Download as pdf or txt
Download as pdf or txt
You are on page 1of 15

Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - Europe

SAFETY DATA SHEET


DULUX WEATHERSHIELD TILE

SECTION 1: Identification of the substance/mixture and of the company/


undertaking
1.1. Product identifier
Product name : DULUX WEATHERSHIELD TILE

1.2. Relevant identified uses of the substance or mixture and uses advised against
Product use : Waterborne coating for exterior use.

1.3. Details of the supplier of the safety data sheet

Registered Office: Akzo Nobel India Ltd.


Geetanjali Apartment,
1st Floor, 8B Middleton Street, Kolkata -
700071

Head Office:
Akzo Nobel India Limited
9th Floor, Magnum Towers
Golf Course Ext. Rd.
Sector 58, Gurugram 122011
Haryana, India.
Telephone number : Customer Care (Toll Free) : 1800 3000 4455

e-mail address of person : customercare.india@akzonobel.com


responsible for this SDS

1.4 Emergency telephone number


Version : 8.03
Date of previous issue : 31-8-2020

Date of issue/Date of revision : 14-9-2020 Page: 1/15


Page: 2/15

DULUX WEATHERSHIELD TILE

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Skin Sens. 1, H317
Aquatic Chronic 2, H411
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
Ingredients of unknown : 0%
toxicity
Ingredients of unknown : 0%
ecotoxicity
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms :

Signal word : Warning


Hazard statements : H317 - May cause an allergic skin reaction.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements
General : P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Prevention : P262 - Do not get in eyes, on skin, or on clothing.
Response : P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national or international regulations.
Hazardous ingredients : methylisothiazolinone
C(M)IT/MIT(3:1)
Supplemental label : Not applicable.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards


Other hazards which do : None known.
not result in classification

Date of issue/Date of revision : 14-9-2020 Page: 2/15


Page: 3/15

DULUX WEATHERSHIELD TILE

SECTION 3: Composition/information on ingredients


3.2 Mixtures : Mixture
Product/ingredient name Identifiers % Regulation (EC) No. Type
1272/2008 [CLP]
diuron (ISO) EC: 206-354-4 ≤0.77 Acute Tox. 4, H302 [1]
CAS: 330-54-1 Carc. 2, H351
Index: STOT RE 2, H373
006-015-00-9 Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410 (M=10)
ammonia EC: 215-647-6 ≤0.18 Skin Corr. 1B, H314 [1]
CAS: 1336-21-6 Eye Dam. 1, H318
Index: STOT SE 3, H335
007-001-01-2 Aquatic Acute 1, H400 (M=1)
pyrithione zinc EC: 236-671-3 ≤0.17 Acute Tox. 3, H301 [1]
CAS: 13463-41-7 Acute Tox. 3, H331
Eye Dam. 1, H318
Aquatic Acute 1, H400 (M=100)
Aquatic Chronic 1, H410 (M=1)
methylisothiazolinone CAS: 2682-20-4 <0.01 Acute Tox. 3, H301 [1]
Index: self Acute Tox. 3, H311
classification Acute Tox. 2, H330
Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1A, H317
Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410 (M=1)
EUH071
ethyl acrylate EC: 205-438-8 <0.1 Flam. Liq. 2, H225 [1] [2]
CAS: 140-88-5 Acute Tox. 4, H302
Index: Acute Tox. 4, H312
607-032-00-X Acute Tox. 3, H331
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Skin Sens. 1, H317
STOT SE 3, H335
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures


4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.

Date of issue/Date of revision : 14-9-2020 Page: 3/15


Page: 4/15

DULUX WEATHERSHIELD TILE

SECTION 4: First aid measures


Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains methylisothiazolinone, C(M)IT/MIT(3:1). May produce an allergic reaction.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

See toxicological information (Section 11)

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture


Hazards from the : Fire will produce dense black smoke. Exposure to decomposition products may
substance or mixture cause a health hazard.
Hazardous combustion : Decomposition products may include the following materials: carbon monoxide,
products carbon dioxide, smoke, oxides of nitrogen.

5.3 Advice for firefighters


Special protective actions : Cool closed containers exposed to fire with water. Do not release runoff from fire to
for fire-fighters drains or watercourses.
Special protective : Appropriate breathing apparatus may be required.
equipment for fire-fighters

Date of issue/Date of revision : 14-9-2020 Page: 4/15


Page: 5/15

DULUX WEATHERSHIELD TILE

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
personnel Refer to protective measures listed in sections 7 and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.3 Methods and material : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and earth, vermiculite or diatomaceous earth and place in container for disposal
cleaning up according to local regulations (see Section 13). Preferably clean with a detergent.
Avoid using solvents.

6.4 Reference to other : See Section 1 for emergency contact information.


sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe : Prevent the creation of flammable or explosive concentrations of vapours in air and
handling avoid vapour concentrations higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
Mixture may charge electrostatically: always use earthing leads when transferring
from one container to another.
Operators should wear antistatic footwear and clothing and floors should be of the
conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this mixture. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or watercourses.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth,
ventilation is unlikely to be sufficient to control particulates and solvent vapour in all
cases. In such circumstances they should wear a compressed air-fed respirator
during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.

7.2 Conditions for safe storage, including any incompatibilities

Date of issue/Date of revision : 14-9-2020 Page: 5/15


Page: 6/15

DULUX WEATHERSHIELD TILE

SECTION 7: Handling and storage


Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight.
Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)


Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection


The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
ethyl acrylate EU OEL (Europe, 2/2017). Notes: list of indicative occupational
exposure limit values
TWA: 21 mg/m³ 8 hours.
TWA: 5 ppm 8 hours.
STEL: 42 mg/m³ 15 minutes.
STEL: 10 ppm 15 minutes.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
DNELs/DMELs
No DNELs/DMELs available.

PNECs
No PNECs available

8.2 Exposure controls


Appropriate engineering : Provide adequate ventilation. Where reasonably practicable, this should be
controls achieved by the use of local exhaust ventilation and good general extraction. If
these are not sufficient to maintain concentrations of particulates and solvent
vapours below the OEL, suitable respiratory protection must be worn.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Use safety eyewear designed to protect against splash of liquids.
Date of issue/Date of revision : 14-9-2020 Page: 6/15
Page: 7/15

DULUX WEATHERSHIELD TILE

SECTION 8: Exposure controls/personal protection


Skin protection
Hand protection
Gloves : When prolonged or frequently repeated contact may occur, a glove with a protection
class of 6 (breakthrough time >480 minutes according to EN374) is recommended.
Recommended gloves: Viton ® or Nitrile, thickness ≥ 0.38 mm.
When only brief contact is expected, a glove with protection class of 2 or higher
(breakthrough time >30 minutes according to EN374) is recommended.
Recommended gloves: Nitrile, thickness ≥ 0.12 mm.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.

The performance or effectiveness of the glove may be reduced by physical/chemical


damage and poor maintenance.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators.

OLD LEAD-BASED PAINTS:

When surfaces are to be prepared for painting, account should be taken of the age
of the property and the possibility that lead-pigmented paint might be present. There
is a possibility that ingestion or inhalation of scrapings or dust arising from the
preparation work could cause health effects. As a working rule you should assume
that this will be the case if the age of the property is pre 1960.

Where possible wet sanding or chemical stripping methods should be used with
surfaces of this type to avoid the creation of dust. When dry sanding cannot be
avoided, and effective local exhaust ventilation is not available, it is recommended
that a dust respirator is worn, that is approved for use with lead dusts, and its type
selected on the basis of the COSHH assessment, taking into account the
Workplace Exposure Limit for lead in air. Furthermore, steps should be taken to
ensure containment of the dusts created, and that all practicable measures are
taken to clean up thoroughly all deposits of dusts in and around the affected area.

Respiratory protection in case of dust or spray mist formation. (particle filter EN143
type P2) Respiratory protection in case of vapour formation. (half mask with
combination filter A2-P2 til concentrations of 0,5 Vol%.)

The current Control of Lead at Work Regulations approved code of practice should
be consulted for advice on protective clothing and personal hygiene precautions.
Care should also be taken to exclude visitors, members of the household and
especially children from the affected area, during the actual work and the
subsequent clean up operations. All scrapings, dust, etc. should be disposed of by
the professional painting contractor as Hazardous Waste.

Extra precautions will also need to be taken when burning off old lead-based paints
because fumes containing lead will be produced. It is recommended that a
respirator, approved for use with particulate fumes of lead is selected on the basis
of the COSHH assessment, taking into account the Workplace Exposure Limit for
lead in air. Similar precautions to those given above about sanding should be taken
with reference to protective clothing, disposal of scrapings and dusts, and exclusion
of other personnel and especially children from the building during actual work and
the subsequent clean up operations.

Avoid the inhalation of dust. Wear suitable face mask if dry sanding. Special
precautions should be taken during surface preparation of pre-1960s paint surfaces
over wood and metal as they may contain harmful lead.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

Date of issue/Date of revision : 14-9-2020 Page: 7/15


Page: 8/15

DULUX WEATHERSHIELD TILE

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Various: See label.
Odour : Not available.
Odour threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point and boiling : 100°C
range
Flash point : Not applicable.
Evaporation rate : Not available.
Upper/lower flammability or : Not available.
explosive limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : 1.029
Solubility(ies) : Easily soluble in the following materials: cold water.
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): 5.83 cm2/s
Explosive properties : Not available.
Oxidising properties : Not available.
9.2. Other information
Solubility in water : Not available.

SECTION 10: Stability and reactivity


10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.

10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.

10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.

Date of issue/Date of revision : 14-9-2020 Page: 8/15


Page: 9/15

DULUX WEATHERSHIELD TILE

SECTION 11: Toxicological information


11.1 Information on toxicological effects
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains methylisothiazolinone, C(M)IT/MIT(3:1). May produce an allergic reaction.


Acute toxicity
Product/ingredient name Result Species Dose Exposure
ethyl acrylate LC50 Inhalation Gas. Rat 2180 ppm 4 hours
LC50 Inhalation Gas. Rat 1414 ppm 4 hours
LD50 Dermal Rat 3049 mg/kg -
LD50 Intraperitoneal Rat 450 mg/kg -
LD50 Oral Rat 800 mg/kg -
Conclusion/Summary : Not available.
Acute toxicity estimates
Route ATE value
Oral 56818.7 mg/kg
Inhalation (vapours) 1704.6 mg/l
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
ammonia Eyes - Severe irritant Rabbit - 250 -
Micrograms
Eyes - Severe irritant Rabbit - 0.5 minutes -
1 milligrams
ethyl acrylate Eyes - Mild irritant Rabbit - 45 milligrams -
Skin - Mild irritant Rabbit - 24 hours 10 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
Conclusion/Summary : Not available.
Sensitisation
Conclusion/Summary : Not available.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)

Date of issue/Date of revision : 14-9-2020 Page: 9/15


Page: 10/15

DULUX WEATHERSHIELD TILE

SECTION 11: Toxicological information


Product/ingredient name Category Route of Target organs
exposure
ammonia Category 3 Not applicable. Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
diuron (ISO) Category 2 Not determined Not determined

Aspiration hazard
Not available.

Other information : Not available.

SECTION 12: Ecological information


12.1 Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
classified for eco-toxicological properties accordingly. See Sections 2 and 3 for details.
Product/ingredient name Result Species Exposure
diuron (ISO) Acute EC50 0.0023 mg/l Fresh water Algae - Chlorella pyrenoidosa 96 hours
Acute EC50 2.4 ppb Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 0.005 mg/l Fresh water Aquatic plants - Lemna sp. 96 hours
Acute EC50 7.6 μg/l Fresh water Aquatic plants - Lemna 72 hours
aequinoctialis
Acute EC50 8.6 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute EC50 8.6 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute EC50 8.4 ppm Fresh water Daphnia - Daphnia magna 48 hours
Acute IC50 2.41 μg/l Marine water Aquatic plants - Halodule 72 hours
uninervis
Acute IC50 5.89 μg/l Marine water Aquatic plants - Halodule 72 hours
uninervis
Acute IC50 2.47 μg/l Marine water Aquatic plants - Zostera muelleri 72 hours
Acute LC50 3044 μg/l Marine water Crustaceans - Palaemon 48 hours
serratus - Zoea
Acute LC50 1.95 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Acute LC50 3100 μg/l Fresh water Fish - Morone saxatilis 96 hours
Acute LC50 2900 μg/l Fresh water Fish - Cyprinus carpio - Fry 96 hours
Chronic EC10 0.11 μg/l Fresh water Algae - Fragilaria capucina - 96 hours
Exponential growth phase
Chronic EC10 0.76 μg/l Fresh water Algae - Fragilaria capucina ssp. 96 hours
rumpens
Chronic IC10 0.47 μg/l Marine water Aquatic plants - Halodule 72 hours
uninervis
Chronic IC10 0.7 μg/l Marine water Aquatic plants - Halodule 72 hours
uninervis
Chronic IC10 0.49 μg/l Marine water Aquatic plants - Zostera muelleri 72 hours
Chronic NOEC 0.283 μg/l Marine water Algae - Nitzschia pungens 96 hours
Chronic NOEC 0.34 μg/l Marine water Aquatic plants - Halodule 72 hours
uninervis
Chronic NOEC 0.34 μg/l Marine water Aquatic plants - Zostera muelleri 72 hours
Chronic NOEC 26.4 ppb Fish - Pimephales promelas 60 days
Chronic NOEC 26.4 ppb Fish - Pimephales promelas 60 days
Chronic NOEC 26.4 ppb Fish - Pimephales promelas 60 days
Chronic NOEC 33.4 μg/l Fresh water Fish - Pimephales promelas - 63 days
Embryo
Date of issue/Date of revision : 14-9-2020 Page: 10/15
Page: 11/15

DULUX WEATHERSHIELD TILE

SECTION 12: Ecological information


ammonia Acute LC50 37 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours
pyrithione zinc Acute EC50 0.51 μg/l Marine water Algae - Thalassiosira 96 hours
pseudonana
Acute EC50 8.25 ppb Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2.68 ppb Fresh water Fish - Pimephales promelas 96 hours
Chronic EC10 0.36 μg/l Marine water Algae - Thalassiosira 96 hours
pseudonana
Chronic NOEC 2.7 ppb Fresh water Daphnia - Daphnia magna 21 days
methylisothiazolinone Acute EC50 0.24 mg/l Daphnia 48 hours
Acute LC50 0.18 mg/l Fish 96 hours
Acute LC50 12.4 mg/l Fish - Lepomis Macrochirus 96 hours
Acute LC50 6 mg/l Fish - Oncorhynchus Mykiss 96 hours
ethyl acrylate Acute LC50 4784 μg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 2500 μg/l Fresh water Fish - Pimephales promelas 96 hours
Conclusion/Summary : Not available.

12.2 Persistence and degradability


Conclusion/Summary : Not available.

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
diuron (ISO) 2.84 5.2 low
pyrithione zinc 0.9 11 low
ethyl acrylate 1.18 2.072 low

12.4 Mobility in soil


Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment


PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no
longer apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
Packaging

Date of issue/Date of revision : 14-9-2020 Page: 11/15


Page: 12/15

DULUX WEATHERSHIELD TILE

SECTION 13: Disposal considerations


Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from
the relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or
national legal provisions.
Type of packaging European waste catalogue (EWC)
CEPE Paint Guidelines 15 01 10* packaging containing residues of or contaminated by
hazardous substances
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information


Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
ADR IMDG

14.1 UN number UN3082 UN3082

14.2 UN proper ENVIRONMENTALLY HAZARDOUS ENVIRONMENTALLY HAZARDOUS


shipping name SUBSTANCE, LIQUID, N.O.S. (diuron (ISO)) SUBSTANCE, LIQUID, N.O.S. (diuron (ISO)).
Marine pollutant (diuron (ISO))
14.3 Transport
hazard class(es)
Class 9 9

Subsidiary class - -

14.4 Packing group III III

14.5
Environmental
hazards
Marine pollutant Yes. Yes.

Marine pollutant diuron (ISO)


substances
14.6 Special Transport within user’s premises: always
precautions for transport in closed containers that are upright
user and secure. Ensure that persons transporting
the product know what to do in the event of an
accident or spillage.

HI/Kemler number 90

Emergency F-A, S-F


schedules (EmS)

14.7 Transport in bulk : Not applicable.


according to Annex II of
MARPOL and the IBC Code

Date of issue/Date of revision : 14-9-2020 Page: 12/15


Page: 13/15

DULUX WEATHERSHIELD TILE

Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
Additional This product is not regulated as a dangerous This product is not regulated as a dangerous
information good when transported in sizes of ≤5 L or ≤5 kg, good when transported in sizes of ≤5 L or ≤5 kg,
provided the packagings meet the general provided the packagings meet the general
provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1. provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.
1.8. 1.8.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed, or the component present is below its threshold.
Substances of very high concern
None of the components are listed, or the component present is below its threshold.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
VOC for Ready-for-Use : Not applicable.
Mixture
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.

Seveso Directive
This product may add to the calculation for determining whether a site is within the scope of the Seveso Directive on
major accident hazards.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)


Not listed.

Stockholm Convention on Persistent Organic Pollutants


Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)


Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

15.2 Chemical safety : No Chemical Safety Assessment has been carried out.
assessment

Date of issue/Date of revision : 14-9-2020 Page: 13/15


Page: 14/15

DULUX WEATHERSHIELD TILE

SECTION 16: Other information


CEPE code : 1
Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Skin Sens. 1, H317 Calculation method
Aquatic Chronic 2, H411 Calculation method
Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Acute Tox. 2, H330 ACUTE TOXICITY (inhalation) - Category 2
Acute Tox. 3, H301 ACUTE TOXICITY (oral) - Category 3
Acute Tox. 3, H311 ACUTE TOXICITY (dermal) - Category 3
Acute Tox. 3, H331 ACUTE TOXICITY (inhalation) - Category 3
Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4
Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4
Aquatic Acute 1, H400 SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 1
Aquatic Chronic 2, H411 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 2
Carc. 2, H351 CARCINOGENICITY - Category 2
EUH071 Corrosive to the respiratory tract.
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2
Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317 SKIN SENSITISATION - Category 1
Skin Sens. 1A, H317 SKIN SENSITISATION - Category 1A
STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - Category 2
STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Respiratory tract irritation) - Category 3
Date of printing : 14-9-2020

Date of issue/Date of revision : 14-9-2020 Page: 14/15


Page: 15/15

DULUX WEATHERSHIELD TILE

SECTION 16: Other information


Date of issue/ Date of : 14-9-2020
revision
Date of previous issue : 31-8-2020
Version : 8.03
Notice to reader
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the
present state of our knowledge and on current laws: any person using the product for any purpose other than
that specifically recommended in the technical data sheet without first obtaining written confirmation from us
as to the suitability of the product for the intended purpose does so at his own risk. It is always the
responsibility of the user to take all necessary steps to fulfill the demands set out in the local rules and
legislation. Always read the Material Data Sheet and the Technical Data Sheet for this product if available. All
advice we give or any statement made about the product by us (whether in this data sheet or otherwise) is
correct to the best of our knowledge but we have no control over the quality or the condition of the substrate
or the many factors affecting the use and application of the product. Therefore, unless we specifically agree
in writing otherwise, we do not accept any liability whatsoever for the performance of the product or for any
loss or damage arising out of the use of the product. All products supplied and technical advice given are
subject to our standard terms and conditions of sale. You should request a copy of this document and review
it carefully. The information contained in this data sheet is subject to modification from time to time in the
light of experience and our policy of continuous development. It is the user's responsibility to verify that this
data sheet is current prior to using the product.

Brand names mentioned in this data sheet are trademarks of or are licensed to AkzoNobel.

Head Office
AkzoNobel Decorative Coatings BV, Christian Neefestraat 2, 1077 WW Amsterdam, The Netherlands

Date of issue/Date of revision : 14-9-2020 Page: 15/15

You might also like