing EA1 Na, Be, B, K
(b) The hot glowing gases around the Sun, the corona, can reach millions of degrees Celsius, high enough to
remove many electrons from gaseous atoms. Iron ions with charges as high as 14+ have been observed
in the corona. Which ions from Fe+ to Fe14+ are paramagnetic? [1.5+1.5+2]
Q.3 With the help of EN values [ENH = 2.1, ENO = 3.5, ENA = 1.8, ENB = 2.6, ENC = 1.6, END = 2.8]
answer the following questions for the compounds
HOA, HOB, HOC, HOD
(a) Compounds whose aqueous solution is acidic and order of their acidic strength [2.5]
(b) Compounds whose aqueous solution is basic and order of their basic strength [2.5]
Q.4 Give increasing order of following specified in brackets
(a) CH4, SiH4, GeH4, SnH4 (Acidity)
(b) HOCl, HClO2, HClO3, HClO4 (Acidity)
(c) Li2O, Na2O, K2O, Cs2O (Basic nature)
(d) HF, HCl, HBr, HI (Stability)
(e) Na+, Mg2+, Al3+, K+ (Oxidising Nature) [1+1+1+1+1]

Q.5 A compound of iron & chlorine is soluble in H2O. An excess of silver nitrate was added to precipitate the
Cl– ion as AgCl. If a 10 gm of the compound gave 22.6 gm of AgCl. What is the formula of the compound.
[5]
Q.6 Ionisation energies of five elements A, B, C, D & E are listed below:
Atom IE1 IE2 IE3(kJ/mol)
A 300 550 920
B 100 735 1100
C 118 1090 1650
D 176 350 1850
E 500 950 1500
Two elements are non-metals and three are metals. One of the elements is a noble gas. Identify
(a) The noble gas
(b) The reactive non-metal
(c) The most reactive metal
(d) The atom which exhibits a common oxidation state of +2.
(e) The atom(s) which exhibit a common oxidation state of +1 [1+1+1+1+1]
Q.7 Using Slater's rues, calculate Z* for the following electrons:
(a) a 3p electron in P (b) a 4s electron in Co (c) a 3d electron in Mn (d) a valence electron in Mg
(e) last electron of K [1+1+1+1+1]
Q.8 Write all the possible orbitals in each case (upto n = 3) which fulfill following condition [5]
Case – I  having only one radial node
Case – II  having XY plane as angular node
Case – III  having only two maxima if a curve is plotted between radial distribution function
vs radial distance
Case – IV  both case – I and case – II are fulfilled
Q.9 Explain the following
(a) The valence shell electronic configuration of both Ca & Zn is 4s 2 . Explain why first ionization
energy of Ca is lower than that of Zn.
(b) EA value of Cl is higher than that of F although the electronegativity value of these elements is in the
reverse order.
(c) Predict the sign of H for each of the following reactions
(i) Li(g) + Na–(g)  Li–(g) + Na(g) (ii) Na+(g) + K(g)  Na(g) + K+(g)
[1.5+1.5+2]
Q.10 Electron present in hydrogen atom jumps from energy level 3 to 1. Emitted photons when passed through
a sample containing excited He+ ion causes further excitation to some higher energy level. Determine
Z2
principal quantum number of initial excited level & higher energy level of He+. (Given En = –13.6 )
n2
[5]
Q.11 The maximum amount of energy which can be obtained by a mixing 30 gm of carbon with 48 gm oxygen
will be?
Given:– C(s) + O2  CO2 H = – 80 kJ/mol
1
C(s) + O  CO H = – 50 kJ/mol [5]
2 2
Q.12 Find the number of diffusion steps required to separate the isotopic mixture initially containing some
amount of H2 gas and 1 mol of D2 gas in a container of 3 lit capacity maintained at 24.6 atm & 27 °C
 wD 
 2  1
to the final mass ratio  w  equal to 4 . [R = 0.082 lit-atm/mol/K] [5]
 H2 
Q.13 Two containers of equal volume containing equal masses of gas A (MA = 32) & gas B (MB = 16)
separately are maintained at temperature T & 2T respectively. (A = 2B)
Find
(a) ratio of total translational K.E. of gas A & gas B.
(b) ratio of the mean free path of gas A & gas B
(c) ratio of the collision frequency of gas A & gas B [1.5+1.5+2]
Q.14 A balloon containing 1 mole air at 1 atm initially is filled further with air till pressure increases to 3 atm.
The initial diameter of the balloon is 1 m and the pressure at each state is proportion to diameter of the
balloon. Calculate
(a) No. of moles of air added to change the pressure from 1 atm to 3 atm.
(b) balloon will burst if pressure increases to 7 atm. Calculate the number of moles of air that must be added
after initial condition to burst the balloon. [2+3]
Q.15 Fluorides of the relatively unreactive noble gas Xenon can be formed by direct reaction of the elements
at high pressure and temperature. Depending on the temperature and reactant amounts, the product
mixture may include XeF2, XeF4 & XeF6. Under the conditions that produce only XeF4 & XeF6,
2 mole of Xe reacted with 5 mole of F2, and 0.2 mol of Xe was found to be in excess. What are the mass
percent of XeF4 and XeF6 in the product mixture. (Xe = 132, F = 19). [5]
Q.16 1 mole of CCl4 vapours at 27°C occupies a volume of 40 lit. If vander Waals constant are a = 24.6 L2
atm mol–1 and b = 0.125 Lmol–1. Calculate compressibility factor under
(a) Low pressure region
(b) High Pressure region
[Take R = 0.082 lit-atm/mol/K] [2.5+2.5]
Q.17 NO2 partially converts into NO, O2 and N2O4 according to following reaction.

1
NO(g)  O 2 (g)
2
NO2(g)
1
N 2O 4 (g)
2
Pressure increases from 5 atm to 5.25 atm due to above reactions at constant temperature and the ratio
of number of moles of O2 & N2O4 becomes 3/2. Calculate the final partial pressure of each gas in the
final state. [5]
Q.18 A 500 ml solution was prepared by dissolving 28.5 gm of MgCl2 in water. If the density of MgCl2
solution is 1.2 gm/ml, calculate
(a) Molarity of Cl– ion
(b) Mole fraction of Mg2+ ion
(c) Concentration in ppm of Mg2+ ion [1.5+1.5+2]
Q.19 Photon having wavelength 12.42 nm was allowed to strike a metal plate having work function 25 eV.
Calculate the
(a) Maximum kinetic energy of photoelectrons emitted in eV.
(b) Wavelength of electron with maximum kinetic energy in Å.
(c) Calculate the uncertainity in wavelength of emitted electron if the uncertainity in the momentum is
6.62 × 10–28 Kg m/sec. (h = 6.62 × 10–34 J-sec) [1.5+1.5+2]
Q.20(a) A 40 ml sample of a mixture of H2 & O2 was placed in a gas burette at 27 °C and 1 atm pressure. A
spark was applied so that the formation of water was complete. The remaining pure gas that diffuses
faster than N2 gas under similar condition had a volume of 10 ml at same temperature and pressure as
given initially.What was the initial mole percent of H2 in the mixture? [2]
Q.20(b) Air is pumped into the tubes of a bicycle at a pressure of 2 atm. The volume of each tube at this pressure
is 2 lit. One of the tube get punctured and the volume of the tube reduces to 0.5 lit. Assuming temperature
to be constant at 300 K and air behaving as an ideal gas, calculate the fraction of moles of air leaked out?
[Take Atmospheric Pressure = 1 atm, R = 0.082 lit-atm/mol/K] [3]
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