Dougherty Valley HS AP Chemistry WORKSHEET

Hess’s Law Problems #1

o
1. Calculate the standard enthalpy change, ΔH , for the formation of 1 mol of strontium carbonate (the material that gives
the red color in fireworks) from its elements. (–1220 KJ)

Sr (s)  C(graphite)  3
2 O2 (g)  SrCO 3 (s)
The informatio n available is
(1) Sr (s)  1
2 O2 (g)  SrO (s) H  - 592 kJ
(2) SrO (s)  CO2 (g)  SrCO 3 (s) H  - 234 kJ
(3) C(graphite)  O2 (g)  CO2 (g) H  - 394 kJ

2. The combination of coke and steam produces a mixture called coal gas, which can be used as a fuel or as a starting
material for other reactions. If we assume coke can be represented by graphite, the equation for the production of coal
gas is (+ 15.3 kJ)

2 C (s)  2 H2O (g)  CH4 (g)  CO2(g)

Determine the standard enthalpy change for this reaction from the following
standard enthalpies of reaction :
(1) C(s)  H2O (g)  CO (g)  H2 (g) H  131.3 kJ
(2) CO (g)  H2O (g)  CO2 (g)  H2 (g) H  - 41.2 kJ
(3) CH4 (g)  H2O (g)  3 H2 (g)  CO (g) H  206.1 kJ

The next one is challenging!

3. One reaction involved in the conversion of iron ore to the metal is (– 11 kJ)

FeO (s)  CO (g)  Fe (s)  CO2 (g)

Calculate the standard enthalpy change for this reaction from these reactions
of iron oxides with CO :
(1) 3 Fe2O3 (s)  CO (g)  2 Fe3O4 (s)  CO2 (g) H  - 47 kJ
(2) Fe2O3 (s)  3 CO (g)  2 Fe (s)  3 CO2 (g) H  - 25 kJ
(3) Fe3O4 (s)  CO (g)  3 FeO (s)  CO2 (g) H  19 kJ
[4] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
PCl5(g) → PCl3(g) + Cl2(g)

P4(s) + 6Cl2(g) → 4PCl3(g) ΔH = 2439 kJ

4PCl5(g) → P4(s) + 10Cl 2(g) ΔH = 3438 kJ
Answer = 249.8 kJ

[5] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
2CO2(g) + H2O(g) → C 2H2(g) + O2(g)

C2H2(g) + 2H2(g) → C2H6(g) ΔH = 94.5 kJ

H2O(g) → H2(g) + O2 (g) ΔH = 71.2 kJ
C2H6(g) + O2(g) → 2CO2(g) + 3H2O(g) ΔH = 283 kJ
Answer = 235 kJ

[6] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
N2H4(l) + H2(g) → 2NH3(g)

N2H4(l) + CH4O(l) → CH2O(g) + N2(g) + 3H2 (g) ΔH = 37 kJ

N2(g) + 3H2(g) → 2NH 3(g) ΔH = 46 kJ
CH4O(l) → CH2O(g) + H 2(g) ΔH = 65 kJ
Answer = 18 kJ

[7] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
H2SO4(l) → SO3(g) + H2O(g)

H2S(g) + 2O2(g) → H2SO4(l) ΔH = 235.5 kJ

H2S(g) + 2O2(g) → SO 3(g) + H2O(l) ΔH = 207 kJ
H2O(l) → H2O(g) ΔH = 44 kJ
Answer = 72 kJ

[8] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
2C2H4O(l) + 2H2O(l) → 2C2H6O(l) + O2(g)

C2H6O(l) + 3O2(g) → 2CO2(g) + 3H2O(l) ΔH = 685.5 kJ

C2H4O(l) + O2(g) → 2CO2(g) + 2H2O(l) ΔH = 583.5 kJ
Answer = 204.0 kJ

[9] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
N2(g) + 2O2(g) → 2NO 2(g)

N2(g) + 3H2(g) → 2NH3(g) ΔH = 115 kJ

2NH3(g) + 4H2O(l) → 2NO2(g) + 7H2(g) ΔH = 142.5 kJ
H2O(l) → H2(g) + O 2(g) ΔH = 43.7 kJ
Answer = 83 kJ

[10] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
CO2(g) → C(s) + O2(g)

H2O(l) → H2(g) + O2(g) ΔH = 643 kJ

C2H6(g) → 2C(s) + 3H 2(g) ΔH = 190.6 kJ
2CO2(g) + 3H2O(l) → C 2H6(g) + O2(g) ΔH = 3511.1 kJ
Answer = 886 kJ
[11] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
N2H4(l) + CH4O(l) → CH2O(g) + N2(g) + 3H2 (g)

2NH3(g) → N2H4(l) + H2(g) ΔH = 22.5 kJ

2NH3(g) → N2(g) + 3H 2(g) ΔH = 57.5 kJ
CH2O(g) + H2(g) → CH 4O(l) ΔH = 81.2 kJ
Answer = 46.2 kJ

[12] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
H2(g) + Cl2(g) → HCl(g)

COCl2(g) + H2O(l) → CH2Cl2(l) + O2(g) ΔH = 47.5 kJ

2HCl(g) + O2(g) → H2O(l) + Cl2(g) ΔH = 105 kJ
CH2Cl2(l) + H2(g) + O 2(g) → COCl2(g) + 2H2O(l) ΔH = 402.5 kJ
Answer = 230 kJ

[13] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
C2H2(g) + O2(g) → 2CO2(g) + H2O(g)

C2H6(g) → C2H 2(g) + 2H2(g) ΔH = 283.5 kJ

H2(g) + O2(g) → H2O(g) ΔH = 213.7 kJ
2CO2(g) + 3H2O(g) → C2H6(g) + O2(g) ΔH = 849 kJ
Answer = 705 kJ

[14] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
HCl(g) + NaNO2(s) → HNO2(l) + NaCl(s)

2NaCl(s) + H2O(l) → 2HCl(g) + Na2O(s) ΔH = 507 kJ

NO(g) + NO2(g) + Na2O(s) → 2NaNO2(s) ΔH = 427 kJ
NO(g) + NO2(g) → N2O(g) + O2(g) ΔH = 43 kJ
2HNO2(l) → N2O(g) + O2(g) + H 2O(l) ΔH = 34 kJ
Answer = 78 kJ

[15] Find the ΔH for the reaction below, given the following reactions and subsequent ΔH values:
Zn(s) + S8(s) + 2O2(g) → ZnSO4(s)

Zn(s) + S8(s) → ZnS(s) ΔH = 183.92 kJ

2ZnS(s) + 3O2(g) → 2ZnO(s) + 2SO2(g) ΔH = 927.54 kJ
2SO2(g) + O2(g) → 2SO3(g) ΔH = 196.04 kJ
ZnO(s) + SO3(g) → ZnSO4 (s) ΔH = 230.32 kJ
Answer = 976.03 kJ

These problems involve using heat of formation values that are found in the appendix of your textbook.
[16] What is the enthalpy of the following reactions? Use equation from Equation Sheet – [Products minus reactants]
(a) SiF4(g) → Si(s) + 2F2(g)
(b) SiF4(g) → Si(g) + 2F2(g)
(c) SO3(g) + H2O(g) → H2SO4(aq)
(d) 3K2O2(s) + 3H2O(l) → 6KOH(aq) + O3(g)
(e) Fe3O4(s) + 8HCl(g) → 2FeCl3(s) + FeCl2(s) + 4H2O(g)

SiF4 - Hf = 1615.0 KJ/mol

FeCl2 - Hf = 341.8 KJ/mol
FeCl3 - Hf = 399.5 KJ/mol
Fe3O4 - Hf = 1118.4 KJ/mol
SO3 - Hf = 454.5 KJ/mol
Si(g) - Hf = 450 KJ/mol
Dougherty Valley HS AP Chemistry WORKSHEET
Enthalpies of Formation Practice #2
Directions: use your textbooks appendix to calculate the standard enthalpy change for each of the following
reactions using heats of formation. Must show all work to receive credit. These are from another textbook, Hf
values may be a bit different.
(5.71)

[1] __SO2(g) + __O2(g)  __SO3(g) (196.6 kJ)

[2] __Mg(OH)2(s)  __MgO(s) + __H2O(l) (37.1 kJ)

[3] __N2O4(g) + __H2(g)  __N2(g) + __H2O(g) (976.94 kJ)

[4] __SiCl4(l) + __H2O(l)  __SiO2(s) + __HCl(g) (68.3 kJ)

(5.72)

[5] __HBr(g) + __O2(g)  __H2O(l) + __Br2(l) (426.74 kJ)

[6] __NaOH(s) + __SO3(g)  __Na2SO4(s) + __H2O(g) (382.5 kJ)

[7] __CH4(g) + __Cl2(g)  __CCl4(l) + __HCl(g) (433.7 kJ)

[8] __Fe2O3(s) + __HCl(g)  __FeCl3(s) + __H2O(g) (150 kJ)

 WORKSHEET #3
PRACTICE TEST/THERMOCHEMISTRY/AP CHEMISTRY
1.
a) Calculate the amount of heat transferred when 10.00 g of N2O(g) is formed by the
following reaction: (18.54 kJ)

2N2(g) + O2(g) → 2N2O(g) ΔHrxn = +163.2 kJ

b) Draw an energy diagram for this process.

2. Predict the value for ΔH°f for the following scenarios: and explain why

a) Br2(g)
b) Br2(l)
c) I2(g)
d) I2(s)

3. Calculate the ΔHrxn for the following reaction: (-1584.2 kJ/mol)

C2H4(g) + 3O2(g) → 2CO2(g) + 2H2O(l)

ΔH°f C2H4(g) = 226.6 kJ/mol

ΔH°f CO2(g) = -393.5 kJ/mol
ΔH°f H2O(l) = -285.8 kJ/mol

4. A 5.00 g sample of liquid water at 25.0°C is heated by the addition of 84.0 J of energy. The
final temperature of the water is _______________°C. The specific heat capacity of the liquid is
4.18 J/g°C. (E, work must prove that)

a) -21 b) 4.02 c) 25.2 d) 95.2 e) 29.0

5. This problem was taken directly from the 1995 AP chem. exam.
Propane is a hydrocarbon that is commonly used as a fuel for cooking.
Propane’s formula is C3H8.
a) Write a balanced equation for the complete combustion of propane gas.

b) Calculate the volume of air at 30°C and 1.00 atm that is needed to burn completely
10.0 g of propane. Assume that air is 21.0% O2 by volume. (134 L of air)

c) The heat of combustion (ΔH°combustion) is -2,220.1 kJ/mol. Calculate the heat of

formation, ΔH°f, of propane given that ΔHf of H2O(l) is -285.3 kJ/mol and ΔH°f of
CO2(g) is -393.5 kJ/mol. (-101.6 kJ/mol)
d) Assuming that all of the heat evolved burning 10.0 g propane is transferred to 8.00 kg
of water (specific heat = 4.184 J/g°C), calculate the increase in temperature of the
water. (15.0 C is change in T)
AP Chemistry Thermochem FRQs
WORKSHEET #4
2003

2003B
3.

2006
 Skip part (d) for now.
2005B