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Literature Review
Literature Review
LITERATURE REVIEW
2.1 INTRODUCTION
In this chapter, the results of extensive search of published papers available and
which are relevant to the objectives of this work can be conveniently categorized
General reviews
Naher et al. (2004) produced Al-SiC composites using the liquid and semi-solid stir-
casting methods. A significant part of the work consists of the design, construction
processing method. Stainless steel was chosen as the main crucible and stirrer
resistance heated furnace chamber. A linear actuator was integrated to the rig to
allow the crucible to be quickly extracted from the furnace for quenching.
Stirring speed ranging from 200 to 500 rpm and different shear periods were
investigated. Ten percentage volumes of 30 µm sized SiC particles were used. The
main research challenge was to obtain a uniform distribution of SiC in the aluminium
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matrix. In the compo casting experiments, it was found that the uniformity of SiC
particles in the aluminium matrix were dependent on shear rate, shear period, cooling
rate and volume fraction of primary solid. The quick quench compo caster system
was successful in producing cast MMC samples. The use of clean heat-treated SiC
particles and the quick quench method was sufficient to produce homogeneous
composites. Castings from the liquidus condition were found to result in poor
incorporation of SiC particles whereas castings from the semi-solid condition were
solidification, after cesation of mixing, was found to improve the uniformity of the
included microstructure recording and image analysis thereof. The matrix phase size,
morphology and distribution of SiC particles throughout the stir castings were
examined.
Rajan et al. (2007) studied the effect of three different stir casting routes on the
structure and properties of fine fly ash particles reinforced Al-7Si-0.35Mg alloy
and modified compo- casting followed by squeeze casting routes evaluated, the latter
has resulted in well-dispersed and relatively agglomerate and porosity-free fly ash
particle-dispersed composites. Interfacial reactions between the fly ash particle and
the matrix leading to the formation of MgAl2O4 spinel and iron inter-metallics are
The study reported by Reddy et al. (2009) described an effort at enhancing the wear
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condition from liquidus temperature. The study involved the use of pin-on-flat wear
system to understand the wear features of the alloy under investigation tested over a
range of normal load (10 - 40 N) at constant average sliding speed (0.2 m/s) against
cast iron and stainless steel counter surface. The finding of their research indicated
the amount of the Al (6063) scrap billets and silicon carbide required to produce 3, 6,
9 and 12 vol.% SiC reinforcements in the composite. They reported that the borax
which serves as a wetting agent was dehydrated by heating at 250 °C for 20 minutes
after which it was mixed with specified amounts of SiC in a ratio of 1:2. They hinted
that the Al (6063) billets were charged into the furnace and melting was allowed to
temperature) was attained. The melt was then allowed to cool to 600°C (slightly
below the liquidus temperature) to a semi-solid state. They pointed out that at this
stage, the silicon carbide and dehydrated borax mixture was added into the melt and
manual stirring of the slurry was performed for 20 minutes. An external temperature
probe was utilized in all cases to monitor the melt temperature. After manual stirring,
the composite slurry was reheated and maintained at a temperature of 750°C ± 10°C
(above the liquidus temperature) and then mechanical stirring was performed. The
stirring operation was performed for 20 minutes at an average stirring rate of 300
rpm. Casting was then performed on prepared sand moulds at a pouring temperature
of 720°C.
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Recently, Gopalakrishnan & Murugan (2012) attributed the primary attraction of
matrix reinforced with titanium carbide (Al/TiCp) was reported by the authors to
have a good potential. In composite fabrication, the main challenge, as noted by the
authors is to produce this composite in a cost effective way to meet the above
requirements. In the study, Al/TiCp castings with different volume fraction of TiC
specific strength of the composite has increased with higher % of TiC addition. Dry
sliding wear behaviour of AMC was analyzed with the help of a pin-on-disc wear
and friction monitor. The presented analyses revealed the improved specific strength
composites with hard phase-reinforcements such as SiC, which are being used to
produce sheets for engineering constructions due to their light-weight combined with
good-strength and wear resistance. In this work, the hot rolling behaviour of stir-cast
composites having the matrices as Al 6061 and Al 6082 alloys and fine SiCp
particulates with size of 15 μm and 8 μm and volume fraction up to 30% was studied.
It was reported that for composite casting, optimum casting procedures and materials
pretreatment was carried out for successful insertion of particles into the melt, better
at a strain rate of 1 s - 1 rate for each step, using intermediate heat treatment at 450°C
improved with improvement in the casting quality. Successive hot rolling resulted in
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decreasing voids and the agglomeration clusters and hence, enhanced mechanical
properties were achieved. The flow behaviour under rolling of Al-particulate metal
MATRIX
2.3.1 Al/SiC
Haizhi Ye (2003) discussed Al-Si binary alloy system and established that silicon
reduces the thermal expansion coefficient. Al-Si alloys usually have casting defects
such as porosity and inclusion, which can greatly degrade the mechanical properties
of the materials. Porosity cannot sustain external load and thus can lead to micro
Ortega-Celaya et al. (2007) concluded that Al/SiCp MMCs have significant problems
from the formation of oxide layer on the surface of Al melt. Undesirable reactions at
the Al/SiC interface are also experienced. It is difficult to avoid the formation of
2.3.2 Al/TiB2
In this in-situ reactive casting technique, the reinforcement phase i.e., TiB2 forms via
chemical reaction and subsequently disperse in the molten alloy. Al-TiB2 composite
Ti and B is highly exothermic in nature and the heat generated helps to accelerate the
aluminium.
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Zhang et al. (2001) reported that the in-situ formed reinforcement in the melt is free
of surface oxide and present in fine condition. The selection of TiB2 as the alternative
thermal expansion is (8.6 X 10-6 °C-1). The synthesized TiB2 is in block shape and the
Tjong et al. (2005) used aluminium, TiO2 and B2O3 powders as starting materials. Al
with in-situ formed TiB2 and Al2O3 submicron particles was fabricated. The TiB2 and
Al2O3 particles of 0.3-1.2 µm, was distributed uniformly in the aluminium matrices
whereas submicron particles of TiB2 and Al2O3 exhibit high yield strength.
Hongzhan Yi et al. (2006) explained the method of reaction processing used to obtain
the in-situ formed TiB2 particle reinforced Al-Si alloy composites. The matrix alloy
used in this study was Al and the reactive salts used were K2TiF6 and KBF4. After the
casting specimens were made, X-ray diffraction analysis was carried out which
confirms the presence of TiB2 in the cast. The TiB2 particles synthesized in-situ in
the matrix is cubic and spherical in form, with sizes ranging from 0.2 to 0.8 µm with
an average size of approximate 0.5 µm, which is one to two orders of magnitude
lower than that of ex-situ particles used in composites. It can also be seen that the
cast Al 6061 alloy with 12% by weight TiB2 and describe that aluminium containing
which takes place between advancing solidification front and the particles. Such
interactions affect the front morphology and the particle solidification as well. The
solidification front pushes or engulfs the particles. Due to this reason the particles
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can be found at the grain boundaries, the inter dentritic regions, and within the
uniform in size and irregularly shaped are dispersed throughout the aluminium alloy
matrix.
Cup et al. (2000) studied the in-situ synthesis of metal matrix composites having the
reinforcement treatment stages and plays an important role in the enhancement of the
Tee et al. (2001) formed in-situ, ceramic reinforcing particles from the chemical
contamination and disperse more uniformly within the matrices of MMCs, leading to
stronger particle matrix bonding. Such unique properties make in-situ MMCs possess
Varma et al. (2001) explain the ex-situ MMCs are still not economically favorable
due to the high cost of reinforcing particles. Moreover, ex-situ ceramic particulates
generally have a size ranging from a few microns to several hundred microns. Large
ceramic particulates often act as micro concentrators of stress and give rise to particle
Mandal et al. (2004) identified the difficulties involved in the ex-situ Particulate
between the matrix and reinforcement, etc., which have led to the development of
somewhat limited and the particle size is much coarser with non-uniform
distribution. These features would lead to fragmentation of the particles and de-
Jiang et al. (2006) locally fabricated the steel matrix composites reinforced with in-
two types of TiB2 and TiC particulates concerning particulate size and distribution
and white Fe-rich regions. Moreover, the results show that the hardness and wear
resistance of the composites are higher than those of the steel matrix.
Montoya Davila et al. (2007) observed the effect of particle size and distribution on
as well as on the micro hardness and fracture toughness (KIC) of particulate silicon
carbide (SiCp). Preforms with 0.6 bimodal and trimodal distribution were infiltrated
with the alloy Al-15.52 Mg-13.62 Si (wt.%) in argon followed by nitrogen at 1100
°C for 60 min. Results show that density behaves linearly with increase in particle-
size distribution whilst superficial hardness, micro hardness and fracture toughness
exhibit all a parabolic behavior. Superficial hardness behavior was explained by the
impingement. Due to the highly covalent nature of SiC, the parabolic response shown
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by microhardness and KIC could be attributed to a dislocation mechanism as in
strain-hardening.
further aging the composite at 250°C was studied. In-situ formed micron-sized
alumina particles were present in the Al (Cu) matrix of the un-aged composite, while
additional nanometer-sized Al2Cu rods were obtained in the matrix of the aged
composite. Both hardness and bending strength were enhanced after the composite
was aged. In the bending test, the sample was plastically deformed before fracture.
Micro-structural analysis revealed that the size of dimples found in the fracture
mouth of the un-aged composite was micron-sized, and that in the aged composite
was much smaller. It was evident that when the composite was subjected to stress,
micron-sized alumina particles were responsible for the formation of cracks in the
un-aged sample, while in the aged sample, Al2Cu nano rods were the dominant
Hajjari & Divandari (2008) worked on 2024 aluminium alloy, conventionally used
for wrought products. The author stated that if this alloy was subjected to cast
microstructure due to its long solidification range. Therefore, in order to see the
type of alloy, the effect of squeeze pressure on the microstructure and tensile
properties of the alloy was investigated in this research. The results showed that
squeeze casting caused the refinement of the microstructure and reduction in the
DAS of the cast structure possibly due to increasing the cooling rate. Increasing the
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pressures decreased the percentage of porosity and increased the density of the cast
alloy. The ultimate tensile strengths of the squeezed cast samples improved when the
Wahab et al. (2009) carried out the preparation and characterization of aluminium
Metal Matrix Composites reinforced with aluminium nitride. A graphite crucible and
a stainless steel permanent mold were used to prepare the samples. An optimum
stirring speed was determined for a fixed stirring time before cast in the permanent
optical microscopy. An interesting observation was that the reinforcing particles were
clearly shown at the edges and around grains of silicon primary, silicon needles and
hardness test was 44 Hv for Al-Si matrix and increased to 89 Hv for an Al-Si
composite reinforced with 5% wt. % AlN powder. The higher values in hardness
indicated that the AlN particles contributed to the increase of hardness of the matrix.
aluminium alloy 6061-T6 to determine the effect of artificial ageing on the hardness
treatment, quenching and artificial ageing process. The experimental study is focused
on artificial ageing carried between 175°C to 420°C at different time periods. The
Vickers hardness test is to evaluate the hardness of aluminium alloy 6061-T6 before
and after ageing process. The optimum ageing time and temperature is determined at
the end of this experiment to obtain reduction in energy and total cost. The study
leads to the conclusion that the optimum aged was achieved between 175°C to 195°C
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with 2 to 6 hours of ageing time. The contribution of short time ageing is comparable
Bai& Zhao (2010) studied the contribution, and the effect of the micro-structural
to slow shot die-cast A356 alloy die casting in the as-cast and T6 heat-treated
conditions. The results show that inferior tensile properties of the casting partially-
squeezed part were caused by the Al cells with fragment, rosette, angular and
globular shapes, while finer dendrites with smaller secondary dendrite arm spacing
and more rounded silicon particles corresponded to higher tensile properties. After
silicon phase.
Adeosun et al. (2011) established the processes that were utilized to improve the
tensile strength and hardness of aluminium alloys, some of which include elemental
and particle additions, since work hardening cannot be used to improve strength and
hardness of 1xxx wrought aluminium alloys. This work examined the possibility of
introducing secondary processing of transverse rolling after the initial primary rolling
to strengthen and hardened wrought aluminium alloy. The effects of transverse and
longitudinal rolling on the tensile strength and hardness of AA1230 aluminium alloy
worked at ambient temperature (32 °C) have been studied. Samples were rolled in
passes in two-high irreversible mill. The samples rolled in transverse direction have
hardness and tensile strength which are superior to samples rolled in the longitudinal
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direction. The resultant crystals in transverse directions were elongated in the rolling
Raman & Mishra (2012) modified the mechanical properties of Al based alloy by
varying the amounts of different constituents in Al alloy. The process through sand
casting and ferrous casting is done on different Al based alloys [Al-6Si-4Cu, Al-
different types of casting. Each Al-based alloy out of two is cast by different
processes (sand casting and ferrous casting) and selected one-by-one from each phase
alloys composition from different casting processes, researcher further evaluated the
Guo et al. (2012) investigated the laser welding of AA1100-16 vol.% B4C metal-
matrix composites. It was found that most B4C particles were decomposed and that
needle-like AlB2 and Al3BC phases were substantially formed during the welding
process without filler. Consequently, a joint efficiency of 63% was obtained. They
pointed out that the addition of Ti with 150 μm thick foil increased the joint
efficiency to 75% due to the decrease of needle-like phase formations. On the other
hand, the addition of Ti with filler wire did not show significant tensile property
weld zone. The fracture surfaces of laser welded joints were investigated to
Beffel et al. (1986) make use of a typical, state of the art finite element application to
examine the investment casting processes and their work reveals the extent of
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information available from a typical FEM-based solidification simulator. It also
Kannan et al. (1990) acknowledged that the present thrust of solidification modelling
research lays in the enhancement of heat transfer and fluid flow techniques towards
the goal of solving micro structural modelling problems. The current state of the art,
which takes the form of 3D finite element and finite difference codes, fully coupled
with a computational fluid dynamics simulation. Ghosh et al. (1994) explained that
since to a large extent leftover the unidentified about the process of nucleation in
these materials, some level of ambiguity exists in their model. Brown and Spittle et
al. (1989) spot out that while finite element and finite difference analysis methods
physical model of the solidification process upon which to support their analysis.
Ismar, H. et al. (2000) described FEM is one of the most powerful available tool to
the mechanical engineers in general, manufacturers in particular. FEM codes are used
to solve range of problems in various field viz., civil engineering, fluid dynamics etc.
These codes can be incorporated in the deformation of MMCs at both macro and
micro scale.
Guo, Y.M. et al. (2001) has reported modeling task involves sketching the cross
section of billet and developing a parametric modeling using package such as PRO/E,
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2.6.1 ProCAST Software
and fluid flow package developed to perform numerical simulation of molten metal
flow and solidification phenomena in various casting processes, primarily die casting
(gravity, low pressure and high pressure die casting) and sand casting. It is
particularly helpful for foundry applications to visualize and predict the casting
Hu-Hong jun et al. (2006) described ProCAST extensively to create sand casting and
die casting models for the simulation of molten metal flow (mold filling) and
solidification (crystallization in the process of cooling). The cast and mold design of
conduct the sand casting process simulation. Sand casting is the casting process that
Mintuan et al. (2006) reported that with the help of ProCAST system, casting
castings with respect to flow field, temperature field and stress field in the formation
Viswanathan et al. (2007) described the extended utility of ProCAST software for
avoiding shrinkage, improving cast metal yield, optimizing the gating system,
optimizing mold filling, and finding the thermal stresses, as means to maintain the
casting quality. Moreira Jose et al. (2004) reported that successful solidification
modeling of steel sand castings using ProCAST which resulted reducing the
Zoqui et al. (2002) did significant research on as rheocast A356 structure aluminium
for heat-treatment at 580 °C. In this paper, they reported the higher the holding time,
the higher the grain and globule size produced. There is a relationship between grain
and globule size for those structures and this relationship is affected by heat-
treatment.
E.J. Zoqui et al. (2004) studied the effect of macrostructure and microstructure of the
A356 alloy in the semi-solid state and they reported that increasing the holding time,
increases the globularisation of the structure, and the RQI reflected this change on
the morphology very well. The best globularisation achieved was for long periods of
time, and they concluded 600 s for all raw materials tested, but the best thixo forming
behaviour, i.e., the lowest viscosity was achieved for shorter periods of time (around
210 s). Short periods of time were enough to produce suitable raw material for the
J. Wang et al. (2010) reported about the Microstructural evolution of AlSi7Mg alloys
the pouring temperature is one of the most effective ways to promote the formation
an even greater extent and consequently the globular structure is apparent at the
pouring temperature of 630 °C. The formation of the globular structure could
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encourage the utilization of the superheated + EMS in the preparation of SSM slurry
for rheoforming.
Surappa (2003) studied Aluminium Matrix Composites (AMCs) referred to the class
Presently several grades of AMCs are manufactured by different routes. Further, they
noted that three decades of intensive research had provided a wealth of new scientific
addition, they stated that AMCs had been utilised in high-tech structural and
management areas, as well as in sports and recreation. The authors further stated that
research on particle-reinforced cast AMCs took root in India during the 1970’s,
attained industrial maturity in the developed world and is currently in the process of
applications.
Rahman et al. (2012) presented the necessity for the design of efficient load bearing
materials together with superior functional properties, high strength and stiffness that
can be tailored for specific applications where monolithic materials and conventional
alloys cannot be used, has given impetus to the development of modern composites.
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They noted that the development of composite technology spanning several decades
has given rise to an exotic class of materials whose characteristics could be tailored
conventional tools. The paper deals with the charting of a strategy for the application
of aluminium metal matrix composites citing the specific reasons for selecting the
discussion and logical choice of a particular material system that has gained wide
acceptance. With this knowledge as the basis, the authors noted that the materials
engineer is well placed to create innovative designs that are having vast
improvements over its predecessor designs and achieve not only fast effective gains,
Al/fly ash and Al/TiC MMCs, fabricated by stir casting technique have better
wear properties.
Al/TiB2 MMCs, fabricated in-situ have hardness and wear resistance higher
commercial software.
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