REVIEW TEST-7/6

CHEMISTRY
Class : XI (P,Q,R,S & J)
PAPER CODE : A
Time : 2 hour Max. Marks : 130
INSTRUCTIONS
1. The question paper contains 12 pages and 3-parts. Part-A contains 20 objective questions, Part-B contains
3 "Match the Column" questions and Part-C contains 4 "Subjective" questions. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and Pages. If
you found some mistake like missing questions or pages then contact immediately to the Invigilator.
PART-A
(i) Q.1 to Q.15 have only one correct alternative and carry 3 marks each.
There is NEGATIVE marking and 1 mark will be deducted for each wrong answer.
(ii) Q.16 to Q.20 have one or more than one correct alternative(s) and carry 5 marks each.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.
PART-B
(iii) Q.1 to Q.3 are "Match the Column" type which may have one or more than one matching options and
carry 8 marks for each question. 2 marks will be awarded for each correct match within a question.
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match. Marks will be awarded
only if all the correct alternative(s) is/are selected.
PART-C
(iv) Q.1 to Q.4 are "Subjective" questions and carry 9 marks each. There is NO NEGATIVE marking.
Marks will be awarded only if all the correct bubbles are filled in your OMR answer sheet.
2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.
3. Use only HB pencil for darkening the bubble.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answer(s) of the questions must be marked by shading the circles against the question by dark HB pencil only.

PART-A PART-B PART-C

For example if only 'B' choice is For example if correct match for Ensure that all columns
correct then, the correct method for (A) is P, Q; for (B) is P, R; (4 before decimal and 2 after decimal) are
filling the bubble is for (C) is P and for (D) is S then the filled. Answer having blank column will
A B C D correct method for filling the bubbles is be treated as incorrect. Insert leading
P Q R S zero(s) if required after rounding the
(A) result to 2 decimal places.
For example if only 'B & D' choices e.g. 86 should be filled as 0086.00
are correct then, the correct method (B) .
for filling the bubbles is .
A B C D (C) .
.
(D)
The answer of the question in any .
other manner (such as putting , .
.
cross , or partial shading etc.)
will be treated as wrong. .
.
.
 USEFUL DATA
Atomic weights: Al = 27, Cl = 35.5, O = 16, H = 1, N = 14, S = 32, Na = 23, C = 12, Br = 80, Fe = 56,
Atomic No. H = 1, O = 8; P = 15,
Useful constant : h = 6.626 × 10–34 Js; mass of electron = 9.1 × 10–31 Kg; R = 0.082 lt-atm/mol–K
PART-A
Select the correct alternative. (Only one is correct) [15 × 3 = 45]
There is NEGATIVE marking and 1 mark will be deducted for each wrong answer.
Q.1 Choose the only incorrect statement
(A*) K.E of photo electron does not depend upon wavelength of incident radiation and its value ranges
from zero to KEmax
(B) Photoelectric current depends on intensity of incident radiation and not on frequency whereas stopping
potential depends on frequency of radiation & not on intensity.
(C) If the accelerating potential V eV is applied on photo electron in discharge tube, then the value of KE
of photo electrons vary from V eV to (a–b+V) eV where a & b are energy of incident radiation and
work function in eV respectively with a > b.
(D) None of these
hc
[Sol: (A) KEmax = – E0 & KEmin = 0

q Ne
(B) i = 
t t
so current depends on no. of photoelectrons emitted which in turn depends on intensity of incident
radiation.
h
V0 = – E0
e
(C) KEmin = (eV)J = (V) eV; KEmax = KEmin + E – E0 = [(a–b) + V] eV
ans: is (A) ]

Q.2 Statement 1: If the number of -particles observed in Rutherford experiment are 150 at 90° then the
number of particles scattered under similar experimental conditions at 120° are approx 67.
Statement 2 : Ionisation energy of deuterium atom is slightly lesser than that of hydrogen atom.
Statement 3 : The difference in potential energy always remain same between any two electronic shell
in hydrogen atom irrespective of any reference value of potential energy assigned to n = .
Select the correct statement.
(A) Statements 1, 2 and 3 (B) Statements 1 and 2
(C*) Statements 1 and 3 (D) Statements 2 and 3
1
[Sol: statement 1 : N  4
 
 sin 
 2

1 1
N1 
sin 45 
0 4 
 1 
 
4 4

 2

1 1 16
& N2 
sin 60  0 4 
 3
 
4 
9
 2 
 
 N1 4 9
so N  16  9 =
2 4
150 9
 N2 =
4
4 150
 N2 =  67 (correct)
9
Statement 2 : Ionization energy of deuterium is slightly greater than that of hydrogen atom.
Statement 3 : Correct
(C) ]

Q.3 30 ml of CH3OH (d = 0.8 gm/cm3) is mixed with 60 ml of C2H5OH (d = 0.92 gm/ cm3) at 25°C to form
a solution of density 0.88 gm/cm3.Select the correct option.
(A) Molarity & molality of resulting solution are 6.33 & 13.59 respectively.
(B*) The mol fraction of solute and molality are 0.385 and 13.59 respectively.
(C) % change in volume and molarity are zero and 13.59 respectively.
(D) Molarity & mol fraction of solute are 13.59 & 0.485 respectively.
[Sol: mass of CH3OH = 30 × 0.8 = 24 gm
mass of C2H5OH = 60 × 0.92 = 55.2 gm
Total mass of solution formed = 24 + 55.2 = 79.2 gm
79.2
 final volume = = 90 ml
0.88
 % change in volume = 0
24  1000
molarity of solute (i.e. CH3OH) = = 8.33 M
32  90
24
moles of CH3OH = = 0.75
32
55.2
moles of CH3OH = = 1.2
46
0.75
 mole fraction of CH3OH = = 0.385
0.75  1.2
n CH 3OH  1000 0.75 1000
 molality of solution = = = 13.59 m
mass of solvent 55.2
So (B) option is correct ]

Q.4 Al2(SO4)3 solution of 1 molal concentration is present in 1 litre solution of density 2.684 gm/cc. How
many moles of BaSO4 would be precipitated on adding BaCl2 in excess.
(A) 3 moles (B) 2.684 × 3 moles (C*) 6 moles (D) 2 moles
[Sol: Mass of solution = 1000 × 2.684 = 2684 gm
molar mass of Al2(SO4)3 = 342 gm
 mass of solute in 1342 gm solution = 342 gm
 mass of solute in 2684 gm solution = × 2684 = 684 gm
 moles of Al2(SO4)3 = 2
Al2(SO4)3 + 3BaCl2  3BaSO4 + 6AlCl3
  moles of BaSO4 precipitated = 3 × 2 = 6
(C) ]

Q.5 Number of P–H , P–O–P , P–O–H and P = O bonds in sodiumdihydrogenpyrophosphate respectively

are
(A) 1, 1, 1, 2 (B*) 0, 1, 2, 2 (C) 0, 1, 1, 3 (D) 2, 0, 0, 2
[Sol: Na2H2P2O7
O O
|| ||
HOPOPOH
| |
O O
no. of P–H bond = 0
no. of P–O–P bond = 1
no. of P–O–H bond = 2
no. of P=O bond = 2 (B) ]
Q.6 The question below consists of an Assertion and the Reason. Mark appropriate option using the given
directions.
(A) If both assertion and reason are CORRECT, and reason is the CORRECT explanation of the
assertion.
(B) If both assertion and reason are CORRECT, but reason is not the CORRECT explanation of the
assertion.
(C) If assertion is CORRECT but reason is INCORRECT.
(D) If assertion is INCORRECT but reason is CORRECT.
Assertion: Bond energy of F2 is higher than that of Cl2.
Reason: According to VBT, 2p-2p overlap is stronger than 3p-3p.
[Sol: Bond energy of F2 is lesser than that of Cl2 According to VBT, 2p–2p overlap is stronger than 2p–3p
(D)]

Q.7

(A) 1–Formyl–2–chloro–4–hydroxy–hex–5–en–4–one
(B) 5–chloro–6–formyl–3–hydroxy–4–keto–hex–1–enal
(C*) 3–chloro–5–hydroxy–4–oxo–hept–6–enal
(D) none of these

[Sol: 3–chloro–5–hydroxy–4–oxo–hept–6–enal]
Q.8

IUPAC nomenclature of this compound is

(A) 6–chloro–3, 7, 8, 9 tetramethylundecane
(B*) 6–chloro–3, 4, 5, 9 tetramethylundecane
(C) 5–chloro–2–ethyl–3, 4, 8 trimethylundecane
(D) 6–chloro–9–ethyl–3, 7, 8 trimethylundecane

[Sol: 6–chloro–3, 4, 5, 9 tetramethylundecane]

Q.9 44 gm of a sample on complete combustion gives 88 gm CO2 & 36 gm of H2O. The molecular formula
of the compound may be
(A) C4H6 (B) C2H6O (C*) C2H4O (D) C2H4
88
[Sol: moles of CO2 = =2
44
36
moles of H2O = =2
18
C  CO2 H  H2O
POAC for C POAC for H
nC = n CO 2 = 2 nH = 2 × n H 2 O = 4
c = 24 gm H = 4 gm
 wt. of oxygen = 44 – (24 + 4) = 16
molecular formula of compound = C2H4O (C) ]

Q.10 The hybridization of iodine in ICl 4 , IOCl 4 , IOCl 4 is

(A) sp3d, sp3d2, sp3d2 (B) sp3d, sp3d2, sp3d
(C*) sp3d2, sp3d2, sp3d (D) sp3d2, sp3d, sp3d2
[Sol: ICl4– AB4E2 hybridisation of iodine = sp3d2
IOCl4– AB5E hybridization of iodine = sp3d2
IOCl4 + AB5 hybridisation of iodine = sp3d
(C) ]
Q.11 Which of the following would have permanent dipole moment.
(A*) SF4 (B) XeF4 (C) SiF4 (D) BF3
[Sol: SF4  see - saw shape (unsymmetrical)
XeF4  square planar (symmetrical)
SiF4 tetrahedral (symmetrical)
BF3 triangular planar (symmetrical)
(A) ]
Q.12 The correct order of bond angles is
(A) H2S < NH3 < BF3 < SiH4 (B*) H2S < NH3 < SiH4 < BF3
(C) NH3 < H2S < SiH4 < BF3 (D) H2S < SiH4 < NH3 < BF3
[Sol: H2S NH3 SiH4 BF3
   
sp3 sp3 sp3 sp2
+2lp +1lp
so the order of the bond angle
H2S < NH3 < SiH4 < BF3
(B) ]

Q.13 The maximum number of 90° angles between bond pair – bond pair is observed in
(A) sp3d hybridisation (B*) sp3d2 hybridisation
(C) sp3d3 hybridisation (D) sp3 hybridisation

[Sol: sp3d six 900 angles

sp3d2 twelve 900 angles

sp3d3 ten 900 angles

sp3 no 900 angles

(B) ]

Q.14 Which molecular geometry is least likely to result from a trigonal bipyramidal geometry?
(A*) Trigonal planar (B) See-Saw (C) Linear (D) T-shape
[Sol: See saw, T–shape and linear are derived geometries of TBP
but trigonal planar is least likely to form from a TBP geometries
(A) ]

Q.15 Ionic conductance (I.C.) is a measure of electrical conductivity of ions in their aqueous solution. Select
the option in which the values of ionic conductance given, are correctly matched with ions. Data:
(A) Na+  50.1 mho cm2 mol–1, Cl–  65.5 mho cm2 mol–1 & K+  64.5 mho cm2 mol–1
(B) Na+  64.5 mho cm2 mol–1, Cl–  65.5 mho cm2 mol–1 & K+  50.1 mho cm2 mol–1
(C) Na+  50.1 mho cm2 mol–1, Cl–  64.5 mho cm2 mol–1 & K+  65.5 mho cm2 mol–1
(D) Na+  64.5 mho cm2 mol–1, Cl–  50.1 mho cm2 mol–1 & K+  65.5 mho cm2 mol–1
[Sol: Order of extent of hydration is
Cl– < K+ < Na+
 order of ionic conductance is
 Cl–(aq) > K+(aq) > Na+(aq)
(A) ]

Select the correct alternatives. (One or more than one is/are correct) [5 × 5 = 25]
There is NO NEGATIVE marking.
Q.16 Select the incorrect statement(s):
(A*) In PO 34 ion, the P–O bond order is 1.33.
(B*) Covalent bond can be formed by overlapping of py and pz orbitals
(C) Bond angle in H2O is lesser than bond angle in OCl2 molecule.
(D*) SeF4 and CH4 have same shape.

5
[Sol: (A) PO43– B.O. = 1.25
4

(B) no bond can be formed

(C)

(D) SeF4  see saw ; CH4  Tetrahedral

Answers are (A) (D) ]
Q.17 Species having maximum number of lone pairs on the central atom is/are:
(A*) ClO– (B) XeF5— (C) SF4 (D*) I3—

[Sol: – O– (ABE3) number of lp = 3

XeF5– (AB5E2) number of lp = 2
SF4 (AB4E) number of lp = 1
I3 –
(AB2E3) number of lp = 3
order of bond length is (A), (B), (D) ]
Q.18 Which is/are correct statement(s)?
(A*) The increasing order of carbon-carbon bond length is:
Acetylene < Ethene < Benzene < Ethane
(B*) The increasing order of O–O bond length is:
O2 < O3 < H2O2
(C*) The decreasing order of O–N–O bond angle is:
NO2+ > NO2 > NO2–
(D*) The decreasing order of first ionisation potential is:
Ne > Cl > P > S > Mg > Al
[Sol: (A) HC  CH < H2C=CH2 < C6H6 < H3C–CH3
(B) order of bond length

O=O< < H–O–O–H

 .. .
(C) N O N O 2 N O2
2
 
sp sp2
+ 1 lp
order of bond angle NO2+ > NO2 > NO2–
(D) order of first ionization potential is
Ne > Cl > P > S > Mg > Al
Ans are (A), (B), (C), (D)]

Q.19 The molecule shown is a__________ alcohol because ________

OH
|
CH 3  CH 2  CH  CH 2  CH 3 .
(A) primary; it has one -OH group.
(B) primary; its -OH group is on the central carbon.
(C*) secondary; the carbon bonded to the -OH group is bonded to two other carbons.
(D*) secondary; because -OH group is attached with 2oC of secondary pentyl group.
[Sol: CH 3  CH 2  CH 
|
CH 2 CH 3

is known as "secondary" pentyl group & –OH group is attached with 20C atom therefore e.g. of 20 ol]

Q.20 Assuming the bond direction to be z-axis, which of the overlapping of atomic orbitals of two atom (A)
and (B) will result in bonding?
(A) s-orbital of A and px orbital of B (B*) s-orbital of A and pz orbital of B
(C) py-orbital of A and pz orbital of B (D*) s-orbitals of both (A) and (B)
[Sol: + 
s s
+  ]
s p2
 PART-B
MATCH THE COLUMN [3 × 8 = 24]
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match.
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.

Q.1 Column I Column II

(A) XeF5+ (P) Two lone pairs

(B) ICl4– (Q) Planar

(C) TeCl4 (R) Non-planar

(D) I3+ (S) sp3d2 (Hybridization of central atom)

[Sol: XeF5+ AB5E sp3d2 square pyramidal non planar
ICl4 AB4E2 sp3d2 square pyramidal planar
TeCl4 AB4E 3
sp d see-saw non planar
I3+ AB2E2 sp3 bent planar
(A)  (R, S); (B)  (P, Q, S); (C)  (R); (D)  (P, Q) ]

Q.2 Column - I Column -II

(A) KCN (P) Polar covalent bond

(B) CuSO4.5H2O (Q) Co-ordinate bond

(C) O3 (Resonating structures) (R) Ionic bond

(D) Solid N2O5 (Resonating structures) (S) Non Polar Covalent bond
[Sol: (A) K+[CN]–

(B) . H2O

(C)

(D) [NO2+] [NO3–]  [O=N=O]+

(A)  (P, R); (B)  (P, Q, R); (C)  (Q, S); (D)  (P, Q, R) ]
Q.3 Column - I Column -II
(A) Energy of a photon having (P) 3.2 × 10–19 J
wavelength 2484 Å is

(B) Kinetic energy of an e– having (Q) 66.67 eV

wavelength 150 pm is

(C) Maximum kinetic energy (R) 3.0 × 10–16 J

a photoelectron emitted
from a metal [work function= 2eV]
by a photon of wavelength 310.5 nm is

(D) Energy of a particle of mass 2 × 10–6 amu, (S) 5 eV

converted into energy is
1242
[Sol: (A) E = = 5eV = 5 × 1.6 × 10–19 J = 8 × 10–19 J
248.4

h 6.626 1034
(B)  =  150 × 10–12 =
2mKE 2  9.11031  K.E.
 K.E. = 66.67 eV
1242
(C) KEmax = E– E0 = – 2 = 2eV = 2 × 1.6 × 10–19 J = 3.2 × 10–19 J
310.5

2 10- 6  10 3 2 10-9
(D) energy = mc2
= 8 2
× (3 × 10 ) = × (3 × 108)2 = 3.0 × 10–16J
NA 6 1023
(A)  (S); (B)  (Q); (C)  (P); (D)  (R) ]

PART-C
SUBJECTIVE: [4 × 9 = 36]
There is NO NEGATIVE marking.
Q.1 Mr Gupta has to decode a number ABCD. EF, where each alphabet is represented by a single digit.
From the following information given about each alphabet. Identify the number.
Info A = number of radial nodes of the orbital having 2(r) vs r curve given as

Info B = number of subshells having energy between 8s & 8p.

Info C = ratio of density of SO2 at 400 K to density of O2 at 800 K at same pressure.
Info D = ratio of radius of 2nd Bohr orbit of He+1 to radius of 1st Bohr orbit of Be+3
Info E = number of radial nodes of an orbital whose radial wavefunction is represented as
r / K2
Y(r) = K1. e (r2 – 5 K3r + 6K 32 )
Info F = ratio of T.E to K.E for 1st orbit of H-atom assuming (P.E) = 27.2 eV
[Sol: Info A The given orbital is 2s
no. of radial node = 1
A=1
 Info B Number of subshells having energy between 2sand 2p = 3 (5g, 6f, 7d)
Info C PM SO 2 = d SO 2 RTSO 2 .......(1)
PM O 2 = d O 2 RT O 2 .......(2)

64 d SO 2 400
dividing (1) by (2) = d ×
32 O2 800

d SO 2
 d O2 = 4
 C=4


2
2
2
Info D (r2 ) He 
2

(r1 ) Be3 
1
2

1
4 4
( r2 ) He 
 ( r1 ) Be3 = 8
 D=8
Info E E = 2
1 Ze 2
Info F KE =
2 r

Ze 2
PE =  + (PE)
r
1 Ze 2
TE = – + (PE)= –13.6 + 27.2 = 13.6 eV
2 r
1 Ze 2
KE = = 13.6 eV
2 r
TE 13.6eV
ratio =  =1
KE 13.6eV
Ans: A = 1; B = 3; C = 4; D = 8; E = 2; F = 1 ]
Q.2 During preparation of sodium carbonate in the Solvay process CO2 gas is bubbled into the brine solution
(NaCl in water) saturated with NH3 giving rise to following equations.
NH3 + H2O + CO2  NH4HCO3
NaCl + NH4HCO3  NaHCO3 + NH4Cl
Sodium hydrogen carbonate formed precipitate out & is then subjected to photoelectric dissociation to
obtain sodium carbonate.
h
2NaHCO3  Na2CO3 + CO2 + H2O
If 100g of 58.5% brine solution (w/w) is mixed with 34 gm of NH3 & then 49.2 litres of CO2 at 1 atm
pressure & 300 K is bubbled into the solution & the sodium bicarbonate is subjected to photochemical
 moles of reactan t dissociated 
dissociation to obtain a quantum efficiency   = 0.75 then what is the
 moles of photons subjected 
 value of total energy subjected in kJ if  of radiation is 1242 nm. Assume no NaHCO3 to be remaining
after photochemical dissociation. [Use NA = 6 × 1023; R = 0.082 lt-atm/K-mol]
58.5 100
[Sol: moles of NaCl =  =1
100 58.5
34
moles of NH3 = =2
17
PV 1 49.2
moles of CO2 = = =2
RT 0.082  300
Now NH3 + H2O + CO2  NH4HCO3
t=0 2 excess 2
 moles of NH4HCO3 formed = 2
NH4HCO3 + NaCl  NaHCO3 + NH4Cl
t=0 2 1
 moles of NaHCO3 formed = 1
moles of reactant dissociated
moles of quantum subjected =
0.75
1 4 4
= 
3 3
4
 total number of photons used = N
3 A
4 1242
Total energy subjected = NA × eV
3 1242
4
= × 6 × 1023 × 1.6 × 10–19 J
3
= 128000 J = 128 kJ ]

Q.3 Gaseous ethylene, C2H4 reacts with hydrogen gas in the presence of a platinum catalyst to form ethane,
C2H6 according to C2H4(g) + H2(g)  C2H6(g). A mixture of C2H4 & H2 known to contain more
H2 than C2H4 had a pressure of 60 atm in an unknown volume. After the mixture had passed over
platinum catalyst & C2H4 completely reacted, the pressure was 90 atm in the original volume and at
double the absolute temperature as was earlier. Find out the mole % of H2 in the original mixture.
[Sol: C2H4(g) + H2(g)  C2H6(g)
t=0 p 60 – p –
on completion – 60 – 2p p
total pressure = 60 – p (at the original conditions)
 (60 – p)2 = 90
 120 – 2p = 90
 p = 15
45
so mole % of H2 =  100 = 75% ]
60
Q.4 The key reaction in the manufacture of synthetic cryolight for aluminium electrolysis is
HF(g) + Al(OH)3 (s) + NaOH (aq)  Na3AlF6(aq) + H2O(l)
Assuming a 96 % yield of dried, crystallized product, what mass (in kg) of cryolite can be obtained from
the reaction of 351 kg of Al(OH)3, 1.10 m3 of 50.0% by mass aqueous NaOH (d = 1.50 g/mL), and
225 m3 of gaseous HF at 312.08 kPa and 87oC? (assume that the ideal gas law holds)
[Given: Al = 27, O = 16, H = 1, Na = 23, F = 19, R = 8.3 JK–1 mol–1]
[Sol: 6HF + Al(OH)3 + 3NaOH  Na3AlF6 + 6 H2O(l)
351 103
moles of Al(OH)3 = = 4500
78

moles of NaOH =
1.110 1.5  0.5 = 20625
6

40
PV 312080  225
moles of HF = = = 23500
RT 8.3  360
Here HF is limiting reagent
23500 96
so moles of Na3AlF6 formed =  = 3760
6 100
3760  210
wt. of Na3AlF6 formed = = 789.6 kg ]
1000