Isoterma de Langmuir

Datos)
W= 250 mg Chart Title
V= 0.1 L
160

140
f(x) = 224.216228242243 x + 26.8254989676763
120 R² = 0.997126135034266
Co (mg/L) Ce (mg/L) qe 1/Ce 1/qe
100
500 398 0.0408 0.002513 24.5098
300 209 0.0364 0.004785 27.47253 80
250 159 0.0364 0.006289 27.47253 60
200 112 0.0352 0.008929 28.40909
40
150 69 0.0324 0.014493 30.8642
100 34 0.0264 0.029412 37.87879 20
50 7 0.0172 0.142857 58.13953
0
20 2 0.0072 0.5 138.8889 0 0.1 0.2 0.3 0.4

Modelo de Freundlich
Modelo de Freundlich
Co (mg/L) Ce (mg/L) qe log(Ce) log(qe) 0
0 0.5 1 1.5 2
500 398 0.0408 2.599883 -1.38934
300 209 0.0364 2.320146 -1.438899
-0.5
250 159 0.0364 2.201397 -1.438899
200 112 0.0352 2.049218 -1.453457
150 69 0.0324 1.838849 -1.489455 -1

100 34 0.0264 1.531479 -1.578396

f(x) = 0.309541786022645 x − 2.11653925937676
50 7 0.0172 0.845098 -1.764472 -1.5 R² = 0.9148270836135
20 2 0.0072 0.30103 -2.142668
-2

-2.5

Isoterma de Temkin
Isoterma de Temkin
Co (mg/L) Ce (mg/L) qe ln(Ce) 0.045
500 398 0.0408 5.986452
0.04 f(x) = 0.00631681441864233 x + 0.00411513566897175
300 209 0.0364 5.342334 R² = 0.989357790825636
0.035
250 159 0.0364 5.068904
200 112 0.0352 4.718499 0.03
150 69 0.0324 4.234107 0.025
100 34 0.0264 3.526361 0.02
50 7 0.0172 1.94591
0.015
0.01
0.005
 0.03
0.025
0.02
0.015
20 2 0.0072 0.693147
0.01
0.005
0
0 1 2 3 4 5
 Chart Title

26.8254989676763

0.3 0.4 0.5 0.6

delo de Freundlich
1.5 2 2.5 3

22645 x − 2.11653925937676
35

erma de Temkin

1864233 x + 0.00411513566897175
5636
3 4 5 6 7
Estudio cinético

Datos)
W= 0.25 g
V= 0.1 L
Ce= 3.87 (mg/L)
Co= 10.68 (mg/L)
qe= 2.724

Pseudo primer orden

t (min) Ct (mg/L) qt log(qe-qt)

0 10.68 0 0.435207 Pseudo primer orden
0.08 10.05 0.252 0.393048 0.5
0.17 9.65 0.412 0.363988
0.33 9.36 0.528 0.341632 0.4
0.5 9.16 0.608 0.325516
f(x) = − 0.0764336890915904 x + 0.356644279404346
0.67 8.68 0.8 0.284205 0.3 R² = 0.934161556350365
0.83 8.43 0.9 0.261025
1 8.32 0.944 0.25042 0.2
1.5 7.89 1.116 0.206286
2 7.33 1.34 0.141136 0.1
3 6.95 1.492 0.090611
4.2 6.47 1.684 0.017033 0
0 1 2 3 4 5 6
5.02 6.48 1.68 0.0187
6 6 1.872 -0.06956 -0.1
24 3.87 2.724 Err:502
inf 3.87 2.724 Err:502

Pseudo segundo orden

3.5
t (min) Ct (mg/L) qt t/qt f(x) = 0.480616798225792 x + 0.490117058093494
0 10.68 0 3 R² = 0.986475393580218
0.08 10.05 0.252 0.31746
0.17 9.65 0.412 0.412621 2.5
0.33 9.36 0.528 0.625
0.5 9.16 0.608 0.822368 2
0.67 8.68 0.8 0.8375
0.83 8.43 0.9 0.922222 1.5
1 8.32 0.944 1.059322
1.5 7.89 1.116 1.344086 1

2 7.33 1.34 1.492537

0.5
3 6.95 1.492 2.010724
4.2 6.47 1.684 2.494062
0
5.02 6.48 1.68 2.988095 0 1 2 3 4 5
6 6 1.872 3.205128
 24 3.87 2.724 8.810573
inf 3.87 2.724 #VALUE!

Modelo de Elovich

t (min) Ct (mg/L) qt ln t
0 10.68 0
0.08 10.05 0.252 -2.525729
Modelo de Elovich
0.17 9.65 0.412 -1.771957
0.33 9.36 0.528 -1.108663
0.5 9.16 0.608 -0.693147
0.67 8.68 0.8 -0.400478 f(x) = 0.433983536351943 x + 1.05859740341552
0.83 8.43 0.9 -0.18633 R² = 0.957183940203884

1 8.32 0.944 0
1.5 7.89 1.116 0.405465
2 7.33 1.34 0.693147
3 6.95 1.492 1.098612
4.2 6.47 1.684 1.435085
5.02 6.48 1.68 1.61343
6 6 1.872 1.791759
24 3.87 2.724 3.178054 -3 -2 -1 0 1 2
inf 3.87 2.724
mer orden

4279404346

4 5 6 7

90117058093494

3 4 5 6 7
elo de Elovich

1.05859740341552

0 1 2 3 4
Difisión intraparticular

Datos)
W= 0.25 g
V= 0.1 L
C0= 20.01076

t (min) C qt t^1/2
0 20.01076 0 0
2.5 15.50592 1.801936 1.581139
5 14.83208 2.071472 2.236068 Difusión intrapartícula
7.5 13.68568 2.530032 2.738613 9
10 12.81916 2.87664 3.162278 8
15 10.65124 3.743808 3.872983
7
30 6.643703 5.346823 5.477226
6
45 4.21098 6.319912 6.708204
60 2.940258 6.828201 7.745967 5
75 2.17944 7.132528 8.660254 4
90 1.804952 7.282323 9.486833 3
105 1.536491 7.389708 10.24695
2
120 1.157158 7.541441 10.95445
135 0.979548 7.612485 11.61895 1
165 0.721206 7.715822 12.84523 0
0 2 4 6 8 10 12 14
180 0.699677 7.724433 13.41641
195 0.592034 7.76749 13.96424

Chart Title
7.8
f(x) = 0.0935620838652743 x + 6.48617011236804
R² = 0.928633424228283
7.7

7.6

7.5

7.4

7.3

7.2
10 10.5 11 11.5 12 12.5 13 13.5 1

Chart Title
8
f(x) = 0.798314523081537 x + 0.425919236487685
7 R² = 0.976798372435305

5
 Chart Title
8
f(x) = 0.798314523081537 x + 0.425919236487685
7 R² = 0.976798372435305

0
0 1 2 3 4 5 6 7 8
trapartícula

8 10 12 14 16

rt Title

8617011236804

12.5 13 13.5 14 14.5

rt Title
6487685
rt Title
6487685

5 6 7 8 9 10
Modelo Langmuir-Hinshelwood

t Ct C/Co Modelo Langmuir-Hinshel

0 40.53 1 1.2
20 32.69 0.806563
40 26.36 0.650382 1
60 20.36 0.502344 f(x) = − 0.00652691128264777 x + 0.941859645412569
80 16.22 0.400197 0.8 R² = 0.976111187575383

100 10.88 0.268443

0.6
120 9.07 0.223785

0.4

0.2

0
0 20 40 60 80

m= -0.0065
b= 0.9414

Constante cinética de la reacción (k) =

Constante de adsorción (K) =
odelo Langmuir-Hinshelwood

+ 0.941859645412569

60 80 100 120 140

1.062248
-144.8308