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Chemical Kinetics Vedantu PDF
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Study Materials
• Sample Papers
Rate of a reaction
The rate (speed or velocity) of a reaction is the change in
concentration in per unit time.
x
t
or dxdt xt tx
2 1
2 1
1
Thus, rate constant k is also called specific reaction rate.
Its value depends on the nature of reactant,
temperature and catalyst. It value is independent of reactants
concentration.
Unit of rate constant mol
n 1
litre 1
sec
Some Reactions
S. No. Chemical equation Rate law
dx
1. aA bB product k [ A]a [B]b
dt
dx
2. aA bB product k [ A]2 [B]0
dt
dx
3. Pt ,
2 H 2 O2 2 H 2 O O2 k [H 2 O2 ]
dt
dx
4. CH 3 COOC 2 H 5 H 2 O
H
k [CH 3 COOC 2 H 5 ]
dt
CH3COOH C2 H5 OH
2
C 12 H 22 O 11 H 2 O dx
5. Sucrose
H
k [C12 H 22 O11 ]
dt
C6 H12 O6 C6 H12 O6
Glucose Fructose
dx
6. (CH 3 )3 CCl OH (CH 3 )3 COH Cl k [(CH 3 )3 CCl]
dt
dx
7. CH 3 Cl OH CH 3 OH Cl k [CH 3 Cl][OH ]
dt
dx
8.
C6 H 5 N 2 Cl C6 H5 Cl N 2 k [C6 H 5 N 2 Cl]
dt
dx
9.
CH 3 CHO CH 4 CO k [CH 3 CHO ]3 / 2
dt
dx
10. H 2 O2 2 I 2 H 2 H 2O I2 k [H 2 O 2 ][ I ]
dt
dx
11. 2O3 3O2 k[O3 ] [O 2 ]
dt
2
1 k1
2 .303 a
log10 , C C0 e k 1 t
time–1 (s–1) 0 .693
t ax k1
3
2.303 (a x1 )
N N 0 e k 1 t , k1 log10
(t2 t1 ) (a x 2 )
2 1 1 1 x conc–1 time–1 1
k2 (for the
t (a x ) a ta(a x) k 2a
3 1 1 1 conc–2 time–1 3
k3 2
2 t (a x )2
a 2k 3 a 2
(mol L–1)–2 s–1
L2 mol–2 s–1
n 1 1 1 conc(1–n) time–1 2 n 1 1
kn n 1
n 1 ; n 2
(n 1)t (a x ) (a) (n 1)k n (a)n 1
(mol L–1)(1–n) s–1
t1/2
t1/2
Plots from
Zero order
integrated
1 order 2 order
rate equations
3 order
st nd rd
Conc. [A]
log. [A]
t t t t
6
Arrhenius equation
Arrhenius proposed a quantitative relationship between rate
constant and temperature as,
k Ae Ea / RT
…..(i)
The equation is called Arrhenius equation.
In which constant A is known as frequency factor. This factor
is related to number of binary molecular collision per second
per litre.
E is the activation energy.
a
parameters.
Taking logarithm equation (i) may be written as,
log k log A
E
2.303 RT
a
…..(ii)
The value of activation energy (E ) increases, the value of k
a
respectively (T T ) . 2 1
7
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