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E Zinc Nickel SLOTOLOY ZN 320
E Zinc Nickel SLOTOLOY ZN 320
E Zinc Nickel SLOTOLOY ZN 320
SLOTOLOY ZN 320
Zinc-Nickel SLOTOLOY ZN 320 is a weak acidic, ammonium- and boric acid-free
electrolyte. It’s used for the deposition of silky matt or bright zinc-nickel alloy coatings with a
nickel content of 12 - 15 % by weight.
Zinc-Nickel SLOTOLOY ZN 320 is suitable for both rack (preferably cast iron !) and barrel
application.
The metal content of the electrolyte is maintained in the correct ratio by the application of
separate zinc- and nickel anodes. The electric circuit is separated on the anode side that
means separate rectifiers are used for the particular anode type.
The electrolyte is characterized by a constant alloy composition over a wide current density
range.
The information in this data sheet is based on laboratory as well as practical experience.
Figures quoted for operating limits and replenishment quantities are for guidance. Actual
values necessary will depend on the components being plated (material and geometry), their
application and plating plant conditions.
Important:
Please read this instruction carefully prior to the use of the process and carefully follow all the
parameters that have a direct influence on the operation. We reserve the right to make technical
changes. In the interest of safety, please pay attention to the hazard warnings on the labels of the
containers. The minimum shelf life of the products is included on the labels and is also available in the
appropriate Quality Assurance (QA03).
The current IMDS number of the layer deposited from the process is available on the internet at
www.schloetter.com/downloads.
For the storage of chemical products the TRGS 510 must be followed.
If the additives used in this process contain a SVHC-substance, then this will be specified in
the corresponding Material Safety Data Sheet, section 15.
The electrolyte is ready for use when the operating temperature has been reached.
* The optimum of 75 ml/l is valid for used electrolytes. The optimum for a new make-up
is 60 ml/l.
** The operating temperature shouldn’t drop below 25 °C, since crystallizations may form
but normally they’re reversible.
3.1 Pre-treatment
The parts are treated as usual according to the basic material. Our technical field service and
our service department would be pleased to provide you with information about suitable
process sequences respectively -methods as well as suitable products from our
pre-treatment programme.
Our service department would be pleased to provide you with information about the specific
pre-treatment of cast iron.
3.3 Post-treatment
The first static rinse after the zinc-nickel electrolyte is acidified with hydrochloric acid to
pH 3 - 4. This will prevent from the adhesion of electrolyte residues on the surface. This
would lead to problems in the passivating process.
3.4 Stripping
Racks and rework are stripped in non-inhibited 1 : 1 hydrochloric acid solution. Inhibitors may
cause a dark, sweepable film, which, in general, cannot be removed completely by anodic
degreasing. As a second step, the parts must be briefly treated in a nickel stripper
(e.g. BATH 01033-E Stripper L or BATH 01039-E Stripper N 10).
Zinc: 28 - 35 g/l
Nickel: 28 - 35 g/l
The total metal content should be 60 - 70 g/l. Otherwise, there’s a risk of burnings in the high
current density area.
In order to get a coating with a nickel content of 12 - 15 % by weight, the zink : nickel ratio
must be adjusted to 1.0 - 1.2 : 1.
To increase the zinc content by 1 g/l, 2.08 g/l of zinc chloride are needed.
To increase the nickel content by 1 g/l, 4.05 g/l of nickel chloride x 6 H2O are needed.
At insignificant deviations from the optimum zinc : nickel concentration ratio, a correction can
be made by a change of the zinc : nickel current ratio.
NB
It should be ensured that a highest possible quality (> 97 %) of the zinc chloride applied is
used. The content of heavy metals should be as low as possible. The current product
qualities respectively -specifications recommended by us can be found
on the internet at www.schloetter.com/downloads.
Furthermore, salts (also potassium chloride and potassium acetate) with anticaking agents or
other parting agents should generally not be used. In case of doubt please contact our
service department or technical field service.
4.2 Chloride
The chloride concentration is co-responsible for a good alloy- and metal distribution.
Therefore, it should be monitored at regular intervals and maintained in the close range of
160 - 190 g/l. An addition of 10 g of potassium chloride corresponds to 4.7 g of chloride, i.e.
in order to increase the chloride concentration by 1 g/l, 2.1 g/l of potassium chloride must be
added.
NB
We generally recommend operating barrel electrolytes without Additive SLOTOLOY ZN 323
→ danger of tinsel formation.
Caution: Additive SLOTOLOY ZN 327 is diluted with deionised water at a ratio of 1 : 1 prior
to the corrective additions. If a continuous dosing with Additive SLOTOLOY ZN 327 should
be necessary, it can be added as a mixture of additives with
Additive SLOTOLOY ZN 322. The range for a continuous dosing is approx.
0.15 - 0.3 l/10 kAh
4.9 pH value
The pH value is monitored at regular intervals and maintained in the range of 5.3 - 5.6, an
optimum 5.5.
raise pH value ↑: KOH, 10 % (110 g/l aqueous)
decrease pH value ↓: diluted HCl (1 : 1) aqueous
If necessary it’s under current stirring slowly raised ↑ by KOH, 10 % (110 g/l aqueous) in
order to avoid flocculation.
An automated control of the pH value with acid dosage is recommended to increase the
process stability.
NB
The operating temperature shouldn’t drop below 25 °C, since crystallizations may form.
There’s normally a re-dissolution at operating temperature.
6.0 EFFLUENT
Legal regulations must be observed for disposal of the Bright Zinc SLOTOLOY ZN 320.
Different regulations normally apply for the additives and the ready-made electrolyte. Please
refer to section 13 of the appropriate Material Safety Data Sheet for disposal code and
recommendations.
Waste waters from Zink-Nickel SLOTOLOY ZN 320 also contain a marginal content of
complex bound metal ions. For rinse water treatment a pH value of 6 has to be adjusted with
diluted sodium hydroxide. The metal ions are subsequently precipitated with e.g.
Precipitant AW 10 and filtered.
EC Material Safety Data Sheets must be made available to all personnel dealing with the
chemicals to ensure they have all required information about product composition, hazards
identification, first-aid measures, handling and storage, exposure controls, toxicological and
ecological information, etc. It is required to ensure the supply and use of suitable protective
clothing and -equipment.
The user must verify the designated purpose of the electrolyte. Previous experience has shown that not all metal
surfaces are suitable for a trouble-free electroplating.
The above mentioned data are made according to our best knowledge. Consistent operation of the working solution requires appropriate
maintenance. Zinc-Nickel SLOTOLOY ZN 320 is a process of Dr.-Ing. Max Schlötter GmbH & Co KG. it can only be operated with the
products described in this technical data sheet. Use of other chemicals (also partly) will impair quality and invalidates our service- and
quality commitments (quality assurance).