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0.1N Silver Nitrate
0.1N Silver Nitrate
0.1N Silver Nitrate
Experiment no. 1
Preparation and Standardization
0.1 Silver Nitrate (AgNO3) VS
I. Principle Involved
Dissolve about 17.5 g of silver nitrate in 1000 mL of water and standardize the solution
as follows:
N=
After the standardization, decant the liquid from the reaction flask. The liquid can be
disposed into the sink. The silver chloride precipitate can be disposed to the metal wastes bottle.
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0.1 N Silver Nitrate VS Preparation and Standardization
indicator, eosin y, is repelled by the precipitate and remains in the solution where it has a
greenish yellow color. After the end point, the precipitate has a positive surface charge due
to the adsorption of excess Ag+. The anionic indicator now adsorbs to the precipitate’s
surface where its color is pink. This change in color signals the endpoint. (Harvey, 2000, 354)
5. Acetic Acid is added to the solution to prevent a premature endpoint by suppressing the
ionization of eosin, thus, avoiding the displacement of Cl -. in the primary adsorbed layer.
(Jeffery, et al., 1989, 347) The color change is also sharpest in acetic acid solution. (Knevel
and Digangi, 1977. 131)
6. Alcohol, in this case methanol, is added to help keep the precipitated silver chloride in a
colloidal state and thus give sharpness to the color change which occurs in the precipitate
surface. (Knevel and Digangi, 1977, 139)
7. Slow addition of the titrant should be employed with constant stirring to produce a
precipitate with larger particles. (Knevel and Digangi, 1977, 132) In using adsorption
indicators, the precipitate formed should remain highly dispersed, allowing for maximum
surface area of adsorption. (Christian, 2004, 351)
Factor: 1
Explanation: 1 mole of AgNO3 is needed to react with 1 mole of NaCl to form AgCl
VII. Computations
Preparation:
N = MF
0.1 N = M (1)
M = 0.1 mol/liter
Standardization:
VIII. References
CHRISTIAN, G.D., 2004. Analytical Chemistry. 6th edition. New York: John Wiley and Sons, Inc.,
238, 352
HARVEY, D., 2000. Modern Analytical Chemistry. New York: McGraw-Hill Companies, Inc., 354
JEFFERY, G.H., BASSETT, J., MENDHAM, J., DENNEY, R.C., 1989. Vogel’s Textbook of Quantitative
Chemical Analysis. 5th edition. UK: Longman Scientific and Technical, 347, 349
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0.1 N Silver Nitrate VS Preparation and Standardization
KNEVEL, A.M., DIGANGI, F.E., 1977. Jenkins’ Quantitative Pharmaceutical Chemistry. 7th edition.
New York: McGraw-Hill Book Company, 131-132, 130
SVEHLA, G., 1996. Vogel’s Qualitative Inorganic Analysis. 7th edition. England: Longman Group
Ltd., 191
UNITED STATES PHARMACOPOEIAL CONVENTION, INC., 2007. United States Pharmacopoeia 30th
Revision and the National Formulary 25th edition. USP Convention, Rockville, Maryland, 821
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