Down to the wire: Inexpensive technique for making high quality nanowire solar cells developed

Enlarge Schematic shows how to make core/shell nanowire solar cell starting from left with a CdS nanowire (green) that is dipped in CuCl where cation exchange reaction creates a Cu2S shell coating (brown). Metal contacts are then deposited on the CdS core and Cu2S shell. Credit: Image courtesy of Yang, et. al (PhysOrg.com) -- Solar or photovoltaic cells represent one of the best possible technologies for providing an absolutely clean and virtually inexhaustible source of energy to power our civilization. However, for this dream to be realized, solar cells need to be made from inexpensive elements using low-cost, less energy-intensive processing chemistry, and they need to efficiently and cost-competitively convert sunlight into electricity. A team of researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory has now demonstrated two out of three of these requirements with a promising start on the third. Ads by Google IBM Data Center Design - Defer 50% of capital & operational costs with flexible data centers! www.ibm.com Peidong Yang, a chemist with Berkeley Lab's Materials Sciences Division, led the development of a solution-based technique for fabricating core/shell nanowire solar cells using the semiconductors cadmium sulfide for the core and copper sulfide for the shell. These inexpensive and easy-to-make nanowire solar cells boasted open-circuit voltage and fill factor values superior to conventional planar solar cells. Together, the open-circuit voltage and fill factor determine the maximum energy that a solar cell can produce. In addition, the new nanowires also demonstrated an energy conversion efficiency of 5.4-percent, which is comparable to planar solar cells. "This is the first time a solution based cation-exchange chemistry technique has been used for the production of high quality single-crystalline cadmium sulfide/copper sulfide core/shell nanowires," Yang says. "Our achievement, together with the increased light absorption we have previously demonstrated in nanowire arrays through light trapping, indicates that core/shell nanowires are truly promising for future solar cell technology."

Yang, who holds a joint appointment with the University of California (UC) Berkeley, is the corresponding author of a paper reporting this research that appears in the journal Nature Nanotechnology. The paper is titled "Solution-processed coreshell nanowires for efficient photovoltaic cells." Co-authoring this paper with Yang were Jinyao Tang, Ziyang Huo, Sarah Brittman and Hanwei Gao. Typical solar cells today are made from ultra-pure single crystal silicon wafers that require about 100 micrometers in thickness of this very expensive material to absorb enough solar light. Furthermore, the high-level of crystal purification required makes the fabrication of even the simplest silicon-based planar solar cell a complex, energy-intensive and costly process. Ads by Google MEMS Manufactory - Reliable MEMS Processing, Micro Systems, Developement & Consulting - www.microfab.de A highly promising alternative would be semiconductor nanowires one-dimensional strips of materials whose width measures only one-thousandth that of a human hair but whose length may stretch up to the millimeter scale. Solar cells made from nanowires offer a number of advantages over conventional planar solar cells, including better charge separation and collection capabilities, plus they can be made from Earth abundant materials rather than highly processed silicon. To date, however, the lower efficiencies of nanowire-based solar cells have outweighed their benefits. "Nanowire solar cells in the past have demonstrated fill factors and open-circuit voltages far inferior to those of their planar counterparts," Yang says. "Possible reasons for this poor performance include surface recombination and poor control over the quality of the pn junctions when high-temperature doping processes are used."

This scanning electron microscopy image shows three solar cells in series on a single nanowire with the core-shell regions marked by brown lines. Credit: Image courtesy of Yang, et. al

At the heart of all solar cells are two separate layers of material, one with an abundance of electrons that function as a negative pole, and one with an abundance of electron holes (positively-charged energy spaces) that function as a positive pole. When photons from the sun are absorbed, their energy is used to create electron-hole pairs, which are then separated at the pn junction the interface between the two layers - and collected as electricity. About a year ago, working with silicon, Yang and members of his research group developed a relatively inexpensive way to replace the planar p-n junctions of conventional solar cells with a radial p-n junction, in which a layer of n-type silicon formed a shell around a p-type silicon nanowire core. This geometry effectively turned each individual nanowire into a photovoltaic cell and greatly improved the light-trapping capabilities of silicon-based photovoltaic thin films. Now they have applied this strategy to the fabrication of core/shell nanowires using cadmium sulfide and copper sulfide, but this time using solution chemistry. These core/shell nanowires were prepared using a solution-based cation (negative ion) exchange reaction that was originally developed by chemist Paul Alivisatos and his research group to make quantum dots and nanorods. Alivisatos is now the director of Berkeley Lab, and UC Berkeley's Larry and Diane Bock Professor of Nanotechnology. "The initial cadmium sulfide nanowires were synthesized by physical vapor transport using a vaporliquidsolid (VLS) mechanism rather than wet chemistry, which gave us better quality material and greater physical length, but certainly they can also be made using solution process" Yang says. "The as-grown single-crystalline cadmium sulfide nanowires have diameters of between 100 and 400 nanometers and lengths up to 50 millimeters." The cadmium sulfide nanowires were then dipped into a solution of copper chloride at a temperature of 50 degrees Celsius and kept there for 5 to 10 seconds. The cation exchange reaction converted the surface layer of the cadmium sulfide into a copper sulfide shell. "The solution-based cation exchange reaction provides us with an easy, low-cost method to prepare high-quality hetero-epitaxial nanomaterials," Yang says. "Furthermore, it circumvents the difficulties of high-temperature doping and deposition for typical vapor phase production methods, which suggests much lower fabrication costs and better reproducibility. All we really need are beakers and flasks for this solution-based process. There's none of the high fabrication costs associated with gas-phase epitaxial chemical vapor deposition and molecular beam epitaxy, the techniques most used today to fabricate semiconductor nanowires." Yang and his colleagues believe they can improve the energy conversion efficiency of their solar cell nanowires by increasing the amount of copper sulfide shell material. For their technology to be commercially viable, they need to reach an energy conversion efficiency of at least tenpercent. Provided by Lawrence Berkeley National Laboratory (news : web)

Flexible, Nanowire Solar Cells

Exotic materials and cheaper substrates could lead to better photovoltaics. Researchers at McMaster University, in Ontario, say that they have grown light-absorbing nanowires made of high-performance photovoltaic materials on thin but highly durable carbonnanotube fabric. They've also harvested similar nanowires from reusable substrates and embedded the tiny particles in flexible polyester film. Both approaches, they argue, could lead to solar cells that are both flexible and cheaper than today's photovoltaics. Now the researchers' challenge is to improve the efficiency of the cells without increasing cost. The research team, led by Ray LaPierre, a professor in the university's engineering physics department, has been given three years to achieve its goals--backed by about $600,000 from the Ontario government and private-sector research partner Cleanfield Energy, a Toronto-area developer of wind and solar technologies. LaPierre says that the aim is to produce flexible, affordable solar cells composed of Group III-V nanowires that, within five years, will achieve a conversion efficiency of 20 percent. Longer term, he says, it's theoretically possible to achieve 40 percent efficiency, given the superior ability of such materials to absorb energy from sunlight and the light-trapping nature of nanowire structures. By comparison, current thin-film technologies offer efficiencies of between 6 and 9 percent. "Most of the nanowire work to date has focused on silicon nanowires," says LaPierre, explaining that McMaster's approach relies on nanowires containing multiple layers of exotic Group III-V materials, such as gallium arsenide, indium gallium phosphide, aluminum gallium arsenide, and gallium arsenide phosphide. "It creates tandem or multi-junction solar cells that can absorb a greater range of the [light] spectrum, compared to what you could achieve with silicon. That's one of the major unique aspects of our work."
When used in conventional crystalline solar cells, Group III-V materials are known to have much higher efficiencies than silicon, but the great cost of these materials has limited their use. LaPierre says that cost becomes less of an issue with nanowires because so little material is needed. This is in part because the structure of the nanowires provides a more efficient way to absorb light and extract electrons freed by the light. In conventional solar cells, which are made of slabs of crystalline material, greater thickness means better light absorption, but it also means that it's more difficult for electrons to escape. This forced trade-off is overcome with nanowires. Each nanowire is 10 to 100 nanometers wide and up to five microns long. Their length maximizes absorption, but their nanoscale width permits a much freer movement and collection of electrons. "The direction in which you absorb the light is essentially perpendicular to how you collect electricity," explains LaPierre. "The dilemma is overcome."