PHYS2020 Semester One 2016 ‘Worksheet 3: Energy, enthalpy and heat capacities, 3 Energy, enthalpy and heat capacities 3.1 Energy vs Enthalpy (10 mins) Explain the difference between the change in internal energy and the change in enthalpy ‘accompanying a chemical or physical process. He U+PV |. ses Pav = BU — Wejnasion AX constant pressure, We change wm Ht We crowe in U less Tne expausid ugorle de to any value cw mAe > A= Qo comaul exesne av= Qa » w \roluwe Woo other work 3.2. Isothermal ys adiabatic (10 mins) Consider two identical sealed pistons containing air. ‘They are each compressed from an initial volume V; to a final volume V;, but one is compressed quickly (before heat can escape), and one is compressed very slowly. Which one requires the most amount of work? Include sketches of PY curves in your explanation. gqack adialor\ic (GQ) =0) oT (ow . cotlerwal(eten) | dec cue. agerker a ork eg Mi | (hiqher pressor, sive euetgy, taunt eacope as Week , leading, Jo an Waclease iw a) 6 0f 37PHYS2020 Semester One 2016 ___Worksheet 3: Bnergy, enthalpy and heat capacities 3.3. Anice cup of tea (20 mins) Your 200 g cup of tea is boiling-hot. About how much ice should you add to bring it down toa comfortable sipping temperature of 65° C? (Assume that the ice is initially at 15°C. The enthalpy of fusion is 6,01 kJ/mol, the enthalpy of vaporization is 40,68 kI/mol, the specific heat of ice is 2.084 Ug, the specific heat of water is 4,184 I/g.K, and the specific heat of steam (at 100°C) is 1.996 Jig.K) To dectesse Wa lew pecocture Of Mae on , we wast exicack energy, (ac trea). Que Mey OT : = + 3 BK 7 2004 4 beth Re a 1,300 3 a (s Shack wah 7) 2 The neat apis, trio He ce wil case ts lempenlhe do OC, wel} th, thew tase Vs lem petaluve agnie) OAD a tence) OS, care : a Be grow pea \ wee CRIS + BR | — NY wanler © woe ws +O 465% wes Ti BE = LOBE TBKxISK + Boley + pith She + 66K Alvi 5 B26 Sly + B34 Se ~y 24a 34 = 63% 3 Awoon of sce required, : MM of 37