Chapter I:

1. Convert 1 dm^3 to cm^3

= 1,000cm

2. Convert 10km to m
= 10,000 m

3. Convert 100L to mL
= 100,000 mL

4. Convert 1 Kilo^3 to deka

= 100 da

5. How many Significant Figures does 6574 have?

=4

6. How many Significant Figures does 0.0054 have?

=2

7. How many Significant Figures does 0.564 have?

=3

Chapter II:
1. What is the name of this compound?
- PCl3 = Phosphorus trichloride

2. What is the name of this compound?

- NH3 = Ammonia

3. What is the name of this compound?

- S2F10 = Disulfur decafluoride

4. What is the name of this compound?

- BrCl5 = bromine pentachloride
5. Name the following ionic compound.
- Fe3(PO4)2 = Iron(II) phosphate

6. Name the following ionic compound.

- KHSO4 = Potassium bisulfate

7. Name the following ionic compound.

- Ca(ClO4)2 = Calcium perchlorate
Chapter III:
1. Balance the following Chemical Equation Fe2O3 + C = Fe + CO2
- 2Fe2O3 + 3C = 4Fe + 3CO2

2. Balance the following Chemical Equation C3H8 + O2 = H2O + CO2

- C3H8 + 5O2 = 4H2O + 3CO2

3. Balance the following Chemical Equation Na3PO4 + MgCl2 = NaCl + Mg3(PO4)2

- 2Na3PO4 + 3MgCl2 = 6NaCl + Mg3(PO4)2

4. Balance the following Chemical Equation Al + H2SO4 = Al2(SO4)3 + H2

- 2Al + 3H2SO4 = Al2(SO4)3 + 3H2
Chapter IV:
1. What is the molar mass of Cr3(AsO4)2?
- = 433.83g/mol

2. What is the molar mass of Ca3(PO4)2?

- = 310.18g/mol

3. What is the molar mass of Mg3(PO4)2?

- = 262.86g/mol

4. What is the molar mass of Ni3(AsO4)2?

- = 598.04g/mol

5. How many g of NA are present in 3.096 moles of NA?

- S

6. How many moles of NA are present in 434.0 g of NA?

- s

7. How many moles of NA are present in 515.0 g of NA?

- S
Chapter V:
1. A balloon holds 28.7 kg of helium. What is the volume of the balloon if the pressure is 1.07 atm
and the temperature is 25 °C?
=

= The temperature is converted to kelvins.

T = 273 + 25 = 298 K
=

= 1.64 x 10^5 L He

2. A sample of gas has a volume of 2.61 L at a temperature of 47.20 °C. The gas sample
is heated to a temperature of 122.00 °C (assume pressure and amount of gas are held constant).
Predict whether the new volume is greater or less than the original volume, and calculate the new
volume.

= =

=
Final Answer is: = 3.22L

3. A sample of gas has a volume of 492 mL at a pressure of 4.06 atm. The gas is allowed to expand
and now has a pressure of 1.00 atm. Predict whether the new volume is greater or less than the
initial volume, and calculate the new volume. Assume temperature is constant and no gas escaped
from the container.
= Use Boyle's Law: P1V1 = P2V2

P1 = 4.06 atm
P2 = 1.00 atm =
V1 = 492 mL

= Final answer is 2.00×103 mL

4. A 1.15-g sample of an unknown gas has a volume of 649 mL and a pressure of 714 mmHg
at 41.4 °C. Calculate the molar mass of this compound.
V = 649 mL
P = 714 mmHg
T = 41.4 °C

= Molar mass is equals to: = 48.7 g/mol

5. A sample of gas has a volume of 515 mL at a pressure of 3.15 atm. The gas is allowed to expand
and now has a pressure of 1.17 atm. Predict whether the new volume is greater or less than the
initial volume, and calculate the new volume. Assume temperature is constant and no gas escaped
from the container.
Use Boyle's Law: P1V1 = P2V2

= Final answer is 1.39×103 mL

6. A tank holds 30.9 kg of helium. What is the volume of the tank if the pressure is 1.02 atm and the
temperature is 24 °C?

The temperature is converted to kelvins.

T = 273 + 24 = 297 K

= 1.85x10^5 L He

7. A sample of gas has a volume of 2.80 L at a temperature of 53.70 °C. The gas sample
is cooled to a temperature of -26.30 °C (assume pressure and amount of gas are held constant).
Predict whether the new volume is greater or less than the original volume, and calculate the new
volume.

T1 = 53.70 °C + 273.15 = 326.85 K

T2 = -26.30 °C + 273.15 = 246.85 K

T1 = 327 K
T2 = 247 K
V1 = 2.80 L

= 2.11 L
Chapter VI:
1. Some local phone produce at a frequency of 668 kHz. What is the wavelength at which is
broadcasting?
- (1 kHz = 10 3 sec -1)

Final answer = 449 m

2. Another local phone produce at a frequency of 92.3 MHz. What is the wavelength at which is
broadcasting?
- (1 MHz = 106 s -1)

=
Final asnwer = 3.25m

3. Infrared radiation falls in the wavelength region of 1.00×10-6 to 1.00×10-3 meters.

What is the frequency of infrared radiation that has a wavelength of 5.20×10-5 m?

Final answer = 5.77×1012 sec-1

4. Figure the frequency of 431 nm. Using this Formula:

Final answer: = 4.61 x 10^-23 kJ

5. A local AM radio station broadcasts at an energy of 4.43 x 10^-31 kJ/photon.

What is the frequency at which it is broadcasting.

Final answer is: = 668 KHz

6. Ultraviolet radiation falls in the wavelength region of 1.00×10-8 to 1.00×10-7 meters. What is the
frequency of ultraviolet radiation that has a wavelength of 1.00×10-8 m?

Finals answer is: 3.00×1016 sec-1 

7. A local AM radio station broadcasts at a frequency of 541 kHz. Calculate the

wavelength at which it is broadcasting.
(1 kHz = 10 3 sec -1)

Final answer is: = 554m

Chapter VII:
1. From this Lewis Structure what is the Central atom, total electron, and octet rule?
Central atom = Al
Total electron = 6
Octet rule = No

2. Lewis structure and it Valence electrons CO2

Valence electrons of CO2 = 16
Lewis Structure:

3. What Molecular Geometry is this and its Formula?

Molecular Geometry: Tetrahedral
Formula: SiH4

4. What is the Lewis Structure for PF5?

5.  What is the electron-pair geometry around the central atom of XeF4?

Final Answer: Octahedral

6. From this Lewis Structure what is the Central atom, total electron, and octet rule?

Central atom = P
Total electron = 12
Octet rule = No

7. From this Lewis Structure what is the Central atom, total electron, and octet rule?
Central atom = N
Total electron = 8
Octet rule = Yes
Chapter VIII:
1. Solid manganese(II) oxide has the same kind of crystal structure as NaCl. If the edge length of
the unit cell is 443.5 pm, what is the density of MnO in g/cm3.
Density = Mass / Volume
D = Mcell / Vcell

Formula unit = (70.94 g/mol) / (6.022×1023 units/mol) = 1.178×10-22 g/unit

Mcell = (4 units) × (1.178×10-22 g/unit) = 4.712×10-22 g

D = (4.712×10-22 g) / (8.723×10-23 cm3) = 5.402 g/cm3

Final Answer: 5.402 g/cm3

2. Metallic palladium crystallizes in a face-centered cubic lattice, with one Pd atom per lattice point. If the
metallic radius of Pd is 137 pm, what is the volume of the unit cell pm^3 in cm^3 and in ?

Pm = 387

The final answer: 5.82 x 10^-23 cm^3

3. determine the molar volume of Al(s), in units of cm3/mol.

molar mass: 26.98 g/mol
density: 2.699 g/cm3
- Molar volume of Al: 9.996 cm3/mol = 572.8
- Diagonal length = 572.8 pm = 405.0
- Diagonal length = 572.8 pm
Edge length = 405.0 pm
= 4.05x10^-8 cm
- Diagonal length = 572.8 pm
Edge length = 405.0 pm
Edge length = 4.05 × 10-8 cm
= 6.64x10^-23  cm3
- Diagonal length = 572.8 pm
Edge length = 405.0 pm
 Edge length = 4.05 × 10-8 cm
Volume of the unit cell = 6.64 × 10-23 cm3
- Molar volume = 9.996 cm3/mol
number of atoms per cubic centimeter = 6.02 × 1022 atoms/cm3
- S

= 6.01x10^23

4. Metallic lithium crystallizes in a body-centered cubic lattice, with one Li atom for each point in

the crystal lattice. How many atoms are there per unit cell? If the edge length of the unit cell is
found to be 351 pm, what is the metallic radius of Li in pm?

Rearrange and solve for r, where a = 351 pm.

Atom = 2
Pm = 151.99