Journal of Food Engineering: Fangyuan Chen, Alexander D. Warning, Ashim K. Datta, Xing Chen

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Journal of Food Engineering 180 (2016) 87e100

Contents lists available at ScienceDirect

Journal of Food Engineering


journal homepage: www.elsevier.com/locate/jfoodeng

Thawing in a microwave cavity: Comprehensive understanding of


inverter and cycled heating
Fangyuan Chen a, b, Alexander D. Warning b, Ashim K. Datta b, *, Xing Chen a
a
School of Electronic and Information Engineering, Sichuan University, Chengdu, 610065, China
b
Department of Biological and Environmental Engineering, Cornell University, Ithaca, NY, 14853, USA

a r t i c l e i n f o a b s t r a c t

Article history: A comprehensive understanding of the electromagnetics and thermal aspects of the thawing of frozen
Received 22 October 2015 foods in a domestic microwave oven cavity was developed through a model that two-way couples
Received in revised form Maxwell's equations with the heat conduction equation with continuous variation of dielectric and
11 February 2016
thermal properties with temperature. Tylose, a material with properties similar to those of lean beef, was
Accepted 13 February 2016
Available online 20 February 2016
used to experimentally validate the model. Temperatures were measured using fiber optic and infrared
sensors. Various salt contents that were used in formulating the tylose represented important variations
in dielectric properties, latent heat release, and initial freezing point. Spatial and time variations of all
Keywords:
Electromagnetics
important parameters are used to explain the results. As material thaws, total energy absorption de-
Heat transfer creases, a novel result that is explained by reference to continuous changes in dielectric properties. Shifts
Non-uniformity in the resonant frequency of the cavity as load size changes explain the changes in total energy ab-
Inverter heating sorption with size. Inverter heating, a newer technology that claims superiority over ordinary cycled
Power absorption heating, produced only minimal differences in temperature uniformity or color.
© 2016 Elsevier Ltd. All rights reserved.

1. Introduction newer approach, inverter heating, uses continuous power at the


desired level, which purportedly improves the uniformity and
As ubiquitous as microwave thawing is today, it is a physically heating efficiency (Panasonic, 2015). The size of the object being
complex and interesting process that has major implications in heated (the load) also affects the heating process in a complex
everyday food preparation, among other applications. The advan- manner by changing the amount of energy absorbed. Even small
tages of microwave thawing include faster heating and reduced changes in composition, such as in the salt content, can change the
energy consumption (Watanabe et al., 2010). However, the elec- process significantly. The salt concentration combined with the
tromagnetics of a microwave oven renders the spatial energy microwave frequency significantly affects the dielectric properties
deposition highly non-uniform. As heating continues and temper- and penetration depth, thus thawing time. The dielectric loss of
ature rises, the thermal and, more importantly, dielectric properties salted food increases with increasing salt concentration and
change with temperature. In particular, as the material thaws, the decreasing microwave frequency (Llave et al., 2016). Conversely, the
change in dielectric properties is massive and this changes the penetration depth increases with decreasing salt concentration
electromagnetic field inside the oven as well as the spatial energy (Llave et al., 2016). The non-uniformities involved in heating frozen
absorption; in other words, the electromagnetics and heat transfer foods in a microwave oven manifest to the user in terms of quality
are strongly two-way coupled. The typical household microwave and microbiological safety (Chandrasekaran et al., 2013). Quality
oven performs cycled heating whereby the microwaves are on at can deteriorate significantly in regions where time-temperature
full power a fraction of the time over one cycle (equal to the fraction history leads to greater kinetic changes and pathogens can sur-
of the desired maximum power delivered by the oven) followed by vive in locations where the time-temperature history leads to the
zero power when the microwaves turn off. On the other hand, a least kinetic change (Rao et al., 2014). Because of the large spatial
temperature variation during microwave heating, it is imperative to
understand when microwave heating is satisfactory in terms of
* Corresponding author. Department of Biological and Environmental Engineer- safety and quality (i.e., small sized food products) and when other
ing, Cornell University, 208 Riley-Robb, Ithaca, NY, 14853-5701, USA. methods of thawing are more efficient (e.g., radio frequency
E-mail address: akd1@cornell.edu (A.K. Datta).

http://dx.doi.org/10.1016/j.jfoodeng.2016.02.007
0260-8774/© 2016 Elsevier Ltd. All rights reserved.
88 F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100

heating for large food sizes (Uyar et al., 2015)) (Taher and Farid, temperatures during thawing of mashed potatoes. Pitchai et al.
2001a). The impetus for the present study is that we can greatly (2016) used a fully coupled heat transfer and electromagnetics
facilitate the design and optimization of newer microwave and simulation to demonstrate the importance of the frequency range
combination microwave ovens and the design of microwaveable in domestic microwave ovens. Their results showed how incorpo-
products to achieve improved quality and safety through improved rating a 50 MHz standard deviation into the microwave frequency
mechanistic understanding of microwave heating. improve predictive capabilities of the simulation versus the stan-
dard assumption of a constant 2.45 GHz frequency (Pitchai et al.,
1.1. Challenges in mathematical modeling of microwave thawing 2016). In another such study (Tilford et al., 2007), a two-way
coupled mechanistic model was developed for thawing of frozen
Realistic modeling of microwave thawing requires a complete cheese sauce but focused on model validation and computational
solution of 3D electromagnetics in a cavity that is coupled with heat implementation versus understanding the mechanisms involved in
transferdthis is already a computationally challenging problem. thawing.
The phase change in a material such as food in which the water
contains many dissolved solutes requires a formulation whereby 1.3. Inverter heating
melting is distributed in space (as opposed to a thawing front) as it
is continuously changing with temperature. With phase change, Inverter heating (Bansal et al., 2011) is a relatively newer mode
the dielectric properties change and this continuous change in of heating that employs a constant power level in thawing, as
dielectric properties needs to be predicted reasonably well and opposed to the more typical cycled power heating. In cycled power
included in the model. The more the dielectric properties vary with heating, the magnetron delivers 100% of the power followed by no
temperature, the more intimately coupled are the electromagnetics power (Fig. 1). Although cycled heating and inverter heating should
and the thermal problems.This translates into taking smaller time deliver the same time-averaged power in the time scale of one
steps and computing more often, again increasing computing cycle, there can be a significant difference in temperature and, over
resource requirements. time, the accumulated effects (color, texture change or any other
reaction) can be different. The physics of inverter heating is not
1.2. Previous work on modeling of microwave thawing known. Thus, although there is a significant body of literature on
cycled power heating (Taher and Farid, 2001b), precise conclusions
Previous work on microwave thawing can be broadly divided applying to constant power level inverter heating from studies on
into two groups based on how the electromagnetics were cycled power heating cannot be drawn.
modeled: 1) using plane waves with or without an exponential
decay solution of the electromagnetic field; and 2) using micro-
wave cavity solutions. Studies in the first group include all the early 1.4. The purpose of this study
work before dramatic improvements in both computer hardware
and software were made, as is the case today. These studies used The purpose of this study was to develop a comprehensive
models with tylose cubes (Chamchong and Datta, 1999b,c), ice and mechanistic understanding of microwave thawing in a cavity that
water slabs (Basak, 2003), tylose cylinders (Basak and Ayappa, includes all the fundamental physics: 1) the complete electro-
2002), and layered frozen and unfrozen materials in an ice-water magnetics, 2) the frozen fraction that changes continuously with
system (Phadungsak et al., 2002; Rattanadecho, 2004). Some of temperature, 3) the dielectric and thermal properties that contin-
the solutions generated by these earlier models that are idealized uously change with the frozen fraction, and 4) the two-way coupled
are analytical but most are numerical. Using an exponentially electromagnetics and heat transfer. This mechanistic understand-
decaying function combined with 3D heat transfer for cavity ing will be presented in terms of transient temperatures and
heating make it possible to capture the effects of power level and temperature non-uniformity within the material and will focus on
cycling as well as the geometry and dielectric properties, but issues that are unanswered today in the citations mentioned in the
without the full electromagnetic solution for which the required previous paragraph: 1) How does the total power absorption
computing resources were difficult to obtain at that time. Such a change as the material thaws? 2) How does cyclic power (as is
solution cannot capture the non-uniformity of the electric field or common) differ from newer inverter heating? 3) What is the effect
other electromagnetic details (Taher and Farid, 2001b). It is fair to of product size on energy absorption? 4) What is the effect of salt
say that while results obtained this way provide some mechanistic content in a material?
understanding of microwave heating, they are far from providing a
full understanding of true cavity heating. 1.5. Objectives and overview
In the second group are the relatively more recent models in
which cavity solutions are coupled with heat transfer and changing The objectives of this study are to: 1) develop and experimen-
dielectric properties are included. With advances in computing tally validate a comprehensive mathematical model for microwave
power, the ability to couple multiphysics simulations where Max- heating of a frozen food analog (a tylose cube), 2) compute the
well's equations are solved in the microwave cavity and food are change in power absorption in the food analog as the dielectric
now readily available. The challenge in computing power was due properties change continuously during heating, 3) compare
to the fact that an accurate solution requires approximately six inverter heating with traditional cycled heating, and 4) determine
elements per wavelength (Jin, 2002) leading many thousands or the effects of size and changes in properties (as the salt content
millions of elements thus previously requiring a super computer changes) on the heating process. Two microwave heating cycles
which can now be solved on a desktop computer. Some studies were tested for temperature, power absorption, and color: cyclic
(Tilford et al., 2007; Watanabe et al., 2010; Chen et al., 2015) focus and inverter output microwave. With inverter microwave heating,
on computational challenges and the steps taken to address these constant power is applied. With cyclic microwave heating, constant
but with little attention to developing a detailed mechanistic un- power is applied temporarily, followed by no power from the
derstanding of the thawing process. For example, Chen et al. (2015) magnetron. Additionally, we tested the effects of salt concentration
demonstrated that decoupling the heat transfer and electromag- and object size. Salt concentration affects electrical permittivity
netics simulation did not considerably affect the predicted while size affects wave absorption of the tylose.
F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100 89

Fig. 1. Power output from cyclic oven and inverter oven, respectively.

2. Model formulation

The properties for Maxwell's equations are two-way coupled


with the properties of the heat transfer equation for thawing a
tylose block in a microwave oven. The color change is modeled with
first-order degradation kinetics to quantify the amount of heating.

2.1. Microwave oven and thawed material

The microwave oven (Fig. 2) in this research is a model


JES738WJ02 (General Electric). It is a domestic microwave oven
operating at a 2.45 GHz frequency at a rated power of 700W. Fig. 2a
shows the geometry model in COMSOL Multiphysics 4.4. Fig. 2b
shows an inside view of the prototype of the oven. As shown in
Fig. 2b, the magnetron is located at the right upper side of the
cavity, where the light is on in the figure. All interior surface di-
mensions were measured and replicated in the COMSOL model. The
material being thawed is a frozen tylose gel cube (L3 mm3) located
in the center bottom of the oven cavity, with L ranging from 10 to
60 mm.

2.2. Governing equations

To model microwave heating, Maxwell's equations are solved to


obtain the electric field. The volumetric heat source term is calcu-
lated from the electric field and used with the conduction equation.
As the temperature changes, the temperature-dependent electrical
and thermal properties change, making the problem two-way
coupled.

2.3. Electromagnetics

The electromagnetic field is calculated by the frequency domain


Maxwell's equation:
   
⃗ js ⃗
V  m1
r V  E  k2
0 ε r  E¼0 (1)
u
Fig. 2. a) Geometry input in COMSOL Multiphysics (detailed dimensions are not
where m is the permeability, εr is the relative permittivity, k0 is the included for clarity, but included in COMSOL). b) Geometry of oven with tylose at the
center, as input in the computational software.
wave number and s is the electrical conductivity of the material (air
and space). The relative permittivity is related to the real ε' and
imaginary ε'' permittivity by the vacuum permittivity ε0.
 00
.
εr ¼ ε0  jε ε0 (2) 1 00
Q¼ uε ε E⃗2 (3)
2 0
The thermal energy absorbed from the cube, Q, is calculated
from the electromagnetic field by Eq. (3): where u is the microwave frequency of 2.45 GHz.
90 F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100

2.4. Heat transfer   . 


xi ¼ ðxw  xb Þ 1  Tfi  273:15 ðT  273:15Þ (9)
The transport of energy in the tylose cube is modeled with
conduction and apparent specific heat is used to account for the The apparent specific heat cp,eff, based on the mass fractions, is
latent heat of thawing. Microwave heating is included in the power used to model the ice melting over a temperature range, starting at
absorption. the initial freezing point:

vT   dxu
reff cp;eff ¼ V$ keff VT þ Q  le I_ (4) cp;eff ¼ xsalt cp;salt þ xs cp;s þ xu cp;u þ xi cp;i þ lm (10)
vt dT
 Fig. 3c shows that the thermal conductivity changes very little
0 T < 100 +C
le I_ ¼ (5) above the freezing point but it changes dramatically below. Fig. 3d
Q T  100 +C shows that the salt concentration has little influence on specific
Here le is the latent heat of evaporation and I_ is the rate of water heat capacity.
evaporation, which is assumed to be equal to the microwave
heating term (Chamchong and Datta, 1999b; Zeng and Faghri, 2.7. Initial and boundary conditions and other input parameters
1994).
The initial temperature of the frozen tylose cube was 253.15 K
and the initial electric field was 0 V/m. The initial color value was
2.5. Color normalized to 100 such that lower values indicate product
darkening.
To validate ongoing claims about the role of invertor heating in The boundary conditions everywhere in the microwave were
producing color in cooked food, color development during cooking perfect electrical conductors. There were 700 W and 2.45 GHz
(Holdsworth and Simpson, 2007) was modeled. For this work, the applied at the magnetron boundary. For heat transfer, tylose cubes
color development, C, was modeled as: were modeled. The surface of the tylose cubes was modeled with a
  natural convection boundary condition with a convective heat
dC Ea transfer coefficient of 20 W/m2 K (Datta, 2007) and air temperature
¼ gexp C (6)
dt RT T0 ¼ 20 C.
Additional input parameters used in the simulation are sum-
where g is the reaction constant, R is the gas constant, and Ea is the marized in Table 1.
activation energy.
3. Numerical implementation
2.6. Material properties
Fig. 4 shows the flow chart of the entire computational process.
A tylose gel cube at varying salt concentrations (2%, 3% and 4%) Tetrahedron meshes were used in COMSOL Multiphysics 4.4 such
was used in the experiments. Fig. 3 shows the dielectric and ther- that there were at least 6 elements per wavelength. To check mesh
mal properties of the tylose gel at these salt concentrations and at convergence, the average temperature and electric field in the
2.45 GHz (Chamchong and Datta, 1999a). The fraction of unfrozen tylose cube were plotted with time (not shown) and did not change.
water and the density of tylose was measured experimentally The frequency domain electromagnetic waves module and heat
(Fig. 3a and b), and dielectric properties were used based on these transfer in the solid module were used to solve Maxwell's equation
data, as shown in Fig. 3e and f. The dielectric constant and loss (Eq. (1)) and the heat transfer equation (Eq. (4)) respectively. The
increase dramatically with the temperature below 0  C, but then domain ordinary differential equation was used to solve for color
the dielectric constant decreases while the dielectric loss increases (Eq. (6)). The computation time step was set to 0.1 s. The simula-
above the freezing point. tions were run on an Intel Xeon 32 core CPU, 2.8 GHz, and 256 GB
The initial freezing point is determined by the equation (Gulati memory. Computation time ranged from one to four days
and Datta, 2013) depending on the size of the tylose cube.
 
1 1 R ðxw  xb Þ=Mw 4. Experimental methods
¼  ln (7)
Tfi Tf 0 lm Mw ðxu  xb Þ=Mw þ xs =Ms
The microwave oven used in the experiments operates with
where Tf0 is the freezing temperature of pure water, lm is the latent cyclical power outputs (Fig. 1). For cyclical heating, the period was
heat of melting, xw is the total water weight of material before 22 s with 11 s on and 11 s off. To measure the temperature of the
freezing, xu is the water in the unfrozen part below the initial cube, a hole (20 mm in diameter) was drilled in the top of the
freezing point, xb (¼0.4xs, where xs is the solid mass fraction) is microwave so that the top face would be visible to an infrared
bound water, Mw is the molecular weight of water, and Ms is the camera. The hole has a negligible effect on heating as radiation does
molecular weight of tylose. For most foods, the freezing point is not escape through it because it can be treated as a circular wave
between 4  C and 0  C (Gulati and Datta, 2013). For pure tylose guide connected to an oven cavity. Although considerable wave
gel, the freezing temperature is 0.62 ± 0.05  C. Higher salt content transmission mode exists in the circular cavity, the lowest wave
in materials generally leads to a lower initial freezing temperature mode is the dominant one. The critical frequency is then
(James et al., 2005).
kc
A mass-averaged equation is used to evaluate the thermal uc ¼ pffiffiffiffiffi (11)
2p mε
conductivity:

keff ¼ xw kw þ xi ki þ xs ks (8) where kc is the cutoff wavenumber, which is determined by the


waveguide's lowest wave mode. For a circular waveguide,
Here the mass fraction of ice, xi, is given by: kc ¼ 92.02 (Pozar, 2009), and thus its cutoff frequency is
F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100 91

Fig. 3. Thermal and electrical properties at various salt concentrations with temperature: a) density, b) unfrozen water fraction, c) thermal conductivity, d) apparent specific heat
capacity, e) dielectric constant, f) dielectric loss.

uc ¼ 4.39 GHz. So in theory, for the 2.45 GHz EM wave, there is no 24 h. Figure 5c shows the fiber optic temperature probe; the sensor
leakage. Negligible EM power was measured near the hole. area C is about 6.5 mm long and with a 1 mm diameter. So the
The tylose gel was made of 23% tylose powder (MH1000, tested point temperature actually is a small volume-average tem-
Hoechst Celanese Corp, North Carolina, USA), 77% pure water, and perature, which is different from the point temperature in the
varying amounts of table salt. The point temperatures in the tylose model. Therefore, to compare the tested temperature with the
gel cube were recorded at six locations with an optical fiber probe temperature in the model, the average temperature of a cylindrical
(temperature range 40 C to 250 C, FISO Company, Quebec, region of 1 mm diameter and 6.5 mm long was used.
Canada) (Fig. 5) and the surface temperature was measured with an
infrared camera (FLIR, Wilsonville, OR). The six fiber optic sensors
were inserted into the tylose cube before freezing at 20 C for
92 F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100

Table 1
Input parameters.

Parameter Symbol Value Units Source

Electromagnetic properties
Vacuum permeability m0 1.2566  106 V s A1 m1 (Pozar, 2009)
Relative permeability of air mr,a 1 (Pozar, 2009)
Relative permeability of tylose mr,t 1 (Chamchong and Datta, 1999a)
Vacuum permittivity ε0 8.854  1012 F m1 (Pozar, 2009)
Relative permittivity of air εr,a 1 (Pozar, 2009)
Relative permittivity of tylose εr,t Eq. (2) (Pozar, 2009)
Microwave frequency u0 2.45 GHz
Electrical conductivity s ∞ S m1 (Pozar, 2009)
pffiffiffiffiffiffiffi
Wave number k0 u mε0 m1 (Pozar, 2009)
Permittivity real ε' Fig. 3e F m1 (Pozar, 2009)
Permittivity imaginary ε'' Fig. 3f F m1 (Pozar, 2009)
Cutoff frequency wc 4.39 GHz (Pozar, 2009)
Cutoff wavenumber kc 92.02 (Pozar, 2009)
Heat transfer properties
Density r 798 kg m3 Measured
Specific heat cp,eff Eq. 10 J kg1 K1 Calculated
Specific heat, water cp,u 4178 J kg1 K1 (Halder et al., 2011)
Specific heat, ice cp,i 2062 J kg1 K1 (Halder et al., 2011)
specific heat, salt cp,salt 630 J kg1 K1 (Sirdeshmukh et al., 2001)
Specific heat, tylose cp,s 1400 J kg1 K1 (Stephen and Phillips, 2014)
Thermal conductivity keff Eq. (8) W m1 K1 Calculated
Thermal conductivity, water ku 0.57 W m1 K1 (Halder et al., 2011)
Thermal conductivity, ice ki 2.22 W m1 K1 (Halder et al., 2011)
Thermal conductivity, salt ksalt 2.03 W m1 K1 (Sirdeshmukh et al., 2001)
Thermal conductivity, tylose ks 0.26 W m1 K1 (Stephen and Phillips, 2014)
Constants
Boltzmann kB 1.3806  1023 J K1 (Pozar, 2009)
Rate constant g 2.07  105 s1 (Ateba and Mittal, 1994)
Activation energy Ea 16.92  103 kJ mol1 (Ateba and Mittal, 1994)
Gas constant R 8.314  103 J mol1 K1

Initial freezing point Tf0 Eq. (7) C (James et al., 2005)
Molecular weight of water Mw 0.018 kg mol1
Molecular weight of tylose Ms 6000 kg mol1 (Fink, 2003)
Latent heat of fusion l Eq. (10) J kg1 (Chamchong and Datta, 1999a)
Mass fraction of water xw 0.77
Mass fraction of ice xi Eq. (9) (Chamchong and Datta, 1999a)

5. Results and discussion

This section first describes validation of computed temperatures


against experimental data. The validated model is used to compute
transient temperatures and their non-uniformities for various salt
contents, load sizes, and cycled vs. inverter heating.

5.1. Model validation

Fig. 6 shows a reasonably good match between the measured


and simulated temperatures. The relative error at locations 1 and 2
are much smaller in magnitude (note the differing scales) than at
locations 3 and 4 due to smaller magnitudes of temperature rise at
those locations since they did not absorb as much microwave en-
ergy. Fig. 7 shows the simulated and measured top surface tem-
perature distributions. Both 60 s and 120 s data show good
agreement between model and experiment as they are within a few
degrees (note the differing color scales). They also show a similar
heating pattern with the colder region being around the center. The
experimentally measured tylose cube is approximately 5 C lower
in temperature than the simulated cube. This difference is most
likely due to the small amount of evaporation that lowers the
experimental temperature.

5.2. Understanding transient power absorption and temperature


rise

Fig. 4. Flow chart of the computation. Fig. 8a and b shows the change in volume-averaged EM field
F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100 93

Fig. 5. Temperature measurement using fiber optic probe: a) Schematic showing placement of the probe. Point 1 is located in the center of the tylose cube; point 2 is the midpoint
between the center and the surface closest to the magnetron. Points 3 and 4 are 12.5 mm from the surface farthest from the magnetron while point 5 is between them. Point 6 is
located 5 mm from the surface. Points 1e5 are located in the same x-y plane that cross-sections the center point. b) Picture from the experiment. c) Geometry of a fiber optic sensor
probe with A z 17 mm, B z 4 mm, C z 6.5 mm, D z 1.0 mm, and E z 2 m.

Fig. 6. Temperature at four locations in the tylose cube, 505050 mm in size with a 3% salt concentration. The bars show the computed range (minimum, maximum) of
temperatures in a cylindrical volume of tylose that would have been taken up by the sensing region of a probe (diameter z 1.7 mm, height z 6.5 mm; see Fig. 5) if a probe were
present.
94 F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100

As the dielectric constant rises drastically when the temperature


increases above 0 C, the solid impedance will decrease. For a fixed
angle of incidence, the Rk and R⊥ will increase as Tk and T⊥ decrease
with increasing temperature difference between the materials.
Hence, a region of low impedance forms near the surface (a shell, as
shown in Figs. 9 and 10) that reflects and does not transmit as much
of the EM waves but absorbs more of the waves because of the
increased dielectric loss. This effect can be seen in Fig. 8a, which
shows the average field intensity in the tylose decreases (while the
average field in the oven increases (Fig. 8b) with time as the un-
frozen outer shell forms from heating. The model can be treated as
a three-layer problem: low dielectric (low impedance) air, medium
dielectric (medium impedance) unfrozen tylose, and low dielectric
(high impedance) frozen tylose. The large difference in impedance
between the frozen and unfrozen layers will increase reflection and
thus more energy will be absorbed in the unfrozen region. As the
unfrozen region increases in temperature, the dielectric loss in-
creases, and thus more energy is absorbed near the surface before
reaching the frozen core region (Fig. 11).
Fig. 8d shows this nonuniform heating where the difference
between the warmest and the coldest temperatures in a 3% salt
50 mm tylose cube is nearly 100 C after 2 min even when the
average temperature is quite high. The warmest point is near the
Fig. 7. Top surface temperature of tylose cube ( C) (Fig. 2) at 60 s and 120 s, respec- surface of the cube facing the magnetron while the coldest tem-
tively, obtained from the simulation (left) and the experiment (right). Note that the
perature is in the core.
color scales from the computational software and the infrared camera are different and
that scales cannot be remapped easily. (For interpretation of the references to color in
this figure legend, the reader is referred to the web version of this article.) 5.3. Effect of salt concentration in tylose, representing variations in
the same food

intensity with time in the tylose cube and in the air in the micro- Any change in salt concentration changes the fraction of un-
wave cavity, respectively. Thus, the average electric field intensity frozen water at a particular temperature. The fraction of unfrozen
(Fig. 8a) in the cube decreases rapidly in the initial 120 s, causing water at any time during the heating process is shown in Fig. 8e.
the average in the cavity air to increase (Fig. 8b). Since the tem- The temperature data were post-processed in COMSOL to find all
perature increase in the cube occurs mainly on the surface (Fig. 10), the volumes with temperatures above the initial freezing point, as
the waves will penetrate less deeply, decreasing the energy shown in Fig. 3. These are added and divided by the total volume to
absorbed in the cube. In other words, a shell of high impedance obtain the unfrozen fraction in Fig. 8e. As expected based on
forms that reflects more of the waves. But in the frozen core, both freezing point depression, for a given duration of heating, the un-
the real and imaginary part of the permittivity are small so very frozen fraction is highest for the highest (4%) salt content.
little energy is absorbed. The energy absorption fluctuates during Fig. 8f shows a very interesting and novel result pertaining to
heating due to the fluctuation of dielectric properties with tem- how the power absorption varies with the unfrozen fraction as
perature (Fig. 8c). heating continues. As the unfrozen fraction increases, the dielectric
A simplified electromagnetic analysis consisting of plane waves constant increases, increasing reflection and reducing power ab-
incident on a layered flat surface (Fig. 11) can be used to explain the sorption. Data for all three salt contents follow each other closely.
lower energy absorption withffi increased temperature. The wave
pffiffiffiffiffiffiffi Fig. 10 shows the simulated electromagnetic field and temper-
impedance for air, Z ¼ m=ε, is much smaller than for the solid ature distributions at a y-z plane at the center of a 50 mm tylose
(tylose) since, while the permeability, m, is always approximately cube after 60 s of heating for various salt concentrations. The
the same value, the permittivity, ε, is much smaller for air than for electric field intensities in the air in the microwave cavity have a
tylose. The parallel reflection coefficient, R, and transmission co- value of ~104 V/m while the electric field intensity in the tylose cube
efficient, T, of the electrical wave are (Pozar, 2009): (regardless of salt content) is ~103 V/m. The electric field strength is
noticeably different with salt concentrations, with a 2% salt con-
Za cos4  Zs cosq centration having the strongest field strength, while a 4% concen-
Rk ¼ (12)
Za cos4 þ Zs cosq tration has the weakest. The region of the higher electric field
moves closer to the surface, i.e., there is more energy deposition
2Zs cosq near the surface as salt content increases. The increase in dielectric
Tk ¼ (13)
Za cos4 þ Zs cosq loss with salt content leads to greater energy absorption and the
greatest temperature rise as thermal properties do not change
and the corresponding coefficients for the perpendicular polarized much between these salt concentrations.
EM wave are
5.4. Comparison of inverter heating and cyclical heating
Zs cosq  Za cos4
R⊥ ¼ (14)
Zs cosq þ Za cos4 One of the goals of this study was to verify the claim that
inverter heating can improve the heating rate and temperature
2Zs cosq uniformity while not overcooking food edges and corners during
T⊥ ¼ (15) microwave thawing (Panasonic, 2015). This section compares re-
Zs cosq þ Za cos4
sults from the simulation of the cycled heating and inverter heating
F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100 95

Fig. 8. Effect of salt concentration on constant power heating of a 50 mm tylose cube, 600 s: a) average electric field intensity in tylose, b) average electric field intensity in cavity, c)
energy absorption in tylose cube, d) coldest, warmest and volume-average temperatures over time, e) unfrozen volume fraction over time, f) energy absorption plotted against
unfrozen volume fraction.

(Fig. 1). heated at the same time averaged rate.


Fig. 12 compares temperatures at four locations for cycled and To compare the heating uniformity between the two methods,
inverter heating. Both heating methods, on average, heat similarly the standard deviation, s, and coefficient of variance, COV, were
(the temperatures follow each other overall). This is expected since defined as
the average power is the same in both cases. But when viewed on
shorter time scales than the cycle time, the cyclic heating method vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
u N    2
leads to faster increases in temperature followed by a short period u1 X !
SDðtÞ ¼ t T t; qi  TðtÞ : (16)
of cooling during which energy conducts whereas the temperature N i¼1
increase is steady for inverter heating. Overall, both methods
96 F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100

Fig. 9. Temperature over a cross-section at mid-thickness (as shown) of 50 mm length tylose cube over various heating durations.

Fig. 10. Effect of salt content on the spatial variation of the electric field and temperature over a cross-section at mid-thickness (as shown) of a tylose cube at 60 s for 2%, 3%, and 4%
salt content, respectively.

COV ¼ SDðtÞ TðtÞ (17)


R
where TðtÞ ¼ ð TdVÞ=V is the average temperature of the tylose.
V
The standard deviation is a measure of the non-uniformity while
the COV normalizes the standard deviation by the average tem-
perature, and was shown to be a more effective measure of non-
uniformity (Geedipalli et al., 2007). A smaller COV represents
greater temperature uniformity. The standard deviation and COV
were plotted with time in Fig. 12b and c. These figures show that
the heating method had no significant impact on heating unifor-
mity since both measures of heating uniformity were nearly equal
for cyclic and inverter heating. One noticeable difference was at
early times when there was a 10 C difference between cyclic
heating and invert heating.
Fig. 11. Simplified description of microwaves incident on a material with varying Due to the difference in temperatures over a cycle between
dielectric properties, showing reflected and refracted waves. cycled and inverter heating, the reaction magnitude of color
F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100 97

Fig. 12. Comparison of inverter and cyclic heating: a) temperature at points 1, 2, and 5, b) coefficients of variance of temperatures, c) standard deviations of temperatures, d)
temperature and color at point 6. (For interpretation of the references to color in this figure legend, the reader is referred to the web version of this article.)

formation will be different and this difference in color should 5.5. Effect of load size on energy absorption and temperature
accumulate over time. Fig. 12d shows the change in color at one
location near the corner. The corner location was chosen as the The effect of load size on the heating rate and uniformity for a
temperatures are generally higher in this location so it may be tylose cube are shown in Figs. 13 and 14. Although average tem-
possible to find greater differences between cycled and inverter peratures (Fig. 8) increase above 0 C for cubes 50 mm or smaller
heating there. Noticeably, there is nearly a 40 C difference in over the 120 s time period, the minimum temperatures do not
temperature at the corner at early times between the cycled and increase above 0 C unless the sample is 40 mm or smaller. Corners
inverter heating. The cycled power heating rapidly defrosts the and edges that reach much higher temperatures influence the
tylose corner, accelerating color formation. Corners and edges are average significantly, sending it above 0 C, while there are still
also locations claimed by the manufacturer (Panasonic, 2015) to be regions below 0 C. This spatial non-uniformity of temperatures
the locations where inverter heating improves quality (e.g., changes can be seen in Fig. 13, which displays temperatures over a mid-
to darker colors in corners and edges in cycled heating do not occur section (see figure legend for details). Fig. 13 shows that the
in inverter heating as claimed). As shown in Fig. 12d, the lightness is lowest temperatures for each size are near the centers while the
only very slightly lower for inverter heating at the end of 220 s (10 highest temperatures are at the edges facing the magnetron. The
cycles) of cyclic heating, and this difference stays pretty much the non-uniformity of temperatures can also be seen in Fig. 14c, which
same after about the first four cycles of heating (less than 1% dif- plots standard deviations of temperatures in a cube over time for
ference). This study therefore concludes that the two methods of various sizes. They show the common pattern (Geedipalli et al.,
heating are unlikely to lead to any appreciable differences in color 2007) of increasing with time initially (as surface regions are
at the food edges. Based on the results of Fig. 12, both methods of heated to a greater extent than interior regions) and later dropping
microwave cooking thawed food at the same time averaged rate, as diffusion equilibrates temperatures and also the maximum
showed similar temperature uniformity, and heated the corners temperature is limited to near 100 C. The time when non-
similarly. While temperature, uniformity, and color differ during uniformity is highest (the peak) extends as size increases. A
cycles, they showed similar cooking patterns as inverter heating longer heating period is needed before the center starts to change
when averaged over time. temperature in a larger size and leads to greater differences be-
tween the surface and certain regions. The highest non-uniformity
(the peak of the standard deviation curve) also increases with size.
The effect of material size on total power absorption is shown in
98 F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100

Fig. 13. The effect of product size on heating is shown using temperatures at two times at the plane shown in the cube above. As size increases, heating becomes less uniform
volumetrically, ultimately changing to corner and edge heating.

Fig. 14. Effect of tylose cube size on heating: a) center temperature, b) volume-average temperature, c) standard deviations of temperatures, d) experimentally tested center
temperature changes.

Fig. 15. It shows S11, which represents the power reflected from the absorption over the entire heating duration. The smallest size cube
transmitted power at the port where microwaves enter the cavity. (10 mm) with S11 of 2, or 80%, microwave reflected back into the
Values of 10, 7 and 4 dB represent 10%, 20%, and 40% reflected magnetron absorbs the least power but many of the larger sizes
power, respectively, so the lower the S11 value, the more completely also exhibit lower power absorption. This power absorption is
the power is absorbed (less is reflected) by the load (tylose), i.e., the complex and depends on factors such as shift in resonant frequency
more energy efficient is the heating process. Fig. 15a shows the and mode pattern in the cavity.
30 mm tylose cube to be typically the most efficient in energy A load placed inside a microwave cavity shifts the resonant
F. Chen et al. / Journal of Food Engineering 180 (2016) 87e100 99

Fig. 15. Heating efficiency for various tylose cube sizes: a) S11 of various cube sizes over time. The 30 mm cube is always the lowest the majority of the time, which means it has the
strongest microwave absorption ability, b) Simulated 30 mm and 50 mm cube S11 from 2.1 GHz to 2.8 GHz at the 60th second and; c) Energy absorption per volume. The smallest
cube's energy absorption ability is the strongest in the initial 40 s but then becomes the weakest.

frequency of the cavity, depending on the dielectric properties and ultimately absorbed by the tylose. With the overall temperature
size of the load (Pozar, 2009). As the tylose heats and its dielectric rise of the tylose cube, the dielectric properties change and the
properties change continuously, it continually changes the reso- resonator effect decreases (S11 stabilizes).
nant frequency of the cavity. Energy absorption is strongest at the
resonant frequency of the cavity since that is when the electro- 6. Conclusion
magnetic fields are the strongest. Thus, S11 is lowest at the resonant
frequency of the cavity in the presence of the load. As the resonant The model showed excellent validation with optical fiber point
frequency for the cavity shifts, while the excitation remains at temperature probes and infrared surface heating profiles. Whether
2.45 GHz, absorption in the load decreases, i.e., S11 increases. inverter or cyclical heating was involved, there was little difference
Fig. 15b shows how S11 would change if the excitation frequency is in overall heating rate or uniformity. The salt concentration
changed. This figure is obtained by running simulations at varying significantly changed the electrical properties of the tylose cube but
excitation frequencies (x-axis) and plotting data after 60 s of did not significantly change the heating rate due to the impedance
heating when the values have generally stabilized (Fig. 15a). The shell that formed on the surface of the cube, preventing EM waves
two curves for 30 mm and 50 mm cubes show a similar trend, with from thawing the core. The heating uniformity and thawing time
lowest S11 (highest energy absorption) at their corresponding grew exponentially with length while energy density demon-
shifted resonant frequencies. Notice that for the 30 mm cube, the strated maximum (most efficient) energy usage at 30 mm. Overall,
resonant frequency is very close to the excitation (2.45 GHz) and the model demonstrates a fast and effective way of predicting mi-
this reiterates the results from Fig. 15a, which shows that S11 is the crowave heating rate and uniformity in a beef substitute.
lowest for the 30 mm cube.
Fig. 15c shows that with continually changing dielectric prop-
Acknowledgment
erties energy absorption increases (S11 decreases) during the initial
5 s, followed by decrease, and eventually stabilizing after 40 s. This
This work is supported in part by a scholarship from the China
is because of the dielectric resonator effect. Because of the low
Scholarship Council (CSC) under CSC grant No. 201306240024.
impedance (due mostly to the high dielectric constant) of tylose
(see Fig. 9), the tylose cube can itself be a high dielectric resonator
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