E Zinc Nickel SLOTOLOY ZN 320

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Zinc-Nickel

SLOTOLOY ZN 320
Zinc-Nickel SLOTOLOY ZN 320 is a weak acidic, ammonium- and boric acid-free
electrolyte. It’s used for the deposition of silky matt or bright zinc-nickel alloy coatings with a
nickel content of 12 - 15 % by weight.

Zinc-Nickel SLOTOLOY ZN 320 is suitable for both rack (preferably cast iron !) and barrel
application.

The metal content of the electrolyte is maintained in the correct ratio by the application of
separate zinc- and nickel anodes. The electric circuit is separated on the anode side that
means separate rectifiers are used for the particular anode type.

The electrolyte is characterized by a constant alloy composition over a wide current density
range.

By a corresponding chromium(III) containing passivation from our SLOTOPAS series,


transparent, blue and black conversion layers with high corrosion protection can be
produced. For a possible subsequent sealing, products of our SLOTOFIN series are
available.

The information in this data sheet is based on laboratory as well as practical experience.
Figures quoted for operating limits and replenishment quantities are for guidance. Actual
values necessary will depend on the components being plated (material and geometry), their
application and plating plant conditions.

Important:
Please read this instruction carefully prior to the use of the process and carefully follow all the
parameters that have a direct influence on the operation. We reserve the right to make technical
changes. In the interest of safety, please pay attention to the hazard warnings on the labels of the
containers. The minimum shelf life of the products is included on the labels and is also available in the
appropriate Quality Assurance (QA03).
The current IMDS number of the layer deposited from the process is available on the internet at
www.schloetter.com/downloads.
For the storage of chemical products the TRGS 510 must be followed.
If the additives used in this process contain a SVHC-substance, then this will be specified in
the corresponding Material Safety Data Sheet, section 15.

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Dr.-Ing. Max Schlötter T +49 (0) 7331-205-0 Certified Quality


GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
1.0 TECHNICAL INFORMATION AND EQUIPMENT REQUIREMENTS
Tanks: rubber-lined steel, polypropylene
Exhaust: required
Part/Electrolyte Agitation: work piece movement parallel to the anodes, 2 - 4 m/min.
stroke length approx. 70 mm; for rack plants an oil-free,
evenly fine-sparking air injection is recommended
Filtration: continuous, turnover 1 - 2 mal per hour;
filter mesh 5 - 15 µm
Anodes: zinc: oval anodes (the contacting of the anodes should be
above the solution level)
nickel: oval- or plate anodes or titanium anode baskets with
rounds, pellets or the like
Anode bags: for rack plants anode bags made of polypropylene fabric are
recommended
Current supply: two separate circuits for zinc- and nickel anodes; Zn : Ni
current ratio = 4 : 1
Heating: immersion heaters made of porcelain, PTFE or titanium
heating coils
Cooling: cooling coils of titanium of PTFE

2.0 MAKE-UP AND OPERATING CONDITIONS

2.1 Product names


List of products required
Product name Articel no. (AN) SG
Zinc chloride* (see point 4.1) supplied by user* --
Nickel chloride x 6 H2O according to DIN 50970* supplied by user* --
Potassium acetate solution, 52 % by weight 130801 1.29
alternatively:
Potassium acetate supplied by user* --
Potassium chloride supplied by user* --
Additive SLOTOLOY ZN 321 083121 1.17
Additive SLOTOLOY ZN 322 083122 1.05
Additive SLOTOLOY ZN 323 083123 1.02
Additive SLOTOLOY ZN 324 083124 1.03
Additive SLOTOLOY ZN 326** 083126 1.09
Additive SLOTOLOY ZN 327 083127 1.10
* Product quality specifications recommended by us can be found on the internet at
www.schloetter.com/downloads.

** Field of application, see point 4.8

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GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
2.2 Requirements for a 100 litre bath

2.2.1 when used in a barrel installation


Product name AN SG Quantity
Zinc chloride (see point 4.1) -- -- 6.25 kg
Nickel chloride x 6 H2O according to DIN 50970 -- -- 11.35 kg
Potassium chloride -- -- 22 kg
Potassium acetate solution, 52 % by weight 130801 1.29 5.4 ltr.
alternatively:
Potassium acetate -- -- 3.6 kg
Additive SLOTOLOY ZN 321 083121 1.17 6.0 ltr.
Additive SLOTOLOY ZN 322 083122 1.05 2.0 ltr.
Additive SLOTOLOY ZN 323 083123 1.02 --* ltr.
* The new make-up is made without Additive SLOTOLOY ZN 323. Dosing with
Additive SLOTOLOY ZN 323 will be started only after an electrolyte load of approx.
5 - 10 Ah/l.

2.2.2 when used in a rack installation


Product name AN SG Quantity
Zinc chloride (see point 4.1) -- -- 6.25 kg
Nickel chloride x 6 H2O according to DIN 50970 -- -- 11.35 kg
Potassium chloride -- -- 22 kg
Potassium acetate solution, 52 % by weight 130801 1.29 5.4 ltr.
alternatively:
Potassium acetate -- -- 3.6 kg
Additive SLOTOLOY ZN 321 083121 1.17 6.0 ltr.
Additive SLOTOLOY ZN 322 083122 1.05 2.0 ltr.
Additive SLOTOLOY ZN 324 083124 1.03 10 ml

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GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
2.3 Make-up sequence for a 100 litre bath
All tanks and equipment to be used should be thoroughly cleaned prior to make-up.

2.3.1 when used in a barrel installation


 fill 70 litres of preferably deionised water into the tank
 heat up to approx. 50 °C
 add 22 kg of potassium chloride and dissolve completely
 add 5.4 litres of potassium acetate solution, 52 % by weight
alternatively:
 add 3.6 kg of potassium acetate and dissolve completely
 add 6.25 kg of zinc chloride and dissolve completely
 add 11.35 kg of nickel chloride and dissolve completely
 add 6 litres of Additive SLOTOLOY ZN 321
 mix thoroughly
 add 2.0 litres of Additive SLOTOLOY ZN 322
 make up to final volume with preferably deionised water
 mix thoroughly
 adjust pH value ↑ with KOH, 10 % (110 g/l aqueous) respectively ↓ HCl diluted
aqueous 1 : 1 to 5.5 - 5.6

The electrolyte is ready for use when the operating temperature has been reached.

2.3.2 when used in a rack installation


 fill 70 litres of preferably deionised water into the tank
 heat up to approx. 50 °C
 add 22 kg of potassium chloride and dissolve completely
 add 5.4 litres of potassium acetate solution, 52 % by weight
alternatively:
 add 3.6 kg of potassium acetate and dissolve completely
 add 6.25 kg of zinc chloride and dissolve completely
 add 11.35 kg of nickel chloride and dissolve completely
 add 6 litres of Additive SLOTOLOY ZN 321
 mix thoroughly
 add 2.0 litres of Additive SLOTOLOY ZN 322
 add 10 ml of Additive SLOTOLOY ZN 324
 make up to final volume with preferably deionised water
 mix thoroughly
 adjust pH value ↑ with KOH, 10 % (110 g/l aqueous) respectively ↓ diluted HCl (1 : 1)
aqueous to 5.5 - 5.6

The electrolyte is ready for use when the operating temperature has been reached.

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GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
2.4 Concentrations and operating conditions

2.4.1 when used in a barrel installation


Range Optimum
Zinc 28 - 35 30 g/l
Nickel 28 - 35 28 g/l
Metal ratio Zn:Ni 1.0 - 1.2 : 1.0 --
Chloride 160 - 190 180 g/l
Potassium acetate 50 - 70 60 g/l
Additive SLOTOLOY ZN 321* 60 - 90 75 ml/l
Additive SLOTOLOY ZN 322 15 - 25 20 ml/l
Additive SLOTOLOY ZN 323 0 - 2 comp. 4.6 ml/l
Additive SLOTOLOY ZN 327 2 - 5 2.5 ml/l
Operating temperature** 28 - 32 30 °C
pH value 5.3 - 5.6 5.5
Cathodic current density 0.5 - 1.0 -- A/dm2
Anodic current density < 4.0 -- A/dm2
Current ratio Zn : Ni 4:1
Deposition rate at 1 A/dm² 0.18 - 0.20 µm/min.

2.4.2 when used in a rack installation


Range Optimum
Zinc 28 - 35 30 g/l
Nickel 28 - 35 28 g/l
Metal ratio Zn : Ni 1.0 - 1.2 : 1.0 --
Chloride 160 - 190 180 g/l
Potassium acetate 50 - 70 60 g/l
Additive SLOTOLOY ZN 321* 60 - 90 75 ml/l
Additive SLOTOLOY ZN 322 15 - 25 20 ml/l
Additive SLOTOLOY ZN 324 0.1 - 0.7 comp. 4.7 ml/l
Additive SLOTOLOY ZN 327 2 - 6 2.5 ml/l
Operating temperature** 28 - 32 30 °C
pH value 5.3 - 5.6 5.5
Cathodic current density 1.0 - 2.0 -- A/dm2
Anodic current density < 4.0 -- A/dm2
Circuit ratio Zn : Ni 4:1
Deposition rate at 1 A/dm² 0.22 - 0.24 µm/min.

* The optimum of 75 ml/l is valid for used electrolytes. The optimum for a new make-up
is 60 ml/l.
** The operating temperature shouldn’t drop below 25 °C, since crystallizations may form
but normally they’re reversible.

raise pH value ↑: KOH, 10 % (110 g/l aqueous)


decrease pH value ↓: diluted HCl (1 : 1) aqueous

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73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
2.5 Consumption and replenishment
The consumption of the additives is due to drag-out, geometry and surface condition of the
parts.

2.5.1 when used in a barrel installation


Approximate values for replenishment:
Additive Replenishment / Consumption
Additive SLOTOLOY ZN 321 approx. 3.0 - 6.0 l/10 kAh
Additive SLOTOLOY ZN 322 approx. 0.8 - 1.8 l/10 kAh
Additive SLOTOLOY ZN 323* (approx. 1.5 - 2.5 l/10 kAh)

* Only when special bright layers are required a continuous dosing of


Additive SLOTOLOY ZN 323 can be necessary.

2.5.2 when used in a rack installation


Approximate values for replenishment:
Additive Replenishment / Consumption
Additive SLOTOLOY ZN 321 approx. 2.0 - 4.0 l/10 kAh
Additive SLOTOLOY ZN 322 approx. 0.8 - 1.2 l/10 kAh
Additive SLOTOLOY ZN 324* approx. 0.5 - 0.8 l/10 kAh

3.0 PROCESS SEQUENCE

3.1 Pre-treatment
The parts are treated as usual according to the basic material. Our technical field service and
our service department would be pleased to provide you with information about suitable
process sequences respectively -methods as well as suitable products from our
pre-treatment programme.

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73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
3.2 Process sequence
Base material steel:
 immersion degreasing
 rinsing
 pickling
 rinsing
 electrolytic degreasing, anodic
 rinsing
 neutralizing in diluted hydrochloric acid
 rinsing
 zinc-nickel plating
 rinsing (see point 3.3)
 passivating
 rinsing
 optionally: sealing
 drying

Our service department would be pleased to provide you with information about the specific
pre-treatment of cast iron.

3.3 Post-treatment
The first static rinse after the zinc-nickel electrolyte is acidified with hydrochloric acid to
pH 3 - 4. This will prevent from the adhesion of electrolyte residues on the surface. This
would lead to problems in the passivating process.

3.4 Stripping
Racks and rework are stripped in non-inhibited 1 : 1 hydrochloric acid solution. Inhibitors may
cause a dark, sweepable film, which, in general, cannot be removed completely by anodic
degreasing. As a second step, the parts must be briefly treated in a nickel stripper
(e.g. BATH 01033-E Stripper L or BATH 01039-E Stripper N 10).

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Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
4.0 MAINTENANCE AND FUNCTION OF THE INDIVIDUAL BATH COMPONENTS

4.1 Metal content


The metal content of the electrolyte must be monitored analytically at regular intervals and
should be in the following concentration ranges:

Zinc: 28 - 35 g/l
Nickel: 28 - 35 g/l

The total metal content should be 60 - 70 g/l. Otherwise, there’s a risk of burnings in the high
current density area.
In order to get a coating with a nickel content of 12 - 15 % by weight, the zink : nickel ratio
must be adjusted to 1.0 - 1.2 : 1.

To increase the zinc content by 1 g/l, 2.08 g/l of zinc chloride are needed.
To increase the nickel content by 1 g/l, 4.05 g/l of nickel chloride x 6 H2O are needed.

At insignificant deviations from the optimum zinc : nickel concentration ratio, a correction can
be made by a change of the zinc : nickel current ratio.

NB
It should be ensured that a highest possible quality (> 97 %) of the zinc chloride applied is
used. The content of heavy metals should be as low as possible. The current product
qualities respectively -specifications recommended by us can be found
on the internet at www.schloetter.com/downloads.
Furthermore, salts (also potassium chloride and potassium acetate) with anticaking agents or
other parting agents should generally not be used. In case of doubt please contact our
service department or technical field service.

4.2 Chloride
The chloride concentration is co-responsible for a good alloy- and metal distribution.
Therefore, it should be monitored at regular intervals and maintained in the close range of
160 - 190 g/l. An addition of 10 g of potassium chloride corresponds to 4.7 g of chloride, i.e.
in order to increase the chloride concentration by 1 g/l, 2.1 g/l of potassium chloride must be
added.

4.3 Potassium acetate


The concentration of potassium acetate is monitored at regular intervals and maintained in
the range of 50 - 70 g/l. Potassium acetate extends the current density range upwards and
contributes to buffer the pH value.

4.4 Additive SLOTOLOY ZN 321


The Additive SLOTOLOY ZN 321 contains complexing agents and buffer substances. It
ensures an even alloy distribution over the entire applicable current density range and at the
same time ensures a stable operation of the system.

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73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
4.5 Additive SLOTOLOY ZN 322
The Additive SLOTOLOY ZN 322 produces as a brightening agent a fine-crystalline, satin-
matt deposition and supports the optimal alloy distribution. At the same time the additive
improves the covering power in the low current density ranges. The formation of pores will
also be prevented by this additive.

4.6 Additive SLOTOLOY ZN 323


The Additive SLOTOLOY ZN 323 operates as a brightener in barrel electrolytes and enables
so the deposition of even, semi-bright to bright alloy layers.
In case of a decrease of the degree of brightness, Additive SLOTOLOY ZN 323 can be
added in increments of 0.25 ml/l. Overdoses have to be avoided, since they have a negative
effect on the ductility of the layer.
The dosage of Additive SLOTOLOY ZN 323 will be started only after an electrolyte load of
approx. 5 - 10 Ah/l. It’s not required for new make-up.

NB
We generally recommend operating barrel electrolytes without Additive SLOTOLOY ZN 323
→ danger of tinsel formation.

4.7 Additive SLOTOLOY ZN 324


The Additive SLOTOLOY ZN 324 acts as a brightener in rack electrolytes and enables so the
deposition of even, bright alloy layers.
In case of a decrease of the degree of brightness, Additive SLOTOLOY ZN 324 can be
added in increments of 0.1 - 0.2 ml/l. The total concentration shouldn’t exceed 0.7 ml/l !
Excess dosing has to be avoided, since they have a negative impact on the ductility of the
layer. Overdoses may result in the formation of tinsel.

4.8 Additive SLOTOLOY ZN 326


When used in a rack installation, applicating Additive SLOTOLOY ZN 324, a milky-hazy
deposition despite of correct concentration of Additive SLOTOLOY ZN 322 occurs, then it
can be corrected by an addition of 0.5 - 1.0 ml/l Additive SLOTOLOY ZN 326.

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GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
4.9 Additive SLOTOLOY ZN 327
Additive SLOTOLOY ZN 327 improves the covering power in the low current density range
and increases the fine grain of the deposition. It can help to improve the appearance and
adhesion in plating of critical components. Additive SLOTOLOY ZN 322 already contains the
active component of Additive SLOTOLOY ZN 327 (1 ml/l of Additive SLOTOLOY ZN 322
contains 0.125 ml/l of Additive SLOTOLOY ZN 327).
Additive SLOTOLOY ZN 327 is added in cases when despite of correct replenishment of
Additive SLOTOLOY ZN 322 a decrease of the concentration has been found. Especially
when there’s a higher iron content in the electrolyte, extra additions of Additive
SLOTOLOY ZN 327 can become necessary.

Caution: Additive SLOTOLOY ZN 327 is diluted with deionised water at a ratio of 1 : 1 prior
to the corrective additions. If a continuous dosing with Additive SLOTOLOY ZN 327 should
be necessary, it can be added as a mixture of additives with
Additive SLOTOLOY ZN 322. The range for a continuous dosing is approx.
0.15 - 0.3 l/10 kAh

4.9 pH value
The pH value is monitored at regular intervals and maintained in the range of 5.3 - 5.6, an
optimum 5.5.
raise pH value ↑: KOH, 10 % (110 g/l aqueous)
decrease pH value ↓: diluted HCl (1 : 1) aqueous
If necessary it’s under current stirring slowly raised ↑ by KOH, 10 % (110 g/l aqueous) in
order to avoid flocculation.
An automated control of the pH value with acid dosage is recommended to increase the
process stability.

4.10 Operating temperature


The acceptable operating temperature range is 28 - 32 °C. Due to the strong influence of the
operating temperature on the alloy composition it has to be taken care on an exact
temperature control and a good electrolyte agitation. The nickel co-deposition is increased by
raising operating temperature.

NB
The operating temperature shouldn’t drop below 25 °C, since crystallizations may form.
There’s normally a re-dissolution at operating temperature.

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Germany DIN EN ISO 50001: 2011
5.0 TROUBLE SHOOTING

5.1 Fault finding chart

Fault Cause Correction


dark deposition in metallic contamination like Cu, dummy plating at 0.3 - 0.5 A/dm²,
the low current Pb or Sn at least 2 Ah/l
density range, poor zinc dust treatment: 1 - 2 g/l of
throwing power zinc dust (PA-quality) intensively
stir into the electrolyte solution
and filter after approx. 2 hours
very high concentration of allowing the content of Additive
Additive SLOTOLOY ZN 321 SLOTOLOY ZN 321 to sink
very low content of Additive addition of 2 - 4 ml/l of
SLOTOLOY ZN 322 SLOTOLOY ZN 322
low content of Additive addition of 0.5 - 1 ml/l of
SLOTOLOY ZN 327 SLOTOLOY ZN 327
dark deposition in metallic contamination dummy plating at 0.3 - 0.5 A/dm²
the area of the contact points have been strip the contacts in diluted HCl
contact Zn-Ni plated respectively bad (1 : 1) aqueous before deposition
contacting
lack of after analysis: addition of
Additive SLOTOLOY ZN 322 2 - 4 ml/l
Additive SLOTOLOY ZN 322
poor covering in the content of Additive allow the content of Additive
low current density SLOTOLOY ZN 321 too high SLOTOLOY ZN 321 to decrease
area content of Additive after analysis:
SLOTOLOY ZN 322 too low addition of 2 - 4 ml/l
Additive SLOTOLOY ZN 322
content of Additive addition of 0.5 - 1 ml/l
SLOTOLOY ZN 327 too low Additive SLOTOLOY ZN 327
temperature too high decrease the temperature to
optimum
nickel content too high allow the content of nickel to
decrease
matt deposition in chloride concentration too low raise the chloride concentration to
the low current optimum
density range
rack electrolyte: lack of addition of
brightness stops, Additive SLOTOLOY ZN 324 Additive SLOTOLOY ZN 324 in
matt deposition in increments of 0.1 - 0.2 ml/l; a
the low current total concentration of 0.7 ml/l
density range shouldn’t be exceeded !

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73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
Fault Cause Correction
milky-hazy lack of addition of 0.5 - 1.0 ml/l of
deposition Additive SLOTOLOY ZN 326 Additive SLOTOLOY ZN 326
lack of after analysis:
Additive SLOTOLOY ZN 322 adjust content of
Additive SLOTOLOY ZN 322 to
optimum
matt deposition in lack of addition of 2 - 4 ml/l
the low current Additive SLOTOLOY ZN 322 Additive SLOTOLOY ZN 322
density range barrel electrolyte: addition of Additive
lack of Additive SLOTOLOY ZN 323 in
SLOTOLOY ZN 323 increments of 0.25 ml/l
rack electrolyte: addition of Additive
lack of Additive SLOTOLOY ZN 324 in
SLOTOLOY ZN 324 increments of 0.1 - 0.2 ml/l
operating temperature too high lower temperature to optimum
again
metallic- or organic selective cleaning at
contamination in the electrolyte 0.3 - 0.5 A/dm² or dummy plating
of the electrolyte
chromium(VI) contamination dummy plating with high current
density 20 - 40 A/dm² at small
surface e.g. wire
alloy contains too too much zinc respectively too increase the nickel content, adjust
much zinc less nickel in the electrolyte the Zn : Ni ratio of the
concentration to a value of
1.0 - 1.2 : 1
temperature too low adjust temperature to optimum
pH value too high decrease ↓ pH value with diluted
HCl (1 : 1) aqueous to optimum
content of Additive after analysis:
SLOTOLOY ZN 321 too low adjust concentration of
Additive SLOTOLOY ZN 321 to
optimum
chloride content too low after analysis:
adjust chloride content to
optimum
electrolyte agitation or work reduce electrolyte agitation
piece movement too strong respectively work piece
movement

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73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
Fault Cause Correction
alloy contains too too much nickel respectively increase the zinc content; adjust
much nickel too less zinc in the electrolyte the Zn : Ni ratio to a value of
1.0 - 1.2 : 1
temperature too high adjust temperature to optimum
pH value too low adjust pH value
content of Additive after analysis:
SLOTOLOY ZN 321 too high adjust concentration of
Additive SLOTOLOY ZN 321 to
optimum
chloride content too high after analysis:
adjust chloride content to
optimum
after analysis zinc Zn anodes without current in change circuit ratio on behalf of Ni,
content too high the electrolyte for a longer e.g. Zn : Ni = 3 : 1 or addition of
period of time, e.g. weekend nickel chloride
wrong circuit ratio
according to analysis, wrong circuit ratio change circuit ratio on behalf of
nickel content too Zn, e.g. Zn : Ni = 6 : 1 or addition
high of zinc chloride
pittings lack of Additive addition of 2 - 4 ml/l
SLOTOLOY ZN 322 Additive SLOTOLOY ZN 322
burnings / matt current density too high reduce current density
deposition in the high total metal content too low add zinc and nickel in ratio
current density area concentration of potassium adjust the concentration of
acetate too low potassium acetate to optimum
rough deposition crystallization due to a too low raise electrolyte temperature to
operating temperature or 30 °C, permanent filtration and use
floating particles in the of anode bags
electrolyte
turbid electrolyte pH value too high for a longer adjust pH value with diluted HCl
period of time, sludge formation (1 : 1) aqueous
electrolyte contaminated filter the electrolyte
electrolyte > 40 °C reduce operating temperature
lack of Additive after analysis:
SLOTOLOY ZN 322 correct content of
Additive SLOTOLOY ZN 322
current efficiency too pH value too low raise ↑ the pH value with KOH,
low 10 % (110 g/l aqueous) while
stirring
total metal content too low correct content of Zn and Ni
according to analysis
electrolyte temperature too low adjust temperature to optimum

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Dr.-Ing. Max Schlötter T +49 (0) 7331-205-0 Certified Quality


GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
Fault Cause Correction
adhesion problems, current density too high reduce current density to values
flake off specified
barrel rotation too high reduce barrel rotation to 6 rpm
deposition period too long reduce deposition period
bad contacts, e.g. disc contacts use oval contacts; check
or current interruption during electrical supply, contacts and
deposition rectifier
poor pre-treatment check pre-treatment
barrel electrolyte: allow concentration of Additive
concentration of SLOTOLOY ZN 323 to decrease
Additive SLOTOLOY ZN 323
too high
rack electrolyte: allow concentration of Additive
concentration of Additive SLOTOLOY ZN 324 to decrease
SLOTOLOY ZN 324 too high
nickel content in the alloy layer decrease nickel concentration in
too high the electrolyte or increase zinc
content or lower the operating
temperature to 30 °C or raise ↑
pH value to 5.5 - 5.6

6.0 EFFLUENT
Legal regulations must be observed for disposal of the Bright Zinc SLOTOLOY ZN 320.
Different regulations normally apply for the additives and the ready-made electrolyte. Please
refer to section 13 of the appropriate Material Safety Data Sheet for disposal code and
recommendations.

The following detoxification sequence is only considered to be an aid:

Waste waters from Zink-Nickel SLOTOLOY ZN 320 also contain a marginal content of
complex bound metal ions. For rinse water treatment a pH value of 6 has to be adjusted with
diluted sodium hydroxide. The metal ions are subsequently precipitated with e.g.
Precipitant AW 10 and filtered.

BATH 08312-E Page 14 of 15 Issue 11.10.2016

Dr.-Ing. Max Schlötter T +49 (0) 7331-205-0 Certified Quality


GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011
7.0 SAFETY
Reasonable care is required when handling chemical products. Only personnel specially
trained on working with chemicals should be deployed with their handling.

EC Material Safety Data Sheets must be made available to all personnel dealing with the
chemicals to ensure they have all required information about product composition, hazards
identification, first-aid measures, handling and storage, exposure controls, toxicological and
ecological information, etc. It is required to ensure the supply and use of suitable protective
clothing and -equipment.

The user must verify the designated purpose of the electrolyte. Previous experience has shown that not all metal
surfaces are suitable for a trouble-free electroplating.

The above mentioned data are made according to our best knowledge. Consistent operation of the working solution requires appropriate
maintenance. Zinc-Nickel SLOTOLOY ZN 320 is a process of Dr.-Ing. Max Schlötter GmbH & Co KG. it can only be operated with the
products described in this technical data sheet. Use of other chemicals (also partly) will impair quality and invalidates our service- and
quality commitments (quality assurance).

BATH 08312-E Page 15 of 15 Issue 11.10.2016

Dr.-Ing. Max Schlötter T +49 (0) 7331-205-0 Certified Quality


GmbH & Co. KG F +49 (0) 7331-205-123 Company according to
Talgraben 30 info@schloetter.de DIN EN ISO 9001: 2008
73312 Geislingen/Steige w w w.schloetter.de DIN EN ISO 14001: 2004
Germany DIN EN ISO 50001: 2011

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