section are to be answered on ths page and Deleting/overuiting isnot allowed. Do not use lead pent. Time allowed: 25 Minutes Fill the relevant bubble ag No, of atoms of oxygen present in 500g of [Version No. | {-ROUNUMBER | a o|goja I L_| @@eoo @®2OOOQD DO0O0@e @®O000 DPOeoOe @®eOOOO@ 2 ® 0 @290000 Answer Sheet No. ®®Oo0 ®©O2O2O000 ®OO®O @2G02O8086 Sign. of Candidate ®©©60® ®®0G0OO0 @e@ooo @ (OMOMOMEG) © ®® Sign. of Invigilator ©2000 ® ®® | seaion = A i conputon: Al pats of ie CHEMISTRY HSSC-1 be¢/-?t/ou hhanded over to the Centre Superintendent. SECTION — A (Marks 17) ee en et estan fet st each question: wihhtvernEsseeLibrs an anode then it will produce X-rays of: 1 (CIO, 16 atm, Ke29, om98.5, 0-14), 73x10" © 361x10" © 24x10" © 35810 ‘Magnesium reacts with Sulphur to produce a ‘MgS.. How many grams of MgS can be 2. made from 24g of Mg with excess of ) 35¢ © 58 © 83g O 2s Sulphur by the reaction Mg-+S > MgS a, Which of the folowing is NOT 9 stale pressure ©) Volume ©) Temperature) Work If frequency of Photon is 4x10" He. then its . oe 7 x ff § Spey uttbe: (heee26e10™ Joy 26Sx10"F © 65x10" CO 265x10?s © 265x10"') ‘According to Moseley’s law, when metals = . 5, having arg atomic number will be used a8 C) 1278 ay na © Senet ath © Lowenerey ‘According to Le-chateliers Principle, in an exothermic reaction, what should be done to 3. Temperature of sysiem to obtain maximum ©) KeetLow — C) Kept High ©) Kept Same product at equilibrium? According to Graham's law which one has 410, highest rate of difusion? (Mt. Wt, S=32, CQ) SO, O 50, Ons 016, H=1) Page 1 of 2 «Total No, of Sigma and Pi Bonds in Etyne -y 2 Sigma and'3 ¢ 3 Sigma and? > § Sigma and 3 8 Sigma ands CH =CH ae: Pibonds © Pibonds Pibonds Pi bonds Icentty the species with maximum bond . ee Pe om, OM”, O #0 O#S | 8. Intead storage battery electrolyte is: O w%Hc! © 30%HNO, © 30% © 30% HBr Temperature O nas no effet O schEtectric current can pass through grepite in = 11. one direction but nt through other direction C Alloropy ©) Anisotropy ©) Isotropy a oe of exysal, such a property is called: 12. Which one is conductor but not mallable? tron © Graphite © siver © Copper Which of the following Concentration Units » Pr 33. Goes NOT depends on Temperature? Molafiy ©) Melatty ow ow Which of the following will contain lowest ™\ vapor pressure at 50°C ? Ot OW OMA Ge! 15, Asolution of HCI having pH =4 willbe: ©) 04M © 40M © 2.0001 =O 0.00044 K,=0.04 at 723K for following reaction PClyeq) =? PClyig) + Cla i mah el 0.04 237 0.64 0.40 K, ofthe reacton vil be: ° ° ° ° where (R= 0.082 atm dn? mol” K") Ina mixture containing 44g each of CO,, S0;, SO, and Cl, gases, which of the 17, following will have highest _partial ©) CO, 50, 50, ) Ch, pressure according to Dalton’s Law? ° ° ° ° (where molar masses COz=44, SO2-64, 16, ‘$0s=80, Che71) ‘SUPPLEMENTARY TABLE awomieno [i] 2,3 747s ]e])7] 8/9 |] a]2] 5] "| 8] e) 7] Bw] | Symbol wiwe|ufel|ea|cl{njolrlne|mime)a}s |r| s|ala| x |o waswo 1a | 4] 7 | 9 | a2 | 2 | o4 | as | a9 | 20 | 23 | 26 | 7 | 2s | 23 | 2 [355] ao | 39 | wo Has 2209-7001 (HA) — ROLL NUMBER | | Page 2 of 2ae, SERS CHEMISTRY HSSC-I 2b Time allowed: 2:35 Hours Total Marks Sections B and C: 68 NOTE! Answer any FOURTEEN parts from Section ‘B” and attempts any TWO questions from Section ‘C’ on the separately provided answer book. Write your answers neatly and legibly. SECTION — B (Marks 42 Q.2 Answer any FOURTEEN parts from the following. All parts carry equal marks. (Why actual yield is always less than theoretical yield? Write three arguments. (i) For CH,COOH +20, —>2C0, 420,09 AH =-875KI (mol Deduce the value of standard enthalpy of formation of acetic acid. (ii) How X-rays are produced? Discuss according to Moseley's aw (iv) By using formula of radius derived by Bohr, how it can be proved that size of ‘eis larger than that of $1? p= Sem () Write three defects of valence bond theory? (vi) Give two causes for deviation of gases from ideality. (vil) Write three differences between Sigma and Pi bond. (vii) What is meant by molar heat of fusion and molar neat of vaporization? Why AH, is always greater than AH, ? (ix) Bolling point increases continuously in hydrides of group IV from CH, to Sn#1, with the increase in atomic size of central atom, Which forces are responsible for this regular change and why? (x) Describe briefly Lattice energy in two ways with suitable example, (xi) Briefly explain with chemical equation, why: ().NH,Cl is acidic (i) NaCl is neutral (il) CH,COONa is basic (xi) Consider the following reaction H, + Br, == *2HBr if concentrations of H; , Br, and HBr are 0.5M 03M and 0.1M respectively at equilibrium then calculate value of K, (xii) How relative lowring of vapour pressure helps to determine the molar mass of non-volatile and non- AP electrolyte solute in a dilute solution? Relationship of relative lowring of V.P is > = (xiv) What is freezing point of a solution containing 30g of Sucrose C,,H ,.0,, dissolved in 50g of Water? (K ay = 186) (xv) Differentiate between AE and AH . Under what conditions AH and Az will be equal? (ivi) Briefly describe the construction and working of standard hydrogen electron (SHE) (ici) What is galvanizing? Why is tt called sacrificial corrosion? (evi) Write thermochemical equation for the following (2) Standard enthalpy of formation of CH1,COCH, is -248.14/ / mol (b) Standard enthalpy of combustion of Cy/iy, 1S ~3512KI/ mol (c) Standard enthalpy of atomization of Cl, is +121K//mot (xix) What is bond energy? Why bond energy of HF is greater than that of H-I? (1) Enlist two factors that affect London Dispersion Forces. Why London Dispersion Forces are stronger in Radon (Rn) than Helium ( He) in noble gases? ‘SECTION - C (Marks 26) Note: Attempt any TWO questions. All questions carry equal marks. (2x 13 = 26) @.3 a. Howcatalyst increases the rate of reaction? Explain its action with suitable example along with the graph. Describe the types of Catalysis, (07) b. Derive Vander Walls equation for real gases and also derive the units of 'a’ an °6' (08) Q.4 a Balance the following redox equations with given methods: (08) () P+HNO,+H,0—>H,PO, + NO Oxidation number method (i) C03 ¥Cr —ser” +h, lon electron method (in acidic media) b. Explain buffer, its types and composition and butfer action with one suitable example, (07) Q.5 a Explain the quantitative aspects of freezing point depression and prove that 7, is inversely proportional to molar mass of solute. 07) b. (i) Asmall piece of 4/ metal having a volume of 2.50cm’ is reacted with excess of HCI . Whatis the weight of 1, liberated? The density of 4! is 270m". 24l +6HCI—924ICI, +341, (08) (i) Ina particular experiment 0.3 of H, gas was obtained. Calculate percentage yield of ths reaction. SUPPLEMENTARY TABLE aomeno TI] 273 [as )e] 7] ae, s w|i) a) po smb | Hie | ti | Be | B | C | N F | xe | Na al Liesswo at | s |p to fn | | | |v n — 1a 2208 (Ha) — Page oft