‘foros Tipton Corp. MATERIAL SAFETY DATA SHEET Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL . Latest revision date: April 7, 2008 NaGO01 1.0 IDENTIFI F THE PI TION AND. NY PRODUCT NAME: (CERAMIC BALL DIFFINITION + Ceramie compounds, which mainly composes Aluminium oxide and Silicon dioxide. PORPOSE OF USE + Ceramic filler fo catalyst bed support applications used in catalyst reaction towers of oil refinery and petrochemical. SUPPLIER: TIPTON CORP. 3-19-21 TOYODA, MINAMI-KU, NAGOYA 457-8566 JAPAN, TELEPHONE: +81 (0)52 692 6666 FAX: +81 (0)52 692 9445 INFORMATION THROUGH: _TIPTON CORP. 3.25-1 ODAKARA, TOBISHIMA-MURA, AMA-GUN, ‘AICHT 490-1438 JAPAN QUALITY ASSURANCE SECTION TELEPHONE: +81 (0)567 56 7503 FAX: +81 (0)S67 56 7513 EMERGENCY TELEPHONE: +81 (0)567 567503 2.0 [CATION GH classification Physical hazards EXPLOSIVES : Not applicable FLAMMABLE GAS : Not applicable FLAMMABLE AEROSL = Not applicable OXDIZING GASES : Not applicable GASES UNDER PRESSURE + Not applicable FLAMMABLE LIQUIDS + Not applicable FLAMMABLE SOLIDS Out of category SELF-REACTIVE SUBSTANCE: Not applicable ‘AND MIXTURES PYROPHORIC LIQUIDS + Not applicable PYROPHORIC SOLIDS : Out of category SELF-HEATING — SUBSTANCE : Out of category AND MIXTURES ‘SUBSTANCES AND MIXTURES : Out of category WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES Page 1 of 8oon Tipton Corp. MATERIAL SAFETY DATA SHEET Original issue date = December 9, 2002 Latest revision date: April 7, 2008 CATALYSIS SUPPORT CERAMIC BALL OXDIZING LIQUIDS +: Not applicable OXDIZING SOLIDS Out of category ORGANIC PEROXIDES Not applicable CORROSIVE TO METALS +: Unclassified ‘Health hazards ACUTE TOXICITY (ORAL) ACUTE TOXICITY (DERMAL) ACUTE TOXICITY (GASES) ACUTE TOXICITY (VAPORS) ACUTE TOXICITY (DUST AND : Unclassified MISTS) ‘SKIN CORROSION /IRRITATION — : Not applicable SERIOUS EYE DAMAGE / EYE : Unclassified IRRITATION ‘RESPRATORY +: Unclassified (SKIN SENSIBILIZATION Unclassified GERM CELL MUTAGENICITY —_: Unclassified CARCINOGENICITY Out of category REPRODUCTIVE TOXICITY + Uncategorized SPECIFIC TARGET ORGAN : Category 3 (TRANSIENT TARGET ORGAN EFFECTS) SYSTEMIC TOXICITY -SINGLE _EXPOSURE- SPECIFIC TARGET ORGAN : Category 1 (LUNGS) SYSTEMIC TOXICITY = - REPEATED EXPOSURE- ASPIRATION HAZARD +: Unclassified Environmental hazards ACUTE AQUATIC TOXICITY + Unclassified CHRONIC AQUATIC TOXICITY —_: Unclassified Page 2 of 8oron Tipton Corp. MATERIAL SAFETY DATA SHEET Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL ision date + April 7,2008 = @ WARNING HAZARD AND —_ TOXICITY: Risk of respiratory INFORMATION + Lung damage caused by repeated exposure or long-time exposure CAUTION ‘SAFTY MEASURE +: Do not drink, eat and smoke when the product is used. + The product must be used outside or in well-ventilated area. ‘not inhale dust and fine particles of the product. fashing hands must be done after handle it. EMERGENCY MEASURE —_: Move the victim to fresh air and get hinv/her take rest in easy breathing position in case of inhalation, + Get medical attention in cause of feeling illness STORAGE ‘Keep the product well sealed with case in well-ventilated area, DISPOSAL + Get the contaminant or contaminated case neutralized by licensed waste disposal contractor in accordance with the related rules and regulations. Countries and Area Information None 3.0 TION ON IN¢ COMPOSITION: ‘Aluminum oxide Silicon dioxide Titanium oxide (Abs) (sion) (Tid CONTAINED AMOUNT 80% Max 13% Min 0.5% Max CAS NUMBER 7631-86-9 1344-28-1 13463-67-7, IMPURE SUBSTANCE OR STABILIZING ADDITIVE :No information available ‘CONTRIBUTED TO CLASSFICATION CONCENTRATION OR CONCENTRATION RANGE No information available 4.0 FIRST-AID MEASURES INHALATION: Move the victim to fresh air and get medical attention immediately. INGESTION: Give the victim plenty of water and induce the victim to vomit. Get ‘medical attention immediately. EYE CONTACT: Flush eyes immediately with water. Get medical attention if necessary. ‘SKIN CONTACT: Flush with water. Predictable acute symptoms or late symptoms INHALATION: + Cough EYE CONTACT: Redness Page 3 of 8howe Tipton Corp. MATERIAL SAFETY DATA SHEET Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL ee eee PROTECTIVE EQUIPMENT FOR FIRST-AIDER: 5.0 FIRE-FIGHTING MEASURES /ear proper apparatus and protective clothing. EXTINGUISHING MEDIA: + Water, foam, and dry powder FORBIDDEN EXTINGUISHING _: No information available MEDIA PARTICULAR HAZARDOUSNESS : None PARTICULAR EXTINGUISHING __: Move the case away from fire area ifthe case itself is not in danger. METHOD PROTECTIVE EQUIPMENT : Wear proper apparatus and protective clothing. 6.0 ACCIDENTAL RELEASE MEASURES PRECAUSTIONS TO PERSONS, : Gather up as many released product as possible because released product, PROTECTION AND makes surface slippery. EMERGENCY MESURE : Wear suitable protective clothing. + Disposal should be in accordance with section 13.0 (Disposal Considerations). ENVIRONMENTAL : Pay atcation not to discharge into public wasted water treat equipment, PROTECTION MEASURES: reviver and so on. COLLECTING MEASURES AND; Collect released product and keep them into case, which can be sealed NEUTRALIZATION completely. CONTAINMENT / CLEANING :None AND QUIPMENT PREVENTION OF SECOND _: Prevent from dust and fine particles occurrence. ACCIDENT 7.0 HANDLING AND STORAGE Handling TECHNICAL + Inhalation of dust and fine particles may cause irritation to eyes, skin COUNTERMEASURE ‘and bronchi. + This product is not ignitable and explosive. LOADING Internal of the vessel or the reactor should be cleaned and dried before filling the support balls. Avoid falling input from high point to prevent crack of balls. LOCAL EVACUATION OF AIR _: Wear suitable protective clothing, as described in section 8.0 (Exposure *GENERAL VENTILATION —_Controls/Personal Protection) because dust and fine particles may be occurred during handling with the product. ‘SAFETY PRECAUTIONS + Care the weight of the product and handle the product under conditions Of good industrial hygiene and safe working practice. PHISICAL CONTACT : None AVOIDANCE Page 4 of‘fon Tipton Corp. MATERIAL SAFETY DATA SHEET a) Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL Latest revision dato: April, 2008 Storage TECHNICAL ‘Store the product ina cool, dry area. COUNTERMEASURE Keep away from heat and ignitable source. + Care the product not to fall down during storage. MIXED TOUCH HAZARDOUS : None ‘SUBSTANCE STORAGE CONDITION + Keep the product well sealed with case in well-ventilated area, MATERIAL OF CASE AND: Particular regulation of case and package is not applied to the product, PACKAGE However well sealed case, which is not easily broken, is required. 8.0 EXPOSURE CONTROL/PERSONAL PROTECTION STANDARD CONTROL This object is not set up. CONCENTRATION TOLERABLE LEVEL, EXPOSEURE LIMITED VALUE / BIOLOGICAL EXPOSURE LIMITED VALUE. JAPANESE — SOCIETY OF: This object isnot set up. OCCUPATIONAL HEALTH 2005 ver. ACGIH 2005 ver. + This object is not set up. FACILITIES RECOMMENDED: _: Dust collector or other effective equipment for fine dust and particles ‘during handling and using the product should be installed. + Safety shower, washroom and eye-washing equipment near to the ‘handling area should be installed as well. The location of those facilities should be shown distinctly. Protection RESPIRTORY PROTECTION + Dustproof respiratory HAND PROTECTION : Protective gloves. ‘EYE PROTECTION Safety goggles ora face visor. ‘SKIN PROTECTION Protective clothing and footwear. ‘IYGIENE MEASURE Do not eat, drink, and smoke during handing withthe product. + Wash hands properly after dandle it. 9.0 PHYSICAL. PR S APPEARANCE : Grey sphere ovor No specific odor PH Not applicable MELTING POINT/ FREEZING _: Not applicable, POINT BOILING POINT Not applicable INITIAL BOILING POINT AND —_: Not applicable BOILING RANGE FLASH POINT + Not applicable IGNISION POINT Not applicable Page 5 of 8Howdy Tipton Corp. MATERIAL SAFETY DATA SHEET ‘Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL EXPLOSIVENESS: Not applicable VAPOR PRESSURE Not applicable VAPOR DENSITY (AIR=1) + Not applicable RALATIVE DENSITY : Typically 2.2-2.6 SOLUBILITY + Insoluble PARTITION COEFFICIENT N- ‘No information available OCTANOL/WATER AUTO-IGNITION TEMPURATURE No information available DECOMPOSITION + No information available TEMPERATURE (ODOR THRESHOLD + No information available EVAPORATION RATE (BUTYLE _: Not applicable ‘ACERATE=1) FLAMMABILITY (SOLID, GAS) _: Nonflammability vascosiTy + No information available 10.0 STABILITY AND REACTIVITY ‘STABILITY +The product remains stable under normal use and storage conditions. POSSIBILIYTY OF HAZARD +: Almost none REACTTIONS: MATERIALS TO AVOID None CONDITIONS To AVOID +: Occurrence of dust and fine particles and spreading dust and fine particles. INCOMPATIBLE MATERIALS None HAZARDOUS DECOMPOSITION —_: None PRODUCTS 11.0 TOXICOLOGICAL INFORMATION ACUTE TOXICITY No date available ‘SKIN CORROSION /IRRITATION —: No date available SERIOUS EYE DAMAGE / EYE :No date available IRRITATION ‘RESPRATORY No date available ‘SKIN SENSIBILIZATION AMES test has been done. However itis unable to classify the product into category due to lack of information. (IN VIVO mutation test has not bbeen conducted yet) GERM CELL MUTAGENICITY —_: ACGIH is classified as Group A4 (substance that is not classified as + Out of category. (Aluminium oxide) ‘REPRODUCTIVE TOXICITY + No information available Page 6 of 8‘econ Tipton Corp. MATERIAL SAFETY DATA SHEET ‘Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL Latest revision date: April 7, 2008 SPECIFIC TARGET ORGAN: According to 1CSC2000 which wrote down acridity upper airway the SYSTEMIC TOXICITY -SINGLE product is classified as category 3'airway acridity’ (Ahuminium oxide) -EXPOSURE- + Risk of acridity to apparatus respiratorius. SPECIFIC TARGET _ ORGAN: According to EHC1997 which wrote down’ itis admitted that exposure SYSTEMIC TOXICITY —— of Aluminium oxide on duty caused Idiopathic Interstitial Pacumonia the ‘REPEATED EXPOSURE- product is classified as category 1. : Lang disability caused by long time exposure or iterative exposure ASPIRATION HAZARD + No information available 12.0 ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY + Unclassified due to lack of information. CHRONIC AQUATIC TOXICITY _: Unclassified due to lack of information. 13.0 DISPOSAL CONSIDERATIONS SURPLUS DISPOSAL: : Dispose the product via a licensed waste disposal contractor in accordance with the related rules and regulations. In case that the product is burned out for disposal, bum it in an incinerator and provide proper treatment in accordance with related rules and regulations to prevent from air pollution. CONTAMINATED CASE OR : Expty used case or package completely when they are disposed. CONTAMINATED PACKAGE 14.0 TRANSPORT INFORMATION International regulation MARIN REGULATION +: Nonhazardous material EARO REGULATION +: Nonhazardous material Domestic regulation LAND- BASED REGULATION None MARIN REGULATION : Nonhazardous material EARO REGULATION : Nonhazardous material Special Safery Measure : When the product is delivered, load up the product without damage, crosion and leakage of case and prevent from collapse of cargo surely. 15.0 REGULATORY INFORMATION INDUSTRIAL SAFETY AND + Notifiable hazardous materials HEALTH LAW ‘Aluminum oxide and Silicon dioxide. Page 7 of 8‘Heron Tipton Corp. MATERIAL SAFETY DATA SHEET Original issue date: December 9, 2002 CATALYSIS SUPPORT CERAMIC BALL Latest revision date: April 7, 2008 16.0 PNEUMOCONIOSIS LAW DISASTERS ‘RECOMMENDED USES AND “According to legal 57 provision?, 2attached tables of enforcement 18* provision 19", + Aluminum oxide, Silicon dioxide and Titanium oxide ‘According to Dust obstacle prevention rule 2nd provision attached table duty under powder and particle substance condition. : Notifiable hazardous materials ‘Aluminum oxide, Silicon dioxide and Titanium oxide ‘According to legal 2 attached table. Duty under powder and particle substance condition. + No information available ‘This product is intended to be used industrially for specific purposes ‘only. it should not be used for any industrial/commercial purposes, applications and uses other than those introduced by our company. Any information mentioned in this Safety Data Sheet may be updated and revised without prior notice because of new knowledge. ‘This Safety Data Shect has been made to the best of our knowledge ‘and as accurate as possible, but not specifications of the product or guarantee of the accuracy of information stated herein. Special attention to the product should be paid whenever handling it, because any chemical materials may have unknown hazard. ‘The final decision of the suitability of the product to be used should be ‘made by users’ responsibility. Page 8 of 8