CHEMIST RY

DPP
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TARGET : JEE(MAIN + ADAVANCE)


ST

NO. 01
CHEMICAL KINETICS
TOPIC : AVERAGE RATE & INSTANEOUS RATE

Single Correct :
1. For the reaction : 2NO2(g)  2NO(g) + O2(g)
at a certain temperature, the initial rate of decomposition of NO2 is 0.0036 Ms–1 . What is initial rate of
formation of O2(g) in Mmin–1?
(A) 0.0018 (B) 0.0108 (C) 0.108 (D) 0.0072

2. The gas phase decomposition of dinitrogen pentoxide is represented by this equation:

2N2O5(g)  4NO2(g) + O2(g)
What is rate of formation of oxygen gas(in mol L–1 s–1) in an experiment where 0.08 mol of N2O5 is
consumed in a 4L container every 0.2 seconds?
(A) 0.02 (B) 0.05 (C) 0.1 (D) 0.2

3. A graph of volume of hydrogen released vs time for the reaction between zinc and dil. HCl is given in
figure. On the basis of this mark the correct option for average rate of formation of H2 gas.
V3  V2 V5
(A) Average rate upto 40 s is
40 V4
V3  V2
(B) Average rate upto 40 s is V3
40  30
V3 V2
(C) Average rate upto 40 s is V1
40
V3  V1
(D) Average rate upto 40 s is
40  20
O 2030 40 50
4. Consider the graph given in above figure. Which of the following options does not show instantaneous
rate of formation of H2 gas at 40th second?
V5  V2 V4  V2
(A) (B)
50  30 50  30
V3  V2 V3  V1
(C) (D)
40  30 40  20

CURVE KO TOUCH KAR RHA HAI V4 JAB KI

ONLY TANGENT KO TOUCH KARNA
CHAHIYE FOR INSTANTANEOUS ISLIYE V4
WAALA WRONG HAI @ARCHANA
Comprehension (Q.5 to Q.7)
Concentrations measured as a function of time when gaseous N2O5 at initial concentration of 0.0200 M
decomposes to gaseous NO2 and O2 at 50°C. The change in concentration with time is given by the
following graph.
0.03 NO2
[NO2]
=0.003 M

Concentration(M) 0.02 0.003 M

[NO2]=0.004M

0.004 M
0.01
O2
N2O5
= tan–1 (2.5 × 10–5)
0.00
0 100 200 300 400 500 600 700 800
Time(s)

5. The instantaneous rate of disappearance of N2O5 at the begining of the reaction is

(A) 2 × 10–5 M/s (B) 1 × 10–5 M/s (C) 5 × 10–5 M/s (D) zero

6. The rate of formation of O2 during the period 600 – 700 s is

(A) 4 × 10–5 M/s (B) 3 × 10–5 M/s (C) 5 × 10–5 M/s (D) 7.5 × 10–6 M/s

7. The rate of decomposition of N2O5 during the period 300 – 400 s is

(A) 4 × 10–4 M/s (B) 3 × 10–5 M/s (C) 2 × 10–5 M/s (D) 4 × 10–8 M/s

8. Which of the following statements regarding rate constant is correct?

(A) Rate constant always depends on concentration of reactant.
(B) Rate constant is temperature dependent.
(C) For instantaneous reactions, rate constant will be very small.
(D) Rate constant will always depend on pressure or volume of the container.

9. The rate of formation O3(g) is 96 × 10–7 gL–1 s–1 for the reaction.: 3O2 (g)  2O3(g)
What is rate of disappearance of O2(g) in mol L–1s–1 ?
(A) 96 × 10–7 (B) 1.5 × 10–7 (C) 3 × 10–7 (D) 0.66 × 10–7
10. Statement-1 : For the reaction : 2A + B  C, the rate of disappearance of A is twice the rate
of disappearance of B
d[C]
Statement-2 : For the reaction : 2A + B  C, Rate of reaction is
dt
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
 CHEMIST RY

TARGET : JEE(MAIN + ADVANCE)

DPP
DAILY PRACTIC E PRO BLEMS


ST

NO. 02
CHEMICAL KINETICS
TOPIC : ORDER OF REACTION
Single Correct
1. In a chemical reaction A(g) is converted to B(g), following observation is made. Identify the incorrect
statement.

PB
8
Pressure (atm)

6
4
PA
2

10 20 30 time (min.)

1
(A) Chemical reaction can be represented as A(g)  B(g).
2
(B) t1/2 of the reaction is independent of initial partial pressure of A.
(C) Reaction must be complex reaction.
(D) Time of completion for the reaction is 40 minutes.

2. The rate of the simple reaction 2NO + O2  2NO2, when the volume of the reaction vessel is
doubled.
(A) Will grow eight times of its initial rate (B) Reduce to one-eight of its initial rate
(C) Will grow four times of its initial rate (D) Reduce to one-fourth of its initial rate

3. The rate of a stoichiometric/elementary reaction between a solid and a gas in a container may be increased
by increasing all of the following factors except the________
(A) pressure of gas (B) temperature of gas
(C) volume of container (D) surface area of solid

4. Consider a first order reaction at 300 K, started with initial partial pressure of A 20 torr and no other
gas. A(g)   B(g) + 2C(g)
After 10 sec. total pressure of gaseous mixture was 40 torr. Determine rate constant for above reaction
with the help of following data :[Take : ln2 = 0.7]
(A) 0.7 sec–1 (B) 0.07 sec–1 (C) 0.05 sec–1 (D) 0.14 sec–1
5. Consider the following reaction 2A(g)  3B(g) + C(g).
Starting with pure A having pressure 2atm initially, the total pressure is exactly doubled in 2hrs. The
possible order of reaction is
(A) zero (B) first (C) second (D) third

6. Decomposition of reaction : 2A(g)   2B(g) + C(g)

Follows zero order kinetics. Initial rate of decomposition of A is 0.1 atm/sec. If initially A is taken at 2
atm pressure then what will be rate of reaction after 10 seconds.
(A) 0.1 atm/sec (B) 0.05 atm/sec (C) zero (D) 0.5 atm/sec

7. The rate constant for the dissociation of N2O5 : 2N2O5  4NO2+O2

is 3.0 × 10–5 sec–1. if the rate is 2.4 × 10–5 mol litre–1 sec–1, then the concentration of N2O5
(in mol litre–1 ) is
(A) 1.4 (B) 1.2 (C) 0.004 (D) 0.8

8. For a gaseous reaction : 2A(g)  3B(g) + 4C(g) occurring in a rigid vessel, if initially pressure is 3 atm and
after 10 minutes & 20 minutes the pressure is 6.75 atm and 10.5 atm respectively, then what will be the
order of reaction?

1
(A) 0 (B) 1 (C) 2 (D)
2

9. For the reaction : A  3B, the molar concentration of 'A' at any time 't' (in min.) may be expressed as

1
[A]2 = . The only incorrect information regarding the reaction is :
25  0.0002 t
(A) The intial concentration of 'A' is 0.2 M.
(B) The rate constant of reaction is 0.001 M–2 min–1
(C) The concentration of 'B' at t = 55000 min, is 0.1 M.
(D) The order of reaction is 3.

10. For the elementary reaction : 2A  Products, on increasing the temperature at constant concentrations,
the rate of reaction
(A) increases, only when the reaction is exothermic
(B) increases, only when the reaction is endothermic
(C) always increases
(D) always decreases
 CHEMIST RY

DPP
DAILY PRACTIC E PRO BLEMS
TARGET : JEE(MAIN) + ADVANCE
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ST

NO. 03
CHEMICAL KINETICS
TOPIC : ORDER OF REACTION

Single correct:
1. For a zero order reaction and a Ist order reaction half life are in ratio of 4 : 1. Calculate ratio of time taken
to complete 87.5 % reaction for zero order : first order reaction respectively.
(A) 7 : 3 (B) 3 : 7 (C) 4 : 1 (D) 5 : 3

2. For first order isomerisation reaction.

CH3NC  CH3CN
How do the properties of the reaction in the table below vary as reaction proceeds?

 [CH 3 NC]
Rate of reaction (M.s 1 ) Half life (s)
t
(a ) Re main the same Decreases
( b) Decreases Re main the same
(c ) Re main the same Re main the same
(d ) Decreases Decreases

(A) (a) (B) (b) (C) (c) (D) (d)

3. At 1800 K ethane gas decomposes to ethene and hydrogen. Rate constant for the reaction is
10–3 Pa–1 sec–1. If initial pressure of ethane is 3 × 105 Pa, how many sec. would it take for the pressure
to reach 5 × 105 Pa?
(A) 1800.2 sec. (B) 3.33 × 10–2 sec. (C) 6.66 ×10–3 sec. (D) 1000.4 sec.

4. For the reaction :

2A + 3B  2C
If initial concentration of A and B are 2 × 10–2 M and 10–2 M respectively with initial ROR is
2 × 10–6 M/sec. Then initial rate of disappearance of A is :
(A) 1 × 10–6 M/sec (B) 6 × 10–6 M/sec
(C) 4 × 10–6 M/sec (D) can't be determined as order is not given
5. If decomposition of A(g)  B(g) + C(g) follows Ist order kinetics then graph of rate of formation of
B is R then, R v/s time will be

R R R R
(A) (B) (C) (D)
time time time time

Match the columm :

6. Column I Column II

Given : C A0 = Initial concentration of reactant 'A'

CA = Concentration of reactant 'A' at time 't'

(A) (P) Graph between degree of dissociation '' vs 'time' for Ist order
reaction.

(B) (Q) Graph between degree of dissociation '' vs 'time' for zero order
reaction.

C A0  C A
(C) (R) Graph between vs 'time' for second order reaction.
CA

(S) Graph between 'half life' vs C A0 for second order reaction.

Subjective
7. The reaction 2A + B C + D goes to completion and follows the rate law – d[B]/dt = K [A]2 [B].
Calculate the values of (x + y) in the following data:

Set [A 0 ] 10 3 M [B0 ] 103 M Half life (sec)

1 300 4 62.5
2 300 6 x
3 5 300 625
4 10 300 y
 CHEMIST RY

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NO. 04
CHEMICAL KINETICS
TOPIC : ORDER OF REACTION

1. Decomposition of reaction 3A (g)  2 B (g) + 2C(s) follows first order kinetics. Starting with pure
A (at 6 atm), the pressure developed after 20 minute and after a long time are 5.05 atm and 4.05 atm,
respectively. Identify the correct statement.
(A) Time for 75% completion is slightly more than 40 minute.
(B) Time for 87.5% completion is slightly less than 60 minute.
(C) Time for 93.75% completion is exactly 80 minute.
(D) Time for 90% completion is more than 80 minute.

2. The reaction : A(aq) — Products, occur 0.01% in 20 milliseconds when the initial concentration of 'A'
was 0.4M and 80 milliseconds when the initial concentration of 'A' was 0.2 M. The order of reaction is:
(A) 0 (B) 1 (C) 2 (D) 3

3. For a first order reaction : A(g)  B(g) + C(g) + D(g). Occurring at 1 bar pressure and 300K if initial
volume of the container containing only A is V0 and after 10 minutes it is V10 then average life of A will
be(in minutes):

2V0 10 V0 10
(A) 0.1 ln 3V  V (B) (C) 0.1 ln V  V (D)
0 10 2V0 0 10 V0
ln ln
3V0  V10 V0  V10

4. For the reaction : A(aq)  2B(aq) , the concentration of 'B' at different time is given as:

Time (min) 0 10 20 30
[B] (in M ) 0 0. 2 0. 4 0.6

The order of reaction is :

(A) 0 (B) 0.5 (C) 1.0 (D) 2.0

5. The following data is obtained for the reaction : A(aq) — 2B(aq) + C(aq)
Time (min) 0 20 40 60
Concentration of ' A ' 0.1 0.09 0.081 0.0729
The order of reaction is :
(A) 0 (B) 1 (C) 2 (D) 3
6. A first order reaction : 2P(g)  Q(g) + 2S(g)

Time(min.) 0 35 
Ptotal(torr) 100 125 150

Then rate of reaction will be ____________ when partial pressure of P is 50 torr.

[Given : ln2 = 0.7]
(A) 1 torr/s (B) 0.5 torr/s
(C) 8.33 × 10–3 torr/s (D) 30 torr/s

Subjective :
7. For the reaction 2A  3B + 5C occurring at constant temperature in a constant volume container,
total pressure is observed at different time interval. If the reaction is first order with respect to A, then
calculate the value of rate constant × 1000 in terms of sec–1. [Take : ln2 = 0.7]

8. For the reaction A + 2B + 3C  D, following data was obtained. Using the data, calculate order of the
reaction.

Concentration (M) Rate of reaction

Experiment –1
[A] [B] [C] M sec

(1) 0.6 1.2 0.3 0.5

(2) 0.6 2.4 0.3 2

(3) 1.2 2.4 0.3 2

(4) 0.6 1.2 0.9 13.5

 CHEMIST RY

TARGET : JEE(MAIN+ ADVANCE)

DPP
DAILY PRACTIC E PRO BLEMS

ST

NO. 05
CHEMICAL KINETICS
TOPIC : MIXED CONCEPT

Single correct :
1. Which of the following graph is incorrect for a zero order reaction of the type R  P
where R represents reactant and P represents product?

Rate of
t1/2
Reaction
(A) (B)
Time Time

[Reactant] [Product]
(C) (D)
Time Time

Given [species] represents concentration of the species.

2. For a reaction of order n, what is the relationship between t3/4 and t1/2 , where t3/4 is the time required for
concentration (C) to become 1/4 C0 where C0 and C are the values of the reactant concentration at the
start and after time t, respectively.
(A) t3/4 = t1/2 [2n–1 + 1] (B) t3/4 = t1/2 [2n–1 – 1]
(C) t3/4 = t1/2 [2n+1 – 1] (C) t3/4 = t1/2 [2n+1 + 1]

3. For the parallel first order reaction:

1
K1 0.02 min
A     B
1
A K2 
0.03 min
  2C
The molar ratio of B and C in the product at t = 10 min, is
(A) 1 : 1 (B) 1 : 2 (C) 2 : 3 (D) 1 : 3
4. Which change will decrease the rate of elementary reaction between I2(s) and H2(g)?
(A) Increasing the partial pressure of H2(g).
(B) Adding I2(s) as one piece rather than as several small ones.
(C) Heating the reaction mixture.
(D) Adding a catalyst for the reaction.

5. The rate of a certain reaction depends on concentration (C) according to the equation:

 dC K1C

dt 1  K 2C

What will be the difference in order of reaction at very low concentration and very high concentration?
(A) 0 (B) 0.5 (C) 1 (D) 2

Assertion Reason
6. Statement-1 : If the graph between t1/2 (y-axis) of reaction : A  Products, and A0 [Initial concentration]
(x-axis) is straight line, then the reaction must be of first order.
Statement-2 : In first order reaction : A  Products, the t1/2 is independent of A0 [Initial concentration].
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Subjective :
7. For the elementary reaction :
H2S(aq) + Cl2(aq)  S(s) + 2H+(aq) + 2Cl–(aq)
The rate constant for disappearance of H2S at 25°C is 4 × 10–2 M–1 sec–1. If [H2S] = 2 × 10–4 M and
[Cl2] = 0.025 M. What is rate of formation of Cl– ?
[Multiply your answer by 107]
 CHEMIST RY

TARGET : JEE(MAIN + ADVANCE)

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ST

NO. 06
CHEMICAL KINETICS
TOPIC : SEQUENTIAL & PARALLEL REACTION
Single correct
1. For the reaction k1 R – OH + X¯
er
n d rd
the rate is given by R – X + OH¯ II o
Rate = k1 [RX] [OH¯] + k2 [RX] k2
I sot r
der R – OH + X¯
Calculate % of RX which reacts by
2nd order mechanism, when [OH]¯ is 0.1 M.

k1 100 k 2 100 10 k1 100 k1

(A) k  k (B) k  k (C) k  k (D) k  10k
1 2 1 2 1 2 1 2

k1 k2 k3
2. In the given sequence of first order reaction : A  B  C  D
What is the ratio of numbers of atoms of A to the number of atoms of B after long time interval starting

ln 2 ln 2
with pure A, where k1 = ; k2 =
20  60 30
(A) 2/3 (B) 10 (C) 20 (D) 40

3. 75 % of a first order reaction occurs in 30 min at 27°C. 87.5 % of the same reaction occurs in 30 min at
57°C. The activation energy of reaction is [ln2 = 0.7, ln3=1.1]
(A) 2.64 kJ/mol (B) 2.64 Kcal/mol
(C) 10.97 Kcal/mol (D) zero

4. For a reaction : A(g) + 2B(g)  C(g) + D(g). If initially [A] = a & [B] = b and the rate law is
ROR = K[B]t where [B]t represents concentration of [B] at any time 't'. Then calculate the time at
which concentration of 'A' reduces to half of original.

a 1 b
(A) (B) t = ln
2K K ba

ln 2 1 b
(C) (D) t = ln
K 2K b  a
Subjective :

5. A gaseous compound 'A' reacts by three independent first order processes

(as shown in figure) with rate constant 2 × 10–3 , 3 × 10–3 and

1.93 × 10–3 sec–1 respectively for products B, C and D respectively. If

initially pure 'A' was taken in a closed container with P = 1.386 atm, find

the partial pressure of 'B' (in atm) after 100 sec from start of experiment.

6. A substance ''A'' undergoes a reaction such that its concentration at any time t(in sec.) can be represented

4 1
by the equation [A]t  where 't' is time in sec, and [At] represents molar concentration. Calculate
( t  1)

rate of disappearance of 'A' at a concentration of 2M.

 C HE M I S T R Y

DPP
DAILY PRACTICE PROBLEMS
TARGET : JEE(MAIN + ADVANCE)
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NO. 07
CHEMICAL KINETICS
TOPIC : TEMPERATURE DEPENDENCE OF RATE
1. The rate constant, the activation energy and the frequency factor of a chemical reaction at 25°C are
3.0 × 10–4 s–1, 104.4 KJ mol–1 and 6.0 × 1014 s–1 respectively. The value of the rate constant as
T   is :
(A) 2.0 × 1018 s–1 (B) 6.0 × 1014 s–1 (C) infinite (D) 3.6 × 1030 s–1

2. The rate constant K1 of a reaction is found to be double that of rate constant K2 of another reaction. The
relationship between corresponding activation energies of the two reactions at same temperature
(E1 and E2) can be represented as :
(A) E1 > E2 (B) E1 < E2 (C) E1 = E2 (D) None of these

3. When a graph between log K and 1/T is drawn a straight line is obtained. The point at which line cuts
y-axis and x -axis respectively correspond to the temp :
(A) 0, Ea / 2.303 R log A (B) , Ea / (R ln A)
(C) 0, log A (D) None of these

4. How much faster would a reaction proceed at 25°C than at 0°C if the activation energy is 65 kJ?
(A) 2 times (B) 5 times (C) 11 times (D) 16 times

5. For a reaction A  B, Ea = 10 kJ mol–1 , H = 5 kJ mol–1 . Thus, potential energy profile for this reaction
is :

PE

(A) (B)

Reaction progress

PE

(C) (D)

Reaction progress Reaction progress

6. The Ea of a reaction in presence of a catalyst is 4.15 kJ mol–1 and in absence of a catalyst is 8.3 kJ
–1 1
mol . What is slope of the plot of ln k vs in the absence of catalyst
T
(A) + 1 (B) –1 (C) + 1000 (D) –1000

7. For the decomposition of H the following logarithmic plot is shown : [R = 1.98 cal/mol-K]

1
0
logk
–1
–2
–3
1.2 1.3 1.4 1.5 1.6
3
10 /T
The activation energy of the reaction is about
(A) 45600 cal (B) 13500 cal (C) 24600 cal (D) 32300 cal

8. For the reaction H2 (g) + Br2 (g)  2HBr (g) the experiment data suggested that r = k[H2][Br2]1/2
The molecularity and order of the reaction are respectively :
(A) 2, 3/ 2 (B) 3/2 , 3/2 (C) Not defined, 3/2 (D) 1,1/2

9. The reaction of NO2 (g) and O3 (g) is first-order in NO2 (g) and O3 (g)
2 NO2 (g) + O3 (g) 
 N2O5 (g) + O2 (g)
The reaction can take place by mechanism :
slow
I : NO2 + O3   NO3 + O2
fast
NO3 + NO2   N2O5
ka fast
II : O3 O2 + [O]
kb
slow
NO2 + O   NO3
fast
NO3 + NO2   N2O5
Select correct mechanism.
(A) I only (B) II only
(C) both I and II (D) None of I and II

10. A hypothetical reaction X2 + Y2 

 2XY follows the mechanism given below.
X2 X + X [Fast]
X + Y2 
 XY + Y [Slow]

X + Y 
 XY [Fast]
The order of overall reaction is
(A) 2 (B) 1 (C) 1.5 (D) Zero
11. The reaction of hydrogen, and iodine monochloride is represented by the equation :

H2(g) + 2Cl(g) 
 2HCl(g) + 2(g)

This reaction is first–order in H2(g) and also first–order in Cl(g). Which of these proposed mechanism

can be consistent with the given information about this reaction ?

Mechanism  : H2(g) + 2Cl(g) 

 2HCl(g) + 2(g)

Slow
Mechanism  : H2(g) + Cl(g)   HCl(g) + H(g)

fast
HI(g) + Cl(g)   HCl(g) + I2(g)

(A)  only (B)  only

(C) both  and  (D) neither  nor 

12. Reaction A + B 
 D + E take place as

K1
A + B  2C

K2
C + B  2D

K3
C + A  2E

The rate of disapperance of C is given by

d[C]
(A) – = K2 [B][C] + K3[A][C] – 2K1[A][B]
dt

d[C]
(B) – = K2[B][C] + K3 [E] – K1[C]
dt

d[C]
(C) – = K2[D]O + K3[E] – K1[C]
dt

d
(D) – [C] = 2K1[A][B] – K2 [B][C] – K3[A][C]
dt