Exercises #2:

1. Given the following enthalpies, calculate the lattice energy of NaI (s) .
Enthalpies (kJ/mol):
Hof[NaI(s)] = -288; Hs(Na) = 107; IE(Na) = 496; Hs(I2) = 62; D(I—I) = 149;
EA[I] = -295;

2. Given the following enthalpies, calculate the lattice energy of CsCl (s).
Hof[CsCl(s)] = -443; Hs(Cs) = 78; IE(Cs) = 376; D(Cl—Cl) = 244; EA[Cl] = -349.

3. Given the following processes and their enthalpies (in kJ/mol):

(1) Mg(s)  Mg(g); Hs = 150; (2) Mg(g)  Mg2+(g) + 2e-; IE = 2180;
(3) Cl2(g)  2Cl(g); D = 243; (4) Cl(g) + e-  Cl-; EA = -349, and
(5) Mg(s) + Cl2(g)  MgCl2(s); Hof = -642.
Calculate the enthalpy change for the following process, which is also called the lattice
energy for MgCl2(s):
Mg2+(g) + 2Cl-(g)  MgCl2(s).

4. Calculate the lattice enthalpy for lithium fluoride, given the following information:

o Enthalpy of sublimation for solid lithium = 161 kJ/mol

o First ionization energy for lithium = 520 kJ/mol
o F-F bond dissocation energy = 154 kJ/mol
o Enthalpy of formation for F(g) = 77 kJ/mol
o Electron affinity for fluorine = -328 kJ/mol
o Enthalpy of formation for solid lithium fluoride = -617 kJ/mol

5. Use the following information to calculate the heat of sublimation for potassium:

o Heat of formation for KCl(s) = -437 kJ/mol

o Electron affinity for Cl = -349 kJ/mol
o Ionization energy for K = 418 kJ/mol
o Lattice energy for KCl = 717 kJ/mol
o Heat of formation for Cl(g) = 122 kJ/mol
o Bond dissociation energy for Cl2(g) = 243 kJ/mol

6. Calculate the second ionization energy for calcium using the following information:

o Bond dissociation energy for gaseous molecular fluorine = 158 k/mol

o First ionization energy for calcium = 589.8 kJ/mol
o Heat of sublimation for calcium = 178.2 kJ/mol
o Electron affinity for fluorine = -328 kJ/mol
o Lattice energy for CaF2(s) = -2630 kJ/mol
o Heat of formation for CaF2(s) = -1215 kJ/mol