Materials & Streams Report March 2, 2023

for CHLOROMETHAN

1. OVERALL PROCESS DATA

Annual Operating Time 7,905.00 h

Recipe Batch Time 21.72 h
Recipe Cycle Time 21.72 h
Number of Batches per Year 364.00
MP = Undefined

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2.1 STARTING MATERIAL REQUIREMENTS (per Section)

Amount
Gross
Needed Molar Mass
Mass
Section Starting Material Active Product (kg Yield Yield
Yield
Sin/kg (%) (%)
(%)
MP)
Main Section (none) (none) Unknown Unknown Unknown Unknown
Sin = Section Starting Material, Aout = Section Active Product

2.2 BULK MATERIALS (Entire Process)

Material kg/yr kg/batch kg/kg MP

Chlorine 405,132 1,113.00
Methane 3,234,868 8,887.00
Water 3,640 10.00
TOTAL 3,643,640 10,010.00

2.3 BULK MATERIALS (per Section)

SECTIONS IN: Main Branch

Main Section
Material kg/yr kg/batch kg/kg MP
Chlorine 405,132 1,113.00
Methane 3,234,868 8,887.00
Water 3,640 10.00
TOTAL 3,643,640 10,010.00

2.4 BULK MATERIALS (per Material)

Chlorine
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)
P-1 100.00 405,132 1,113.00
TOTAL 100.00 405,132 1,113.00

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Methane
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)
P-1 100.00 3,234,868 8,887.00
TOTAL 100.00 3,234,868 8,887.00

Water
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)
P-1 100.00 3,640 10.00
TOTAL 100.00 3,640 10.00

2.5 BULK MATERIALS: SECTION TOTALS (kg/batch)

Raw Material Main Section

Chlorine 1,113.00
Methane 8,887.00
Water 10.00
TOTAL 10,010.00

2.6 BULK MATERIALS: SECTION TOTALS (kg/yr)

Raw Material Main Section

Chlorine 405,132
Methane 3,234,868
Water 3,640
TOTAL 3,643,640

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3. STREAM DETAILS

Stream Name S-101 S-102 S-103

Source INPUT P-1 P-1
Destination P-1 OUTPUT OUTPUT
Stream Properties
Activity (U/ml) 0.00 0.00 0.00
Temperature (°C) 25.00 25.00 25.00
Pressure (bar) 1.01 986,015.37 98,604.75
Density (g/L) 0.72 1,324.68 1,324.68
Total Enthalpy (kW-h) 219.30 1.56 0.00
Specific Enthalpy (kcal/kg) 18.85 7.87 7.87
Heat Capacity (kcal/kg-°C) 0.48 0.31 0.31
Component Flowrates (kg/batch)
Carb. TetraCh 0.00 24.34 0.00
Chlorine 1,113.00 0.00 0.00
Dichloromethane 0.00 135.87 0.00
Methane 8,887.00 0.00 0.00
Water 10.00 10.00 0.00
TOTAL (kg/batch) 10,010.00 170.21 0.01
TOTAL (L/batch) 13,936,514.68 128.49 0.00

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4. OVERALL COMPONENT BALANCE (kg/batch)

COMPONENT INITIAL INPUT OUTPUT FINAL IN-OUT

Carb. TetraCh 0.00 0.00 24.34 0.00 - 24.34
Chlorine 0.00 1,113.00 0.00 298.11 814.89
Dichloromethane 0.00 0.00 135.88 0.00 - 135.88
HCl 0.00 0.00 0.00 419.03 - 419.03
Methane 0.00 8,887.00 0.00 8,735.91 151.09
Methyl Chloride 0.00 0.00 0.00 386.74 - 386.74
Nitrogen 0.13 0.00 0.00 0.13 0.00
Oxygen 0.04 0.00 0.00 0.04 0.00
Water 0.00 10.00 10.00 0.00 0.00
TOTAL 0.17 10,010.00 170.22 9,839.95 0.00

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5. EQUIPMENT CONTENTS

R-101
Procedure Operation Time (in h) Volume (in L) Vapor (in kg)
P-1 START 0.00 0.00 0.17
P-1 CHARGE-1 (Charge) 16.93 10.05 10,000.17(*)
P-1 REACT-1 (Batch Stoich. Reaction) 17.93 10.05 10,000.17(*)
P-1 REACT-2 (Batch Stoich. Reaction) 18.93 123.32 9,850.85(*)
P-1 REACT-3 (Batch Stoich. Reaction) 19.93 125.86 9,845.40(*)
P-1 REACT-4 (Batch Stoich. Reaction) 20.93 128.50 9,839.95(*)
P-1 TRANSFER-OUT-1 (Transfer Out) 21.47 0.00 9,839.95(*)
P-1 TRANSFER-OUT-2 (Transfer Out) 21.72 0.00 9,839.95(*)
(*) Contains material in vapor phase other than Oxygen & Nitrogen

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