File:13_65.EES 21/10/2021 12:21:36 p. m.

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er. 9.944: #4402: EASY ENGINEERING, https://www.youtube.com/channel/UCjC8ulmve2QNRJXhDpk-L2A+  CN xJID_JLN yNINGGBDE CJH@NYX _NJF

"Tarea #2 - Segundo Parcial - Plantas Térmicas y Uso Racional de la

Energía"
"Espinoza Rocha José Manuel - 390497"

"13.65 Moran 7th"

"Liquid octane (C8H18) at 25°C, 1 atm, enters an insulated reactor
operating at steady state and burns with 90% of theoretical air at
25°C to form products consisting of CO2, CO, H2O, and N2 only.
Determine the temperature if the exiting products, in K."

"C8H18+x*12.5*(O2 +3.76N2) ---bCO2 +cCO+dH2O+eN2"

x=0.9

"!Balance de los elementos"

"!Balance de Carbono"
8=b+c
"!Balance de Hidrógeno"
18=2*d
"!Balance de Oxígeno"
12.5*x*2=2*b+c+d
"!Balance de Nitrógeno"
12.5*x*3.76=e

"C8H18+11.25*(O2 +3.76N2) ---5.5*CO2 +2.5*CO+9*H2O+42.3*N2"

"Entalpías de Formación"
hf_CO2=Enthalpy(CO2,T=298)
hf_CO=Enthalpy(CO,T=298)
hf_H2O=Enthalpy(H2O,T=298)
hf_N2=Enthalpy(N2,T=298)
hf_O2=Enthalpy(O2,T=298)
hf_C8H18=-249910
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er. 9.944: #4402: EASY ENGINEERING, https://www.youtube.com/channel/UCjC8ulmve2QNRJXhDpk-L2A+  CN xJID_JLN yNINGGBDE CJH@NYX _NJF

"!Balance de Energía específica"

Q_dot_CV-W_dot_CV=SIGMA_Hp-SIGMA_Hr
Q_dot_CV=0
W_dot_CV=0
SIGMA_Hp=b*(hf_CO2+DELTA_hp_CO2) +d*(hf_H2O+
DELTA_hp_H2O) + e*(hf_N2+DELTA_hp_N2)+c*(hf_CO+
DELTA_hp_CO)

SIGMA_Hr=(hf_C8H18+DELTA_hr_C8H18)+x*12.5*(hf_O2+
DELTA_hr_O2)+x*12.5*3.76*(hf_N2+DELTA_hr_N2)

T_ref=298 "°C"
DELTA_hp_CO2=Enthalpy(CO2,T=TFA)-Enthalpy(CO2,T=T_ref)
DELTA_hp_CO=Enthalpy(CO,T=TFA)-Enthalpy(CO,T=T_ref)
DELTA_hp_H2O=Enthalpy(H2O,T=TFA)-Enthalpy(H2O,T=T_ref)
DELTA_hp_N2=Enthalpy(N2,T=TFA)-Enthalpy(N2,T=T_ref)

DELTA_hr_C8H18=0
DELTA_hr_O2=0
DELTA_hr_N2=0

SOLUTION
Unit Settings: SI K kPa kJ molar deg
b = 5.5 c = 2.5 d =9 Dhp,CO = 67105
Dhp,CO2 = 108685 Dhp,H2O = 87954 Dhp,N2 = 66426 Dhr,C8H18 = 0
Dhr,N2 = 0 Dhr,O2 = 0 e = 42.3 hfC8H18 = -249910
hfCO = -110533 hfCO2 = -393492 hfH2O = -241816 hfN2 = -4.36
hfO2 = -4.386 QCV = 0 SHp = -250144 SHr = -250144
TFA = 2283 [K] Tref = 298 W CV = 0 x = 0.9

9 potential unit problems were detected.