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Solids JEE NEET PDF
Solids JEE NEET PDF
Questions
based on
Radius Ratio
Q.34 For tetrahedral co-ordination the radius ratio
(r+ /r¯) should be - Cation
(A) 0.414 - 0.732 (B) > 0.732 Anion
(C) 0.156 - 0.225 (D) 0.225 - 0.414
Q.37 The co-ordination number of a body centred Q.46 8 : 8 coordination number of CsCl change into
atom is- 6 : 6 on -
(A) 4 (B) 6 (A) Applying high P
(C) 8 (D) 12 (B) Increasing temperature
(C) Both A and B
Q.38 Which is ferromagnetic- (D) Can't be changed
(A) Ni (B) Co
(C) CrO2 (D) All Q.47 Point defect which lowers the density of
materials -
Q.39 Which of the following is ferroelectric compound (A) schottky (B) Frenkel
(A) BaTiO3 (B) K4[Fe(CN)6] (C) Both (D) None of these
(C) Pb2O3 (D) All.
Q.40 An example of body cubic is - Q.48 At low temperature O2 freezes to form crystalline
(A) Sodium (B) Magnesium solid. Which term best describer the solid -
(C) Zinc (D) Copper. (A) Ionic crystal (B) Covalent crystal
(C) Metallic crystal (D) Molecular crystal
Q.41 Sodium crysrallizes in cubic lattice with cell
edge a=4.29Å. What is the radius of Na atom - Q.49 Arrangement of Cl– in CsCl is -
(A) HCP (B) Simple cubic
(A) 1.86 Å (B) 6.81 Å
(C) FCC (D) BCC
(C) 8.61 Å (D) 2.94 Å
Q.50 The decreasing order of the size of void is -
Q.42 A binary solid x+ y– crystallizes in rock structure.
(A) Cubic > Octahedral > Tetrahedral > Trigonal
If the edge lenght is 400pm and radius of cation
(B) Trigonal > Tetrahedral > Octahedral > Cubic
75pm, the radius of anion will be -
(C) Trigonal > Octahedral > Tetrahedral > Cubic
(A) 325 pm (B) 250 pm
(D) Cubic > Tetrahedral > Octahedral > Trigonal
(C) 125 pm (D) 325 pm
Q.51 In Ax By atoms of A occupy each corner of the
Q.43 A mineral having the formula AB2 crystallize in
cube and atom of B occupy centre of each face.
cubic close packed lattice with the A atoms
The composition will be -
occupying the lattice points. The coordination
(A) AB3 (B) A2 B3 (C) A3B (D) A3B4
number of atoms of A, atoms of B and the
fraction of the tetrahedral sites occupied by B
Q.52 Among solids highest melting point is
are respectively -
established by -
(A) 2, 6, 75% (B) 8, 4, 100%
(A) Covalent solids (B) Amorphous solids
(C) 3, 1,25% (D) 6, 6, 50%
(C) Ionic solids (D) Molecular solid
Q.2 In ccp, ratio of no. of atoms to no. of tetrahedral Q.6 Statement - I. By increasing the temperature
void is - C.N. of CsCl changes from 8 : 8 to 6 : 6.
Statement - II. Temperature also influences
1 2 the C.N. of solid.
(A) (B)
1 1
0 .5 3 Q.7 Statement - I. Solid having more F-centers
(C) (D)
1 1 have intense color.
Statement - II. Excess of Na+ in NaCl solid
having F-centers make it appears to pink.
Q.3 Size order of octahedral, tetrahedral & cubic void
is - Q.8 Statement - I. Close packing of atoms in
(A) cubic < tetrahedral void < octahedral void cubic structure is in order of : fcc > bcc > sc
Statement - II. Packing density =
(B) cubic > tetrahedral void > octahedral void
vol. of sphere in an unit cell
(C) cubic = tetrahedral void = octahedral void
a3
(D) cubic > octahedral void > tetrahedral void
Q.9 Statement - I. Pure NaCl is diamagnetic in
nature.
Q.4 In certain metallic oxide, metal M occupy HCP Statement - II. In NaCl, Na + occupy
2 octahedral voids.
lattice & O–2 occupy rd of octahedral void,
3
formula of crystal is -
COLUMN MATCHING
Q.6 In a solid AB having the NaCl structure, A atoms Q.8 Alternate tetrahedral void in FCC are occupied
in -
occupy the corners of the cubic unit cell. If all
(A) NaCl (B) ZnS
the face centered atoms along one of the axes
(C) CaF2 (D) Na2O
are removed, then the resultant stoichiometry
of the solid is - Q.9 For a cubical system the following information
(A) AB2 (B) A2B are available.
Edge length = 5Å ; density = 2 gm/cm 3, Atomic
(C) A4B3 (D) A3B4
wt. = 75
Determine the radius of the atom in pm ?
Q.10 Match the crystal system/unit cells mentioned in Column I with their characteristic feature mentioned
in Column II.
Column I Column II
(A) simple cubic and face centred (P) have these cell parameters
cubic a = b = c and = =
(B) cubic and rhombohedral (Q) are two crystal systems
(C) cubic and tetragonal (R) have only two crystallographic
angles of 90°
(D) hexagonal and monoclinic (S) belong to same crystal system
Ans. B B C C C C B D D B A B A B C D C D D A
Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. B D A A D B B C C B B D D D B B B C C A
Q.No. 41 42 43 44
Ans. B D C C
LEVEL # 2
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. D C C C D A C B B B C B A A A A A C A D
Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. C B C A A A C B B A D B C D A C C D A A
Q.No. 41 42 43 44 45 46 47 48 49 50 51 52 53
Ans. A C B A B B A D B A A A C
LEVEL # 3
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Ans. D C D D A A C A B True True True False False
Q.No. 15
Ans. A - Q,T ; B - P,U ; C - R,W ; D - S,V
LEVEL # 4
SECTION-A
Q.No. 1 2 3 4 5 6 7
Ans. B C B D C D B
SECTION-B
Ques. 1 2 3 4 5 6 7 8 9 10 11
Ans. B D B A A D A B 0217 A - P,S ; B - P,Q ; C - Q; D - Q,R B,C