LATIHAN REAKSI REDOKS

1. Calculate the standard e.m.f, standard free energy change and equilibrium
constant for the following redox reaction taking place in a galvanic cell at 25 0C.
½ Cu (s) + ½ Cl2 (g) ½ Cu2+ (aq) + Cl- (aq)
E0 Cl2/2Cl- = + 1.36 V, E0 Cu2+/Cu = +0.34 V
Jawaban: No 1 dan 2
2. Determine the equilibrium constant at the following reaction at 298 K.
2 Fe3+ + Sn2+ 2 Fe2+ + Sn4+ From the calculated value of the equilibrium
constant, predict whether Sn2+ ions can reduce Fe3+ ions to Fe2+ ions quatitively
or not (E0 Fe3+ , Fe2+ /Pt = +0.771 V, E0 Sn4+, Sn2+/ Pt = +0.15 V)
3. EMF diagram for Mn is given as: E0A (volts)
+1.51

MnO4- +0.56 MnO42- + 2.26 MnO2 +0.95 Mn3+ +0.51 Mn2+ -1.81 Mn0

+ 1.70 +1.23
 Calculate EA0 value for MnO4- – Mn3+ couple
Jawaban:

4. Calculate the maximum work that can be obtained from the Daniell cell given
below: Zn (s) / Zn2+ (aq) II Cu2+ (aq) / Cu (s) Given that E0 Zn2+/Zn = -0.76 V and
E0 Cu2+/Cu = +0.34V
Jawaban:

5. Will tin metal reduce Pb2+ ion if concentration of Pb2+ ions is 0,50M, that of Sn2+
being 0,01M? The cell set up Sn │Sn2+ (0,01M) ║Pb2+ (0,50M) │Pb
Diket: E0Sn2+/Sn = -0,136V and E0Pb2+/Pb = -0,126V
Jawaban: