Soural of Environmental Chemical Engineering 9 (2021) 106496,
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ELSEVIER Journal homepage: yn elsevier.comvocatelece ~—
Kinetic modeling of the photocatalytic degradation of 17-( estradiol using “=
polythiophene modified Al-doped ZnO: Influence of operating parameters,
interfering ions, and estimation of the degradation pathways
Abhradeep Majumder’, Ashok Kumar Gupta"
1 scan feet Sc Beer. nd i of Toner, Kare 721902 ea
‘eneoomeel garg Poo, pera of Gl gee nan eo Fn Rhu, Keogh 72132, de
ARTICLE INFO AnsTRAcT
ior Br Gone The Kins modeling ofthe photocatalytic deeadation of the endoeine-drupting compound, 17-p eral
using 047% polthopbene modified 3.6% Al-doped 200 hasbeen invesgete in hs std. The degradation
Kept nets were inverigte by varying the ferent operational parameters, sch ak pH, se, ight nest, and
Berdtien mechanism int concentton. The degradation ate conrtants wee eimatd ng a non-near eos ele
‘vel Acopimim condition, rod 9% emer of 17-9 eral cau be achieved a degradation re of
Glo Pe tne knatc model doped bed onthe Ramen non of potosays ae he
=e Se sl I an he cee of empestv rs Comnunly pee nie wer tn were
Sensi scaly revealed that gt intensity, photocatalyst de, 160, concentration, nd pnt the
17 ead remo] he nos. The entifcton facie radia was vestige by the dl cavenging
study. Characterization of the photoetayat before and after photocatalyals was cared aut to identify any
anges Inthe physicochemical properties that might have occured Ging the process. The itezmodtes
Tormed during photocaayls were iene to undettand the degradation mechani. and preciet the
Or Stpersde aes Yep ln constant
OH Hydroxyl radicals La Wel the caput yer
Otis Adsorbed hydro radicals Me Meum alt er
wah Soaaeecim raion
aM omic fo mY PUyAl-z50 Polyhtiopene modifed aluminum doped zinc oxide
AANFIS —Adapivesetwor-based fuzzy inference system BSE Root mean gure or
4900 Arial nea newer TA Themopvie smi
Fahd elon el electon misonne USEPA Une Sites envimmentalptson agensy
SEM Pl nln reaming ceton mlonpe wen a mepecnopy
FTIR Fourier transformed infrared radiation
IIR Fourier transformed infrared radiation
bY Holes
HPLC High performance Liquid Chromatography
za0 Zine oxide
al eden sp ci. tgp. 2c (AK. Gap.
hups/do.org/10.1016/ jes 2021106496
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