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IMPORTANT
REACTIONS
OF ORGANIC
CHEMISTRY

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Grooves' process

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MARKOWNIKOV RULE AND
PEROXIDE EFFECT

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FINKELSTEIN REACTION

SWARTZ REACTION

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SUBSTITUTION NUCLEOPHILIC
BIMOLECULAR, SN2

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SUBSTITUTION NUCELOPHILIC
UNIMOLECULAR, SN1

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DEHYDROHALOGENATION /
Β-ELIMINATION /
1,2 - ELIMINATION

SAYTZEFF ELIMINATION
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GRIGNARD REAGENT

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WURTZ REACTION

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WURTZ- FITTIG REACTION

FITTIG REACTION

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FRIEDEL CRAFT’S REACTION

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HYDROBORATION - OXIDATION
OF ALKENES

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DOW PROCESS

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 LUCAS TEST

Alcohols are soluble in Lucas reagent but the product alkyl chloride is not. Hence, the clear
solution becomes turbid when product starts forming. Tertiary alcohols reacts fast and the
reagent turns turbid instantaneously. Secondary alcohols turn the reagent turbid slowly.
Primary alcohols turn the reagent turbid only on heating.

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ESTERIFICATION

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REIMER-TIEMANN REACTION

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KOLBE REACTION

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WILLIAMSON SYNTHESIS

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ROSENMUND REDUCTION

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STEPHEN REACTION

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ETARD REACTION

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GATTERMAN –KOCH FORMYLATION
OF ARENE

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SAPONIFICATION

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HALOFORM REACTION

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ALDOL CONDENSATION

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CROSS ALDOL CONDENSATION

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CANNIZZARO REACTION

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CROSS CANNIZZARO REACTION

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CLEMMENSEN REDUCTION

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WOLF-KISHNER REDUCTION

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MENDIUS REDUCTION

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GABRIEL PHTHALIMIDE SYNTHESIS

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 HOFMANN DEGRADATION / HOFMANN
REARRANGEMENT /
HOFMANN BROMAMIDE DEGRADATION /
HOFMANN HYPOBROMITE DEGRADATION

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HOFMANN’S EXHAUSTIVE ALKYLATION

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HOFMANN ELIMINATION

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 THANK YOU

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