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Faculty of Health Sciences

Advanced Analytical Techniques

Tutorial -01

1. What mass of Ca(OH)2 is present in a sample if it is titrated to its equivalence point with
44.02 mL of 0.0885 M HNO3?
2. What mass of H2C2O4 is present in a sample if it is titrated to its equivalence point with
18.09 mL of 0.2235 M NaOH?
3. If 25.00 mL of HCl solution with a concentration of 0.1234 M is neutralized by 23.45 mL of
NaOH, what is the concentration of the base?
4. A 20.0 mL solution of Strontium hydroxide is placed in a flask and a drop of indicator is
added. The solution turns colour after 25.0 mL of a standard 0.0500 M HCl solution is
added. What was the original concentration of the Strontium hydroxide solution?
5. Calculate the pH of a solution prepared by adding 88.0 mL of a 0.213 M HCl solution to
125.0 mL of a 0.150 M solution of ammonia. The pKb of ammonia is 4.75 at 25°C.
6. A student carried out a non-aqueous titration at chemistry laboratory using 0.1N solution of
HClO4 acid. She obtained with 0.06 N as the calculated normality of HClO4 acid after the
standardization. Standardized HClO4 acid was titrated with 0.2 g of Ephedrine
hydrochloride in mercuric acetate solution. Calculate the percentage of Ephedrine
hydrochloride. Volume of titrant consumed at end point was 25 mL.
Note: 1 ml of 0.1 M HClO4 acid is equivalent to 0.02017 g of Ephedrine hydrochloride.