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JEE Advanced Chapter Test
JEE Advanced Chapter Test
JEE Advanced Chapter Test
1 1409187 SO 2Cl 2 (sulphuryl chloride) reacts with water to give a mixture of H 2SO 4 and HCl. What volume of 0.2M Ba(OH) 2 is
needed to completely neutralize 25ml of 0.2M SO 2Cl 2 solution.
B
(A) 25ml (B) 50ml
(C) 100ml (D) 200ml
2 1409188 5g sample contain only Na 2CO 3 and Na 2SO 4. This sample is dissolved and the volume made up to 250ml. 25ml of this
solution neutralizes 20mL of 0.1M H 2SO 4. Calculate the % of Na 2SO 4 in the sample
B
(A) 42.4 (B) 57.6
(C) 36.2 (D) None of these
3 1409189 20mL of 0.2M NaOH(aq) solution is mixed with 35mL of 0.1M NaOH(aq) solution and the resultant solution is diluted to
100mL. 40mL of this diluted solution reacted with 10% impure sample of oxalic acid (H 2C 2O 4). The mass of impure
sample is A
(A) 0.15gram (B) 0.135gram
(C) 0.59gram (D) None of these
4 1409190 If Pd vs. P(where P denotes pressure in atm and d denotes density in gm/L) is plotted for He gas (assume ideal) at a
particular temperature. If [ d
dp
(Pd)
] P = 8.21atm
= 5. Then the temperature will be
A
(A) 160K (B) 320K
(C) 80K (D) None of these
5 1409191 What is the density of wet air with 75% relative humidity at 1 atm and 300K? Given: vapour pressure of H 2O is 30 torr
and average molar mass of air is 29gmol − 1
D
(A) 1.614g/L (B) 0.96g / L
(C) 1.06g/L (D) 1.164g/L
6 1409192 T
7 moles of a tetra-atomic non-linear gas ‘A’ at 10 atm and TK are mixed with 6 moles of another gas B at K and 5 atm
3
5T
in a closed, rigid vessel without energy transfer with surroundings. If final temperature of mixture was K, then gas B
6 B
is? (Assuming all modes of energy are active)
(A) monoatomic (B) diatomic
(C) triatomic (D) tetra atomic
7 1409193 Which of the following statements are correct?
(A) It is not possible to compress a gas at a temperature (B) At a temperature below T C, the molecules are close
below T C enough for the attractive forces to act, and condensation
occurs B;C;D
(C) No condensation takes place above T C (D) Due to higher kinetic energy of the gas molecules above
T C, it is considered as super critical fluid
13 1409199 Among the following, identify the species having only one peroxy linkage
(A) CrO 5 (B) H 2SO 5 B;C;D
(C) BaO 2 (D) H 2S 2O 8
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14 1409200 Which of the following statements is/are correct about the following reaction?
Δ
Fe 3O 4 → Fe 2O 3
(A) The equivalent weight of Fe 3O 4 is m 1 / 1(M 1 = Molecular (B) The equivalent weight of Fe 3O 4 is M 1 / 3
A;C
weight of Fe 3O 4
(C) The equivalent weight of Fe 2O 3 is 3M 2 / 2(M 2 = Molecular (D) The equivalent weight of Fe 2O 3 is M 2 / 2
weight Fe 2O 3)
15 1409201 A open ended mercury manometer is used to measure the pressure exerted by a trapped gas as shown in the figure .
Initially manometer shows no difference in mercury level in both columns as shown in diagram.
A;B;D
After sparking ‘A’ dissociates according to following reaction A(g) → B(g) + 3C(g) If pressure of Gas ‘A’ decreases to 0.9
atm, then (Assum temperature to be constant and is 300K)
(A) total pressure increases to 1.3atm (B) total pressure increases by 0.3 atm
(C) total pressure increases by 22.3 cm of Hg (D) difference in mercury level is 228mm
16 1409202 Which of the following statements are not true about the following decomposition reaction. 2KClO 3 → 2KCl + 3O 2
(A) Potassium is undergoing oxidation (B) Chlorine is undergoing oxidation
A;B;C;D
(C) Oxygen is reduced (D) None of the species are undergoing oxidation or
reduction
17 1409203 Comprehension
2− − 2−
A solution 0.1m KMnO 4 is used for the reaction S 2O 3 + MnO 4 + H 2O → MnO 2 + SO 4 + OH −
-- * --
Question : What volume of solution in mL will be required to react with 0.158g of Na 2S 2O 3? C
Van der Wall’s equation for calculating the pressure of a non ideal gas is P +
( ) an 2
V2
(V– nb) = nRT
-- * -- D
Question : At relatively high pressures, the van der Waal’s equation of state reduces to
(A) PV = RT– a / V m (B) PV = aRT / V 2
m
20 1409206 Question : The van der Waals’ constant ‘a’ for CO 2 gas is greater than that of H 2gas. Its mean that the
(A) strength of van der Waals’ force of CO 2 gas is less than (B) strength of van der Waals’ force of CO 2 gas is equal to
that of H 2 gas that of H 2 gas C
(C) CO 2 gas can be more easily liquefied (D) H 2 gas can be more easily liquefied
21 1409207
If α, α 2, α 3, α 4 are the angles made by a line with the diagonals of a cube, then |∑∑ 1≤i<j≤4
(A) 1 (B) 2
(C) 3 (D) None of these
→
22 1409208 Let →
a, b, →
c be the position vectors of A, B, C respectively where the origin ‘O’ is not in the plane of ABC. If →r be some
→ 1
non zero vector such that →r . →
a = →r . b = →r . →
c = , then the area of triangle ABC is
2
1 1
(A)
4 | [a→ →
b →
c ]| |r |
→
(B)
2 | [a b c ] | | r |
→ → → →
(C) | [a→ →
b c→
]| |r |
→
4|r |→
(D)
| [a b c ] |
→ → →
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23 1409209 Given four vectors a, b, c and d , the vectors a, b, c are coplanar but not collinear (pair by pair) and the vector →
→ → → → → → →
d is not
→ → →
coplanar with the vectors →a, b, →
c . It is known that the angle between →
a and b is equal to the angle between b and → c each
π → → → →
being equal to . Also, the angle between d and a is α and angle between d and b is β . Then angle between d and →
→
c= A
3
(A) cos −1 (B) sin −1
(cosβ– cosα) (cosβ– cosα)
(C) sin − 1(sinβ– sinα) (D) cos − 1(tanβ– tanα)
24 1409210 11
The vector î + xĵ + 3k̂ is rotated about its initial point through an angle of cos − 1 and its magnitude is doubled. If the
14
vector in the new position is given by 4î + (4x– 2)ĵ + 2k̂ , then the number of values of admissible real value(s) of ‘x’ is B
(A) 0 (B) 1
(C) 2 (D) None of these
25 1409211
[ ] [] []
−1 1 1
Consider the plane E : →r = 1 + λ 2 + μ 0 , λ ∈ R, μ ∈ R . Let F be plane containing the point A(-4, 2, 2) and
1 0 1
B
parallel to E. Suppose B is a point on the plane E such that B has the minimum distance from the point A. If C (-3, 0, 4)
lies in the plane F, then the area of ΔABC (in square units) is
(A) 3/2 (B) 9/2
(C) 3 (D) None of these
26 1409212 →
Let O be the origin, P be a given point and M, N be the projections of P on ZX and XY planes respectively. If OP makes
angles θ, α, β, γ with the plane OMN and the coordinate planes YZ, ZX, XY respectively, then cot 2θ =
C
(A) cot 2α– cot 2β– cot 2γ − 2 (B) − cot 2α + cot 2β + cot 2γ − 1
(C) cot 2α + cot 2β + cot 2γ + 2 (D) cot 2α– cot 2β– cot 2γ − 1
27 1409213
Let A + B + C = π. If the line x = y = z intersects the line
( xsinA + ysinB + zsinC = 2d 2
xsin2A + ysin2B + zsin2C = d 2 ) ,
sin
() () ()
A
2
sin
B
2
sin
C
2
may possibly take the value(s) A
1 1
(A) (B)
16 8
1 1
(C) (D)
32 12
28 1409214 Which of the following pair of straight lines in space have no points in common
(A) L 1 : x = 1 + t, y = t, z = 2– 5t, t ∈ R ; x−1 y−3 z−2 x−2 y−6 z+2
(B) L 1 : = = ; L2 : = =
2 2 −1 1 −1 3
→
( ) ( )
L 2 : r = 2î + ĵ– 3k̂ + λ 2î + 2ĵ– 10k̂ , λ ∈ R C;D
(C) L 1 : x = − 6t, y = 1 + 9t, z = − 3t, t ∈ R ; x y−1 z−2 x−3 y−2 z−1
(D) L 1 : = = ; L2 : = =
L 2 : x = 1 + 2s, y = 4– 3s, z = s, s ∈ R 1 2 3 −4 −3 2
32 1409218 π
The lengths of two opposite edges of a tetrahedron are 2 and 3 units and the angle between them is . If the volume
6
of the tetrahedron is 4 cubic units, then the shortest distance between those edges (in units) can be C
(A) 2 (B) 4
(C) 8 (D) 16
33 1409219 A variable plane cuts the x-axis, y-axis and z-axis at the points A, B and C respectively such that the volume of the
tetrahedron OABC remains constant equals 32 cubic unit and O is the origin of the coordinate system.
(A) The locus of the centroid of the tetrahedron is xyz = 3 (B) The locus of the point equidistant from O, A, B and C is
xyz = 24 A;B
(C) The locus of the foot of perpendicular from origin to the (D) If PA, PB and PC are mutually perpendicular then the
plane is (x 2 + y 2 + z 2) 3 = 1536xyz locus of P is (x 2 + y 2 + z 2) 3 = 192xyz
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34 1409220 Find the equation of a line in x-z plane which is equally inclined with x and z axis and which is at a unit distance from
x−1 y−1 z
the line = = .
1 1 1
x − √6 + 1 y z x + √6 − 1 y z A;C
(A) = = (B) = =
1 0 −1 1 0 −1
x– 1 − √2 y z x + 1 + √2 y z
(C) = = (D) = =
1 0 1 1 0 1
35 1409221 A sphere with centre at origin touches the line 2(x + 1) = 2 – y = z + 3 , then
(A) equation of sphere is x 2 + y 2 + z 2 = 5 (B) equation of sphere is 9(x 2 + y 2 + z 2) = 5
B;C
(C) point of contact with line is
( 2 −4 −5
, ,
9 9 9 ) (D) point of contact with line is
( 2 4 −5
, ,
9 9 9 )
36 1409222 → →
→
In ΔABC , if AB = b, AC = →c and M,N and P are on the sides of AB, BC and CA respectively such that
AM BN CP → → →
= = = α , Δ be the area formed with the vectors AN, BP and CM , then
AB BC CA
→ → →
( )
→ → → → → →
→
(A) AN + BP + CM = 3α b + → c ( ) (B) AN + BP + CM = α AB + BC + CA and Δ = 0
C
→ → →
( )
(α 2 + α + 1) → →
→ → → → → →
(C) AN + BP + CM = α AB + BC + CA and
→
(D) AN + BP + CM = 3α b + →
c and Δ =( ) 2
b×c | |
(α 2 − α + 1)
Δ=
2 |b × c |
→ →
37 1409223 Comprehension
→ → → → → → → → → → → →
OABCD is a pyramid with square base ABCD such that OA, OB, OC, OD are unit vectors and OA. OB = OB. OC = OC. OD = OD. OA = cosθ
-- * --
π
Question : If θ = , the angle between the planes OAB and OBC is cos − 1α where α = C
4
(A) √2 − 1 (B) 2 − √3
(C) 3– 2√2 1
(D)
2
38 1409224 π
Question : If θ = , the volume of the pyramid is (in cubic units)
3
1 1
(A) (B)
√ 3 3 √2 B
1 1
(C) (D)
2√ 3 √2
39 1409225 Comprehension
→
Let → a = xî + ĵ– 2k̂ , b = 2î + xĵ + 4k̂ and → c = 3î + 3ĵ + xk̂ be three vectors where 0 < x < 3
-- * --
→
Question : The maximum possible volume of the tetrahedron whose coterminous edges are → a, b, →
c (in cubic units), is
8√2 16√2 B
(A) (B)
3√3 9√3
32√3 32√3
(C) (D)
3√ 2 9√2
→ → →
40 1409226 Question : The value of x for which the vectors a, b, c are not able to make the edges of a tetrahedron, is
2√2 (B) 2√2
(A)
3 B
(C) 0 2√2
(D)
√3
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41 1409227 Two identical co – axial rings (radius R, each) are kept separated by a small distance d, one of them carrying a charge
+ Q and the other a charge − Q . The charges are uniformly distributed over the respective rings. A point charge q is
kept on the common axis of the rings, at a distance R from the mid point of their centers, O. The net force on the
charge q is
(
d << R, k =
1
4π ∈ 0 ) A
k. q(Qd) 5qQd
(A) (B) k
4√2R 3 4√2R 3
3qQd (D) zero
(C) k
4√2R 3
42 1409228 Two identical charged particles each carrying charge q = 0.1 mC and of mass m = 10 mg are projected along two
parallel lines separated by a distance ′ ℓ ′ with equal speed V 0 = 10m / s in opposite directions. In the beginning
electrostatic interaction between the charges can be ignored due to a large distance between them. The minimum
distance between the particles is found to be 12 cm. The value of ℓ is equal to A
(A) 6 cm (B) 8 cm
(C) 12 cm (D) 4 cm
43 1409229 A charged conducting sphere of radius R is cut into two parts along a plane whose perpendicular distance from centre
of sphere is h. The total charge on sphere is Q. If the force required to hold two parts of the sphere together is f and the
f
force required to hold two parts is f 0 when h = 0, then is
f0
A
R 2– h 2 (B) 1
(A)
R2
h2
(C)
( )
1−h
R
(D)
R2
44 1409230 The diagram shows three concentric conducting spherical shells having radii R, 2R and 3R. The initial potential of each
shell is shown in the figure. If the inner most shell is earthed then the charge present on the outer surface of the
innermost shell would be equal to
A
(A) zero (B) 40π ∈ 0R
(C) 4π ∈ 0R (D) − π ∈ 0R
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45 1409231 In the above figure a dielectric is released inside the capacitor at t = 0 from the end of the capacitor. Then which of the
following current (i) Vs time (t) graph is correct in one complete oscillation. If clockwise current is taken as positive and
anticlockwise as negative. (a > c). Neglect electrical and mechanical resistance.
(A) (B)
(C) (D)
46 1409232 One of the plates of the capacitor of capacitance C is given a charge 4Q. Now this capacitor is connected by a battery
of emf 4Q/C and then battery is disconnected. Now this capacitor is connected with uncharged capacitor of same
capacitance C through a switches S 1 and S 2 (as shown in the figure). When switches are closed charge flowing through
the switch S 1 will be
A
(A) 2Q (B) 3Q
(C) 4Q (D) Q
47 1409233 Two small identical metal balls A and B of radius ‘r’ are placed apart. The distance between centre of balls is ′ a ′ . The
0
net potential of ball A is V 1 and that of B is V 2 . Let q 1 and q 2 are the charges on balls A and B respectively. Then the
charge on A and B are (given r << a 0 )
a 0r(V 1a 0– V 2r) a 0r(V 1a 0 + V 2r)
(A) q 1 = 4π ∈ 0 (B) q 1 = 4π ∈ 0 A;D
a 20– r 2 a 20 + r 2
a 0r(V 2a 0 + V 1r) a 0r(V 2a 0– V 1r)
(C) q 2 = 4π ∈ 0 2
(D) q 2 = 4π ∈ 0 2
a0 + r2 a 0– r 2
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48 1409234 A conducting sphere of radius b has a spherical cavity with its centre displaced by ‘a’ from centre of sphere. A point
charge q is placed at the centre of cavity, Q charge is given to conducting sphere and charge q 0 is placed at a distance
A;B;C
(A) charge distribution on inner surface of cavity is uniform
(B) potential of conductor is
( q0
4π ∈ 0C
+
Q+q
4π ∈ 0b )
(C) charge distribution of outer surface of conducting sphere (D) none of these
is non uniform
49 1409235 There is an annular disc of inner and outer radii R and 3R respectively. Charge is uniformly distributed with surface
A;D
(A) The minimum work done by an external agent to move a (B) The minimum work done by an external agent to move a
point charge q from point A to point B on the axis of the disc point charge q from point A to point B on the axis of the disc
qσR qσR
is
2 ∈0 √(
2 10– 4√2 ) is
2 ∈0 √ (
2 10– 2√2 )
(C) Magnitude of electric field at the point A is (D) Magnitude of electric field at the point A is
σ
2 ∈0 ( 4
√10
−
1
√2 ) σ
2 ∈0 ( 3
√10
−
1
√2 )
50 1409236 Two charged particles have same mass m and charge ( + q) and ( − q) and are kept at same horizontal level in
gravitational field of earth with large separation between them so that Columbian attraction becomes negligible. There
exists a uniform horizontal electric field of strength E = mg / q. Now the charge particles are projected with equal speed
at t = 0 vertically upward direction. Then at any time t.
(A) magnitude of change in momentum of two charged (B) magnitude of change in momentum of positively charge A;B;C
particles system in time t is 2mgt particle will be equal to √2gmt
(C) sum of linear momentum of +q and -q is zero in (D) none of these
horizontal direction.
51 1409237 Two point charges q 1 = + 2μC and q 2 = − 4μC are placed at A and B respectively as shown. The distance between
q 1 and q 2is 4 cm
A;B;C
(A) a line of force emanates from q 1 making a angle 90° with (B) the net electric flux will be zero over any surface that
AB enters q 2 at angle 60° encloses a volume excluding A and B
(C) the electrostatic potential is zero at infinitely many points (D) none of these
in space
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A;D
q q
(A) Potential of the conductor is (B) Potential of the conductor is
4π ∈ 0(d + R) 4π ∈ 0d
(C) Potential of the conductor cannot be determined as (D) Potential at point B due to the induced charges is
nature of distribution of induced charge is not known
[ − qR
4π ∈ 0(d + r)d ]
53 1409239 A conductor A is given charge of amount +Q and then placed inside conducting cubical base B of thickness without
touching it.
B;C;D
(A) the potential of A does not changes when it is placed (B) If B is earthed, +Q amount of charge will flow to earth.
inside B.
(C) If B is earthed, the potential of A is reduced. (D) If A is connected to B by a wire it will become neutral
54 1409240 A system of two capacitors is shown in the figure. If V P– V Q = + 20V, then
D
(A) If switch S 2 is closed potential difference between plate A 20 10
(B) if all switches are closed, Q A = μC and Q C = μC
and plate B is 15 volt. 6 3
10 (D) if all switches are closed, energy loss in the circuit is 75
(C) if all switches are closed V P– V Q = volt μJ
6
55 1409241 A 4μF capacitor is given 20μC charge and is connected with an uncharged capacitor of capacitance 2μF as shown in
figure. When switch S is closed.
B;C
40 20
(A) charged flown through the battery is μC (B) charged flown through the battery is μC
3 3
200 100
(C) work done by the battery is μJ (D) work done by the battery is μJ
3 3
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56 1409242 Four identical plates (equally spaced) and battery are connected as shown. If the capacitance between two
consecutive plates are C then choose the correct statement
A;C;D
(A) energy supplied by the battery is CV 2 (B) energy linked in the spaced between plates 1 and 2 is
1 2
CV
6
(C) potential difference between plates 2 and 4 is V (D) the surface charge density on plates 3 on it’s right side is
more than that of on left side.
57 1409243 Comprehension
A point charge Q (of negligible dimension) is kept near (not touching any face) the corner A along the body diagonal of a cube (having faces of
negligible thickness) as shown in the figure. Under the appropriate assumption (considering the size of the charge). Answer the following questions.
-- * --
Question : The flux crossing three faces close to the charge if charge is just inside the cube will be
q q
(A) (B)
8 ∈0 ∈0
7q q
(C) (D)
8 ∈0 6 ∈0
58 1409244 The flux crossing the three symmetric faces which are close to the point charge will be if point charge is just outside of
Question : the cube
q q
(A) (B) A
8 ∈0 ∈0
7q q
(C) (D)
8 ∈0 6 ∈0
59 1409245 Comprehension
Four batteries of EMF E 1 = 4V, E 2 = 8V, E 3 = 12V (battery near vertex E) and E 4 = 16V, four capacitors with the same capacitances
C 1 = C 2 = C 3 = C 4 = 1μF, and four identical resistance are connected in circuit shown in figure. The internal resistance of the batteries are negligible.
-- * --
Question : At steady – state the potential difference across capacitor C 2 is
(A) 1 V (B) 5 V
(C) 4 V (D) 6 V
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60 1409246 Question : At steady - state, the total energy accumulated on the capacitors is
(A) 52 μJ (B) 13μJ C
(C) 26μJ (D) 39μJ
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