ANNUAL EXaMy |ATIONS * 2022-23 " Class - xy cience) Subject - chemistry Time - 3 hrs, MM. 70 General instructions (2) There are 35 questions in this Paper wit intemal cholce. (6) Section- A: 18 Multiple Choice Questions of t mark each. (©) Section- 8 : 7 Very Short ‘Answer questions carrying 2 marks each. (9) Section C : Consists of 5 Short answer questions carrying 3 marks each. (e) Section~ D : Consists of 2- Case Based questions carrying 4 marks each. (9 Section - E : Consists of 3 - Long answer questions carrying § marks each. ° (9) Allquestions are compulsory, (h) Use of log table and calculator isnot allowed. SECTION-A 1 Which of the following is independent of temperature 7 (a) Molarity (b) Normality (co) Motality (d) None of these 2 The number of molecules in a drop of water weighing 0.05 g (H = 1, O= 16) (3) 1895 x 10% mol (0) 1.672x 10 molecules (c) 1.278% 10" mol (d) 1.672 10 molecules 3 How many unpaired e's are present in the ground state of P, Fe", CI (a)2,3,3 (b) 1,2,4 (93,41 (0) 34,0 4 Total number of orbitals associated with thicd shell wil be (a2 (b) 9 (4 (a) 3 5. Arrange following in. t increasing order of size BEC Na’ + Br (a) Na’ < Mg?" < Be™ < Br Cl <5? (0) Mu 274): HCH of te fotowing is valid ? (@) AH = AU (b) AH > AU () anecay (d) None of the above In. which of the following solvent is AgCI most soluble (a) 0.1 movidm* AgNO; solution. (b) 0.1 Movi? Hoy Solution (c) H,0 (4) Aquous Ammonia CaCO, (8) = Ca0(5)+CO,(g) AH = 1101 The pressure of CO, (a) f increases on adding catalyst (b) 4 decreases if T is raised (c) t increases if Tis raised (2) T increases if an inert as \s passed keeping T constant Which of the following carbocation is most stable (a) (CH,), CCH, (b) (CH,),c° (©) CA,Ch (6) CH, ~C°H-CH, - CH, The correct IUPAC name of following Alkane is HC —CH, ~ CH ~ CH, ~CH, ~ CH -CH,—CH, bi bi a Non, cH, (2) 3, 6 Diethyl-2-methyloctane (0) Sisopropyl-3-ethyloctane {c) 3-Ethyl-5-isopropyloctane (8) Hsopropy!-6-ethyloctane “Assertion - Reason” : (a) (b) (c) (d) 15. A&R correct and R Is correct explanation of A. A&R correct but R is not correct explanation. Ais right but R is wrong. Ais wrong but R is right. Assertion (A) : Copper Suiphate solution is not stored in Zn vessel Reason (R) : Zinc form compiex with copper sulphate.Q Q 20 19. an Q 22 a 23 Q 24 Q. 25 Q 26 ru! assertion (A) Ally free Radical is mory Stabe pan sire ie Radical thal Reason (R) The allyl free Radical is Sabized ny resonance by Assertion (A): Nitration of benzene With Nitric acid requires the use of sulphuric acid. Reason (R). The mixture of conce: . ntrated & Conc. Nithic Acid produce the electrophie yo: SupnuncAcd Assertion (A) Steam is a mixture Reason (R} In a compound, the Composition of the elements must be fixed, SECTIon-B Calculate the mass of sodium (Na) which contains same number of aloms as are present in 159 of Ca (Al mass. Ca = 40 NA=23) ‘Whal are the frequency and wavele: during a transition fram n = § ton = 2 state in the H-atom, Ngth of a photon emitted during oR pride w What ts the maximum number of emission lines, when the existed © of aH-atom Inn = 6 drops to the ground state (i) Which senes of Hydrogen spectrum lie in the visible region 7 Identify best choice in the List (Largest loni¢ size = fe Ba?) Cu () Smatlest size po ys, p (uw) Highest Negative © gainentnalpy pr. FCI W All the bonds in C1, are not Equivalent. Why 7 (i) Tohalides are tess covalent than pentahaliaes. Why? ‘An Alkene ‘A on ozonolysis gives a mixture of otnanal and pentan-3-one Write structure and IUPAC name of ‘A’ Wate down hybridisation and number of Of + bonds are present in each of follownng mol (a) HO » C-CH=CHCH, @) CH,=C=CHCHy idenify he substance Oxidised, Reduced Oxiising Agent and Reducing Agent for each of folowing Reactions (a) 2AgBr(s) + Cee (ag) —> 2Ag(8) * ZHB4(aq) + CyH,0,(39) (b) NcHytl) + 2H,0,(1) —+ Nao) + 4H) SECTION-C Balance the following redox reaction in Acidic medium CRO} + SOF —9r" +50,Q 27 2. 28 Q 29 Q 30 Qa Q. 32, i its enthalpy of combustion 1s ~/ Calculate the enin tion of Acetic . Ne enihaipy of formation Aeid (CH,COOH) He {285 9 kJimol respectively kuimol. The enthalpies of formation of C2 and 1.6 gre 399.8 Consider the reaction 280, (g)+ O,(g) == 280, (¢) +1899 Indicate the ditection in which the equillP™4™ wil shift when () Temperature is f increased ()) Pressure | decreased (uy) Te gas is added at constt Prossule Define Butter solution Give an ex2™PIe of Acidic and Basic Buller. wo ) Define extensive and intensive properties with example Oraw the shape of molecule, name the Sh3P° of molecule and central atom hybridisation of following molecules 0 SFy BF (i) CIF SECTION - > ation enthalpy, e gain enthalpy and 108 ofthe elements such as atomic or onic ra, Lonisalion enthainy. ¢ gain enthalpy ae Fee riot cneddrecty orindrecty related to thelr electronic contiguration and are properties. A part of the periodic table 's given below c N ° F P s cl Se 8r {a) Which element has highest lonisation Enthalpy 7 (b) Bronvine belongs to which period. © (©) Which is strongest Oxidizing Agent 7 (4) Which is having more negative e° gain enthalphy Q or S 7 Alkynes have a triple bond between (C = C) two C-atoms in their moiecules. Terminal Alkynes are acidic. They undergo addition reactions like alkenes. But in alkynes addition occurs in two steps x x —Cxc_+x, > cee” 7% ¥ 205 > ee x Xx Electrophile ()Analkyne having molecular formula C,H, cuprous chloride. Write the name of Aikyne neither reacts with sodamide nor with AmmoniacalState the hybridisation of c.2 6.5 a6 of the compound cH, cn, | | CH,~C=CH =CH~ CHC xy | cH, (ii) Propyne is tess acidic than athyng Fieorteee. (Wy) CH,-CacH—m=, oa. Complete the reaction SECTION -E Q 33. (@) Consider 1, and Ny usin Crbitet +O Rory Write Electronic configuration of each{ Metiason © a) (i) Calculate Bond order of each (ii) Predict Magnetic Character (b) What is disproportionation reaction ? Explain with example. \ . 34. (i) Write the naming Reactions (2) Wurtz ‘Reaction (©) Friede! Graft acylation of benzene. (i) Write down the mechanism of Anti Markovnikov's Rule Q. 35. Explain the following with example = () Law of multiple proportion (i) Dipole moment Jak Hybridisation C 3} _/ Nucleophile “()— Molarity