a-

it
%) effect ;
Tp#
-4 Since due to trans

↓ to Gita
be
opposite
can
a

hence its
a
/ \
a
replaced easily ,

&
less
bond strength is
bond
length is more .

d. 2)
According to series
givenparagraph ;
in

to
Cz Hq has man
tendency form
.

trans product .
 =
Fz Uz Brz & -1-2
Halogens
exist as
,
,

& noble He Ne Ar Kr Xe , Rn
gases are
.

, ,
, ,

In both cases ,%Yondon forces operate

^
.

4$
.

HOMO
of Nz is Tzpz (Bono) .

Only option
is (4) ( s -

p mixing is
present )
⑤

[Cr DikBrz]⊖
}

spin not
defined ( d -

)
octahedral

NqfFe s-N0 ]
isomerism
Magb → no .

[Milena U2)
spin not
defined ( D8 -
octahedral )

[Fe @ nzUz)⊕
☒
d
}f3
shows both GI & OI .

l4a low spin

6 .

?
I
HsP0++HsP°3
he
OH

/
ÉonÉ :
'
1131003+43004
no
in on

Hypo phosphoric
:
PF} & CO both are 8- donor
,
I -

acceptor .

CO & Pfg are both toxic since

they are

highly reactive

odour less
co & Pfz are .

(4) is correct & is a

dissimilarity .

except [Cofe]ˢÉ¢dHz%fz]
}
(A) All cost Octa
complexes are d }p
(B) Nice E-→ sp
}
; MnOI→d3s
(c) MLAA) , show only OI

(D) GI
[MCA B) 2) sq .

planar complex
show
only .
g.

✓ ✓ ✓ ✓ ✓

Ans 5 .

No distortion due to lone

pair
10 .

Look Rule

All
complexes are
explained in class .

(Agfa) →
dsf ( diamagnetic)
d.
4d series
:

✓
B. P order

Sb ASH PH
Hz > NH >
} }
>
} .
13 .

=
Class illustrations .

14°
Column I Column #

Complex characteristics

( I) Ferrocene PQRS ( P) follow

Sidgwick's
Rule
(E) Brown
Ring Complex
•
(a) Can show

(E)
Rosy (
Red
"
ppt s synergic Bonding
Ni complex) ( RJ
(E) Wilkinson
organometallic
catalysta ( )
s

chelating complex
.
15 .
-844
02--5 + e-

0-1*0 + e-

\i56o
760

To 390K
23

g- (2329+23/528)
21 +
2960
1560
760
+ 980+4×(-14-2)
+41844)
answers
Prove Answer ( No obvious
your allowed)

Let total atoms

of Fe area .

Fett Fe3+=
=

¥ ; 2¥ .

0-+5 Off
g-
→

fees)
→
Fea 04 ( s)
✗ +
2021g )

Hsub)K

§
? HBDE
☐

Fe
✗
(g) 40 (g)
IE ' 213 IE ,
1,4 @ HEAT , " "
{ Félg
"

5- Fe+(g)
) 40 (g)
-

f?§IEz I?%ᵗE2 1,4 GHEG) ,

Fe+4g ¥✗fe+48 ) 402

-

g- ) (g)
1,23 IE
}

2÷Fe→Cg#
390K
-1%(760+1560) -123-(76041560+2960)
1092
2×490 1- 4. (-1427+41-844) 18930 =
-
-

1-

On solving x
16 .

✓
( Naz 112%07)
( Naz H Pz 06 )
( Naz Hz PLO 6)

Hypophosphite 032 (H
-

is HP is not acidic
& hence will not

be included in

name
)
17
of complexes among
. Number the

following
well
that
paramagnetic are as

as isomerism
show
optical .

[ Niles] @ KEEP
"
-

[Pᵗ↳(GHa7J
,
◦
,
,

[Pt9zÑHDz] [Fecicac} ] [Hiding≥] , ,

,

coasters'T
Ans (2)
18 Number
of species among the
following
.

orbital
for bonding
"
that use
"
d .

(either by central atom or

surrounding atom

Xe0Tt.CdUTiTH2sJ4.I0I@hUyPPhD5.N $ 3) 3
, -1-296 ,
É

Ans (8)