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FIITJEE

ALL INDIA TEST SERIES


JEE (Advanced)-2023
OPEN TEST – II
PAPER –2
TEST DATE: 16-04-2023

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

Section – A

1. C
Sol. kx0 = Smg …(i)
1 1
Now, kx02  k(x 0  S)2  kmgs
2 2
1
k(2x 0  S)S  k mgS
2
kS
kx0   k mg
2
kS
Smg   k mg
2
kS
 S  k 
2mg
100  6  102
S  0.50 
2  10
S  0.50  0.30  0.80

2. A
9v 9v 9  330 9
Sol. f     m  112.50 cm
4 4f 4  660 8
The amplitude of pressure variation in the pipe is
x=0 x=
a  P0 sin kx
 2x 
a  P0 sin  
  
 2  9x 
a  P0 sin  
 4 

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 2

 9x 
a  P0 sin  
 2 
At x = 18.75 cm = /6
 9  
a  P0 sin   
 2 6 
 3  P0
a  P0 sin   
 4  2
The maximum pressure at x = 18.75 cm is
 P 
Pmax   P0  0 
 2 

3. B
Sol. Thermal resistance of the spherical shell,
3a 3a
dr dr 2a a
R  k4r
a
2
 
a

4r 2
 
4 2
2
r
d     0 
Now, mS  
dt  R 
50 t
d
mSR 
70
(   0 )
 dt 
0
70
t  mSR  n(  0 50
 70  30 
t  mSRn  
 50  30 
t = mSRn2
mSan2
t
2

4. A
Sol. eE = evB
E = Bv …(i)
 A k
q   0  V0 (V0 = potential drop)
 d 
 A
q   0  Ed
 d 
q = 0AE I
d
q = 0ABv
x v
dq dv B
I  0 AB …(ii)
dt dt
Now,
dv
m  kx  BId
dt
dv  dv 
m  kx  Bd  0 AB 
dt  dt 

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3 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

dv dv
m  kx  0 VB 2 (where V = Ad = volume of the disc)
dt dt
dv
 m  0 VB 2
dt

 kx

dv kx

dt (m  0 VB 2 )
d2 x kx

dt 2 (m  0 VB2 )
(m  0 VB2 )
Time period, T  2
k

5. A, C
Sol. Fex  (P2  P1 )A …(i)
dW ex = dU Fex
Fexdx = 2nCVdT V1, T P1 A P 2A
3R V 2, T
(P2  P1)Adx = 2 1 dT
2
dx
P2 dV2  P1dV1  3RdT
dV1 = dV2 = Adx
dV2 nRT
nRT  dV1  3RdT
V2 V1
4V0 2V0
3 3 T
dV1 dV2 dT
 
V0
V1
 
V0
V2
3
T 
T0

 4  2   T 
 n    n     3n  
 3  3   T0 
3 1/3
9  T  T 9
n    n     
8  T0  T0  8 
1/3
 T  250   9   520 K
U  2nCV T
3R
U  2  1  20
2
U  60  8.3  498 Joule

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 4

6. B, C
Q M, R
Sol. I
2
 I  Q R 
B 0  0
 2 O
Induced electric field on the surface of the long cylinder, T
R dB R 0 Q E
E  ( a = R)
2 dt 2 2 T
 Qa a
E 0 …(i) m
4
mg  T = ma …(ii)
MR2 
RT  QER =
2
Ma
T  QE 
2
0 Q 2 a
T  2ma ( M = 4m)
4
T = 3ma …(iii)
From equation (ii) and (iii), we get
3mg
a = g/4 and T =
4

7. A, D
Sol. After the switch ‘S’ is shifted from position-1 to position-2 the current through the inductor L is I1 =
 3Rt 
   
and the current through the inductor 2L is I2  e  2L  .
R R
Hence the current through the switch ‘S’ is I = I1  I2
  3Rt  
  
I  1  e  2L  
R 
 
The total heat dissipated in the resistor 3R after having shifted the switch ‘S’ from position-1 to
position-2 is
2
1 
H  2L  
2 R
L2
H
R2

8. A, B, D
 v  w  vD   330  2  1 
Sol. f1   f     320  327 Hz
 v  w  vS   330  2  8 
The frequency of sound received by the reflector,
 v  w  u   330  2  2 
f      320  330 Hz
 v  w  v S   330  2  8 
The frequency of the reflected wave received by the detector
 v  w  vD   330  2  1 
f2   f     330  333 Hz
 v  w u   330  2  2 
The wavelength of the reflected wave received by the detector,

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5 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

 v  w  vD   330  2  1 
2  
f2

333   1m
   
The beats frequency received by the detector,
fb  f2  f1  333  327  6 Hz

9. A, D
Sol. P = P2 cos 
P1 = P2 sin 
P 2  P12  P22
2mk + 2m1k1 = 2m2k2
9k2  4k1 = k
9k2  4k1 = 13 …(i)
Also,
k1 + k2 = k  |Q|
k1 + k2 = 13  5.72
k1 + k2 = 7.28
4k1 + 4k2 = 29.12 …(ii)
Solving equation (i) and (ii), we get
13k2 = 42.12
K2 = 3.24 MeV
K1 = 4.04 MeV

10. A, D
Sol. J = mv0 m, R v = R
Using conservation of angular J J R
momentum about contact point. h h
v0 4v 0
2
mv0 (R  h)  mR2   mvR C

v=
3 0
R
5
5
mv0 (R  h)  mvR
3 rough rough
5 4v
mv0 (R  h)  mR  0
3 5
R
 h
3
R 2 v
Now, mv0  mR20  0  0
3 3 2R
Total work done by the frictional force,
Wfr  k
1 2 1  1 2 1 
Wfr    mR2 2  mv 2     mR2 20  mv 02 
 2 3 2   2 3 2 
5  mv 02 mv 20 
Wfr  mv 2    
6  12 2 

8mv 20 7mv 02 mv 02
Wfr   
15 12 20

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 6

Section – B

11. 8
Sol. x and  are small kx/4
Since, the rod is light, A = 0
 4k  2      x m
k 2       3k  x  
 3 3   3 3
17k2       
 k  x   3k  x  
9  3  3 

17   4k 
 x
9 3  3  A
  
20
 x …(i) k
9
For the block
d2 x kx      
m   3k  x   3k  x  
dt 2 4  3   3
kx  3x 
  3k  x 
4  20 
kx 51 kx
= 
4 20
d2 x  56k 
 
2 x
dt  20m 
1 56k
Frequency of small oscillations, f 
2 20m
Hence n = 8

12. 6
3 1   2  1   3  2 
Sol.    
v u  R1   R2 
1.8 1.3  1.5  1.3   1.8  1.5 
  
v ( 40)  20   20 
1.8 1.3 0.2 0.3
  
v 40 20 20
1.8 0.1 1.3
 
v 20 40
1.8 1.5

v 40
 v = 48 cm
Hence, d + 48 = 60
d = 12 cm
 d/2 = 6 cm

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7 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

13. 4
r 0 r m
Sol. a  u=0
2 2
Using Kepler’s law
3/2
T r / 2 r
 
T0  r 
T
T 0
2 2
Sun
The time taken by the body to fall on the surface of sun,
T T
  0
2 4 2
T
 0
4 2
Hence, n = 4

14. 9
Sol. Let the volume of air bubble is V ( )Vg
For equilibrium of the air bubble,
(  )V2 dsin2   (  )Vgcos  
2
( )V dsin
2 dsin2   gcos 
gcos  (90)
d
2 sin2  
4
10  d
d 5  2m
9 9
100 
25
 = density of air
2
d m  = density of water
9
 2
Hence, the value of the ratio,  9
d 2/9

15. 3
Sol. For a pure rolling motion, m, R
v = R

 f dt  mv  2mv
s 0 …(i) v
m
2
 f Rdt  mR 
s 

 f dt  mR
s
fs
 f dt  mv
s …(ii)
From (i) and (ii), we get
mv = mv0  2mv
 3mv = mv0
 v 0 = 3v
Now using COE

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 8

1 1 1  1
mv 20   mR2 2  mv 2   mv 2  mgR
2 2 2  2
1 3
mv 20  mv 2  mgR
2 2
2
v
v 02  0  2gR
3
2v 20
  2gR
3
v 0  3gR  3  10  0.3  3 m/s

16. 8
kq2 1 1 
Sol.  2  mv 20  mv 20 
d0 2 2 
kq2
 2mv 20
d0
Using COE in the CM frame,
2 2
1 mv 0 kq kq2
  
2 2 d0 d
kq2 kq2 kq2
 
8d0 d0 d
9 kq2 kq2

8 d0 d
8 8
d d0   90  80 cm
9 9
Hence, the distance of the closest approach,
d = 80 cm
n=8
17. 3
  AV  V
Sol. q 0  and I 
 d  R
Fe  Fm
q2  I2
 0
20 A 2d
0 AV 2 0I2
 ( A  b )
2d2  2d
0bV 2 0 V 2
 …(i)
2d2 2dR2
When R= 2R, the net force of interaction per unit length between the strips will be
 bV 2  1
F  0 2 1  
2d  4
30bV 2
F
8d2
Hence n = 3

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9 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

18. 7
n(n  1)
Sol. 6
2
n(n1) = 12
n=4
1 1 
Now, 13.6z2     22.95
 4 16 
 3 
13.6z 2    22.95
 16 
2
z =9z=3
Hence, n + z = 4 + 3 = 7
(n + z) = 7

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 10

Chemistry PART – II

Section – A

19. C

Sol. In tautomerism is not possible.


O

20. D
Sol. K 2 Cr2 O7  14HCl  2CrCl3  3Cl2  2KCl  7H2 O
6 3
n-factor of HCl  
14 7
M M 7M
 EHCl   
n.F 3 / 7 3

21. A
Sol. Total two stereo isomers are possible.

22. D
Sol. O O O O
Et O C CH C OEt  NaOEt  Et O C CH C OEt
H
CH2  CH2  CH2 CH2 Br
|
Br

O O
NaOEt
Et O C CH C OEt
O O
CH2
Et O C C C OEt
CH2
H2 C CH2 Br

H3 O 

O O O
C C OH C OH
HO


 CO 

2

23. A, B, C
Sol. Eocell , depression in freezing point and molarity are intensive property.

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11 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

24. A, B, C, D
Sol. Factual

25. A, B, C
OH cannot be cleaved by periodic acid because both OH groups are at axial position.

Sol.
C OH

26. A, C, D
Sol.
O O
H Br Br

 Me  ONa 

O O
C OH C OMe O

H O/H
2 Me  O/MeoH
 

1. LiAlH4
A
2. H2 O

CH2 OH

H /
  Br2 /CCl4
 Br H H Br

C 
D  H Br Br H
E  F 

27. C, D
Sol. Complex is paramagnetic with 3 unpaired electron, Fe is in +1 oxidation state.

28. A, B, C
Sol. O O

H OH H OH
H OH HO H
H OH H OH
H OH H OH

OH OH
D-Allose D-Glucose
Maltose and Lactose have hemiacetal group therefore, they are reducing sugar but in sucrose
hemiacetal group is absent.

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 12

Section – B

29. 2
Sol. Number of radial node = n –  – 1
=3–2–1=0
Angular node =  = 2
 Total node = 2 + 0 = 2

30. 6
Sol. H2C Cl CH3 CH3
Cl
, , 4
Cl
Total = 6.

31. 6
Sol. K SP AgCN  1016 , K a HCN  10 10
As we know that,
 H  
  
S  K SP 1  
 Ka 

 106  10 6
S  1016 1  10   10 16  1016  10
 10  10
S  1012  10 6 mol / L .

32. 5
Sol. X  g  Y  g  W  g , K C  4  1012
5 ab 5a a
X  g  T  g  Q  g , K C  1012
5 b a 5 b b
W 
Now, 4  1012  … (1)
 X Y 
 Q
1012  … (2)
 T X
4  10 12
 W  T X  a   5  b 
    … (3)
10 12
 X Y  Q  5  a  b
And as, the KC is very high,
ab  5 … (4)
From Eq. (3)
a a a2 a
4    2
 5  a   5  a   5  a 2 5  a
10
 a  10  2a  3a  10  a 
3
5 10
 T   5  b  5   x
3 3

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13 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

3x
The value of is 5
2

33. 5
Sol. Following will respond the Haloform test
O
O O O O Br
H3C C H , H3C C CH2 C CH3 , H3C C CI3 , H3C CH CH3 ,
O
34. 5
Sol. K K K
O O
O
O O O O
O O O
H O S O OH , Cr , Cr
,
O O O O
O

O O O O
H O P O O P OH , H O P O O H , H O I O
OH OH O H O
Except HIO4 in all peroxide linkages are present.

35. 4
Sol. The species in which central atom is in intermediate oxidation state will disproportionate.

36. 8
Sol. H H
C
H
Al H
H H Total atoms = 8
C
C H
H
H
C
H H

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 14

Mathematics PART – III

Section – A

37. C
Sol. y – tx – t – 3 = 0  (y – 3) = t(x + 1) y=5
1
ty + x – 2 = 0  y    x  2 
t y – 3 = t(x + 1) P(, 4 –  )
2

y=5 1
(–1, 3) 4
2
Point P(, 4 –  ) lie on curve y = 4 – x
2
y    x  2
t
Hence,   (–1, 2) –2 (2, 0)
2
y=4–x

38. D
2 ri Bi
Sol. A iPi  ri and ri1 
5 5 Pi
2
Ei
ri r ri21 2
Ci+1
And Si   Si1   i Pi+1
5 5 25 Ci
S 1 Ci+2
 i 1  Ei+1
Si 5
Qi + 1 Qi
 1 
  1 O Ai+2 Ai+1 Di Ai
 lim  S1  S 2  S3  .....  Sn   lim  5  
n  n 
 1  1  4
 5

39. A
Sol. g(x) = f(x) + f(x) = 2f(x) at g(x) has maximum at x = 2  g(2) = 2f(2) = 0
 6x  x  1 ; x  0, 1

  6   
x 1 x  2  ; x  1, 2
 f  x  
 6  x  2   x  3  ; x   2, 3
 6  x  3   x  4  ; x  3, 4

4
1
 1 f  t  dt   2
2

40. B
Sol. (A) Since, |A| = 0 hence non-invertible  B  C
6ab
(B) |A| = 6ab, |B| = –2ab  AB1   3
2ab

41. A, C
Sol. Equation of transverse axis, is bisector of asymptote containing point P(1, 1)
x  y 1  y  7x  3 
   
2  5 2 
 5x + 5y – 5 = –y + 7x – 3

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15 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

1
 6y = 2x + 2  3y = x + 1  slope m1 
3
And slope of asymptote x + y – 1 = 0, m2 = –1
1
1
b m1  m2 b
 tan     3   2  e  1  22  5 if b = 4, a = 2
a 1  m1m2 1 a
1
3

42. B, D
Sol. f(x) = x(x – 2)(3x – 7) – 2 = 0
Where f(0) < 0, f(1) > 0, f(2) < 0, f(3) > 0
 [] = 0, [] = 1, [] = 2
 g(x) = x(x – 1)(x – 2) y=2
 7
 x  x  2   3x  7   3 x  0 1 2
x
 lim    xlim  3 7/3 3
x   x  x  1  x  2  
 1  1 

y = x(x – 2)(3x – 7)
 x
f x  2
y
g x

43. A, B, D
Sol. Since, line L1 II L2. Hence, there will be infinite A(1, 2, 3) D.R’s(1, 2, 3)
planes cutting line L and parallel to given line. L1 
p  ˆi  2jˆ  3kˆ
1 5
x z
Equation of line L : 2  y 1  2 L
1 2 3 P 1 5 
 ,  1, 
 Plane P1 : 2x – y – 2 = 0  2 2  p  ˆi  2jˆ  3kˆ
Plane P2 : 3x – z – 4 = 0 B(0, –4, –8)
 Required plane p : p1 + p2 = 0
(2x – y – 2) + (3x – z – 4) = 0,   R
Another is system of planes parallel to plane containing L1 and L2
ˆi ˆj kˆ

Normal to lines L1 and L2 : x  1 6 11  4iˆ  8ˆj  4kˆ
1 2 3
 One of D.R’s normal = (1, –2, 1)
 Equation of plane containing line’s L1 and L2 x – 2y + z = 0
 Any plane parallel to the plane is x – 2y + z = d, d  R

44. B, C
Sol. h(x) = f(x)·f(x) – f(x)·f(x)  h(x) = –(f(x))2  0  x  R
 h(x) is decreasing function let h(x0) = 0, x0  (, )
 x0 is point of local maximum
h(x0) = f(x0)·f(x0) – (f(x0))2 < 0 if |a| > 1  h(x) < 0  x  (, ) if |a| > 1

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 16

45. C, D
1 1 y=x
Sol. For point A: x 2  xx 1
2n 2n y2  x
1 1
2n
2n
 x   1 2 3 x 2  2n  1 1 
 An   x  dx =  A , 2 
 
 2n   2n
 x2 
3

2 0
An  2n  2n  
0

2 1 1 1 O
=   
3  2n 2 2  2n  2 6  2n  2
1
 An 
2n 6
 1  1 
 A r  A r 1  A r  2    r  
 48 6  r  1  r  2  
n
1  1 1  1  1 1 
= r   
2  48 6  r  1  r  1 r  2  
 A r A r 1 A r  2   1.2  n 
96 6 

n  1 
r 1

46. A, B, D
Sol. In PQB Q
2 2 2
2 6   6  x    f  x   1
cos   6–x 2
3 12  6  x  2
3
 f  x   x 2  18x  108  x  [0, 6] B 
f(x)
In PQB x
2 2 2 g(x) R
g x   6  x    f  x   6 A P
cos   
6x 2f  x    6  x  6 3
x 2  15x  54
 g x 
x 2  18x  108 4
R is a point from where down-hill road will begin
 g(x) will be maximum where x = 0 i.e. when QR is maximum
54
 g0   3 3 and f  0   6 3
2.54

Section – B

47. 3
2025 2021 2025 2021
Sol. N =  2021   2025  =  289  7  2    289  7  2 
2025 2021 2021 2025
= 7x – 2 + 7y + 2 = 7m + 2 –2
673 675
= 7m + 4(7 + 1) – (7 + 1) = 7m + 4.7 + 4 – 7k – 1
= 7p + 3  Remainder is 3

48. 6
2 –1
Sol. Given A = I, A = A = A and X2023  
APA   APA    AP 2023 A 
  .....  APA

2023 times

 0 0 1 0 0 0  0 0 0 
  2   3  
Let P = I + B where B   1 0 2   B  0 0 1 , B  0 0 0 
 0 0 0  0 0 0  0 0 0 
2023 2023 2023 2023 2022 2023 2021 2
P  C0I  C1I B  C2I B

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17 AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023

 A X 2023 A 1  A AP 2023 A A  P 2023


 Tr  A X2023 A 1   3

49. 0
2n 1 2n
Sol.  6  1    6   1 ,   6  1

50. 2
1 2
Sol. f  x   x  1
2
2 1  2
1   x 2  2x  1  2x  2  2 
 I    2  x  1  dx   
2
 dx

0  x 2  2x  1 
 2 0  x 2  2x  1 
2 2  x  1 1
1  
=  1  2 2 2  dx
2 0  x  2x  1  x  1   2  
2

2
1 2  x  1 2  
=  x  ln  x 2  2x  1  ln  
2 2 2  x  1  2   0

1 1  1  2  1  1 2  
= 2  0  ln   ln  
2  2  1  2  2  2  1  
2   1 2   1   2  1 
= 1  ln     1  ln  
2 2   2  1  2   2  1 
 1 
= 1  2 ln  2  1  1  2 ln    1  2 ln  2  1
 2  1

51. 1
Sol. (n + 2)an – (n + 1)an + 1 = 3–n(n + 1)(n + 2)
a a
 n  n 1  3  n
n1 n 2
a a
 1  1  3 1
2 3
a2 a3
  3 2
3 4
a3 a4
  3 3
4 5

an1 a
 n  3n1
n n1
–––––––––––––––––––––––––––––––––––––––
1 1 
1  
3 an 1 1 1 3  3n1 
   2  .....  n1 =
2 n1 3 3 3 2
3
an 3 1 1   an  3 1
  1    nlim     1
n  1 2 2  3n1    n  1  2 2

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AITS-OT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 18

52. 3

     a  b 
Sol. AA = I  a, b, c are orthogonal unit vectors  c    
ab

53. 4
Sol. Min AR = AS
B(z2)
t=1

O1(2 + 6i)

A(z1)
1 
P  z1 
2 
R(z3)
S

O Q(t, 0)

54. 2
A A
Sol. P    P  A   x  say   P    P  A   1  x
B B
2
 a x  b  1 x  
3
2
Let x  cos   1  x  sin   a cos   b sin  
3
w.k.t. a cos   b sin   a2  b2
4
a2  b2   k
9

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