File:13_38.EES 21/10/2021 12:24:56 p. m.

Page 1
er. 9.944: #4402: EASY ENGINEERING, https://www.youtube.com/channel/UCjC8ulmve2QNRJXhDpk-L2A+  CN xJID_JLN yNINGGBDE CJH@NYX _NJF

"Tarea #2 - Segundo Parcial - Plantas Térmicas y Uso Racional de la

Energía"
"Espinoza Rocha José Manuel - 390497"

"13.38 Moran 7th"

"A fuel oil with the mass analysis 87% C, 11% H, 1.4% S, 0.6% inert
matter burns with 120% of theoretical air. The hydrogen and sulfur
are completely oxidized, but 95% of the carbon is oxidized to CO2
and the remainder to CO."

"(a) Determine the balanced reaction equation"

m_C=0.87
m_H=0.11
m_S=0.014

n_C=m_C/molarmass(C)
n_H=m_H/molarmass(H)
n_S=m_S/molarmass(S)

"Reacción estequeométrica"
"0.0724*C+0.1091*H+0.00043*S+a(O2+3.76N2) -- bCO2+cH2O+
dSO2+eN2"

{"!Balance de Carbono"
n_C=b
"!Balance de Hidrógeno"
n_H=2*c
"!Balanceo de Sulfur"
n_S=d
"!Balanceo de Oxígeno"
2*a=2*b+c+2*d
"!Balanceo de Nitrógeno"
a*3.76=e}

a=0.1002
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er. 9.944: #4402: EASY ENGINEERING, https://www.youtube.com/channel/UCjC8ulmve2QNRJXhDpk-L2A+  CN xJID_JLN yNINGGBDE CJH@NYX _NJF

b=0.07244
c=0.05457
d=0.0004366
e=0.3766

"Combustión real"
"0.0724*C+0.1091*H+0.00043*S+0.1002*x*(O2+3.76N2) -- 0.07244*(
0.95)*CO2+0.07244*(0.05)*CO+0.05457*H2O+0.0004366*SO2+
0.3766*x*N2+eO2"
x=1.2

n_CO2r=0.07244*(0.95)
n_COr=0.07244*(0.05)
n_N2r=0.3766*x
n_O2r=0.1002*x-(n_CO2r+0.5*n_COr+0.5*c+d)

"0.0724*C+0.1091*H+0.00043*S+0.1002*1.2*(O2+3.76N2) --
0.06878*CO2+0.00362*CO+0.05457*H2O+0.0004366*SO2+0.45156*
N2+0.021820*O2"

"(b) For the CO and SO2, determine the amount, in kmol per 10E6
kmol of combustion products"
n_p=n_CO2r+n_COr+c+n_N2r+n_O2r
ppmCO=(n_COr/n_p)*1E6
ppmSO2=(d/n_p)*1E6

SOLUTION
Unit Settings: SI C kPa kJ mass deg
a = 0.1002 b = 0.07244 c = 0.05457 [kmol/kg]
d = 0.0004366 [kmol/kg] e = 0.3766 mC = 0.87
mH = 0.11 mS = 0.014 nC = 0.07244 [kmol/kg]
nCO2r = 0.06882 [kmol/kg] nCOr = 0.003622 [kmol/kg] nH = 0.1091 [kmol/kg]
nN2r = 0.4519 [kmol/kg] nO2r = 0.02189 [kmol/kg] np = 0.6008 [kmol/kg]
nS = 0.0004366 [kmol/kg] ppmCO = 6028 ppmSO2 = 726.7
x = 1.2

2 potential unit problems were detected.

EES suggested units (shown in purple) for d n_p .