Chem Mains 2023 PDF

FINAL JEE–MAIN EXAMINATION – JANUARY, 2023
(Held On Wednesday 01st February, 2023) TIME : 3 : 00 PM to 6 : 00 PM
CHEMISTRY TEST PAPER WITH ANSWER

SECTION-A 34. The graph which represents the following reaction
31. In a reaction, is :
OH OH OCOCH 3
OH 
COOCH 3 COOH COOH (C6 H 5 )3 C  Cl 
Pyridine (C 6 H 5 )3 C  OH
‘Y’ ‘X’
rate rate
reagents ‘X’ and ‘Y’ respectively are :
(1) (2)
(1) (CH3CO)2O/H+ and CH3OH/H+, 
(2) (CH3CO)2O/H+ and (CH3CO)2O/H+
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[(C6 H5) 3C–Cl] –
[OH ]
(3) CH3OH/H+,  and CH3OH/H+, 

rate rate
+ +
(4) CH3OH/H  and (CH3CO)2O/H (3) (4)
Official Ans. by NTA (1)
[(C6 H5) 3C–Cl] [Pyridine]
Allen Ans. (1)
32. The correct order of bond enthalpy (kJ mol–1) is :
Allen Ans. (3)
(1) Si – Si > C – C > Sn – Sn > Ge – Ge
35. ‘X’ is : HF
(2) Si – Si > C – C > Ge – Ge > Sn – Sn + X
 Major product
(3) C – C > Si – Si > Sn – Sn > Ge – Ge
(4) C – C > Si – Si > Ge – Ge > Sn – Sn
Official Ans. by NTA (4) (1) (2)

Allen Ans. (4)
33. All structures given below are of vitamin C. Most
stable of them is :
OH (3) (4)
(1) HO O
O
(2)
H
OH OH
Allen Ans. (1)
(3) (4) 36. The complex cation which has two isomers is :
(1) [Co(H2O)6]3+ (2) [Co(NH3)5Cl]2+
(3) [Co(NH3)5NO2]2+ (4) [Co(NH3)5Cl]+
Official Ans. by NTA (1) Official Ans. by NTA (3)
Allen Ans. (1) Allen Ans. (3)
1
37. Given below are two statements : 40. Given below are two statements : one is labelled
Statement I : Sulphanilic acid gives esterification
as Assertion (A) and the other is labelled as
test for carboxyl group.
Reason (R).
Statement II : Sulphanilic acid gives red colour in
Lassigne’s test for extra element detection. Assertion (A) : -halocarboxylic acid on reaction
In the light of the above statements, choose the
with dil. NH3 gives good yield of -amino
most appropriate answer from the options given
below : carboxylic acid whereas the yield of amines is very
(1) Statement I is correct but Statement II is low when prepared from alkyl halides.
incorrect.
Reason (R) : Amino acids exist in zwitter ion form
(2) Both Statement I and Statement II are incorrect.
(3) Both Statement I and Statement II are correct. in aqueous medium.
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(4) Statement I is incorrect but Statement II is In the light of the above statements, choose the
correct.
correct answer from the options given below :
Allen Ans. (4) (1) Both (A) and (R) are correct and (R) is the
38. Given below are two statements : one is labelled correct explanation of (A).
(2) Both (A) and (R) are correct but (R) is not the
Reason (R).
Assertion (A) : Gypsum is used for making correct explanation of (A).
fireproof wall boards. (3) (A) is correct but (R) is not correct.
Reason (R) : Gypsum is unstable at high
(4) (A) is not correct but (R) is correct.
temperatures.
In the light of the above statements, choose the Official Ans. by NTA (1)
correct answer from the options given below : Allen Ans. (2)
(1) Both (A) and (R) are correct but (R) is not the
41. The industrial activity held least responsible for
correct explanation of (A).
(2) (A) is correct but (R) is not correct. global warming is :
(3) (A) is not correct but (R) is correct. (1) manufacturing of cement
(4) Both (A) and (R) are correct and (R) is the
(2) steel manufacturing
correct explanation of (A).
Official Ans. by NTA (1) (3) Electricity generation in thermal power plants.
Allen Ans. (1) (4) Industrial production of urea

39. Which element is not present in Nessler’s reagent ?
(1) Mercury (2) Potassium
(3) Iodine (4) Oxygen Allen Ans. (4)

Allen Ans. (4)
2
42. The structures of major products A, B and C in the In the light of the above statements, choose the
following reaction are sequence. correct answer from the options given below :
O (1) Both (A) and (R) are correct and (R) is the
NaHSO3, dil. HCl LiAlH4
H [A] [B] correct explanation of (A).
NaCN, H2O
(2) (A) is correct but (R) is not correct.
HCl/H2O
[C] (3) (1) is not correct but (R) is correct.

OH CN (4) Both (A) and (R) are correct but (R) is not the
(1) A = ,
H correct explanation of (A).
HO CHO Official Ans. by NTA (1)
B= Allen Ans. (1)
H
, 44. The starting material for convenient preparation of
HO CO2H
C= deuterated hydrogen peroxide (D2O2) in laboratory
H is:
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OSO3Na (1) K2S2O8 (2) 2-ethylanthraquinol
(2) A = , (3) BaO2 (4) BaO
H
OH
Allen Ans. (1)
B=
H 45. In figure, a straight line is given for Freundrich
,
Cl 1
Adsorption (y = 3x + 2.505). The value of and
C= n
H log K are respectively.
HO SO3H Y
(3) A = , x
log m
H I
n
B= OH
,
log K
HO SO2Cl
C=
H log P X
HO CN (1) 0.3 and log 2.505 (2) 0.3 and 0.7033
(4) A = ,
(3) 3 and 2.505 (4) 3 and 0.7033
H
HO NH2
B= Allen Ans. (3)
H 46. Given below are two statements : one is labelled as
,
HO CO2H Assertion (A) and the other is labelled as Reason
C=
H (R).
Official Ans. by NTA (4) Assertion (A) : An aqueous solution of KOH
Allen Ans. (4) when for volumetric analysis, its concentration
43. Given below are two statements : one is labelled should be checked before the use.
Reason (R) : On aging, KOH solution absorbs
Reason (R).
atmospheric CO2.
Assertion (A) : Cu2+ in water is more stable than
Cu+. In the light of the above statements, choose the
Reason (R) : Enthalpy of hydration for Cu2+ is correct answer from the options given below.
much less than that of Cu+.
3
(1) (A) is not correct but (R) is correct 50. O–O bond length in H2O2 is X than the O–O bond
(2) Both (A) and (R) are correct but (R) is not the length in F2O2. The O – H bond length in H2O2 is
correct explanation of (A) Y than that of the O–F bond in F2O2.
Choose the correct option for X and Y from the
(3) Both (A) and (R) are correct and (R) is the
given below.
correct explanation of (A)
(1) X – shorter, Y – shorter
(4) (A) is correct but (R) is not correct
(2) X – shorter, Y – longer
Official Ans. by NTA (3) (3) X – longer, Y – longer
Allen Ans. (3) (4) X – longer, Y - shorter
47. Which one of the following sets of ions represents Official Ans. by NTA (4)
a collection of isoelectronic species? Allen Ans. (4)
(Given : Atomic Number : F :9 , Cl : 17, Na = 11,
Mg = 12, Al = 13, K = 19, Ca = 20, Sc = 21) SECTION-B
51. 0.3 g of ethane undergoes combustion at 27°C in a
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(1) (Li+ , Na+ , Mg2+ , Ca2+
(2) (Ba2+ , Sr2+ , K+ , Ca2+ bomb calorimeter. The temperature of calorimeter
system (including the water) is found to rise by
(3) (N3– , O2– , F– , S2–
0.5°C. The heat evolved during combustion of
(4) (K+ , Cl– , Ca2+ , Sc3+
ethane at constant pressure is ________kJ mol–1.
(Nearest integer)
Allen Ans. (4)
[Given : The heat capacity of the calorimeter
48. The effect of addition of helium gas to the
system is 20 kJ K–1, R = 8.3 JK–1 mol–1.
following reaction in equilibrium state, is :
Assume ideal gas behaviour.
PCI5 (g) PCl3 (g)  Cl2 (g)
Atomic mass of C and H are 12 and 1 g mol–1
(1) the equilibrium will shift in the forward respectively]
direction and more of Cl2 and PCl3 gases will be Official Ans. by NTA (1006)
produced.
Allen Ans. (1006)
(2) the equilibrium will go backward due to
52. Among following compounds, the number of those
suppression of dissociation of PCl5. present in copper matte is_________.
(3) helium will deactivate PCl5 and reaction will
A. CuCO3
stop.
B. Cu2S
(4) addition of helium will not affect the
C. Cu2O
equilibrium.
D. FeO
Official Ans. by NTA (1 & 4)
Allen Ans. (1 & 4)
Allen Ans. (1)
49. For electron gain enthalpies of the elements
53. Among the following, the number of tranquilizer/s
denoted as egH, the incorrect option is :
is/are_________.
(1) egH (Cl) <egH (F)
A. Chloroliazepoxide
(2) egH (Se) <egH (S)
B. Veronal
(3) egH (I) <egH (At)
C. Valium
(4) egH (Te) <egH (Po)
D. Salvarsan
Allen Ans. (2)
Allen Ans. (3)
4
54. A B 58. Testosterone, which is a steroidal hormone, has the
The above reaction is of zero order. Half life of following structure.
this reaction is 50 min. The time taken for the OH
concentration of A to reduce to one-fourth of its CH3
initial value is________min.
CH3
(Nearest integer)
O Testosterone
Allen Ans. (75)
The total number of asymmetric carbon atom/s in
55. 20% of acetic acid is dissociated when its 5 g is
added to 500 mL of water. The depression in testosterone is ______
freezing point of such water is _______ × 10–3 °C. Official Ans. by NTA (6)
Atomic mass of C, H and O are 12, 1 and 16 a.m.u.
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Allen Ans. (6)
respectively.
[Given : Molal depression constant and density of 59. The spin only magnetic moment of [Mn(H2O)6]2+
water are 1.86 K kg mol–1 and 1 g cm–3 complexes is _______B.M. (Nearest integer)
respectively. (Given : Atomic no. of Mn is 25)
Allen Ans. (372)
Allen Ans. (6)
56. The molality of a 10% (v/v) solution of di-bromine
solution in CCl4 (carbon tetrachloride) is 'x'. x = 60. A metal M crystallizes into two lattices :- face
________ × 10–2 M. (Nearest integer) centred cubic (fcc) and body centred cubic (bcc)
[Given : molar mass of Br2 = 160 g mol–1 with unit cell edge length of 2.0 and 2.5 Å
atomic mass of C = 12 g mol–1 respectively. The ratio of densities of lattices fcc to
atomic mass of Cl = 35.5 g mol–1 bcc for the metal M is _______.
density of dibromine = 3.2 g cm–3 (Nearest integer)
–3
density of CCl4 = 1.6 g cm ]
Allen Ans. (4)
Allen Ans. (139)
57. 1×10–5 M AgNO3 is added to 1 L of saturated
solution of AgBr. The conductivity of this solution
at 298 K is ______×10–8 S m–1.
[Given : Ksp(AgBr) = 4.9×10–13 at 298K
0Ag  6  103 Sm 2 mol –1
 0Br   8  103 Sm2 mol –1
 0NO  7  103 Sm2 mol –1 ]

3

Allen Ans. (Bonus)
5
(Held On Wednesday 1st February, 2023) TIME : 9 : 00 AM to 12 : 00 NOON
NOON
SECTION-A 32. The correct representation in six membered
31. Which of the following represents the lattice pyranose form for the following sugar [X] is
CHO
structure of A0.95O containing A2+, A3+ and O2– ions?
A2+ A3+ O2– HO H

HO H
H OH
H OH
A.
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H2COH
Sugar [X]
H2COH
O
H H H
(1)
OH OH H OH
B. H OH
CH2OH
O
H
(2)
HO OH OH OH
H H
C.
(3)
(1) B and C only CH2 OH

O
(2) B only
H H H
(4)
(3) A and B only
HO H OH OH
(4) A only
OH H
1
33. Highest oxidation state of Mn is exhibited in 36. In the following reaction, ‘A’ is
Mn2O7. The correct statements about Mn2O7 are
(A) Mn is tetrahedrally surrounded by oxygen
atoms ‘A’ Major product.
(B) Mn is octahedrally surrounded by oxygen
atoms
NHCOOEt
(C) Contains Mn-O-Mn bridge
(D) Contains Mn-Mn bond. (1)
Choose the correct answer from the options given CH2OH
below
(1) A and C only (2) A and D only O
(3) B and D only (4) B and C only NH
Official Ans. by NTA (1) (2)
O
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Allen Ans. (1)
34. Decreasing order of dehydration of the following
alcohols is
OH OH OH OH (3)
a b c d
(1) a > d > b > c

NH2
(2) b > d > c > a
(3) b > a > d > c (4)
CH2COOEt
(4) d > b > c > a
Allen Ans. (2) Official Ans. by NTA (2)
35. Given below are two statements: One is labelled as Allen Ans. (2)
Assertion A and the other is labelled as Reason R.
37. Match List I with List II.
Assertion A: Amongst He, Ne, Ar and Kr;
1 g of activated charcoal adsorbs more of Kr. List-I List-II
Reason R : The critical volume Vc (cm3 mol–1) and (A) Tranquilizers (I) Anti blood clotting
critical pressure Pc (atm) is highest for Krypton but
(B) Aspirin (II) Salvarsan
the compressibility factor at critical point Zc is
lowest for Krypton. (C) Antibiotic (III) Antidepressant drugs
In the light of the above statements, choose the (D) Antiseptic (IV) Soframicine
correct answer from the options given below.
Choose the correct answer from the options given
(1) A is true but R is false
below:
(2) A is false but R is true
(3) Both A and R are true but R is NOT the (1) (A) – IV, (B) – II, (C) – I, (D) – III
correct explanation of A (2) (A) – II, (B) – I, (C) – III, (D) – IV
(4) Both A and R are true and R is the correct (3) (A) – III, (B) – I, (C) – II, (D) – IV
explanation of A (4) (A) – II, (B) – IV, (C) – I, (D) – III
Allen Ans. (1)
Allen Ans. (3)
2
38. Given below are two statements: 41. A solution of FeCl3 when treated with K4[Fe(CN)6]
Statement I: Chlorine can easily combine with gives a prussiun blue precipitate due to the
oxygen to from oxides; and the product has a formation of
tendency to explode.
(1) K[Fe2(CN)6]
Statement II: Chemical reactivity of an element
(2) Fe[Fe(CN)6]
can be determined by its reaction with oxygen and
halogens. (3) Fe3[Fe(CN)6]2
In the light of the above statements, choose the (4) Fe4[Fe(CN)6]3
correct answer from the options given below. Official Ans. by NTA (4)
(1) Both the statements I and II are true Allen Ans. (4)
(2) Statement I is true but Statement II is false
42. Which of the following are the example of double
(3) Statement I is false but Statement II is true
salt?
(4) Both the Statements I and II are false
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Official Ans. by NTA (1) (A) FeSO4.(NH4)2SO4.6H2O
Allen Ans. (1) (B) CuSO4.4NH3.H2O

39. Resonance in carbonate ion (CO32 ) is (C) K2SO4.Al2(SO4)3.24H2O
(D) Fe(CN)2.4KCN
Choose the correct answer.
(1) A and C only
Which of the following is true? (2) A and B only
(1) It is possible to identify each structure (3) A, B and D only
individually by some physical or chemical (4) B and D only
method.
(2) All these structures are in dynamic equilibrium
Allen Ans. (1)
with each other.
43. Which of the following complex will show largest
(3) Each structure exists for equal amount of time.
(4) CO32 has a single structure i.e., resonance splitting of d-orbitals?
(1) [Fe(C2O4)3]3–
hybrid of the above three structures.
Official Ans. by NTA (4) (2) [FeF6]3–
Allen Ans. (4) (3) [Fe(CN)6]3–
40. Identify the incorrect option from the following: (4) [Fe(NH3)6]3+
Br OH
(1) + KOH(aq)  + KBr Official Ans. by NTA (3)
Allen Ans. (3)
(2) + KOH(alc)  + KBr
44. How can photochemical smog be controlled?
Cl Cl O (1) By using tall chimneys
O
anhyd AlCl (2) By complete combustion of fuel
+ H3C–C–Cl  
(3) 3 CH3+HCl
(3) By using catalytic converters in the
Cl ( i ) NaOH, 623 K, OH
300 atm automobiles/industry
(4)  ( ii ) HCl
(4) By using catalyst
3
45. Match List I with List II. 48. But-2-yne is reacted separately with one mole of
List I List II Hydrogen as shown below:
Na Pd/C
(A) Slaked lime (I) NaOH B 
liq NH3
 CH3 – C  C– CH3  
A
 H2
(B) Dead burnt plaster (II) Ca(OH)2 A. A is more soluble than B.

(C) Caustic soda (III) Na2CO3·10H2O B. The boiling point & melting point of A are
(D) Washing soda (IV) CaSO4 higher and lower than B respectively.
C. A is more polar than B because dipole moment
Choose the correct answer form the options given
of A is zero.
below: D. Br2 adds easily to B than A.
(1) (A) – I, (B) – IV, (C) – II, (D) – III Identify the incorrect statements from the options
(2) (A) – III, (B) – IV, (C) – II, (D) – I given below :-
(3) (A) – II, (B) – IV, (C) – I, (D) – III (1) B and C only
(2) B, C and D only
(4) (A) – III, (B) – II, (C) – IV, (D) – I
(3) A, C and D only
Official Ans. by NTA (3) (4) A and B only
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Allen Ans. (3) Official Ans. by NTA (DROP)
46. Choose the correct statement(s): Allen Ans. (Bonus)
A. Beryllium oxide is purely acidic in nature. 49. Given below are two statements: one is labelled as
B. Beryllium carbonate is kept in the atmosphere Assertion A and the other is labelled as Reason R
Assertion A: Hydrogen is an environment friendly
of CO2.
fuel.
C. Beryllium sulphate is readily soluble in water. Reason R: Atomic number of hydrogen is 1 and it
D. Beryllium shows anomalous behavior. is a very light element.
Choose the correct answer from the options given In the light of the above statements, choose the
below: correct answer from the options given below
(1) A, B and C only
(2) Both A and R are true but R is NOT the correct
(2) B, C and D only explanation of A
(3) A and B only (3) A is false but R is true
(4) A only (4) Both A and R are true and R is the correct
Official Ans. by NTA (2) explanation of A
Allen Ans. (2)
47. Given below are two statements: one is labelled as
Assertion A and the other is labelled as Reason R 50. Match List I and List II.
Assertion A: In an Ellingham diagram, the
List I List II
oxidation of carbon to carbon monoxide shows a
Functional group /
negative slope with respect to temperature. Test
Class of Compound
Reason R: CO tends to get decomposed at higher
(A) Molisch's Test (I) Peptide
temperature.
In the light of the above statements, choose the (B) Biuret Test (II) Carbohydrate
correct answer from the options given below (C) Carbylamine Test (III) Primary amine
(1) Both A and R are correct and R is the correct (D) Schiff s Test (IV) Aldehyde
explanation of A Choose the correct answer from the options given
(2) A is not correct but R is correct below:
(3) Both A and R are correct but R is NOT the (1) (A) – I, (B) – II, (C) – III, (D) – IV
correct explanation of A (2) (A) – III, (B) – IV, (C) –I, (D) – II
(3) (A) – II, (B) – I, (C) – III, (D) – IV
(4) A is correct but R is not correct
(4) (A) – III, (B) – IV, (C) –II, (D) – I
4
SECTION-B 55. Number of isomeric compounds with molecular
51. The density of 3 M solution of NaCl is 1.0 g mL–1. formula C9H10O which (i) do not dissolve in NaOH
Molality of the solution is __________ × 10–2 m. (ii) do not dissolve in HCl. (iii) do not give orange
(Nearest integer). precipitate with 2, 4 – DNP (iv) on hydrogenation
Given: Molar mass of Na and Cl is 23 and give identical compound with molecular formula
35.5 g mol–1 respectively. C9H12O is __________ .

Allen Ans. (0)
Allen Ans. (364 )
52. Electrons in a cathode ray tube have been emitted 56. (i) X(g) Y(g) + Z(g) Kp1 = 3
with a velocity of 1000 ms-1. The number of (ii) A(g) 2B(g) Kp2 = 1
following statements which is/are true about the If the degree of dissociation and initial concentration
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emitted radiation is _________ . of both the reactants X(g) and A(g) are equal, then
Given : h = 6 × 10-34 Js, me = 9 × 10-31 kg.  p1 
the ratio of the total pressure at equilibrium   is
(A) The deBroglie wavelength of the electron
 p2 
emitted is 666.67nm.
equal to x : 1. The value of x is ________
(B) The characteristic of electrons emitted
(Nearest integer)
depend upon the material of the electrodes of
the cathode ray tube.
Allen Ans. (12)
(C) The cathode rays start from cathode and
move towards anode. 57. The total number of chiral compound/s from the
(D) The nature of the emitted electrons depends following is ________.
on the nature of the gas present in cathode Ph
ray tube.
OH
Official Ans. by NTA (2 ) O O Cl
Allen Ans. ( 2) , ,
COOH
53. Sum of oxidation states of bromine in bromic acid
OH
and perbromic acid is ________ .
HO OH
Official Ans. by NTA (12) COOH
OH
Allen Ans. (12) OH , HO OH ,
 2+
54. At what pH, given half cell Mn O (0.1 M) | Mn
4 COOH OH
(0.001 M) will have electrode potential of 1.282 V? CH2

__________ (Nearest Integer)
2.303RT
Given EMnO
o

/ Mn 2
= 1.54 V, = 0.059V
4
F HO2C COOH
5
58. A and B are two substances undergoing radioactive 60. 25 mL of an aqueous solution of KCl was found to
decay in a container. The half life of A is 15 min require 20 mL of 1 M AgNO3 solution when titrated
and that of B is 5 min. If the initial concentration using K2CrO4 as an indicator. What is the depression
of B is 4 times that of A and they both start in freezing point of KCl solution of the given
decaying at the same time, how much time will it concentration? ____________ (Nearest integer).
take for the concentration of both of them to be (Given : Kf = 2.0 K kg mol-1)
same? ____________ min.
Assume
1) 100% ionization and
Allen Ans. (15)
2) density of the aqueous solution as 1 g mL-1
59. At 25oC, the enthalpy of the following processes Official Ans. by NTA (3)
®
are given:
Allen Ans. (3)
H2(g) + O2(g)  2OH(g)  H = 78kJ mol
o -1
H2(g) + ½ O2(g)  H2O(g)  Ho = –242 kJ mol-1
H2(g)  2H(g)  Ho = 436 kJ mol-1
½ O2(g)  O(g)  Ho = 249 kJ mol-1
What would be the value of X for the following

reaction? _____ (Nearest integer)
H2O(g)  H(g) + OH(g)  Ho = X kJ mol-1
Allen Ans. (499)
6
(Held On Tuesday 24th January, 2023) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A 35. The number of s-electrons present in an ion with
31. Which one amongst the following are good 55 protons in its unipositive state is
oxidizing agents? (1) 8 (2) 9
2+ 2+ (3) 12 (4) 10
A. Sm B. Ce
4+ 4+ Official Ans. by NTA (4)
C. Ce D. Tb
Allen Ans. (4)
Choose the most appropriate answer from the 36. In which of the following reactions the hydrogen
options given below : peroxide acts as a reducing agent?
(1) C only (2) D only (1) PbS  4H 2O2  PbSO4  4H 2O
(3) A and B only (4) C and D only
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(2) 2Fe2  H 2O2  2Fe3  2OH 
(3) HOCl  H 2O2  H3O  Cl  O2
Allen Ans. (4)
32. What is the number of unpaired electron(s) in the (4) Mn 2  H 2O2  Mn 4  2OH 
highest occupied molecular orbital of the following Official Ans. by NTA (3)
+
species : N 2 : N2 ; O2; O2 ?
+ Allen Ans. (3)
37. The metal which is extracted by oxidation and
(1) 0, 1, 2, 1 (2) 2, 1, 2, 1
subsequent reduction from its ore is :
(3) 0, 1, 0, 1 (4) 2, 1, 0, 1
(1) Al (2) Ag
Official Ans. by NTA (1) (3) Cu (4) Fe
33. Which of the following cannot be explained by Allen Ans. (2)
crystal field theory? 38. Given below are two statements :
(1) The order of spectrochemical series O
Statement I : H N under
(2) Magnetic properties of transition metal 2
complexes O
(3) Colour of metal complexes Clemmensen reduction conditions will give
(4) Stability of metal complexes HOOC .
Official Ans. by NTA (1) O
Allen Ans. (1) Statement II : under Wolff-Kishner
34. A student has studied the decomposition of a gas Cl
AB3 at 25°C. He obtained the following data. reduction condition will give
p (mm Hg) 50 100 200 400 Cl
Relative t1/2 (s) 4 2 1 0.5 In the light of the above statements, choose the
The order of the reaction is
(1) 0.5
(2) Both Statement I and Statement II are false
(2) 2
(3) 1
(4) Both Statement I and Statement II are true
(4) 0 (zero) Official Ans. by NTA (3)
Official Ans. by NTA (2) Allen Ans. (3)
Allen Ans. (2)
1
39. Given below are two statements, one is labelled as 41. Given below are two statements, one is labelled as
Assertion A : Benzene is more stable than
Assertion A : Beryllium has less negative value of hypothetical cyclohexatriene.
reduction potential compared to the other alkaline Reason R : The delocalized  electron cloud is
attracted more strongly by nuclei of carbon atoms.
earth metals. In the light of the above statements, choose the
correct answer from the options given below:
Reason R : Beryllium has large hydration energy
(1) A is true but R is false.
2+
due to small size of Be but relatively large value (2) A is false but R is true.
(3) Both A and R are correct and R is the correct
of atomization enthalpy. explanation of A.
In the light of the above statements, choose the (4) Both A and R are correct but R is NOT the
correct explanation of A.
most appropriate answer from the options given Official Ans. by NTA (3)
below. Allen Ans. (3)
42. Choose the correct representation of
®
(1) A is correct but R is not correct conductometric titration of benzoic acid vs sodium
(2) Both A and R are correct and R is the correct hydroxide.
explanation of A.
Conductance
(3) A is not correct but R is correct
(4) Both A and R are correct and R is NOT the (1)
correct explanation of A.
Official Ans. by NTA (2) vNaOH
Allen Ans. (2)
Conductance
40. Match List I with List II

LIST I LIST II
(2)
Type Name
Antifertility
A. I. Norethindrone vNaOH
drug
B. Tranquilizer II. Meprobomate
Conductance
C. Antihistamine III. Seldane

D. Antibiotic IV. Ampicillin (3)
below: vNaOH
(1) A-II, B-I, C-III, D-IV

Conductance
(2) A-IV, B-III, C-II, D-I

(3) A-I, B-III, C-II, D-IV
(4)
(4) A-I, B-II, C-III, D-IV
Official Ans. by NTA (4) vNaOH
Allen Ans. (2)
2
43. Find out the major products from the following 46. Which will undergo deprotonation most readily in
reactions. basic medium?
O O O O O O
Hg(OAc) 2 ,H 2O
B
NaBH 4
 
BH3 ,THF
H O /OH 
A MeO OMe OMe
2 2
a b c
(1) a only
OH
(1) A = , B= (2) c only
OH
(3) Both a and c
OH (4) b only
(2) A = , B= OH Official Ans. by NTA (1)
Allen Ans. (1)
OH OH
(3) A = 47. Choose the correct colour of the product for the
, B=
following reaction.
N = N–OOCCH3
®
(4) A = , B=
OH OH
+1–Naphthyl amine
Allen Ans. (1) SO3H
44. Correct statement is : (1) Yellow
(1) An average human being consumes more food (2) White
than air (3) Red
(2) An average human being consumes nearly 15 (4) Blue
times more air than food Official Ans. by NTA (3)
(3) An average human being consumes equal Allen Ans. (3)
amount of food and air 48. Identify the correct statements about alkali metals.
(4) An average human being consumes 100 times A. The order of standard reduction potential
more air than food +
(M | M) for alkali metal ions is Na > Rb > Li.
Official Ans. by NTA (2) B. CsI is highly soluble in water.
Allen Ans. (2) C. Lithium carbonate is highly stable to heat.
45. Given below are two statements : D. Potassium dissolved in concentrated liquid
Statement I : Pure Aniline and other arylamines ammonia is blue in colour and paramagnetic.
are usually colourless. E. All the alkali metal hydrides are ionic solids.
Statement II : Arylamines get coloured on storage Choose the correct answer from the options given
due to atmospheric reduction. below
In the light of the above statements, choose the (1) A, B, D only
most appropriate answer from the options given (2) C and E only
below : (3) A and E only
(1) Both Statement I and Statement II are incorrect (4) A, B and E only
(2) Both Statement I and Statement II are correct Official Ans. by NTA (3)
(3) Statement I is correct but Statement II is Allen Ans. (3)
incorrect
(4) Statement I is incorrect but Statement II is
correct
Allen Ans. (3)
3
49. The hybridization and magnetic behaviour of 54. Total number of tripeptides possible by mixing of
3
cobalt ion in [Co(NH 3 )6 ] complex, respectively valine and proline is _________
is Official Ans. by NTA (8)
3 2
(1) sp d and diamagnetic
2 3 Allen Ans. (8)
(2) d sp and paramagnetic
2 3
(3) d sp and diamagnetic 55. The number of units, which are used to express
3 2
(4) sp d and paramagnetic concentration of solutions from the following is
Official Ans. by NTA (3) _________.
Allen Ans. (3)
Mass percent, Mole, Mole fraction, Molarity, ppm,
50. K2Cr2O7 paper acidified with dilute H2SO4 turns
Molality.
green when exposed to
(1) Carbon dioxide Official Ans. by NTA (5)
®
(2) Sulphur trioxide
Allen Ans. (5)
(3) Hydrogen sulphide
(4) Sulphur dioxide 56. The number of statement's, which are correct with
Official Ans. by NTA (4) respect to the compression of carbon dioxide from
Allen Ans. (4) point (a) in the Andrews isotherm from the
SECTION-B
following is _________.
51. The number of statement/s which are the
characteristics of physisorption is ___________.
A. It is highly specific in nature d

Pressure
B. Enthalpy of adsorption is high
C. It decreases with increase in temperature
D. It results into unimolecular layer c b a

E. No activation energy is needed Volume
Official Ans. by NTA (2) A. Carbon dioxide remains as a gas upto point (b)
Allen Ans. (2) B. Liquid carbon dioxide appears at point (c)
52. Sum of -bonds present in peroxodisulphuric acid C. Liquid and gaseous carbon dioxide coexist
and pyrosulphuric acid is between points (b) and (c)
Official Ans. by NTA (8) D. As the volume decreases from (b) to (c), the
Allen Ans. (8) amount of liquid decreases
53. Maximum number of isomeric monochloro Official Ans. by NTA (2)
derivatives which can be obtained from 2,2,5,5- Allen Ans. (2)
tetramethylhexane by chlorination is _________
Allen Ans. (3)
4
7. The Total pressure observed by mixing two liquid 60. Following figure shows spectrum of an ideal black
A and B is 350 mm Hg when their mole fractions body at four different temperatures. The number of
are 0.7 and 0.3 respectively. correct statement/s from the following is _______.
The Total pressure becomes 410 mm Hg if the T1

mole fractions are changed to 0.2 and 0.8
Energy distribution
T2
respectively for A and B. The vapour pressure of
T3
pure A is ______ mm Hg. (Nearest integer)
Consider the liquids and solutions behave ideally. T4
Allen Ans. (314)

Wavelength
®
58. One mole of an ideal monoatomic gas is subjected
A. T4 > T3 > T2 > T1
to changes as shown in the graph. The magnitude
B. The black body consists of particles performing
of the work done (by the system or on the system)
simple harmonic motion.
is _______ J (nearest integer).
C. The peak of the spectrum shifts to shorter
1
1.0 2 wavelength as temperature increases.
T1 T2 T3
D.    constant
Pressure (bar)
v1 v 2 v3
0.5 3
E. The given spectrum could be explained using
quantisation of energy.
20 40 Official Ans. by NTA (2)
Volume (L)
Allen Ans. (2)
Given : log 2 = 0.3, ln 10 = 2.3
Allen Ans. (620)
59. If the pKa of lactic acid is 5, then the pH of 0.005

M calcium lactate solution at 25° C is __________
–1
× 10 (Nearest integer)
H
|
Lactic acid CH3  C  COOH
|
OH
Allen Ans. (85)
5
(Held On Tuesday 24th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A 34. Increasing order of stability of the resonance
31. Compound (X) undergoes following sequence of structure is :
reactions to give the Lactone (Y).
A.
B.
(1)
®
C.
(2)
(3) D.
(1) C, D, B, A
(4)
Official Ans. by NTA (1) (2) C, D, A, B
Allen Ans. (1) (3) D, C, A, B
32. Assertion A : Hydrolysis of an alkyl chloride is a (4) D, C, B, A
slow reaction but in the presence of NaI, the rate of
the hydrolysis increases.
Reason R : I– is a good nucleophile as well as a Allen Ans. (BONUS)
good leaving group. 35. The magnetic moment of a transition metal
In the light of the above statements, choose the compound has been calculated to be 3.87 B.M. The
correct answer from the options given below. metal ion is
(1) A is false but R is true (1) Cr2+ (2) Mn2+
(3) V2+ (4) Ti2+
(3) Both A and R are true and R is the correct
explanation of A Official Ans. by NTA (3)
(4) Both A and R are true but R is NOT the correct Allen Ans. (3)
explanation of A 36. Match List I with List II.
Allen Ans. (3)
33. Order of Covalent bond;
A. KF > KI; LiF > KF
B. KF < KI; LiF > KF
C. SnCl4 > SnCl2; CuCl > NaCl (1) A – IV, B – II, C – I, D – III
D. LiF > KF; CuCl < NaCl (2) A – I, B – IV, C – II, D – III
E. KF < KI; CuCl > NaCl (3) A – I, B – III, C – II, D – IV
(1) C, E only (2) B, C only (4) A – III, B – IV, C – I, D – II
(3) B, C, E only (4) A, B only
Allen Ans. (1)
Allen Ans. (3)
1
37. It is observed that characteristic X-ray spectra of 41. 'R' formed in the following sequence of reaction is:
elements show regularity. When frequency to the
power 'n' i.e. vn of X-rays emitted is plotted against
atomic number 'Z', following graph is obtained.
(1)
The value of 'n' is

(2)
®
(1) 1 (2) 2
1
(3) (4) 3
2

Allen Ans. (3)
38. Which of the Phosphorus oxoacid can create silver
mirror from AgNO3 solution ?
(4)
(1) (HPO3)n (2) H4P2O5
(3) H4P2O6 (4) H4P2O7
Allen Ans. (2)
Allen Ans. (2)
39. The primary and secondary valencies of cobalt
respectively in [Co(NH3)5Cl]Cl2 are :
(1) 3 and 5 (2) 2 and 6
(3) 2 and 8 (4) 3 and 6
below :
Allen Ans. (4)
(1) A – III, B – I, C – II, D – IV
40. An ammoniacal metal salt solution gives a brilliant
(2) A – II, B – I, C – III, D – IV
red precipitate on addition of dimethylglyoxime.
(3) A – III, B – IV, C – I, D – II
The metal ion is :
(4) A – II, B – III, C – IV, D – I
(1) Cu2+ (2) Co2+
(3) Fe2+ (4) Ni2+
Allen Ans. (1)
Allen Ans. (4)
2
43. Statement I : For colloidal particles, the values of
colligative properties are of small order as
compared to values shown by true solutions at
same concentration. (3)
Statement II : For colloidal particles, the potential
difference between the fixed layer and the diffused
layer of same charges is called the electrokinetic
potential or zeta potential.
(4)
correct answer from the options given below. Official Ans. by NTA (4)
(1) Statement I is true but Statement II is false Allen Ans. (4)
46. In the following given reaction 'A' is
(3) Both Statement I and Statement II are true
®
Allen Ans. (3)
44. Reaction of BeO with ammonia and hydrogen
fluoride gives 'A' which on thermal decomposition
gives BeF2 and NH4F. What is 'A' ?
(1) (NH4)2BeF4 (2) H3NBeF3
(3) (NH4)BeF3 (4) (NH4)Be2F5
Allen Ans. (1)
45. 'A' and 'B' formed in the following set of reactions
are :
(2)
(3)
(1)
(4)
Allen Ans. (4)
(2)
3
47. Decreasing order of the hydrogen bonding in SECTION-B
following forms of water is correctly represented
51. The dissociation constant of acetic is x × 10–5.
by
When 25 mL of 0.2 M CH3COONa solution is
A. Liquid water
mixed with 25 mL of 0.02 M CH3COOH solution,
B. Ice
the pH of the resultant solution is found to be equal
C. Impure water
(1) A = B > C (2) B > A > C to 5. The value of x is _______.
(3) C > B > A (4) A > B > C Official Ans. by NTA (10)
Allen Ans. (2)
52. 5 g of NaOH was dissolved in deionized water to
48. Given below are two statements :
prepare a 450 mL stock solution. What volume (in
Statement I : Noradrenaline is a neurotransmitter.
Statement II : Low level of noradrenaline is not mL) of this solution would be required to prepare
500 mL of 0.1 M solution ?
®
the cause of depression in human.
In the light of the above statements, choose the Given : Molar Mass of Na, O and H is 23, 16 and 1
correct answer from the options given below g mol–1 respectively
(1) Statement I is correct but Statement II is
incorrect
(2) Statement I is incorrect but Statement II is Allen Ans. (180)
correct 53. If wavelength of the first line of the Paschen series
(3) Both Statement I and Statement II are correct of hydrogen atom is 720 nm, then the wavelength
(4) Both Statement I and Statement II are incorrect of the second line of this series is _______ nm.
(Nearest integer)
Allen Ans. (1)
49. In the depression of freezing point experiment Official Ans. by NTA (492)
A. Vapour pressure of the solution is less than that Allen Ans. (492)
of pure solvent 54. The number of correct statement/s from the
B. Vapour pressure of the solution is more than
following is _______.
that of pure solvent
C. Only solute molecules solidify at the freezing A. Larger the activation energy, smaller is the
point value of the rate constant.
D. Only solvent molecules solidify at the freezing B. The higher is the activation energy, higher is the
point value of the temperature coefficient.
(1) A and D only (2) B and C only
C. At lower temperatures, increase in temperature
(3) A and C only (4) A only
causes more change in the value of k than at higher
Allen Ans. (1) temperature.
50. Which of the following is true about freons ? 1
D. A plot of ln k vs is a straight line with slope
(1) These are chlorofluorocarbon compounds T
(2) These are chemicals causing skin cancer Ea
equal to 
(3) These are radicals of chlorine and chlorine R
monoxide
(4) All radicals are called freons
Allen Ans. (1)
4
55. At 298 K, a 1 litre solution containing 10 mmol of 58. For independent process at 300 K.
Cr2O72– and 100 mmol of Cr3+ shows a pH of 3.0.
Given : Cr2O72–  Cr3+; E0 = 1.330 V and
2.303 RT
= 0.059 V
F The number of non-spontaneous process from the
The potential for the half cell reaction is x × 10–3 following is _______.
V. The value of x is _______. Official Ans. by NTA (2)
Allen Ans. (917) 59. Uracil is base present in RNA with the following
56. When Fe0.93O is heated in presence of oxygen, it structure. % of N in uracil is _______.
®
converts to Fe2O3. The number of correct
statement/s from the following is _______.
A. The equivalent weight of Fe0.93O is

Molecular weight
.
0.79
B. The number of moles of Fe2+ and Fe3+ in 1 mole Given :
of Fe0.93O is 0.79 and 0.14 respectively. Molar mass N = 14 g mol–1; O = 16 g mol–1;
C. Fe0.93O is metal deficient with lattice comprising C = 12 g mol–1; H = 1 g mol–1;
of cubic closed packed arrangement of O2– ions. Official Ans. by NTA (25)
D. The % composition of Fe2+ and Fe3+ in Fe0.93O Allen Ans. (25)

is 85% and 15% respectively. 60. Number of moles of AgCl formed in the following
Official Ans. by NTA (4) reaction is _______.
Allen Ans. (4)
57. The d-electronic configuration of [CoCl4]2– in

tetrahedral crystal field is emt2n. Sum of 'm' and
'number of unpaired electrons is _______. Official Ans. by NTA (2)
Allen Ans. (7)
5
(Held On Wednesday 25th January, 2023) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A 33. Which of the following represents the correct order
31. Match List I with List II of metallic character of the given elements ?
(1) Si < Be < Mg < K
List I List II (2) Be < Si < Mg < K
A. Cobalt catalyst I, (H2 + Cl2) (3) K < Mg < Be < Si
production (4) Be < Si < K < Mg
B. Syngas II. Water gas Official Ans. by NTA (1)
production Allen Ans. (1)
®
C. Nickel catalyst III. Coal 34. Given below are two statements, one is labelled as
gasification Assertion A and the other is labelled as Reason R
D. Brine solution IV. Methanol Assertion A :- The alkali metals and their salts
production impart characteristic colour to reducing flame.
Choose the correct answer from the options given Reason :- Alkali metals can be detected using
below :- flame tests.
(1) A-IV, B-I, C-II, D-III In the light of the above statements, choose the
(2) A-IV, B-III, C-I, D-II most appropriate answer form the options given
(3) A-II, B-III, C-IV, D-I below
(4) A-IV, B-III, C-II, D-I (1) Both A and R are correct but R is NOT the
Official Ans. by NTA (4) correct explanation of A.
Allen Ans. (4) (2) A is correct but R is not correct.
32. Given below are two statements :- (3) A is not correct but R is correct
Statement I :- In froth floatation method a rotating (4) Both A and R are correct and R is the correct
paddle agitates the mixture to drive air out of it. explanation of A.
Reason :- Iron pyrites are generally avoided for Official Ans. by NTA (3)
extraction of iron due to environmental reasons. Allen Ans. (3)
In the light of the above statements, choose the 35. What is the mass ratio of ethylene glycol (C2H6O2,
correct answer from the options given below :- molar mass = 62 g/mol) required for making 500 g
(1) Both Statement I and Statement II are true of 0.25 molal aqueous solution and 250 mL of 0.25
(2) Statement I is false but Statement II is true molar aqueous solution ?
(3) Statement I is true but Statement II is false (1) 1 : 1 (2) 3 : 1
(4) Both Statement I and Statement II are false (3) 2 : 1 (4) 1 : 2
1
36. Statement I :- Dipole moment is a vector quantity 38. A. Ammonium salts produce haze in atmosphere.
and by convention it is depicted by a small arrow B. Ozone gets produced when atmosphere oxygen
with tail on the negative centre and head pointing reacts with chlorine radicals.
towards the positive centre. C. Polychlorinated biphenyls act as cleansing
Statement II :- The crossed arrow of the dipole solvents.

D. ‘Blue baby’ syndrome occurs due to the
moment symbolizes the direction of the shift of
presence of excess of sulphate ions in water.
charges in the molecules.
below :-
(1) A, B and C only
below :-
(2) B and C only
(1) Both Statement I and Statement II are correct.
(3) A and D only
(2) Statement I is incorrect but Statement II is
®
(4) A and C only
correct.
(3) Both Statement I and Statement II are
Allen Ans. (4)
incorrect.
(4) Statement I is correct but Statement II is
List I (Amines) List II
incorrect.
(pKb)
A. Aniline I. 3.25
Allen Ans. (2)
B. Ethanamine II. 3.00
37. Given below two statements, one is labelled as
C. N-Ethylethanamine III. 9.38
Assertion A and the other is labelled as Reason R
D. N, N-Diethylethanamine IV. 3.29
Assertion A :- Butylated hydroxyl anisole when
added to butter increases its shelf life.
below :-
Reason :- Butylated hydroxyl anisole is more
(1) A-I, B-IV, C-II, D-III
reactive towards oxygen than food.
(2) A-III, B-II, C-I, D-IV
(3) A-III, B-II, C-IV, D-I
(4) A-III, B-IV, C-II, D-I
below :-
(1) Both A and R are correct and R is the correct
Allen Ans. (4)
explanation of A.
40. Which one among the following metals is the
(2) A is correct but R is not correct.
(3) A is not correct but R is correct. weakest reducing agent ?
(4) Both A and R are correct but R is NOT the (1) K (2) Rb
correct explanation of A. (3) Na (4) Li
2
41. Match List I with List II. 43. Given below are two statements, one is labelled as
List I List II Assertion A and the other is labelled as Reason R
Isomeric pairs Type of Assertion A :- Carbon forms two important oxides
isomers – CO and CO2. CO is neutral whereas CO2 is
A. Propanamine and N- I. Metamers acidic in nature.
Methylethanamine Reason :- CO2 can combine with water in a form
B. Hexan-2-one and II. Positional carbonic acid, while CO is sparingly soluble in
Hexan-3-one isomers water.
C. Ethanamide and III. Functional In the light of the above statements, choose the
Hydroxyethanimine isomers most appropriate answer from the options given
D. o-nitrophenol and p- IV. Tautomers below :-
(1) Both A and R are correct but R is NOT the
®
nitrophenol
Choose the correct answer from the options given correct explanation of A.
below :- (2) Both A and R are correct and R is the correct
(1) A-III, B-IV, C-I, D-II explanation of A.
(2) A-IV, B-III, C-I, D-II (3) A is not correct but R is correct.
(3) A-II, B-III, C-I, D-IV
(4) A is correct but R is not correct.
(4) A-III, B-I, C-IV, D-II
42. Match List I with List II 44. Potassium dichromate acts as a strong oxidizing
List I (Name of List II (Uses) agent in acidic solution. During this process, the
polymer) oxidation states changes from
A. Glyptal I. Flexible pipes (1) + 3 to + 1 (2) + 6 to + 3

(3) + 2 to + 1 (4) + 6 to + 2
B. Neoprene II. Synthetic wool Official Ans. by NTA (2)
Allen Ans. (2)
C. Acrilan III. Paints and Lacquers 45. When the hydrogen ion concentration [H+] changes
by a factor of 1000, the value of pH of the solution
D. LDP IV. Gaskets
_______.
Choose the correct answer from the options given (1) increases by 1000 units
below :- (2) decreases by 3 units
(1) A-III, B-II, C-IV, D-I (3) decreases by 2 units
(2) A-III, B-IV, C-II, D-I (4) increases by 2 units
(3) A-III, B-IV, C-I, D-II Official Ans. by NTA (2)
(4) A-III, B-I, C-IV, D-II Allen Ans. (2)

Allen Ans. (2)
3
46. Match List I with List II 48. ‘A’ in the given reaction is
List I List II
Coordination entity Wavelength of
light absorbed
in nm
2+
A. [CoCl(NH3)5] I. 310
3+
(1) (2)
B. [Co(NH3)6] II. 475
C. [Co(CN)6]3– III. 535
D. [Cu(H2O)4]2+ IV. 600
Choose the correct answer from the options given (3) (4)
below :-
®
(1) A-IV, B-I, C-III, D-II Official Ans. by NTA (2)
(2) A-III, B-II, C-I, D-IV Allen Ans. (2)
(3) A-III, B-I, C-II, D-IV 49. The isomeric deuterated bromide with molecular
(4) A- II, B-III, C-IV, D-I formula C4H8DBr having two chiral carbon atoms
Official Ans. by NTA (2) is
Allen Ans. (2) (1) 2–Bromo–1–deuterobutane
47. Find out the major product from the following (2) 2–Bromo–2–deuterobutane
reaction. (3) 2–Bromo–3–deuterobutane
(4) 2–Bromo–1–deutero–2–methylpropane
Allen Ans. (3)
50. A chloride salt solution acidified with dil. HNO3
(1) (2) gives a curdy white precipitate, [A], on addition of

AgNO3. [A] on treatment with NH4OH gives a
clear solution, B.
(1) H[AgCl3] & [Ag(NH3)2]Cl
(3) (4) (2) H[AgCl3] & (NH4)[Ag(OH)2]
(3) AgCl & [Ag(NH3)2]Cl
Official Ans. by NTA (1) (4) AgCl & (NH4)[Ag(OH)2]
Allen Ans. (A, D) Official Ans. by NTA (3)
Allen Ans. (3)
4
SECTION-B 54. 28.0 L of CO2 is produced on complete
51. The number of given orbitals which have electron combustion of 16.8 L gaseous mixture of ethane
density along the axis is _______ and methane at 25ºC and 1 atm. Heat evolved
p x ,p y ,pz ,d xy ,d yz ,d xz ,d 2 ,d during the combustion process is ________ kJ.

z x2 y2
Given : HC (CH4) = –900 kJ mol–1
Official Ans. by NTA (5.00)
HC (C2H4) = –1400 kJ mol–1
Allen Ans. (5.00)
52. Number of compounds giving (i) red colouration
Allen Ans. (847.00)
with ceric ammonium nitrate and also (ii) positive
iodoform test from the following is _______ 55. Total number of moles of AgCl precipitated on
addition of excess of AgNO3 to one mole each of
the following complexes [Co(NH3)4Cl2]Cl,
®
[Ni(H2O)6]Cl2 , [Pt(NH3)2Cl2] and [Pd(NH3)4]Cl2 is
Allen Ans. (5.00)
56. Number of hydrogen atoms per molecule of
hydrocarbon A having 85.8% carbon is _________
(Given : Molar mass of A = 84 g mol–1)
Official Ans. by NTA (3.00) Allen Ans. (12.00)
Allen Ans. (3.00) 57. Pt  s  H2  g 1bar  H   aq 1M  M3  aq  ,M  aq  Pt s 
53. The number of pairs of the solution having the
The Ecell for the given cell is 0.1115 V at 298 K
same value of the osmotic pressure from the
 M  aq 
following is ________. when    10a

 M  aq 
3
(Assume 100% ionization)  
A. 0.500 M C2H5OH (aq) and 0.25 M KBr (aq) The value of a is ________
B. 0.100 M K4[Fe(CN)6] (aq) and 0.25 M NaCl Given : E M3 /M  0.2 V
(aq)
2.303 RT
C. 0.05 M K4[Fe(CN)6] (aq) and 0.25 M NaCl  0.059 V
F
(aq)
D. 0.15 M NaCl (aq) and 0.1 M BaCl2 (aq)
E. 0.02 M KCl. MgCl2. 6H2O (aq) and 0.05 M Allen Ans. (3.00)
KCl (aq)
Allen Ans. (4.00)
5
58. Based on the given figure, the number of correct 60. The number of incorrect statement/s from the
statement/s is/are _______ following is/are _______
A. Water vapours are abosorbed by anhydrous
calcium chloride.
B. There is a decrease in surface energy during
absorption.
C. As the absorption proceeds, H becomes more

and more negative.
D. Adsorption is accompanied by decrease in
entropy of the system.
®
A. Surface tension is the outcome of equal
Allen Ans. (2.00)
attractive and repulsion forces acting on the
liquid molecule in bulk.
B. Surface tension is due to uneven forces acting
on the molecules present on the surface.
C. The molecule in the bulk can never come to
the liquid surface.
D. The molecules on the surface are responsible
for vapour pressure if the system is a closed
system.
Allen Ans. (2.00)
59. A first order reaction has the rate constant, k = 4.6
× 10–3 s–1. The number of correct statement/s from
the following is/are ________.
Given : log 3 = 0.48
A. Reaction completes in 1000 s.
B. The reaction has a half-life of 500 s.
C. The time required for 10% completion is 25
times the time required for 90% completion.
D. The degree of dissociation is equal to (1 – e–kt).
E. The rate and the rate constant have the same
unit.
Allen Ans. (1.00)
6
(Held On Wednesday 25th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A
31. The compound which will have the lowest rate 33. Identify the product formed (A and E)
towards nucleophilic aromatic substitution on Me
treatment with OH– is Br2

A Sn/HCl B NaNO /HCl
2
C H PO /H O D (i) KMnO /KOH E
3 2 2 4
273-278K (ii) H O 3
+
Cl Cl
NO2 NO 2
(1) (2) Me COOH
Br Br
NO2 NO2 ,E =
(1) A =
Cl Br Br
Cl
®
NO 2
(3) NO2 (4)
Me COOH
NO2
Br Br
Official Ans. by NTA (4) (2) A = ,E =
Allen Ans. (4)
NO 2
32. The variation of the rate of an enzyme catalyzed
Me Me
reaction with substrate concentration is correctly Br Br
represented by graph (3) A = ,E =
Rate of reaction
NO 2
Me COOH
(a) Br Br
(4) A = ,E =
O Substrate concentration
NO 2 OH
Rate of reaction

(b) Allen Ans. (2)
O Substrate concentration List I List II
Rate of reaction
Colour imparted to
Elements
the flame
(c) A K I Brick Red
B Ca II Violet
O Substrate concentration C Sr III Apple Green
D Ba IV Crimson Red
Rate of reaction

(d) below:
(1) A-II, B-I, C-III. D-IV
O Substrate concentration (2) A-II, B-IV, C-I. D-III
(3) A-II, B-I, C-IV. D-III
(1) b (2) c (3) d (4) a (4) A-IV, B-III, C-II. D-I
1
35. Reaction of thionyl chloride with white phosphorus Me
H
forms a compound [A], which on hydrolysis gives
(4)
[B], a dibasic acid. [A] and [B] are respectively
(1) P4O6 and H3PO3 H Me
H H
(2) PCl3 and H3PO3
(3) PCl5 and H3PO4
(4) POCl3 and H3PO4 Allen Ans. (1)
Official Ans. by NTA (2) 39. Match items of Row I with those of Row II.
Allen Ans. (2) Row I :
36. A cubic solid is made up of two elements X and Y.
CH2OH
Atoms of X are present on every alternate corner O
H H
1
rd (P) H
and one at the center of cube. Y is at of the total OH H
OH
3 OH
®
faces. The empirical formula of the compound is H OH
(1) X2Y1.5 (2) X2.5Y CH2OH
O
(3) XY2.5 (4) X1.5Y2 H OH
(Q) H
Official Ans. by NTA (2) OH H
H
Allen Ans. (Bonus) OH
H OH
37. The radius of the 2nd orbit of Li2+ is x. The
HOCH2 O CH2OH
expected radius of the 3rd orbit of Be3+ is (R)
H H OH OH
9 4
(1) x (2) x
4 9 OH H
27 16 HOCH2 O OH
(3) x (4) x (S)
16 27
H H HO CH2OH
OH H
Allen Ans. (3)
Row II :
38. Which of the following conformations will be the
most stable ? (i) -D-(–) Fructofuranose.
Me (ii) -D-(–) Fructofuranose
H H (iii) -D-(-) Glucopyranose.
(1) (iv) -D-(-) Glucopyranose

H H
Correct match is
Me
(1) Piv, Qiii, Ri, Sii
Me
Me (2) Pi, Qii, Riii, Siv
(2)
(3) Piii, Qiv, Rii, Si
H H
H H (4) Piii, Qiv, Ri, Sii
Me
H Me
Allen Ans. (4)
(3)
H H
2
40. Given below are two statements : one is labelled as ?
PhCOOH + PhCH 2OH
Assertion A and the other is labelled as 43. P Q R
The correct sequence of reagents for the

Reason
preparation of Q and R is :
R:
(1) (i) Cr2O3, 770 K, 20 atm ;
Assertion A : Acetal/Ketal is stable in basic (ii) CrO2Cl2, H3O+ ;
medium. (iii) NaOH ;
(iv) H3O+
Reason R : The high leaving tendency of alkoxide
(2) (i) CrO2Cl2, H3O+ ; (ii) Cr2O3, 770 K, 20 atm;
ion gives the stability to acetal/ketal in basic
(iii) NaOH ; (iv) H3O+
medium. (3) (i) KMnO4, OH– ; (ii) Mo2O3, A; (iii) NaOH ;
In the light of the above statements, choose the (iv) H3O+
correct answer from the options given below: (4) (i) Mo2O3,  ; (ii) CrO2Cl2, H3O+ ; (iii) NaOH ;
®
(iv) H3O+
(2) A is false but R is true
Allen Ans. (1)
(3) Both A and R are true and R is the correct 44. The correct order in aqueous medium of basic
explanation of A strength in case of methyl substituted amines is :
(1) Me2NH > MeNH2 > Me3N > NH3
(4) Both A and R are true but R is NOT the correct
(2) Me2NH > Me3N > MeNH2 > NH3
explanation of A
(3) NH3 > Me3N > MeNH2 > Me2NH
Official Ans. by NTA (1) (4) Me3N > Me2NH > MeNH2 > NH3
41. Inert gases have positive electron gain enthalpy. Its Allen Ans. (1)
45. '25 volume' hydrogen peroxide means
correct order is
(1) 1 L marketed solution contains 250 g of H2O2.
(1) Xe < Kr < Ne < He (2) 1 L marketed solution contains 75 g of H2O2.
(2) He < Ne < Kr < Xe (3) 100 mL marketed solution contains 25 g of
(3) He < Xe < Kr < Ne H2O2.
(4) 1 L marketed solution contains 25 g of H2O2.
(4) He < Kr < Xe < Ne
Allen Ans. (3) 46. Which of the following statements is incorrect for
42. Which one of the following reactions does not antibiotics?
(1) An antibiotic must be a product of metabolism.
occur during extraction of copper ?
(2) An antibiotic is a synthetic substance produced
(1) 2Cu2S + 3O2  2Cu2O + 2SO2
as a structural analogue of naturally occurring
(2) 2FeS + 3O2  2FeO + 2SO2 antibiotic.
(3) CaO + SiO2  CaSiO3 (3) An antibiotic should promote the growth or
survival of microorganisms.
(4) FeO + SiO2  FeSiO3
(4) An antibiotic should be effective in low
Official Ans. by NTA (3) concentrations.
Allen Ans. (3)
3
47. Compound A reacts with NH4Cl and forms a 50. In the cumene to phenol preparation in presence of
compound B. Compound B reacts with H2O and air, the intermediate is
O
excess of CO2 to form compound C which on
passing through or reaction with saturated NaCl O CH3 O
solution forms sodium hydrogen carbonate. (1) (2)

Compound A. B and C, are respectively.
O–O–H
(1) CaCl2, NH3, NH4HCO3
(2) CaCl2, NH4+, (NH4)2CO3 (3) (4)
(3) Ca(OH)2, NH3, NH4HCO3 Official Ans. by NTA (4)

+
(4) Ca(OH)2, NH4 , (NH4)2CO3 Allen Ans. (4)
Official Ans. by NTA (3) SECTION-B
Allen Ans. (3) 51. An athlete is given 100 g of glucose (C6H12O6) for
®
48. Some reactions of NO2 relevant to photochemical energy. This is equivalent to 1800 kJ of energy.
smog formation are The 50% of this energy gained is utilized by the
Sunlight athlete for sports activities at the event. In order to
NO 2 X +Y
A avoid storage of energy, the weight of extra water
B he would need to perspire is_______g (Nearest
Identify A, B, X and Y integer)
(1) X = [O], Y = NO, A = O2, B = O3 Assume that there is no other way of consuming
stored energy.
(2) X = N2O, Y = [O], A = O3, B = NO
Given : The enthalpy of evaporation of water is 45
1
(3) X = O2, Y = NO2, A = O3, B = O2 kJ mol–1
2
(4) X = NO, Y = [O], A = O2, B = N2O3 Molar mass of C, H & O are 12. 1 and 16 g mol–1.

49. Match the List-I with List-II : 52. A litre of buffer solution contains 0.1 mole of each
Cations Group reaction of NH3 and NH4Cl. On the addition of 0.02 mole
P  Pb , Cu
2+ 2+
(i) H2S gas in presence of dilute HCl of HCl by dissolving gaseous HCl, the pH of the
Q  Al3+, Fe3+ (ii) (NH4)2CO3 in presence of NH4OH solution is found to be _________× 10–3 (Nearest
R  Co2+, Ni2+ (iii) NH4OH in presence of NH4CI integer)
S  Ba2+, Ca2+ (iv) H2S in presence of NH4OH [Given : pKb(NH3) = 4.745

log 2 = 0.301
(1) Pi, Qiii, Rii, Siv log 3 = 0.477
(2) Piv, Qii, Riii, Si
T = 298 K]
(3) Piii, Qi, Riv, Sii
(4) Pi, Qiii, Riv, Sii
Allen Ans. (9079)
Allen Ans. (4)
4
53. The osmotic pressure of solutions of PVC in 57. The total number of lone pairs of electrons on
cyclohexanone at 300 K are plotted on the graph. oxygen atoms of ozone is_____
The molar mass of PVC is___________g mol–1 Official Ans. by NTA (6)
(Nearest integer)
Allen Ans. (6)

58. In sulphur estimation. 0.471 g of an organic
C compound gave 1.4439 g of barium sulphate.
(Atm/g L–1 )
The percentage of sulphur in the compound
is_____________(Nearest Integer)
C(g L– 1)
(Given: Atomic mass Ba: 137 u: S: 32 u, O: 16 u )
(Given : R = 0.083 L atm K–1 mol–1)
®
Allen Ans. (Bonus/41500) Allen Ans. (42)
54. How many of the following metal ions have 59. The number of paramagnetic species from the
similar value of spin only magnetic moment in following is_____.
gaseous state ?___________
[Ni(CN)4]2–, [Ni(CO)4], [NiCl4]2–
(Given: Atomic number : V, 23 ; Cr, 24 ; Fe, 26 ;
[Fe(CN)6]4–, [Cu(NH3)4]2+
Ni, 28)
3+ 3+ 2+ 3+ [Fe(CN)6]3– and [Fe(H2O)6]2+
V . Cr , Fe , Ni
55. The density of a monobasic strong acid (Molar 60. Consider the cell
mass 24.2 g mol) is 1.21 kg L. The volume of its
Pt(s) H2 (s)(1atm) H (aq,[H ]  1) Fe3 (aq),Fe2 (aq) Pt(s)
solution required for the complete neutralization
of 25 mL of 0.24 M NaOH is_____________×
10–2 mL (Nearest integer) Given : EFe3 /Fe2  0.771V and E  1  0V,T  298K
H / H2
2
Official Ans. by NTA (12) If the potential of the cell is 0.712 V the ratio of
Allen Ans. (12) concentration of Fe2+ to Fe2+ is________(Nearest
56. For the first order reaction A  B Br the half life integer)
is 30 mm. The time taken for 75% completion of Official Ans. by NTA (10)
the reaction is_____mm. (Nearest mteger)
Allen Ans. (10)
Given : log 2 = 0.3010
log 3 = 0.4771
log 5 = 0.6989
Allen Ans. (60)
5
(Held On Sunday 29th January, 2023) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A 33. Match List-I and List-II.
31. Given below are two statements: List-I List-II
A. Osmosis I. Solvent molecules pass
Statement I : The decrease in first ionization through semi permeable
enthalpy from B to Al is much larger than that membrane towards solvent
side.
from Al to Ga. B. Reverse osmosis II. Movement of charged
Statement II : The d orbitals in Ga are completely colloidal particles under the
influence of applied electric
®
filled. potential towards oppositely
In the light of the above statements, choose the charged electrodes.
C. Electro osmosis III. Solvent molecules pass
through semi permeable
below membrane towards solution
side.
(1) Statement I is incorrect but statement II is
D. Electrophoresis IV. Dispersion medium
correct. moves in an electric field.
(2) Both the statements I and II are correct
below:
(3) Statement I is correct but statement II is (1) A-I, B-III, C-IV, D-II
incorrect (2) A-III, B-I, C-IV, D-II
(3) A-III, B-I, C-II, D-IV
(4) Both the statements I and II are incorrect (4) A-I, B-III, C-II, D-IV
Allen Ans. (2)
Allen Ans. (1)
34. The set of correct statements is:
32. Correct order of spin only magnetic moment of the (i) Manganese exhibits +7 oxidation state in its
oxide.
following complex ions is:
(ii) Ruthenium and Osmium exhibit +8 oxidation
(Given At. No. Fe: 26, Co:27) in their oxides.
(iii) Sc shows +4 oxidation state which is
(1) [FeF6 ]3  [CoF6 ]3  [Co(C 2O 4 ) 3 ]3
oxidizing in nature.
(2) [Co(C 2O4 ) 3 ]3  [CoF6 ]3  [FeF6 ]3 (iv) Cr shows oxidising nature in +6 oxidation
state.
(3) [FeF6 ]3  [Co(C 2O 4 ) 3 ]3  [CoF6 ]3 (1) (ii) and (iii)
(2) (i), (ii) and (iv)
(4) [CoF6 ]3  [FeF6 ]3  [Co(C 2O 4 ) 3 ]3 (3) (i) and (iii)
(4) (ii), (iii) and (iv)
1
35. Match List-I and List-II. 38. Find out the major product for the following
List-I List-II reaction.
A. Elastomeric I. Urea formaldehyde
polymer resin
Major Product
B. Fibre polymer II. Polystyrene
C. Thermosetting III. Polyester
polymer
(1)
D. Thermoplastic IV. Neoprene
polymer
(2)
below:
(1) A-II, B-III, C-I, D-IV
®
(2) A-II, B-I, C-IV, D-III (3)
(3) A-IV, B-III, C-I, D-II
(4) A-IV, B-I, C-III, D-II
(4)
Allen Ans. (3)
36. An indicator ‘X’ is used for studying the effect of
Allen Ans. (2)
variation in concentration of iodide on the rate of
39. The one giving maximum number of isomeric alkenes on
reaction of iodide ion with H2O2 at room temp. The
indicator ‘X’ forms blue colored complex with dehydrohalogenation reaction is (excluding rearrangement)
compound ‘A’ present in the solution. The (1) 1-Bromo-2-methylbutane

indicator ‘X’ and compound ‘A’ respectively are (2) 2-Bromopropane
(1) Starch and iodine
(3) 2-Bromopentane
(2) Methyl orange and H2O2
(4) 2-Bromo-3,3-dimethylpentane
(3) Starch and H2O2
(4) Methyl orange and iodine Official Ans. by NTA (3)

Allen Ans. (1) 40. When a hydrocarbon A undergoes combustion in
37. A doctor prescribed the drug Equanil to a patient.
the presence of air, it requires 9.5 equivalents of
The patient was likely to have symptoms of which
oxygen and produces 3 equivalents of water. What
disease?
(1) Stomach ulcers is the molecular formula of A?
(2) Hyperacidity (1) C8H6 (2) C9H9
(3) Anxiety and stress
(3) C6H6 (4) C9H6
(4) Depression and hypertension
Official Ans. by NTA (4 )
2
41. Find out the major products from the following 42. According to MO theory the bond orders for O22–,
reaction sequence. CO and NO+ respectively, are
(1) 1, 3 and 3
(2) 1, 3 and 2
(3) 1, 2 and 3
(4) 2, 3 and 3
Allen Ans. (1)
43. A solution of CrO5 in amyl alcohol has a….colour
(1) Green
(1)
(2) Orange–Red
®
(3) Yellow
(4) Blue
Allen Ans. (4)
44. The concentration of dissolved Oxygen in water
for growth of fish should be more than X ppm and
(2) Biochemical Oxygen Demand in clean water
should be less than Y ppm. X and Y in ppm are,
respectively.
X Y
(1)
6 5
X Y
(2)
4 8
(3) X Y
(3)
4 15
X Y
(4)
6 12
Allen Ans. (1)
45. Reaction of propanamide with Br2 / KOH (aq)
(4)
produces :
(1) Ethylnitrile
(2) Propylamine
(3) Propanenitrile
(4) Ethylamine
Allen Ans. (4)
Allen Ans. (2)
3
46. Following tetrapeptide can be represented as 49. Given below are two statements:
Statement I : Nickel is being used as the catalyst
for producing syn gas and edible fats.
Statement II : Silicon forms both electron rich and
electron deficient hydrides.
below:
(1) Both the statements I and II are correct
(2) Statement I is incorrect but statement II is
(F, L, D, Y, I, Q, P are one letter codes for amino
correct
acids)
(3) Both the statements I and II are incorrect
(1) FIQY
®
(4) Statement I is correct but statement II is
(2) FLDY
incorrect
(3) YQLF
(4) PLDY
Allen Ans. (4)
Official Ans. by NTA (2) 50. Match List I with List II.
Allen Ans. (2) List I List II
47. Which of the following relations are correct? A. van’t Hoff I. Cryoscopic constant
(A) U  q  pV factor, i
(B) G  H  TS B. kf II. Isotonic solutions
q rev C. Solutions with III. Normal molar mass
(C) S  Abnormal molar mass
T same osmotic
(D) H  U  nRT pressure
Choose the most appropriate answer from the D. Azeotropes IV. Solutions with same
options given below : composition of vapour

above it
(1) C and D only
(2) B and C only
below :
(3) A and B only
(A) A-III, B-I, C-II, D-IV
(4) B and D only
(B) A-III, B-II, C-I, D-IV
(C) A-III, B-I, C-IV, D-II
Allen Ans. (2)
(D) A-I, B-III, C-II, D-IV
48. The major component of which of the following
ore is sulphide based mineral? Allen Ans. (1)
(1) Calamine SECTION-B
(2) Siderite 51. On heating, LiNO3 gives how many compounds
(3) Sphalerite among the following?
(4) Malachite Li2O, N2, O2, LiNO2, NO2
4
52. At 298 K 57. A metal M forms hexagonal close-packed structure.
N2 (g)  3H 2 (g) 2NH3 (g), K1  4  10 5 The total number of voids in 0.02 mol of it is
N2 (g)  O2 (g) 2NO (g), K 2  1.6  1012 __________ × 1021 (Nearest integer)
(Given NA = 6.02 × 1023)
1 13
H 2 (g)  O2 (g) H 2 O (g), K 3  1.0  10
2 Official Ans. by NTA (36)
Based on above equilibria, the equilibrium constant
Allen Ans. (36)
of the reaction,
58. Assume that the radius of the first Bohr orbit of
5
2NH3 (g)  O2 (g) 2NO (g)  3H 2 O (g) hydrogen atom is 0.6 Å. The radius of the third
2
Bohr orbit of He+ is ________ picometer. (Nearest
is ___  10 33 (Nearest integer)
Integer)
®
Allen Ans. (4)
53. For conversion of compound A  B, the rate Allen Ans. (270)
constant of the reaction was found to be 4.6 × 10–5 59. The equilibrium constant for the reaction
L mol–1 s–1. The order of the reaction is ______ . Zn(s)  Sn 2 (aq) Zn 2 (aq)  Sn(s) is 1 × 1020
Official Ans. by NTA (2) at 298 K. The magnitude of standard electrode

Allen Ans. (2) potential of Sn/Sn2+ if EoZn2 / Zn = –0.76 V is
54. Total number of acidic oxides among
_______ × 10–2 V.
N2O3, NO2, N2O, Cl2O7, SO2, CO, CaO, Na2O and
(Nearest integer)
NO is _________ .
2.303RT
Official Ans. by NTA (4 ) Given :  0.059V
F
Allen Ans. (4)
55. When 0.01 mol of an organic compound containing
Allen Ans. (17)
60% carbon was burnt completely, 4.4 g of CO2
60. The volume of HCl, containing 73 g L–1, required
was produced. The molar mass of compound is
__________ g mol–1 (Nearest integer) to completely neutralise NaOH obtained by
reacting 0.69 g of metallic sodium with water, is
_______ mL. (Nearest Integer)
Allen Ans. (200)
56. The denticity of the ligand present in the Fehling’s (Given : molar Masses of Na, Cl, O, H are 23,
reagent is _______ . 35.5, 16 and 1 g mol–1 respectively)
5
(Held On Sunday 29th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A 35. The reaction representing the Mond process for
31. For 1 mol of gas, the plot of pV vs p is shown below. metal refining is ______.
p is the pressure and V is the volume of the gas. 
(1) Ni + 4CO  Ni(CO)4

(2) 2K [Au(CN)2] + Zn  K2 [Zn(CN)4] + 2 Au

(3) Zr + 2I2  Zr I4

(4) ZnO + C  Zn + CO
What is the value of compressibility factor at Official Ans. by NTA (1)
®
point A? Allen Ans. (1)
a b 36. Which of the given compounds can enhance the
(1) 1  (2) 1 
RTV V efficiency of hydrogen storage tank?
b a (1) Li/P4
(3) 1  (4) 1 
V RTV (2) SiH4
Official Ans. by NTA (1) (3) NaNi5
Allen Ans. (1) (4) Di-isobutylaluminium hydride
32. The shortest wavelength of hydrogen atom in Official Ans. by NTA (3)
Lyman series is . The longest wavelength in Allen Ans. (3)
Balmer series of He+ is 37. The correct order of hydration enthalpies is
5 9 (A) K+
(1) (2)
9 5 (B) Rb+
36 5 (C) Mg2+
(3) (4)
5 9 (D) Cs+
Official Ans. by NTA (2) (E) Ca2+
Allen Ans. (2) Choose the correct answer from the options given
33. Which of the following salt solutions would below:
coagulate the colloid soloution formed when FeCl3 (1) C > A > E > B > D
is added to NaOH solution, at the fastest rate? (2) E > C > A > B > D
(1) 10 mL of 0.2 mol dm-3 AlCl3 (3) C > E > A > D > B
(2) 10 mL of 0.1 mol dm-3 Na2SO4 (4) C > E > A > B > D
(3) 10 mL of 0.1 mol dm-3 Ca3(PO4)2 Official Ans. by NTA (4)
(4) 10 mL of 0.15 mol dm-3 CaCl2 Allen Ans. (4)
Official Ans. by NTA (1) 38. The magnetic behaviour of Li2O, Na2O2 and KO2,
Allen Ans. (1) respectively, are
34. The bond dissociation energy is highest for (1) diamagnetic, paramagnetic and diamagnetic
(1) Cl2 (2) I2 (2) paramagnetic, paramagnetic and diamagnetic
(3) Br2 (4) F2 (3) paramagnetic, diamagnetic and paramagnetic
(4) diamagnetic, diamagnetic and paramagnetic
Allen Ans. (1)
Allen Ans. (4)
1
39. “A” obtained by Ostwald‟s method involving air 43. Identify the correct order for the given property for
oxidation of NH3, upon further air oxidation following compounds
(A) Boiling Point: Cl < Cl < Cl
produces “B”. “B” on hydration forms an oxoacid
(B) Density: Br < Cl < I
of Nitrogen along with evolution of “A”. The
Br Br
oxoacid also produces “A” and gives positive Br
(C) Boiling Point: Br < Br < Br
brown ring test Br < Cl
(D) Density: I<
(1) NO2, N2O5 (2) NO2, N2O4 Br
Br
(3) NO, NO2 (4) N2O3, NO2 (E)
Official Ans. by NTA (3) Choose the correct answer from the option given
Allen Ans. (3) below :-
40. The standard electrode potential (M3+/M2+) for V, (1) (B), (C) and (D) only
®
(2) (A), (C) and (E) only
Cr, Mn & Co are -0.26 V, - 0.41 V, + 1.57 V and
(3) (A), (C) and (D) only
+1.97 V, respectively. The metal ions which can
(4) (A), (B) and (E) only
liberate H2 from a dilute acid are Official Ans. by NTA (2)
2+ 2+ 2+ 2+
(1) V and Mn (2) Cr and CO Allen Ans. (2 & 4)
2+
(3) V and Cr 2+ 2+
(4) Mn and Co 2+ 44. The increasing order of pKa for the following
phenols is
(1) 2, 4-Dinitrophenol
Allen Ans. (3)
(2) 4 - Nitrophenol
41. Correct statement about smog is (3) 2, 4, 5- Trimethylphenol
(1) NO2 is present in classical smog (4) 3-Chlorophenol
(2) Both NO2 and SO2 are present in classical smog Official Ans. by NTA (2)
(3) Photochemical smog has high concentration of Allen Ans. (2)
oxidizing agents
List-I List-II
(4) Classical smog also has high concentration of
Reaction Reagents
oxidizing agents (A) Hoffmann (I) Conc.KOH, 
Official Ans. by NTA (3) Degradation
Allen Ans. (3) (B) Clemenson (II) CHCl3, NaOH/H3O+
42. Chiral complex from the following is : reduction
(C) Cannizaro reaction (III) Br2, NaOH
Here en = ethylene diamine
(D) Reimer-Tiemann (IV) Zn-Hg/HCl
(1) cis – [PtCl2 (en)2]2+
reaction
2+
(2) trans – [PtCl2(en)2] (1) (A) – III, (B) – IV, (C) – II, (D) - I
(3) cis – [PtCl2(NH3)2] (2) (A) – II, (B) – IV, (C) – I, (D) - III
(4) trans – [Co(NH3)4 Cl2] + (3) (A) – III, (B) – IV, (C) – I, (D) - II
Official Ans. by NTA (1) (4) (A) – II, (B) – I, (C) – III, (D) - IV
Allen Ans. (1)
Allen Ans. (3)
2
46. The major product „P‟ for the following sequence SECTION-B
of reactions is: 51. Millimoles of calcium hydroxyide required to
produce 100 mL of the aqueous solution of pH 12 is
x × 10–1. The value of x is _______ (Nearest integer).
Assume complete dissociation.
OH OH
(1) Ph OH (2) Ph NH2 Official Ans. by NTA (5)
Allen Ans. (5)
OH OH
(3) Ph NH2 (4) Ph NH2 52. The number of molecules or ions from the
Official Ans. by NTA (3) following, which do not have odd number of
Allen Ans. (3) electrons are ________ .
47. During the borax bead test with CuSO4, a blue (A) NO2
green colour of the bead was observed in oxidising –
(B) ICl 4
®
flame due to the formation of
(1) Cu3B2 (2) Cu (C) BrF3
(3) Cu(BO2)2 (4) CuO (D) ClO2

Allen Ans. (3) (E) NO 2
48. Match List I with List II (F) NO
List I List II
Antimicrobials Names
Allen Ans. (3)
(A) Narrow Spectrum (I) Furacin
Antibiotic 53. Consider the following reaction approaching
(B) Antiseptic (II) Sulphur dioxide equilibrium at 27ºC and 1 atm pressure
(C) Disinfectants (III) Penicillin-G Kr 103
AB CD
(D) Broad spectrum (IV) Chloramphenicol Kr 102
antibiotic
(1) (A) – III, (B) – I, (C) – II, (D) - IV
The standard Gibb‟s energy change  G 
r

at
(2) (A) – I, (B) – II, (C) – IV, (D) - III 27ºC is (–) _______ kJ mol–1
(3) (A) – II, (B) – I, (C) – IV, (D) - III (Nearest integer).
(4) (A) – III, (B) – I, (C) – IV, (D) - II (Given : R = 8.3 J K–1 mol–1 and ln 10=2.3)
Allen Ans. (1)
49. Number of cyclic tripeptides formed with 2 amino Allen Ans. (6)
acids A and B is: 54. Solid Lead nitrate is dissolved in 1 litre of water.
(1) 2 (2) 3 The solution was found to boil at 100.15ºC. When
(3) 5 (4) 4 0.2 mol of NaCl is added to the resulting solution, it
Official Ans. by NTA (4) was observed that the solution froze at –0.8º C. The
Allen Ans. (4) solutbility product of PbCl2 formed is ______ × 106
50. Compound that will give positive Lassaigne‟s test at 298 K. (Nearest integer)
for both nitrogen and halogen is
Given : Kb = 0.5 K kg mol–1 and Kf = 1.8 kg mol–1.
(1) N2H4.HCl (2) CH3NH2. HCl
Assume molality to be equal to molarity in all cases.
(3) NH4Cl (4) NH2OH.HCl
3
55. Water decomposes at 2300 K 58. The sum of bridging carbonyls in W(CO)6 and Mn2
1
H 2 O(g)  H 2  g   O 2 (g) (CO)10 is ________ .
2 Official Ans. by NTA (0)
The percent of water decomposing at 2300 K and
1 bar is ________ (Nearest integer). Allen Ans. (0)
Equilibrium constant for the reaction is 2×10–3 at 59. Following chromatogram was developed by
2300 K adsorption of compound „A‟ on a 6 cm TLC glass
Official Ans. by NTA (2) plate. Retardation factor of the compound „A‟ is
Allen Ans. (2)
______ × 10–1.
56. Following figure shows dependence of molar
conductance of two electrolytes on concentration.
0
 m is the limiting molar conductivity.
®
Allen Ans. (6)
The number of Incorrect statement(s) from the 60. 17 mg of a hydrocarbon (M.F. C10H16) takes up
following is ________ 8.40 mL of the H2 gas measured at 0ºC and 760
0
(A)  m for electrolyte A is obtained by mm of Hg. Ozonolysis of the same hydrocarbon
extrapolation yields
(B) For electrolyte B, vx m vs c graph is a CH3 – C – CH 3 –, H–C–H, H–C–CH 2 – CH 2 – C – C – H
0
straight line with intercept equal to  m O O O O O
(C) At infinite dilution, the value of degree of The number of double bond/s present in the
dissociation approach zero for electrolyte B.
0
hydrocarbon is ________ .
(D)  m for any electrolyte A or B can be Official Ans. by NTA (3)
calculated using  º for individual ions.
Allen Ans. (3)
Allen Ans. (2)
57. For certain chemical reaction X  Y, the rate of
formation of product is plotted against the time as
shown in the figure. The number of Correct
statement/s from the following is _______
(A) Over all order of this reaction is one

(B) Order of this reaction can‟t be determined
(C) In region-I and III, the reaction is of first and
zero order respectively
(D) In region-II, the reaction is of first order
(E) In region-II, the order of reaction is in the
range of 0.1 to 0.9.
Allen Ans. (1)
4
(Held On Monday 30th January, 2023) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A 34. Decreasing order towards SN1 reaction for the
31. Which of the following reaction is correct ? following compounds is:

(1) 2LiNO3 
 2LiNO2  O2

(2) 4LiNO3 
 2Li2 O  2N 2 O 4  O2

(3) 4LiNO3 
 2Li 2 O  4NO2  O2

(4) 2LiNO3 
 2Li  2NO2  O2
®
(1) a > c > d > b (2) a > b > c > d
(3) b > d > c > a (4) d > b > c > a
Allen Ans. (3)
32. The most stable carbocation for the following is: Official Ans. by NTA (3)
NH2 NH2 NH2 NH2 Allen Ans. (3)

+ + CH3 CH3
+
+ 35.
(a) (b) (c) (d) Br Br
(1) c (2) d NO2
(X) (Y)
(3) b (4) a
Official Ans. by NTA (1) In the above conversion of compound (X) to
Allen Ans. (1) product (Y), the sequence of reagents to be used
33. The correct order of pKa values for the following will be:
compounds is: (1) (i) Br2, Fe (ii) Fe, H+ (iii) LiAlH4

OH OH OH OH (2) (i) Br2(aq) (ii) LiAlH4 (iii) H3O+
(3) (i) Fe, H+ (ii) Br2(aq) (iii) HNO2 (iv) CuBr
(4) (i) Fe, H+ (ii) Br2(aq) (iii) HNO2 (iv) H3PO2
N NO2
(a) (b) (c) (d) Allen Ans. (4)
(1) c > a > d > b 36. Maximum number of electrons that can be
accommodated in shell with n = 4 are:
(2) b > d > a > c
(3) b > a > d > c (1) 16 (2) 32
(4) a > b > c > d (3) 50 (4) 72

1
37. Match List I with List II: 40. Chlorides of which metal are soluble in organic
List I List II solvents:

(Complexes) (Hybridisation) (1) Ca (2) Mg
(A) [Ni(CO)4] I sp3 (3) K (4) Be
(B) [Cu(NH3)4]2+ II dsp2 Official Ans. by NTA (4)
(C) [Fe(NH3)6]2+ III sp3d2 Allen Ans. (4)
(D) [Fe(H2O)6]2+ IV d2sp3 41. Given below are two statements : One is labelled as
Assertion A and the other labelled as Reason R.
(1) A – II, B – I, C – III, D – IV
Assertion A: Antihistamines do not affect the
(2) A – I, B – II, C – III, D – IV
(3) A – II, B – I, C – IV, D – III secretion of acid in stomach.
Reason R : Antiallergic and antacid drugs work on
®
(4) A – I, B – II, C – IV, D – III
Official Ans. by NTA (4) different receptors.
Allen Ans. (BONUS) In the light of the above statements, choose the
38. The Cl – Co – Cl bond angle values in a correct answer from the options given below:
fac-[Co(NH 3 ) 3 Cl 3 ] complex is/are: (1) A is false but R is true
(1) 90° & 180° (2) 90°
(2) Both A and R are true and R is the correct
(3) 180° (4) 90° & 120°
explanation of A
Allen Ans. (2)
(4) Both A and R are true but R is not the correct
39. Given below are two statements: One is labelled as
Assertion A and the other is labelled as Reason R. explanation of A.
O Official Ans. by NTA (2)

Assertion A : can be easily reduced Allen Ans. (2)
OH
42. The wave function () of 2s is given by
using Zn-Hg/ HCl to
1/2
1  1   r   r /2a 0
Reason R : Zn-Hg/HCl is used to reduce carbonyl  2s    2 e
2 2  a 0   a0 
group to –CH2 – group.
At r = r0, radial node is formed. Thus, r0 in terms of
a0
correct answer from the options given below:
(1) A is false but R is true (1) r0 = a0
(2) A is true but R is false (2) r0 = 4a0

(3) Both A and R are true but R is not the correct a0
(3) r0 
explanation of A 2
(4) Both A and R are true and R is the correct (4) r0 = 2a0
explanation of A Official Ans. by NTA (4)
Allen Ans. (1)
2
43. KMnO4 oxidises I– in acidic and neutral/faintly 47. Boric acid in solid, whereas BF3 is gas at room
alkaline solution, respectively to temperature because of
(1) I2 & IO3 (2) IO3 & I2 (1) Strong ionic bond in Boric acid
(2) Strong van der Waal’s interaction in Boric acid
(3) IO3 & IO3 (4) I2 & I2
(3) Strong hydrogen bond in Boric acid
Official Ans. by NTA (1) (4) Strong covalent bond in BF3
44. Bond dissociation energy of E–H bond of the Allen Ans. (3)
“H2E” hydrides of group 16 elements (given 48. Given below are two statements:
below), follows order. Statement I: During Electrolytic refining, the pure
(A) O (B) S metal is made to act as anode and its impure

metallic form is used as cathode.
(C) Se (D) Te
Statement II: During the Hall-Heroult electrolysis
®
(1) A > B > C > D (2) A > B > D > C
process, purified Al2O3 is mixed with Na3AlF6 to
(3) B > A > C > D (4) D > C > B > A
lower the melting point of the mixture.
Official Ans. by NTA (1) In the light of the above statements, choose the
Allen Ans. (1) most appropriate answer from the options given
45. The water quality of a pond was analysed and its below:
BOD was found to be 4. The pond has (1) Statement I is incorrect but Statement II is
(1) Highly polluted water correct
(2) Water has high amount of fluoride compounds (2) Both Statement I and Statement II are incorrect
(3) Very clean water (3) Statement I is correct but Statement II is
(4) Slightly polluted water
incorrect
(4) Both Statement I and Statement II are correct
Allen Ans. (3)
46. Match List I with List II:
Allen Ans. (1)
List II 49. Formulae for Nessler’s reagent is:
List I (Mixture) (Separation
(1) KHg2I2 (2) KHgI3
Technique)
(3) K2HgI4 (4) HgI2
(A) CHCl3 + C6H5NH2 I Steam distillation
Differential
(B) C6H14 + C5H12 II Allen Ans. (3)
extraction
50. 1 L, 0.02 M solution of [Co(NH3)5SO4]Br is mixed
(C) C6H5NH2 + H2O III Distillation with 1L, 0.02 M solution of [Co(NH3)5Br]SO4. The
Organic compound Fractional resulting solution is divided into two equal parts
(D) IV (X) and treated with excess AgNO3 solution and
in H2O distillation
BaCl2 solution respectively as shown below:
(1) A-IV, B-I, C-III, D-II 1 L Solution (X) + AgNO3 solution (excess)Y
(2) A-III, B-IV, C-I, D-II 1 L Solution (X) + BaCl2 solution (excess)Z
The number of moles of Y and Z respectively are
(3) A-II, B-I, C-III, D-IV (1) 0.02, 0.02 (2) 0.01, 0.01
(4) A-III, B-I, C-IV, D-II (3) 0.02, 0.01 (4) 0.01, 0.02
Allen Ans. (2)
3
SECTION-B 55. Consider the following equation :
2SO2 (g)  O2 (g) 2SO3 (g), H  190 kJ
51. 1 mole of ideal gas is allowed to expand reversibly
and adiabatically from a temperature of 27°C. The The number of factors which will increase the
yield of SO3 at equilibrium from the following is
work done is 3 kJ mol-1. The final temperature of
_______
the gas is _______K (Nearest integer). Given
A. Increasing temperature
Cv=20 J mol–1K–1. B. Increasing pressure
Official Ans. by NTA (150) C. Adding more SO2
D. Adding more O2
Allen Ans. (150)
E. Addition of catalyst
52. Iron oxide FeO, crystallises in a cubic lattice with a
unit cell edge length of 5.0Å. If density of the FeO
Allen Ans. (3)
in the crystal is 4.0 g cm–3, then the number of FeO
®
x
units present per unit cell is _____ (Nearest 56. The graph of log vs log p for an adsorption
m
integer) process is a straight line inclined at an angle of 45°
with intercept equal to 0.6020. The mass of gas
Given : Molar mass of Fe and O is 56 and 16g
adsorbed per unit mass of adsorbent at the pressure
mol–1 respectively. of 0.4 atm is ______×10–1 (Nearest integer)
NA = 6.0 × 1023 mol–1 Given : log 2 = 0.3010
Allen Ans. (16)
Allen Ans. (4) 57. Number of compounds from the following which
53. An organic compound undergoes first order will not dissolve in cold NaHCO3 and NaOH
decomposition. If the time taken for the 60% solutions but will dissolve in hot NaOH solution is
decomposition is 540 s, then the time required for _____ .
90% decomposition will be is _______ s. (Nearest O O
integer). OH O
Given : ln 10 = 2.3; log 2 = 0.3
, ,
Allen Ans. (1350)
54. Lead storage battery contains 38% by weight

solution of H2SO4. The van’t Hoff factor is 2.67 at O
this concentration. The temperature in Kelvin at
O
which the solution in the battery will freeze is ____
(Nearest integer). O
H3 C CH3 ,
Given Kf = 1.8 K kg mol–1
Allen Ans. (3)
Allen Ans. (243)
4
58. A short peptide on complete hydrolysis produces 3
moles of glycine (G), two moles of leucine (L) and
two moles of valine (V) per mole of peptide. The
number of peptide linkages in it are _______

Allen Ans. (6)
59. The strength of 50 volume solution of hydrogen
peroxide is ______ g/L (Nearest integer).
Given:
Molar mass of H2O2 is 34 g mol–1
Molar volume of gas at STP = 22.7 L.
®
Allen Ans. (150)
60. The electrode potential of the following half cell at
298 K
X | X2+ (0.001 M) || Y2+ (0.01 M) | Y is _____×10–2
V (Nearest integer).
Given : Ex2 |x  2.36V

0
E0Y2 |Y  0.36V
2.303RT
 0.06V
F

Allen Ans. (275)
5
(Held On Monday 30th January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON
CHEMSITRY TEST PAPER WITH ANSWER

SECTION-A 33. Given below are two statements : one is labelled as
31. Which of the following compounds would give the Assertion (A) and the other is labelled as Reason
following set of qualitative analysis ? (R).
Assertion (A) : Ketoses give Seliwanoff’s test
(i) Fehling’s Test : Positive
faster than Aldoses.
(ii) Na fusion extract upon treatment with sodium
Reason (R) : Ketoses undergo -elimination
nitroprusside gives a blood red colour but not
followed by formation of furfural.
N
(1) CHO
®
N correct answer from the options given below :
N (1) (A) is false but (R) is true
(2) CHO (2) Both (A) and (R) are true and (R) is the correct
O
explanation of (A)
N
(3) (A) is true but (R) is false
(3) CHO
S (4) Both (A) and (R) are true but (R) is not the
N correct explanation of (A)
(4)
S CHO
Allen Ans. (4)
34. In the extraction of copper, its sulphide ore is
heated in a reverberatory furnace after mixing with
32. What is the correct order of acidity of the protons
silica to :
marked A–D in the given compounds ? (1) separate CuO as CuSiO3
H CO2HC (2) remove calcium as CaSiO3
D
(3) decrease the temperature needed for roasting of Cu2S
(4) remove FeO as FeSiO3
HA
Official Ans. by NTA (D)
Allen Ans. (D)
HB
35. Amongst the following compounds, which one is
(1) HC > HD > HB > HA
an antacid ?
(2) HC > HD > HA > HB
(1) Ranitidine
(3) HD > HC > HB > HA
(2) Meprobamate
(4) HC > HA > HD > HB (3) Terfenadine
Official Ans. by NTA (2) (4) Brompheniramine
Allen Ans. (1)
1
36. The major products ‘A’ and ‘B’, respectively, are 38. Given below are two statements : one is labelled as
Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : In expensive scientific instruments,
silica gel is kept in watch-glasses or in semipermeable
CH3 CH3 CH3 membrane bags.
(1) H3C C CH3 CH3 C CH C CH3
Reason (R) : Silica gel adsorbs moisture from air via
OSO3H CH3
adsorption, thus protects the instrument from water
CH3 CH3 CH3 corrosion (rusting) and / or prevents malfunctioning.
(2) CH3 C CH C CH3 CH3 C CH3 In the light of the above statements, choose the
CH3 OSO3H
CH3 CH3 CH3 (1) (A) is false but (R) is true
(3) CH CH CH CH CH CH
®
H3C C CH3
3 2 2 3
(2) (A) is true but (R) is false
OSO3H
(3) Both (A) and (R) are true and (R) is the correct
CH3 CH3 CH3
explanation of (A)
(4) H3C C CH3 CH3 CH CH2CH2 HC CH3
OSO3H
(4) Both (A) and (R) are true but (R) is not the
Official Ans. by NTA (C)
Allen Ans. (1)
Allen Ans. (C)
37. Benzyl isocyanide can be obtained by : 39. Match List I with List II
CH2Br List I List II
AgCN
(a) A Cl CH3 I Fitting
reaction
CH2NH2
CHCl3
(b) B Cl II Wurtz
Aq. KOH
Fitting
CH2 NHCH3
CHCl3 reaction
(c)
Aq. KOH C N2Cl Cl III Finkelstein
CH2OTs reaction
KCN
(d)
D C2H5Cl + NaI  C2H5I + IV Sandmeyer
Choose the correct answer from the options given NaCl reaction
below : (1) A – II, B – I, C – III, D – IV
(1) a and d (2) Only b (2) A – III, B – II, C – IV, D – I

(3) A – IV, B – II, C – III, D – I
(3) a and b (4) b and c
(4) A – II, B – I, C – IV, D – III
Allen Ans. (3)
Allen Ans. (4)
2
40. Caprolactam when heated at high temperature in 44. During the qualitative analysis of SO32 using
presence of water, gives
dilute H 2SO 4 ,SO 2 gas is evolved which turns
(1) Teflon
(2) Dacron K 2 Cr2 O 7 solution (acidified with dilute H2SO4 ):
(3) Nylon 6, 6
(1) Black
(4) Nylon 6
Official Ans. by NTA (4) (2) Red
Allen Ans. (4) (3) Green
(4) Blue
41. The alkaline earth metal sulphate(s) which are
Official Ans. by NTA (C)
readily soluble in water is/are:
Allen Ans. (C)
(a) BeSO4
(b) MgSO4
(c) CaSO4
®
45. To inhibit the growth of tumours, identify the
(d) SrSO4
(e) BaSO4 compounds used from the following:
Choose the correct answer from the options given (a) EDTA
below:
(b) Coordination Compounds of Pt
(1) a only (2) b only
(3) a and b (4) b and c (c) D – Penicillamine
Official Ans. by NTA (C) (d) Cis – Platin
Allen Ans. (C)
Choose the correct answer from the option given
42. Which of the following is correct order of ligand below:

field strength? (1) b and d Only
2 2
(1) CO  en  NH3  C2 O4  S
(2) c and d Only
2 2
(2) S  C2 O4  NH3  en  CO
(3) a and b Only
(3) NH3  en  CO  S2  C2 O42
(4) a and c Only
(4) S2  NH3  en  CO  C2 O42
Official Ans. by NTA (A)
Official Ans. by NTA (B)
Allen Ans. (B) Allen Ans. (A)
43. Formation of photochemical smog involves the

46. In the wet tests for identification of various cations
following reaction in which A, B and C are
respectively. by precipitation, which transition element cation
h
(i) NO2  A  B doesn’t belong to group IV in qualitative inorganic
(ii) B  O 2  C analysis?
(iii) A  C  NO2  O2
(1) Fe3
below: (2) Zn 2

(1) O, NO& NO3 (2) O, N 2 O& NO (3) Co2
(3) N,O 2 &O3 (4) NO,O&O3
(4) Ni 2
Allen Ans. (D) Official Ans. by NTA (A)
Allen Ans. (A)
3
47. Match List I with List II 50. Match List – I with List – II
LIST–I LIST–II
LIST–I LIST–II (Atomic number) (Block of periodic
(molecules/ions) (No. of lone pairs of e–
table)
on central atom)
(A) 37 I. p–block
(A) IF7 I. Three
(B) 78 II. d–block
(B) ICl4 II. One
(C) 52 III. f–block
(C) XeF6 III. Two
(D) 65 IV. s–block
(D) XeF2 IV. Zero
below:
below:
(1) A – II, B – III, C – IV, D – I (1) A – II, B – IV, C – I, D – III
(2) A – IV, B – III, C – II, D – I
®
(2) A – I, B – III, C – IV, D – II
(3) A – II, B – I, C – IV, D – III
(4) A – IV, B – I, C – II, D – III (3) A – IV, B – III, C – II, D – I
Official Ans. by NTA (B) (4) A – IV, B – II, C – I, D – III
Allen Ans. (B) Official Ans. by NTA (D)
Allen Ans. (D)
48. For OF2 molecule consider the following:
(a) Number of lone pairs on oxygen is 2.
(b) FOF angle is less than 104.5o . SECTION-B
(c) Oxidation state of O is –2. 51. Consider the cell
(d) Molecule is bent ‘V’ shaped. Pt  s  H 2  g,1atm  H   aq,1M  Fe3  aq  , Fe2  aq  Pt  s 
(e) Molecular geometry is linear.
When the potential of the cell is 0.712 V at 298 K,
Correct options are: the ratio  Fe 2  /  Fe3  is _________.
(1) c, d, e only
(Nearest integer)
(2) b, e, a only
Given: Fe3  e  Fe2 , E o Fe3 , Fe2 Pt  0.771
(3) a, c, d only
2.303RT
(4) a, b, d only  0.06 V
F
Allen Ans. (D)
Allen Ans. (10)
49. Lithium aluminium hydride can be prepared from
the reaction of 52. A 300 mL bottle of soft drink has 0.2 M CO2
(1) LiCl and Al2 H6 dissolved in it. Assuming CO2 behaves as an ideal
gas, the volume of the dissolved CO2 at STP is
(2) LiH and Al2 Cl6 _________ mL. (Nearest integer)
(3) LiCl, Al and H 2 Given: At STP, molar volume of an ideal gas is
(4) LiH and Al  OH 3 22.7 L mol1
Official Ans. by NTA (B) Official Ans. by NTA (1362)

Allen Ans. (B) Allen Ans. ( 1362 ml)
4
53. A solution containing 2 g of a non–volatile solute 58. 600 mL of 0.01M HCl is mixed with 400 mL of
in 20 g of water boils at 373.52 K. The molecular 0.01 M H2SO4 . The pH of the mixture is
1
mass of the solute is _______ g mol . (Nearest
________ 102 . (Nearest integer)
integer)
[Given log 2  0.30 , log 3  0.48
Given, water boils at 373 K, K b for water
log 5  0.69 log 7  0.84
 0.52K kg mol1
log11  1.04 ]
Official Ans. by NTA (100g)
Allen Ans. (100g )
Allen Ans. (186)
54. If compound A reacts with B following first order

kinetics with rate constant 2.011  103 s 1 . The 59. A trisubstituted compound ‘A’, C10 H12 O 2 gives
®
time taken by A (in seconds) to reduce from 7 g to neutral FeCl3 test positive. Treatment of
2 g will be ________. (Nearest Integer)
compound ‘A’ with NaOH and CH3Br gives
[ log5  0.698,log 7  0.845,log 2  0.301 ]
C11H14 O 2 , with hydroiodic acid gives methyl
iodide and with hot conc. NaOH gives a compound
Allen Ans. (623)
B, C10 H12 O 2 . Compound ‘A’ also decolorises
alkaline KMnO4 . The number of  bond/s

55. The energy of one mole of photons of radiation of
1
present in the compound ‘A’ is _______.
frequency 2  1012 Hz in J mol is _______.
(Nearest integer)
Allen Ans. (4)
(Given: h  6.626  1034 Js
NA  6.022  1023 mol1 )

60. Some amount of dichloromethane  CH 2 Cl2  is
added to 671.141 mL of chloroform  CHCl3  to
Allen Ans. (798)
prepare 2.6  103 M solution of CH 2 Cl2  DCM  .
56. The number of electrons involved in the reduction The concentration of DCM is ______ ppm (by
of permanganate to manganese dioxide in acidic mass).
medium is ________. Given: Atomic mass : C = 12; H : 1; Cl = 35.5
Official Ans. by NTA (3) density of CHCl3  1.49g cm
3
Allen Ans. (3)

57. When 2 litre of ideal gas expands isothermally into Allen Ans. (148)
vacuum to a total volume of 6 litre, the change in

internal energy is ______ J. (Nearest integer)
Allen Ans. (0)
5
(Held On Tuesday 31ST January, 2023) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A 35. Cyclohexylamine when treated with nitrous acid
31. In the following halogenated organic compounds yields (P). On treating (P) with PCC results in (Q).
When (Q) is heated with dil. NaOH we get (R) The
the one with maximum number of chlorine atoms
final product (R) is :
in its structure is :
(1) Chloral (2) Gammaxene
(3) Chloropicrin (4)Freon -12
(1) (2)
Allen Ans. (2)
32. Incorrect statement for the use of indicators in
®
acid-base titration is : (3) (4)
(1) Methyl orange may be used for a weak acid vs
weak base titration. Allen Ans. (2)
(2) Methyl orange is a suitable indicator for a 36. Given below are two statements :
strong acid vs weak base titration Statement I : Upon heating a borax bead dipped in
(3) Phenolphthalein is a suitable indicator for a cupric sulphate in a luminous flame, the colour of
weak acid vs strong base titration the bead becomes green.
Statement II : The green colour observed is due to
(4) Phenolphthalein may be used for a strong acid the formation of copper(I) metaborate.
vs strong base titration. In the light of the above statements, choose the
Official Ans. by NTA (1) most appropriate answer from the options given
Allen Ans. (1) below :
33. Which of the following compounds are not used as (1) Both Statement I and Statement II are true
disinfectants?
(A) Chloroxylenol (4) Statement I is false but Statement II is true
(B) Bithional Official Ans. by NTA (3)
(C) Veronal Allen Ans. (3)
(D) Prontosil 37. Evaluate the following statements for their
(E) Terpineol correctness.
(A) The elevation in boiling point temperature of
water will be same for 0.1 M NaCl and 0.1 M
below: urea.
(1) A, B, E (2) A, B (B) Azeotropic mixtures boil without change in
(3) B, D, E (4) C, D their composition
Official Ans. by NTA (4) (C) Osmosis always takes place from hypertonic
Allen Ans. (1) to hypotonic solution
(D) The density of 32% H2SO4 solution having
34. A hydrocarbon ‘X’ with formula C6 H8 uses two
molarity 4.09 M is approximately
moles of H 2 on catalytic hydrogenation of its one
1.26 g mL1
mole. On ozonolysis, ‘X’ yields two moles of (E) A negatively charged sol is obtained when KI
methane dicarbaldehyde. The hydrocarbon ‘X’ is : solution is added to silver nitrate solution.
(1) hexa-1, 3, 5-triene Choose the correct answer from the options
(2) 1-methylcyclopenta-1, 4-diene given below :
(3) cyclohexa-1, 3-diene (1) B, D, and E only (2) A, B, and D only
(4) cyclohexa-1, 4-diene (3) A and C only (4) B and D only
1
38. Compound A, C5 H10 O5 , given a tetraacetate with 41. Match List-I with List-II
List-I List-II
Ac2O and oxidation of A with Br2  H2 O gives (A) Physisorption I Single
an acid, C5 H10 O6 . Reduction of A with HI gives layer adsorption
isopentane. The possible structure of A is : (B) Chemisorption II 20-40 kJ mol-1
(1) (C) N2 (g)  3H2 (g) 
Fe(s)
2NH3 (g) III Chromatography
(D) Analytical Application IV Heterogeneous
or Adsorption catalysis

below :
(2) (1) A – II, B – III, C – I, D – IV
(2) A – III, B – IV, C – I, D - II
(3) A – IV, B – II, C – III, D - I
(4) A – II, B – I, C – IV, D – III
(3) Official Ans. by NTA (4)
Allen Ans. (4)
®
42. Given below are two statements : one is labelled
Reason (R)
Assertion (A) : The first ionization enthalpy of
3d series elements is more than that of group 2
metals
Reason (R) : In 3d series of elements successive
filling of d-orbitals takes place.
(4) In the light of the above statements, choose the
(1) Both (A) and (R) are true and (R) is the
Official Ans. by NTA (1) (2) Both (A) and (R) are true but (R) is not the
Allen Ans. (1)
(3) (A) is false but (R) is true
39. Arrange the following orbitals in decreasing order (4) (A) is true but (R) is false
of energy ? Official Ans. by NTA (1)
(A) n = 3, l = 0, m = 0 Allen Ans. (3)
(B) n = 4, l = 0, m = 0 43. The element playing significant role in
(C) n = 3, l = 1, m = 0 neuromuscular function and interneuronal
(D) n = 3, l = 2, m = 1 transmission is :
The correct option for the order is : (1) Be (2) Ca (3) Li (4) Mg
(1) B  D  C  A Allen Ans. (2)
(2) D  B  C  A 44. Given below are two statements :
(3) A  C  B  D Statement I : H2 O2 is used in the synthesis of
(4) D  B  A  C Cephalosporin
Official Ans. by NTA (2) Statement II : H2 O2 is used for the restoration
Allen Ans. (2) of aerobic conditions to sewage wastes.
40. The Lewis acid character of boron tri halides In the light of the above statements, choose the
follows the order : most appropriate answer from the options given
(1) BBr3  BI3  BCI3  BF3 below :
(2) BCl3  BF3  BBr3  BI3 (1) Both Statement I and Statement II are correct
(2) Statement I is incorrect but Statement II is correct
(3) BF3  BCl3  BBr3  BI3 (3) Statement I is correct but Statement II is incorrect
(4) BI3  BBr3  BCl3  BF3 (4) Both Statement I and Statement II are incorrect
2
45. The normal rain water is slightly acidic and its pH 49. Which of the following elements have half-filled
value is 5.6 because of which one of the following ? f-orbitals in their ground state ?
(1) CO2  H2O  H2CO3 (Given : atomic number
(2) 4NO2  O2  2H2O  4HNO3 Sm  62; Eu  63; Tb  65; Gd  64, Pm  61 )
(3) 2SO2  O2  2H2O  2H2SO4 A. Sm
(4) N2O5  H2O  2HNO3 B. Eu
Official Ans. by NTA (1) C. Tb
Allen Ans. (1) D. Gd
46. When a hydrocarbon A undergoes complete E. Pm
combustion it requires 11 equivalents of oxygen Choose the correct answer from the options given
and produces 4 equivalents of water. What is the
below:
molecular formula of A ?
(1) B and D only (2) A and E only
(1) C9 H8
(3) A and B only (4) C and D only
(2) C11H4
®
(3) C 5H8
Allen Ans. (1)
(4) C11H8
50. In Dumas method for the estimation of N 2 , the
sample is heated with copper oxide and the gas
Allen Ans. (1)
evolved is passed over :
47. An organic compound  A  C4 H11N  , shows
(1) Ni (2) Copper gauze
optical activity and gives N 2 gas on treatment with (3) Pd (4) Copper oxide
HNO2 . The compound  A  reacts with PhSO2 Cl Official Ans. by NTA (2)
producing a compound which is soluble in KOH. Allen Ans. (2)
The structure of A is:
SECTION-B
(1)
3
51. If the CFSE of  Ti  H 2 O 6  is 96.0 kJ / mol , this
(2) complex will absorb maximum at wavelength ___ nm.

(nearest integer)
Assume Planck’s constant  h   6.4  10 34 Js Speed
of light  c   3.0  108 m / s and Avogadro’s constant

(3)
 N A   6  1023 / mol .
(4) Allen Ans. (480)
52. Amongst the following, the number of species
Official Ans. by NTA (4) having the linear shape is _____.
Allen Ans. (4)
48. Which one of the following statements is incorrect ? XeF2 , I3 , C3O2 , I 3 , CO2 , SO2 , BeCl and BCl 2
(1) Boron and Indium can be purified by zone Official Ans. by NTA (5)
refining method. Allen Ans. (5)
(2) Van- Arkel method is used to purify tungsten.
53. The resistivity of a 0.8 M solution of an electrolyte
(3) Cast iron is obtained by melting pig iron with
scrap iron and coke using hot air blast. is 5  10 3 cm . Its molar conductivity is
(4) The malleable iron is prepared from cast iron by _______ 10 4 1 cm 2 mol 1 . (Nearest integer)
oxidising impurities in a reverberatory furnace.
3
54. At 298 K, the solubility of silver chloride in water 58. Enthalpies of formation of
is 1.434  10 3 g L1 . The value of  log K sp for CCl 4  g  , H2 O  g  , CO2  g  and
HCl  g  are  105,  242,  394 and  92 kJ mol 1

silver chloride is ______.
respectively. The magnitude of enthalpy of the
(Given mass of Ag is 107.9 g mol 1 and mass of
reaction given below is ______ kJ mol 1
Cl is 35.5 g mol 1 )
(nearest integer)
Official Ans. by NTA (10) CCl 4  g   2H2 O  g   CO2  g   4HCl  g 
55. A sample of a metal oxide has formula M0.83O1.00 . Allen Ans. (173)
59. The number of molecules which gives haloform
The metal M can exist in two oxidation states
®
test among the following molecules is ______ .
2 and  3 . In the sample of M0.83O1.00 , the
percentage of metal ions existing in +2 oxidation
state is _____ % (nearest integer)
Allen Ans. (59)

56. Assume carbon burns according to following Official Ans. by NTA (3)
equation : Allen Ans. (3)
2Cs  O2 g   2CO  g  60. The rate constant for a first order reaction is
20 min 1 . The time required for the initial

When 12 g carbon is burnt in 48 g of oxygen, the

volume of carbon monoxide produced is ______ concentration of the reactant to reduce to its
32
101 L at STP [nearest integer] level is ______ 10 2 min . (Nearest integer)
[Given : Assume CO as ideal gas, Mass of C is (Given : ln 10  2.303
12 g mol 1 , Mass of O is 16 g mol 1 and molar log 2  0.3010)

volume of an ideal gas at STP is 22.7 L mol 1 ]
Allen Ans. (17)
Allen Ans. (227)
57. The number of alkali metal(s), from Li, K, Cs, Rb
having ionization enthalpy greater than 400 kJ mol 1

and forming stable super oxide is _____.
Allen Ans. (2)
4
(Held On Tuesday 31st January, 2023) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A 35. When Cu2+ ion is treated with KI, a white
precipitate, X appears in solution. The solution is
31. Nd 2  _______ titrated with sodium thiosulphate, the compound Y
(1) 4f26s2 is formed. X and Y respectively are
(2) 4f4 (1) X = Cu2I2 Y=Na2S4O5
(3) 4f3 (2) X=Cu2I2 Y=Na2S4O6
(3) X=CuI2 Y=Na2S4O3
(4) 4f46s2 (4) X=CuI2 Y=Na2S4O6
32. The methods NOT involved in concentration of ore are
®
(A) Liquation 36.
(B) Leaching
(C) Electrolysis O
(D) Hydraulic washing
C
(E) Froth floatation
(1)
below :
(1) B, D and C only O
(2) C, D and E only
C
(3) A and C only CH 2NH 2
(4) B, D and E only (2)
O
Allen Ans. (3)
33. Consider the following reaction C
OH
NHCH2
Propanal  Methanal  
(i)dil.NaOH
(ii) 
Product B (3)
(iii)NaCN

(C5 H8O3 )
(iv)H3O
O
The correct statement for product B is. It is
(1) optically active and adds one mole of bromine C
NH CH 3
(2) racemic mixture and is neutral
(4)
(3) racemic mixture and gives a gas with saturated
NaHCO3 solution
(4) optically active alcohol and is neutrall Allen Ans. (4)
Official Ans. by NTA (3) 37. Cobalt chloride when dissolved in water forms
Allen Ans. (3) pink colored complex X which has octahedral
34. The correct order of basicity of oxides of vanadium is geometry. This solution on treating with cone HCl
forms deep blue complex, Y which has a Z
(1) V2O3 > V2O4 > V2O5 geometry. X, Y and Z, respectively, are
(2) V2O3 > V2O5 > V2O4 (1) X=[Co(H2O)6]2+, Y=[CoCl4]2-, Z=Tetrahedral
(3) V2O5 > V2O4 > V2O3 (2) X=[Co(H2O6)]2+, Y=[CoCl6]3-, Z=Octahedral
(4) V2O4 > V2O3 > V2O5 (3) X=[Co(H2O)6]3+, Y=[CoCl6]3-, Z=Octahedral
(D)X=[Co(H2O)4Cl2]+, Y=[CoCl4]2-, Z=Tetrahedral
1
38. Identify X, Y and Z in the following reaction. 41. Which transition in the hydrogen spectrum would
(Equation not balanced) have the same wavelength as the Balmer type

Cl O NO2  X 
Y  Z H2 O
transition from n=4 to n = 2 of He+ spectrum
(1) X=ClONO2, Y=HOCl, Z = NO2 (1) n = 2 to n = 1
(2) X=ClNO2, Y=HCl, Z=HNO3 (2) n = 1 to n = 3
(3) X=ClONO2, Y=HOCl, Z=HNO3
(4) X=ClNO3, Y=Cl2, Z=NO2 (3) n = 1 to n = 2
Official Ans. by NTA (3) (4) n = 3 to n = 4
39. The correct order of melting point of dichlorobenzenes is Allen Ans. (1)
Cl Cl Cl
Cl
42. Match items of column I and II
(1) > >
Column I (Mixture of compounds) Column II (Separation Technique)
Cl
Cl A. H2O/CH2Cl2 Crystallization
®
Cl Cl Cl O OH
Cl
(2) B. ii. Differential solvent extraction
> >
NO2
Cl
Cl C. Kerosene/Naphthalene iii. Column chromatography
Cl Cl Cl
Cl D. C6 H12O6 /NaCl iv. Fractional Distillation
(3) > > Correct match is :
Cl (1) A-(iii), B-(iv), C-(ii), D-(i)
Cl
Cl Cl Cl (2) A-(i), B-(iii), C-(ii), D-(iv)
Cl (3) A-(ii), B-(iii), C-(iv), D-(i)
(4) > >
(4) A-(ii), B-(iv), C-(i), D-(iii)
Cl
Cl
Allen Ans. (4) 43. The correct increasing order of the ionic radii is
40. A protein ‘X’ with molecular weight of 70,000 u, on
hydrolysis gives amino acids. One of these amino acid is (1) Cl  Ca 2   K  S2
(1) NH2  CH2  CH  CH2 CH2 COOH (2) K  S2   Ca 2  Cl
|
CH3 (3) S2  Cl  Ca2  K
CH 3
| (4) Ca 2  K  Cl  S2 
(2) CH 3  CH  CH 2  CH  COOH Official Ans. by NTA (4)
|
NH 2 Allen Ans. (4)
CH3 44. H2O2 acts as a reducing agent in
|
(3) CH3  CH  CH  CH 2 COOH (1) 2NaOCl  H 2 O2  2NaCl  H 2 O  O2
| 2  3
NH2 (2) 2Fe  2H  H 2 O2  2Fe  2H 2 O
CH3 2
(3) Mn  2H 2 O2  MnO2  2H 2 O
|
(4) CH3  C  CH2  CH2 COOH
| (4) Na 2S  4H2 O2  Na 2SO4  4H 2 O
NH2
2
45. Which of the following artificial sweeteners has 48. Adding surfactants in non polar solvent, the
micelles structure will look like
the highest sweetness value in comparison to cane
sugar?
polar (Surfactant structure)
non-polar
(1) Aspartame head tail
(2) Sucralose (a) Non Polar Solvent (b) Non Polar Solvent
(3) Alitame
(4) Saccharin

Non Polar Solvent (d) Non Polar Solvent
Allen Ans. (3)
®
List I List II
A. XeF4 I.See  saw (1) b
(2) c
B.SF4 II. Square planar
(3) a
C.NH 4 III. Bent T  shaped
(4) d
D.BrF3 IV. Tetrahedral
Choose the correct answer from the options given Allen Ans. (3)
49. An organic compound ‘A’ with empirical formula
below :
C6H6O gives sooty flame on burning. Its reaction
(1) A-IV, B-III, C-II, D-I with bromine solution in low polarity solvent
(2) A-II, B-I, C-III, D-IV results in high yield of B. B is
OH
(3) A-IV, B-I, C-II, D-III
(4) A-II, B-I, C-IV, D-III (1)

Br
Allen Ans. (4)
CH2 CH2Br
47. Choose the correct set of reagents for the following
conversion (2)
trans (Ph-CH=CH–CH3)  cis (Ph-CH=CH–CH3) O
Br CH 2CH 3
(1) Br2 , alc KOH, NaNH2 , Na(Liq NH3 )
(3)
(2) Br2 , alc KOH, NaNH 2 , H 2 Lindlar Catalyst Br
O
(3) Br2 , aq KOH, NaNH2 , H2 Lindlar Catalyst Br
OH
(4) Br2 ,aq KOH, NaNH2 , Na(Liq NH3 ) (4)

3
50. Which one of the following statements is correct 54. On complete combustion, 0.492 g of an organic
for electrolysis of brine solution? compound gave 0.792 g of CO2.
(1) Cl2 is formed at cathode
The % of carbon in the organic compound is _____
(2) O2 is formed at cathode
(Nearest integer)
(3) H2 is formed at anode
(4) OH– is formed at cathode Official Ans. by NTA (44)
Allen Ans. (4)
55. At 27oC, a solution containing 2.5 g of solute in
SECTION-B
250.0 mL of solution exerts an osmotic pressure of
51. The logarithm of equilibrium constant for the
400 Pa. The molar mass of the solute is ____ g
reaction Pd 2   4Cl  PdCl 24 is ______
mol-1 (Nearest integer)
(Nearest integer)
(Given : R = 0.083 L bar K–1 mol–1)
2.303RT
Given :  0.06V Official Ans. by NTA (62250)
®
F
2 Allen Ans. (62250)
Pd(aq)  2e Pd(s) Eo  0.83V
56. Zinc reacts with hydrochloric acid to give
2  
PdCl (aq)  2e
4 Pd(s)  4Cl (aq) hydrogen and zinc chloride. The volume of
E  0.65V hydrogen gas produced at STP from the reaction of
Official Ans. by NTA (6) 11.5 g of zinc with excess HCl is ______ L
(Nearest integer)
Allen Ans. (6)
52. AB (Given : Molar mass of Zn is 65.4g mol-1 and
The rate constants of the above reaction at 200 K Molar volume of H2 at STP = 22.7L)
and 300K are 0.03 min–1 and 0.05 min–1 Official Ans. by NTA (4)
respectively. The activation energy for the reaction
is _______ J (Nearest integer) Allen Ans. (4)
(Given : In 10 = 2.3 57. How many of the transformation given below

R = 8.3 J K-1 mol-1 would result in aromatic amines?
log5 = 0.70 O
log3=0.48 (1) NH2+Br2 +NaOH
log2 = 0.30
Cl
Official Ans. by NTA (2520) O
Allen Ans. (2520)
(2) NK
53. The enthalpy change for the conversion of
1 O
Cl 2 (g) to Cl– (aq) is (-) _____________ NO2
2
H2
kJ mol–1 (Nearest integer) (3)
Pd/C
Given : dis HCl
o
2( g)
 240kJmol 1 .
NH COCH3
1
eg H o
Cl( g)  350kJmol , dil H2 SO 4
(4)
 hyd HoCl  380kJmol 1 
( g)
4
1 60. The total pressure of a mixture of non-reacting
58. For reaction : SO 2 (g)  O 2 (g) SO3 (g)
2
gases X (0.6 g) and Y (0.45 g) in a vessel is 740
KP = 2 × 1012 at 27oC and 1 atm pressure. The Kc
for the same reaction is _______ × 1013. (Nearest mm of Hg. The partial pressure of the gas X is
integer)
(Given R = 0.082 L atm K–1 mol–1) _________ mm of Hg. (Nearest Integer)
(Given : molar mass X = 20 and Y = 45 g mol-1)
Allen Ans. (1)
59. The oxidation sate of phosphorus in hypophosphoric Official Ans. by NTA (555)
acid is + ________ .
Allen Ans. (4)

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FINAL JEE–MAIN EXAMINATION – JANUARY, 2023

(Held On Wednesday 01st February, 2023) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH ANSWER

(2) (CH3CO)2O/H+ and (CH3CO)2O/H+

(3) CH3OH/H+,  and CH3OH/H+, 

(4) C – C > Si – Si > Ge – Ge > Sn – Sn

Official Ans. by NTA (4) (1) (2)

33. All structures given below are of vitamin C. Most

Allen Ans. (1) (4) Industrial production of urea

Official Ans. by NTA (4)

0Ag  6  103 Sm 2 mol –1

 0Br   8  103 Sm2 mol –1

 0NO  7  103 Sm2 mol –1 ]

Official Ans. by NTA (14)

A2+ A3+ O2– HO H

(1) B and C only CH2 OH

(1) a > d > b > c

Allen Ans. (1) (B) CuSO4.4NH3.H2O

(B) Dead burnt plaster (II) Ca(OH)2 A. A is more soluble than B.

Official Ans. by NTA (364) Official Ans. by NTA (2)

(0.001 M) will have electrode potential of 1.282 V? CH2

H2(g) + ½ O2(g)  H2O(g)  Ho = –242 kJ mol-1

H2(g)  2H(g)  Ho = 436 kJ mol-1

½ O2(g)  O(g)  Ho = 249 kJ mol-1

What would be the value of X for the following

H2O(g)  H(g) + OH(g)  Ho = X kJ mol-1

Official Ans. by NTA (499)

Allen Ans. (499)

CHEMISTRY TEST PAPER WITH ANSWER

40. Match List I with List II

C. Antihistamine III. Seldane

(1) A-II, B-I, C-III, D-IV

(2) A-IV, B-III, C-II, D-I

A. It is highly specific in nature d

B. Enthalpy of adsorption is high

C. It decreases with increase in temperature

D. It results into unimolecular layer c b a

Allen Ans. (2) B. Liquid carbon dioxide appears at point (c)

and pyrosulphuric acid is between points (b) and (c)

Allen Ans. (8) amount of liquid decreases

53. Maximum number of isomeric monochloro Official Ans. by NTA (2)

derivatives which can be obtained from 2,2,5,5- Allen Ans. (2)

tetramethylhexane by chlorination is _________

Official Ans. by NTA (3)

Allen Ans. (3)

The Total pressure becomes 410 mm Hg if the T1

Consider the liquids and solutions behave ideally. T4

Official Ans. by NTA (314)

Allen Ans. (314)

Official Ans. by NTA (620)

Allen Ans. (620)

59. If the pKa of lactic acid is 5, then the pH of 0.005

Official Ans. by NTA (85)

Allen Ans. (85)

CHEMISTRY TEST PAPER WITH ANSWER

The value of 'n' is

Official Ans. by NTA (3) (3)

Given : Cr2O72–  Cr3+; E0 = 1.330 V and

A. The equivalent weight of Fe0.93O is

B. The number of moles of Fe2+ and Fe3+ in 1 mole Given :

of Fe0.93O is 0.79 and 0.14 respectively. Molar mass N = 14 g mol–1; O = 16 g mol–1;

C. Fe0.93O is metal deficient with lattice comprising C = 12 g mol–1; H = 1 g mol–1;

D. The % composition of Fe2+ and Fe3+ in Fe0.93O Allen Ans. (25)