JISK2514-1 - 2013 潤滑油－酸化安定度の求め方－第１部：内燃機関用潤滑油酸化安定度

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4/26/23, 10:13 AM JISK2514-1:2013 Lubricants -- Determination of oxidation stability -- Part 1: Oxidation stability of lubricants for internal combustion engines
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The name has changed due to the revision of the law on July 1, 2019. Except for the preface, read "Japanese Industrial Standards" in this standard as "Japanese Industrial Standards".
K 2514-1ÿ2013
table of contents
page
Preface .................................................. 1
1 Scope of application .................................................. 1
2 Reference Specifications·············································· ············································· ························ 1
3 Terms and definitions .................................................. 2
4 Test Principles .................................................. 2
5 Reagents .................................................. 2
6 Tester and equipment .................................................................. .................................................. 2
7 Method of collecting and preparing samples .................................................. 8
8 Exam Preparation .................................................. 8
9 Testing procedure .................................................................................................. .................................................. 9
10 Calculation method··································· ············································· ····················································· 10
11 How to express the results .................................................. ················· Ten
12 Report of test results .................................................. 11 Annex A (informative) Types of test
methods .................................................. 12
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K 2514-1ÿ2013
Foreword
This standard is based on the provisions of Article 12, Paragraph 1 of the Industrial Standardization Law, from the Japan Lubricating Oil Association (JALOS).
There was a proposal that Japanese Industrial Standards should be enacted with a draft of industrial standards.
It is a Japanese Industrial Standard established by the Minister of Industry.
As a result, JIS K 2514:1996 was abolished and replaced by this standard, which was established by dividing a part of it. This standard is a work protected by copyright
law.
Note that portions of this standard may infringe patent rights, post-publication patent applications, or utility model rights.
evoke The Minister of Economy, Trade and Industry and the Japanese Industrial Standards Committee should consider such patent rights, post-publication patent applications and
We are not responsible for confirmations related to patent rights for use.
The JIS K 2514 standards group has the following divisions.
JIS K 2514-1 Part 1: Oxidation stability of lubricants for internal combustion engines
JIS K 2514-2 Part 2: Turbine oil oxidation stability
JIS K 2514-3 Part 3: Rotating Pressure Vessel Oxidation Stability
ÿ2ÿ
Japanese Industrial Standard JIS
K 2514-1ÿ2013
Lubricating oil - Determination of oxidation stability - Part
1: Oxidation stability of lubricating oil for internal combustion engines
Lubricating oils-Determination of oxidation stability

Part 1: Oxidation stability of internal combustion engine oils
preface
JIS K 2514, which is the basis of this standard, was established in 1959 and has been revised seven times since then. Before
The second revision was made in 1996. This time, JIS K 2514 was divided into three parts as a group of standards, and this standard was established
as JIS K 2514-1.
Corresponding international standards have not yet been enacted.
1 Scope This
standard mainly stipulates the method of determining the oxidation stability of lubricating oils for internal combustion engines.
NOTE This standard group has the test methods shown in Annex A.
WARNING This standard may use dangerous reagents, operations and test equipment, but all prescribe safe usage.
Appropriate safety and health restrictions must be established prior to testing by the user of this test method.
2 Reference Specifications
The following standards form part of the provisions of this standard by being referenced in this standard. For these normative references, the latest
editions (including amendments) apply.
JIS B 7410 Glass thermometer for petroleum test
JIS G 3141 Cold-rolled steel plates and strips
JIS H 3100 Copper and copper alloy sheets and strips
JIS K 0557 Water used for testing water and waste water
JIS K 2251 Crude oil and petroleum products - Sampling methods
JIS K 2283 Crude oil and petroleum products-Kinematic viscosity test method and viscosity index calculation method
JIS K 2501 Petroleum products and lubricating oils-Neutralization value test method
JIS K 8252 Ammonium Peroxodisulfate (Reagent)
JIS K 8848 Hexane (Reagent)
JIS K 8951 Sulfuric acid (Reagent)
JIS K 9701 Heptane (Reagent)
JIS R 6251 abrasive cloth
JIS R 6252 abrasive paper
K 2514-1ÿ2013
JIS Z 8401 How to round numbers
JIS Z 8402-6 Accuracy of measurement methods and results (accuracy and precision)-Part 6: Practical values for accuracy
how to use
3 Terms and definitions
The main terms and definitions used in this standard are as follows.
3.1
Lubricant Oxidation Stability for Internal Combustion Engines
Increase in viscosity ratio and acid value between a sample subjected to oxidation test under specified conditions (hereinafter referred to as oxidized oil) and the same sample
before oxidation test (hereinafter referred to as unoxidized oil), and lacquer after oxidation test expressed by degree (of degree of deterioration)
index.
3.2
Viscosity ratio
Ratio of kinematic viscosities of oxidized and unoxidized oils. The kinematic viscosity of oxidized oil at 40°C is the kinematic viscosity of unoxidized oil at 40°C.
divided by
3.3
increase in acid number
Difference in acid number between oxidized and unoxidized oil. Value obtained by subtracting the acid value of unoxidized oil from the acid value of oxidized oil.
3.4
Lacquer degree
Indicates the degree of lacquer-like substances, sludge, etc. adhering to oxidized oil varnish rods.
4 Test principle
Put the sample in a test container equipped with a catalyst and a varnish rod, and stir under specified conditions (165.5 ° C, 24 hours).
After oxidizing the sample by stirring with a rod, measure the kinematic viscosity and acid number of the oxidized oil and compare them with those of the unoxidized oil to determine
the increase in viscosity ratio and acid number. In addition, the state of adhesion of lacquer-like substances or sludge on the varnish rod after the oxidation test
Determine the degree of lacquer by comparison with an evaluation sample (color scale).
In addition, if there is a specification in the individual product standard, the specified temperature and time shall be used.
5 reagents
The reagent shall be as follows.
a) Heptane Use the heptane specified in JIS K 9701. b) Hexane Use the hexane specified in JIS K 8848.
c) Water Use A3 specified in JIS K 0557. d) Cleaning solution The cleaning solution is 1 L of sulfuric acid
specified in JIS K 8951 and ammonium peroxodisulfate specified in JIS K 8252.
Use a cleaning solution with equivalent performance such as a solution containing 8 g of Ni or a surfactant cleaning solution.
WARNING Ammonium peroxodisulfate is a strong oxidizing agent, so be careful when handling it.
6 Testers and instruments
The tester and equipment shall be as follows.
K 2514-1ÿ2013
6.1 Lubricating oil oxidation stability tester for internal combustion engines The lubricating oil oxidation stability tester for internal combustion engines consists of a) to g)
An example is shown in Figure 1.
a) Constant temperature bath The constant temperature bath is equipped with a stirrer, an electric heater and a temperature controller, and the temperature of the constant temperature bath is 165.5 ° C ± 0.5 ° C.
Place the bottom of the test container at a position approximately 120 mm below the upper surface of the lid of the constant temperature bath, and
use the one that allows the test container to be immersed in the bath liquid for 90 mm or more (see Figure 1). . If it is specified in the individual
product standard, use the one that can be maintained at the specified temperature ±0.5 °C.
b) Thermometer The thermometer is a thermometer number 73 (ISO) specified in JIS B 7410, or a thermometer with equivalent performance.
Or use a temperature measuring device.
c) Test container A test container made of borosilicate glass with the shape and dimensions shown in Figure 2 shall be used. d)
Lid of test container
Use the one with the insertion holes for the stirrer and varnish rods.
e) Sample stirring rod The sample stirring rod shall be borosilicate glass or stainless steel of the shape and dimensions shown in Figure 4.
(SUS304) is used.
f) Rotor The rotor has the shape shown in Figure 1. A sample stirring rod is inserted from below, and the sample container is gripped by a chuck.
Hold it at a position of 10 mm from the bottom of the vessel and rotate it 1 300 times per minute in the direction of pushing down the sample without shaking.
Use one that can rotate 15 times. g) Varnish rod
The varnish rod shall be made of borosilicate glass and have the shape and dimensions shown in Figure 5.
K 2514-1ÿ2013
unit mm
ÿ Motor
ÿ Thermometer ÿ Overflow ÿ Discharge ÿ Operation
ÿ Rotor ÿ Test ÿ Temperature cock ÿ Electric panel ÿ Thermostat lid
container holder ÿ Insulation controller ÿ Sample stirring heater ÿ
material ÿ rod ÿ Stirrer ÿ Test Constant
Insulation wall container temperature bath ÿ Varnish rod
Figure 1 — Example of Lubricant Oxidation Stability Tester for Internal Combustion Engines
K 2514-1ÿ2013
unit mm
Figure 2 — Test vessel
unit mm
Figure 3 — Lid of test vessel
K 2514-1ÿ2013
unit mm
Figure 4 — Sample stir bar
K 2514-1ÿ2013
unit mm
Figure 5 — Varnish bar
6.2 Catalyst The catalyst is a steel plate (steel catalyst) of SPCC specified in JIS G 3141 and a copper plate (copper catalyst) of C1100P specified in JIS H 3100,
with claws and grooves or holes at both ends of the catalyst. use things For the catalyst with claws and grooves, use a copper plate with claws with fold lines (scratches
for bending) on both ends and grooves for the claws on both ends of the steel plate. When assembling, insert the claws of the copper plate into the grooves of the steel
plate, and bend the fold lines deeply to fix them. The dimensions of the tabbed and grooved catalyst are shown in FIG. For catalysts with fixing holes (approximately 1
mm in diameter) at both ends of steel and copper plates, use the following dimensions: When assembling, fix the holes of the catalyst by tying them with cotton thread
or the like.
a) Steel plate 0.5 mm thick, 26 mm wide and 121.4 mm long. b) Copper plate 0.5 mm
thick, 26 mm wide and 60.4 mm long.
K 2514-1ÿ2013
unit mm
Figure 6 - Catalyst with claws and grooves
6.3 Abrasive cloth or abrasive paper
Use a luminous abrasive or garnet with a grain size of P400. 6.4 Absorbent cotton
Absorbent cotton of the Japanese Pharmacopoeia should be used.
6.5 Color scale Use a color scale that divides the degree of coloring of the varnish rod into 9 levels.
Note The color scale is shown in Appended Figure 2 specified in JPI-5S-15 (land diesel engine piston evaluation method).
there is something
7 Sampling and preparation methods
The sample shall be collected according to the primary sample collection method and the secondary sample preparation method specified in JIS K 2251, or a method according to it.
Therefore, it is collected and prepared.
8 Exam preparation
The preparation for the test shall be as follows.
a) Immerse the test container, sample stirring rod and varnish rod in the cleaning solution for at least 2 hours, rinse thoroughly with tap water, and
wash and dry several times. For stainless steel, wash with heptane or hexane and dry. b) After wiping the catalyst (steel plate and
copper plate) thoroughly with absorbent cotton moistened with heptane or hexane, polish with an abrasive cloth or abrasive paper until
a new surface appears. Furthermore, remove the polishing powder completely with dry absorbent cotton, and
Assemble as follows. The assembled catalyst is immediately used for testing.
In addition, always handle this polished catalyst with clean and dry absorbent cotton or cotton gloves, and directly
Do not touch with
c) Adjust the temperature of the thermostat to 165.5°C ± 0.5°C. If specified in the individual product standard, the specified temperature ± 0.5 ° C
Adjust.
K 2514-1ÿ2013
9 Test procedure
The test procedure shall be as follows. In this standard, the temperature and time of oxidation test shall be 165.5 °C and 24 hours. In addition, if it is based
on the individual product standard or the agreement between the parties concerned with delivery, the temperature and time shall be those.
a) Oxidation of samples Oxidation of samples shall be as follows.
1) As shown in Figure 7, put 250 mL of the same sample in each of the two test containers containing the catalyst at room temperature,
These are fixed to the test vessel holder of the constant temperature bath. Next, pass the sample stirring rod through the lid of the test vessel and
close the lid. After attaching the blade to the rotor so that the lower end of the blade is 10 mm above the bottom of the test vessel,
to install. At this time, do not directly touch the parts of the sample stirring rod and varnish rod that are immersed in the sample.
should not.
In addition, if it is confirmed in advance that the increase in viscosity ratio and acid value of the two test results does not exceed the tolerance
shown in Clause 11 and the classification of lacquer degree is the same, and If there is an agreement, one test container (sample for oxidation test)
may be used.
Figure 7 — Assembly of test vessel and catalyst
2) Rotate the sample stirring rod at 1 300 ±15 rpm in the direction of pushing down the sample to stir the sample. Record the start time of the test when
the sample stirrer is rotated.
3) After 24 hours, remove the test container from the constant temperature bath, remove the varnish rod, and remove the catalyst with clean tweezers.
After taking it out, allow the oxidized oil in the test container to cool to room temperature. If specified in the individual product standard,
time. b) Measurement
of samples Perform the following tests immediately on unoxidized oil, oxidized oil and varnished sticks.
1) Measure the kinematic viscosity of unoxidized oil and oxidized oil at 40°C according to JIS K 2283. 2) Measure the acid value
of unoxidized oil and oxidized oil according to JIS K 2501. 3) Rinse the varnish stick with hexane to
remove the oxidized oil and dry it. Adhesion of lacquer-like substances or sludge
If there is deposit, compare it with the color scale to find the color scale No. corresponding to the degree of coloring of the varnish rod, and record it
as the degree of lacquer.
10
K 2514-1ÿ2013
10 calculation method
The increase in viscosity ratio and acid number is calculated by the following formula.
a) Viscosity ratio
D
R= 2
D
1
Here, R: viscosity ratio
D1: Kinematic viscosity of unoxidized oil at 40°C (mm2/s)

D2: Kinetic viscosity of oxidized oil at 40°C (mm2/s)
b) increase in acid number
S =E2 ÿE1
Here, S: Increase in acid number (mg KOH/g)
E1: Acid value of unoxidized oil (mg KOH/g)

E2: Acid value of oxidized oil (mg KOH/g)
11 Presentation of results
The results shall be expressed as follows.
a) Viscosity ratio Round to 0.01 as specified in JIS Z 8401. Under specified conditions (165.5 °C, 24 hours)
If the difference between the two test results obtained does not exceed 14 % of the average value, the average value shall be taken as the viscosity ratio.
If the difference between the two test results is 14 % or more of the average value, it shall be processed according to the
provisions of JIS Z 8402-6. b) Increase in acid value Round to 3 significant digits in accordance with JIS Z 8401. However, if less than 1 mg KOH/g,
Round to a width of 0.01 according to JIS Z 8401. If the difference between the two test results obtained under the specified conditions (165.5 °C, 24
hours) does not exceed the tolerance given in Table 1, the average value shall be the increase in acid value. If the difference between the two test results
exceeds the tolerance given in Table 1, it shall be processed according to the provisions of JIS Z 8402-6.
Table 1 - Tolerance for increase in acid number
Unit mg KOH/g Tolerance
increase in acid number
0.05 or more and 1.0 or less Over 1.0 0.3
and 5.0 or less 1
Over 5.0 and 20 or less 4
c) Degree of lacquer Classify the state of adhesion of lacquer-like substances or sludge to the varnish rod according to Table 2, and
is expressed as degrees of lacquer.
In addition, if the two test results obtained under the specified conditions (165.5 ° C, 24 hours) do not match, the color
The degree of lacquer determined by the varnish rod with the larger scale number.
Table 2 — Classification of degree of lacquer
degree of lacquer Summary
No deposits No deposits are observed on the varnished stick or the degree of coloring of the varnished stick is smaller than
No.1 on the color scale. Deposits (thin) The degree
of coloring of the varnish rod corresponds to No. 1-2 on the color scale. Deposits (medium) The degree of coloring of the
varnish rod corresponds to No. 3-5 on the color scale. Deposits (dark) The degree of coloring of the varnish rod corresponds
to No. 6-9 on the color scale.
11
K 2514-1ÿ2013
12 Reporting of test results
The report of test results shall include the following:
a) Sample name, sampling location and sampling date
b) Number of this standard (JIS K 2514-1) c) Test
conditions (temperature, time) and results (according to the expression in Clause 11)
d) test date;
) special
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e) Special notes
References JPI-5S-15 Land Diesel Engine Piston Evaluation Method (Public Interest Incorporated Association Japan Petroleum Institute Standard)
12
K 2514-1ÿ2013
Annex A
(informative) Types of test methods
A.1 Types of test methods
The JIS K 2514 family of standards has the test methods shown in Table A.1.
Table A.1 — Types of test methods
Standard number Test method Abbreviation of test method Examples of
K 2514-1 Oxidation stability of lubricants for internal combustion engines ISOTa) applicable oil types Lubricating oil for internal
K 2514-2 Turbine Oil Oxidation Stability TOSTb) combustion engines (engine oil)
K 2514-3 Rotating Pressure Vessel Oxidation Stability RPVOTc) Turbine oil, hydraulic oil Turbine oil, hydraulic oil, air compressor oil
Note a) Abbreviation for Indiana Stirring Oxidation Test. b)

Abbreviation for Turbine oil Oxidation
Stability Test. c) Abbreviation for Rotating Pressure Vessel Oxidation Test. Rotating Bomb Oxidation Stability Test
Test: RBOT).

JISK2514-1 - 2013 潤滑油－酸化安定度の求め方－第１部：内燃機関用潤滑油酸化安定度

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Machine Translated by Google

To the top of the site > To the list of this category

You can rest assured because it is a fermentation method

First time limited-1 box 500 yen trial

round throw, single letter

Repeater free with overwhelming cost

It is a Japanese Industrial Standard established by the Minister of Industry.

The JIS K 2514 standards group has the following divisions.

JIS K 2514-2 Part 2: Turbine oil oxidation stability

JIS K 2514-3 Part 3: Rotating Pressure Vessel Oxidation Stability

Japanese Industrial Standard JIS

Lubricating oil - Determination of oxidation stability - Part

1: Oxidation stability of lubricating oil for internal combustion engines

Lubricating oils-Determination of oxidation stability

Corresponding international standards have not yet been enacted.

editions (including amendments) apply.

JIS B 7410 Glass thermometer for petroleum test

JIS G 3141 Cold-rolled steel plates and strips

JIS H 3100 Copper and copper alloy sheets and strips

JIS K 2251 Crude oil and petroleum products - Sampling methods

JIS K 8252 Ammonium Peroxodisulfate (Reagent)

JIS K 8848 Hexane (Reagent)

JIS K 8951 Sulfuric acid (Reagent)

JIS K 9701 Heptane (Reagent)

JIS R 6251 abrasive cloth

JIS R 6252 abrasive paper

JIS Z 8401 How to round numbers

3 Terms and definitions

Lubricant Oxidation Stability for Internal Combustion Engines

increase in acid number

The reagent shall be as follows.

specified in JIS K 8951 and ammonium peroxodisulfate specified in JIS K 8252.

6 Testers and instruments

The tester and equipment shall be as follows.

An example is shown in Figure 1.

Or use a temperature measuring device.

Lid of test container

Use one that can rotate 15 times. g) Varnish rod

ÿ Rotor ÿ Test ÿ Temperature cock ÿ Electric panel ÿ Thermostat lid

container holder ÿ Insulation controller ÿ Sample stirring heater ÿ

material ÿ rod ÿ Stirrer ÿ Test Constant

Insulation wall container temperature bath ÿ Varnish rod

Figure 2 — Test vessel

Figure 3 — Lid of test vessel

Figure 4 — Sample stir bar

Figure 5 — Varnish bar

thick, 26 mm wide and 60.4 mm long.

Figure 6 - Catalyst with claws and grooves

6.3 Abrasive cloth or abrasive paper

Absorbent cotton of the Japanese Pharmacopoeia should be used.

7 Sampling and preparation methods

Therefore, it is collected and prepared.

The preparation for the test shall be as follows.

Assemble as follows. The assembled catalyst is immediately used for testing.

Do not touch with

a) Oxidation of samples Oxidation of samples shall be as follows.

Figure 7 — Assembly of test vessel and catalyst

the sample stirrer is rotated.

as the degree of lacquer.

Here, R: viscosity ratio

D1: Kinematic viscosity of unoxidized oil at 40°C (mm2/s)

b) increase in acid number

Here, S: Increase in acid number (mg KOH/g)