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CHEMISTRY-27-08 - 11th (J-Batch)
CHEMISTRY-27-08 - 11th (J-Batch)
CHEMISTRY-27-08 - 11th (J-Batch)
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Pt = 195,
He = 4, Ba = 137
Q.1 In a mass spectrograph experiment, He+ ion was found to strike at distance of x cm. Calculate
distance where H2O+2 ion would strike if
(a) Potential difference 'V' and magnetic field 'B' are kept constant.
(b) Velocity of ions & magnetic field are constant [2+2]
[Ans. (a) 3x/2 (b) 9x/4]
2Vm m
[Sol.(a) r = r
qB 2 q
r 2 3
He r
= H 2O 2 = x
r 3 2
H 2O 2
mu m
(b) r= r
qB q
r 4 9
He r
= H 2O 2 = x ]
r 2 9 4
H 2O
Q.2 Two vessels connected by a valve of negligible volume. One container (I) has 2.8 g of N 2 &
12.7 g of I2 at temperature T1 (K). The other container (II) is completely evacuated. The container
(I) is heated to T2 (K) while container (II) is maintained at T2/3 (K). The valve is opened. Calculate
masses of N2 in both containers after a very long time. I2 sublimes at T2 (K) and volume of vessel
(I) is half that of vessel (II). Neglect vapour pressure of I2 (s). [4]
[Ans. 0.4 g in (I) & 2.4 g in (II)]
[Sol.
Q.4 Rate of diffusion of ozonized oxygen is 0.4 5 times that of pure oxygen. Find
(a) Percentage by mass of ozone in the ozonized sample
(b) Degree of dissociation of oxygen assuming pure O2 in the sample initially. [3+1]
[Ans. 60%, 0.6]
rmix 32
[Sol. = = 0 .4 5
rO M avg
2
32
= 0.8 Mavg = 40 g/mol
M avg
2
O2 l O
3 3
t=0 1
2
t= 1–
3
32 1 ( / 3)
= = 0.6
40 1
mol. of O2 1 0 .4 mass of O 2 32 2
mol. of O3 = = =1 ; = =
2 / 3 0 .4 mass of O3 48 3
3
mass % of O3 = × 100 = 60% ]
5
Q.5 An open vessel at 27°C is heated. Assuming that volume of vessel remains constant. Calculate
(a) Temperature to which vessel was heated till (3/5)th of air in it has been expelled.
(b) Fraction of molecules escaped out when vessel is heated to 900 K
(c) Temperature at which half of the air escapes out. [1.5+1.5+1]
[Ans. (a) 477°C (b) 2/3 (c) 327°C]
PV 3 PV
[Sol.(a)
300R 1 5 = T (R )
5
T = 300 × = 750 K = 477°C
2
(b) Let x be fraction escaped
PV PV
(1 – x) =
300R 900R
x = 2/3
PV PV
(c) (1 – 0.5) =
300R TR
T = 327°C ]
Q.6 Heat released when 1 mole of acid HX neutralizes 1 mol of base BOH
M
is 30 3 KJ. To a solution containing HX of molarity another
10
solution containing base BOH was slowly added. A plot between heat
liberated (J) and volume of BOH (ml) added was obtained as shown.
(a) Calculate molarity of base.
(b) Calculate volume of original HX solution [2.5+2.5]
[Ans. (a) 0.011 M (b) 66.66 ml]
[Sol.(a) Let V ml of base be added & M be molarity of base
Moles of base = MV × 10–3
Heat released = MV × 10–3 × 30 3 × 103 J = ( 30 3 MV) J
1
Slope = 30 3 M =
3
M = 1/90 = 0.011 M
1
(b) 346.4 = 30 3 × ×V (where V is vol. of HX in ml)
10
V = 66.66 ml ]
Q.7 200 g of an oleum sample was dissolved in excess water. To this solution 1 kg of impure Ba(NO 3)2
was added causing formation of BaSO4 precipitate. The precipitate formed was filtered, washed
& dried. Its weight was 582.5 gm. Find % labelling of oleum sample. [5]
[Ans. 122.5%]
[Sol. moles of BaSO4 = moles of H2SO4 = 2.5 moles
Let x be % labelling of oleum
x 100
moles of SO3 = ×2
18
x 100 1
moles of H2SO4 = 200 80 2
18 98
x 100 200 x 100 80
2× + – = 2.5
18 98 18 49
x = 122.5% ]
Q.8 400 ml of 0.2 × 10–3 M Ca(NO3)2 solution is mixed with 400 ml of 10–4 M NaHCO3 solution. If
density of resulting solution is 1 g/ml. Calculate
(a) ppm of Ca(HCO3)2 in final solution
(b) Molality of Na+ in solution
(c) Molarity of Ca2+ in solution [2+2+1]
[Ans. (a) 4.05 ppm (b) 5 × 10–5 mol/kg (c) 10–4 M]
[Sol. Ca(NO3)2 (aq) + 2NaHCO3 (aq) Ca(HCO3)2 (aq) + 2NaNO3 (aq)
t = 0 80 × 10–6 mol 40 × 10–6 mol
t = 60 × 10–6 mol 0 20 × 10–6 mol 40 × 10–6 mol
40 10 6
(b) Molality of Na+ = × 1000 = 5 × 10–5 mol/kg
800
80 106
(c) Molarity of Ca2+ = = 10–4 M ]
800 103
228
P0 = + 76 = 152 cm Hg
3
At t = 7 min.
114
P= + 76 = 114 cm Hg
3
152e–kt = 114
1 152 1
k= ln = × 0.28 = 0.04 min–1 = 0.04 × 60 hr–1 = 2.4 hr–1 ]
t 114 7
Q.10 Calculate minimum number of balloons each of volume 82.1 lit. required to lift a mass of 1 kg to
a height of 831 m. Given: molar mass of air = 29 g/mol, temperature is constant at 290 K and
mass of each balloon is 50 g. [Use e–0.1 = 0.9, pressure at sea level = 1 atm, acceleration due to
gravity (g) = 10 m/s2] [5]
[Ans. 25 balloons]
29 1 1
[Sol. Density of air at sea level, d0 = = g/lit
0.0821 290 0.821
29 103 10 831
–
1
8.31 290
1 0 .9
Density at 831 m = d = d0e–Mgh/RT = × e = × e–0.1 = g/lit
0.821 0.821 0.821
Let n be number of balloons
0 .9
103 × g + n × 50g = × 82.1 × g × n
0.821
1000 + 50 n = 90 n
n = 25 balloons ]
Q.11 A mixture 1,2–Dipropene and hydrogen gas was placed in a rigid steel container at a constant
temperature of 18°C. Initial pressure of mixture was 10 atm. Sparking the mixture caused
hydrogenation reaction
C3H4 (g) + 2H2(g) C3H8 (g)
causing pressure to decrease by 6 atm. Excess O2 was then added and on sparking the pressure
further decreased by 11 atm. Calculate decrease in pressure by treating final mixture with aqueous
KOH solution. [6]
[Ans. 12 atm]
[Sol. If C3H4 is limiting reagent
C3H4 + 2H2 C3H8
t=0 P 10–P
t= 0 10–3P P
10 – 3P + P = 4 P = 3 atm
On sparking,
C3H8 + 5O2 3CO2 + 4H2O
3 atm 15 atm 9atm
1
H2 + O H2O
2 2
1
1atm atm
2
Pressure decrease = (3 + 15 – 9) + (1 + 0.5) = 10.5 atm 11 atm
Case II: H2 is limiting reagent
C3H4 + 2H2 C3H8
t=0 P 10–P
10 P 10 P
t= P– 0
2 2
P = 4 atm
C3H4 + 4O2 3CO2 + 2H2O
1 atm 4atm 3 atm
(1 + 4 – 3) + (3 + 15 – 9) = 11 atm
Q.12 0.2 gm of an anhydrous organic acid gave on combustion 0.04 g water and 0.195 g of CO 2. 0.5 g
of its silver salt leaves on ignition 0.355 g silver. In another experiment 100 ml of 0.2 M acid
1
solution was neutralised by 400 ml of M caustic potash solution. What is molecular formula
10
of acid? [6]
[Ans. C2H2O4]
0.04
[Sol. moles of H = 2
18
0.195
moles of C =
44
1 0.04 12 0.195
moles of O = 0.2
16 9 44
C : H : O = 0.0044 : 0.0044 : 0.0089 = 1 : 1 : 2
Empirical formula = CHO2
Q.14 A tube of uniform cross-section of 0.5 cm2 and length 118 cm is divided into three compartments
by using two frictionless pistons each of mass 101.32 gm. The compartments I, II & III are filled
by equal masses of CH4, O2 and He gases respectively as shown. The tube is then inverted at
angle of 30° with horizontal as shown. If pressure in CH 4 compartment was 1 atm find volumes
of compartments I, II and III. Assume volume of piston is negligible and temperature is constant.
[Use g = 10 m/s2] [6]
Q.15 1.8 g of MBrx (M is a metal) when heated with a stream of HCl gas was completely converted to
chloride MClx which weighed 1 g. Specific heat of metal is 0.11 cal/g. Calculate percent error in
molecular weight of metal bromide as determined from specific heat data. [6]
[Ans. 0.7 %]
[Sol. MBrx + xHCl MClx + xHBr
6 .4
Atomic mass of metal = = 58.2
0.11
1 .8 1
=
58.2 80 x 58.2 35.5x
0.8(58.2) = (80 – 35.5 × 1.8)x
x = 2.89 x=3
Let M be exact atomic wt. of metal
1 .8 1
=
M 80(3) M 35.5(3)
(80 35.5 1.8) 3
M= M = 60.3
0 .8
Exact mol. wt. of MBr3 = 60.3 + 240 = 300.3
Mol. wt. of MBr3 from specific heat data = 58.2 + 240 = 298.2
300.37 298.2
% error =
300.37
0.7% Ans. ]