1. Which of the following species is not electrophilic in nature ?

 
a) BH3 b) H3O c) CH 3 d) Cl

2. CH3CH2–Cl undergoes homolytic fission to produce.

  
a) CH 3 CH 2 and Cl b) CH 3 CH 2 and Cl ⊝
 Θ
c) CH 3 CH 2 and Cl ⊝ d) CH 3 CH 2 and Cl 

3. The reaction intermediate produced by homolytic cleavage of bond is called

a) carbocations b) carbanions c) free radicals d) carbenes
4. Heterolytic fission of carbon chlorine bond produces:
a) two free radicals b) two carbocations
c) two carbanions d) one cation and one anion
5. Which one of the following characteristics belongs to electrophile?
a) Electron rich species b) Electron deficient species
c) Complete octet d) Lewis base
6. A nucleophile must be
a) Lone pair containing b) An electron deficient
c) Lewis acid d) A positive charge
7. Which of the following intermediates has complete octet?
a) Carbocation b) Carbanion c) Free radical d) Carbene
8. A free radical is
a) reaction intermediate b) neutral in nature
c) paramagnetic d) all of these
9. Inductive effect involves
a) displacement of -electrons b) delocalisation of -electrons
c) delocalisation of - electrons d) displacement of -electrons

10. +I effect is shown by

a) – NO2 b) – Cl c) – Br d) – CH3
11. Maximum –I effect is exerted by the group
a) C6H5 – b) –OCH3 c) –Cl d) –CN
12. IUPAC name of the compound is
O
CH3CH2 – CH = CH – C – H
a) pent-2-en-1-al b) But-2-en-1-al
c) pent-3-en-4-al d) pent-3-en-5-al
13. The structure of 4-methylpent-2-en-1-ol is
a) CH3CH2CH = CH − CH2OH
b) (CH3)2C = CH − CH2CH2OH
c) (CH3)2CH − CH = CH − CH2OH
d) CH3CH(OH)CH2 − CH = C(CH3)2
14. The correct decreasing order of priority for functional groups of organic
compounds in IUPAC system of nomenclature is:
a) – CONH2, – CHO, – SO3H, – COOH
b) – COOH, – SO3H, – CONH2, – CHO
c) – SO3H, – COOH, – CONH2, CHO
d) – CHO, – COOH, – SO3H, – CONH2
15. Correct IUPAC name of the compound is:
O
H3C – C – OH
a) methyl methanoic acid b) ethanoic acid
c) ethan-2-ol d) eth-1-on-1-ol
16. IUPAC of the following compound is :
O O
H3C – C – CH2 – C – CH3
a) pentanone b) propan-2, 4-dione
c) pentan-2, 4-dione d) 1, 5-dimethyl propanone
17. IUPAC name of
O
CH3 – CH2C  C– C – CH2 – CH3
is
a) 3-oxo-2-heptyne b) hept-3-yn-4-oxone
c) hept-4-yn-3-one d) kept-3-yn-4-one
18. Which is saturated compound
a) b) CH3 – C  C – CH3

NH
c) d)

19 IUPAC name of is

a) 4, 4-dimethyl-5,5 -diethylpentane
b) 5, 5-dimethyl-4,4 –diethylpentane
c) 3-ethyl- 4, 4-dimethylheptane
d) 1, 1-diethyl-2, 2-dimethylheptane
20. IUPAC name for the given compound is
CH3 – CH = CH– CH – CH3
C  CH
a) 4-ethylpent-2-ene b) 1-ethyl-3-methylbut-2-ene
c) 3-methylhex-4-en-1-yne d) 4-methylhex-2-en-5-yne

21. Structures CH3 – CH2 – CH = CH2 and CH3 – C = CH2 are

CH3
a) Chain isomers b) Position isomers
c) Both chain & position isomers d) Not isomers
22. How many minimum carbons required for Chain isomerism and Position
isomerism in alkanes ?
a) 4, 5 b) 3, 5 c) 4, 6 d) 4, 4
23. Isomers are essentially identical with
a) Structural formula b) Chemical properties
c) Molecular formula d) Physical properties
24. Find the value of degree of unsaturation of the following structure

a) 4 b) 3 c) 2 d) 5
25. What is the D.U. of Benzene?
a) 4 b) 5 c) 2 d) 3
26. Which of the following isomerism is not related to structural isomerism
a) Position b) Functional c) Geometrical d) Chain

27. and exhibit the isomerism

a) Functional b) Chain
c) Position d) Tautomerism

O O
28. CH3 – CH2 – CH2 – C – OH and CH3 – CH2 – CH – C – H are
OH
a) Position isomers b) Functional isomers
c) Identical d) Chain isomers
29. CH3 – S – CH2 – CH3 and CH3 – CH2 – S – CH3 are
a) Chain isomers b) Functional isomers
c) Identical d) Position Isomers

O O O O
30. CH3 – CH2 – C – O – C – C6H5 and C6H5 – CH2 – C – O – C – CH3 are
a) Metamers b) Chain Isomers
c) Identical d) Position Isomers
31. Total number of isomers of a disubstituted benzene compound is
a) 1 b) 2 c) 3 d) 4
32. Calculate total number of geometrical isomers in the following compound
CH3 – CH = CH – CH = CH – CH = CH – C6H5
a) 2 b) 4 c) 6 d) 8
33. In the given four conformational isomers which of the following has
minimum torsional strain and minimum steric strain.

a) b) c) d)

H H
34. The hybridisation of central and terminal carbon atoms in C=C=C
H H
are respectively
a) sp and sp b) sp2 and sp3 c) sp and sp2 d) sp2 and sp

35. IUPAC name of the compound is

a) 2-Ethyl-1, 1-dimethylcyclopentane
b) 1-Ethyt-2, 2-dimethylcyclopentane
c) 1, 1-Dimethy1-2-ethylcyclopentane
d) 2, 2-Dimethyl -1-ethylcyclopentane
36. The IUPAC name of CH2 = CH – CH2 – OH is
a) Propynal b) Propanol
c) Prop-2-enol d) Propenyl alcohol
37. The number of structural isomers possible for C4H8 is
a) 4 b) 3 c) 5 d) 6
38. IUPAC name of the compound is

a) 5-Hydroxycyclopent-2-enone b) 2-Ilydroxycyclopent-4-enone
c) 5-Hydroxycyclopent-4-enone d) 2-Hydroxycyclopent-2-enone
39. Which of the following is a heterocyclic compound?

a) b) c) d) All of these

40. Carbon-carbon bond-order in benzene is 1.5 due to

a) Inductive effect b) Electromeric effect
c) Resonance d) H-bonding
41. In which of the following, the group attached to the benzene ring shows +R
effect?

a) b) c) d) All of these

42. Which of the following compound can show resonance?

a) CH2 = CH – CH = CH2 b) CH2 = CH – CHO
c) CH2 = CH – NH2 d) All of these
43. Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-
methylhex-3-en-5-ynoic acid is

a) b)

c) d)

44. The IUPAC name of the compound CH3CH = CHC  CH is

a) Pent-4-yn-2-ene b) Pent-3-en-1-yne
c) Pent-2-en-4-yne d) Pent-1-yn-3-ene
45. The IUPAC name of the compound having the formula CH  C– CH = CH2
is
a) 1-butyn-3-ene b) but-1-yne-3-ene
c) 1-butene-3-yne d) 3-butene-1-yne

46. In the hydrocarbon CH3 – CH = CH – CH2 – C  CH

6 5 4 3 2 1
The state of hybridization of carbons 1,3 and 5 are in the following
sequence
a) sp3, sp2, sp b) sp2, sp, sp3 c) sp, sp3, sp2 d) sp, sp2, sp3
47. Mesomeric effect involves
a) delocalisation of  electrons b) partial displacement of  electrons
c) delocalisation of  electrons d) delocalisation of  and  -electrons

+
48. Stability of CH2 – CH = CH2 can be explained by
a) inductive effect b) electrometric effect
c) resonance d) polar effect
⊝
49. CH2 – C – CH3 and H2C = C – CH3 are
⊝
O O
a) resonating structures b) tautomers
c) geometrical isomers d) optical isomers
50. Determine bond length order?
  
CH3 – CH3 CH2 = CH2 CH2 = CH – CH = CH2
a)  >  >  b)  >  >  c)  >  >  d) none of these