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Lakshya JEE (2024)

Chemical Kinetics DPP-07

1. The influence of temperature on the rate of reaction 7. The velocity of a reaction is doubled for every 10°C
is determined by rise in temperature. If the temperature is raised to
(1) Nernst’s equation 50°C, the reaction velocity increases by about
(2) Gibbs-Helmholtz equation (1) 12 times (2) 16 times
(3) Arrhenius equation (3) 32 times (4) 50 times
(4) Van’t Hoff equation
1
2. The temperature coefficient of a reaction is: 8. If we plot a graph between log k and by
T
(1) Ratio of rate constants at two temp. differing by Arrhenius equation, the slope is
1°C (1) –Ea/ R (2) + Ea/ R
(2) Ratio of rate constants at temp. 35°C and 25°C.
Ea Ea
(3) Ratio of rate constants at temp. 30°C and 25°C (3)  (4) 
2.303R 2.303R
(4) Specific reaction rate at 25°

9. The rate constant of a reaction does not depend upon

3. In general, with every 10°C rise in temperature, the
(1) Temperature
rate of reaction becomes approximately ______
(2) Activation energy
(1) Ten times (2) Double
(3) Catalyst
(3) Half (4) One tenth
(4) Concentration of reactants and products
4. The temperature coefficient of most of the reactions 10. For a reaction, activation energy Ea = 0 and the
lies between rate constant at 200 K is 1.6 × 106 s-1.
(1) 2 and 3 (2) 1 and 2 The rate constant at 400 K will be
(3) 2 and 4 (4) 3 and 4 [Given that gas constant
R = 8.314J K-1 mol-1]
5. According to Arrhenius equation, rate constant of a (1) 3.2 × 104 s-1 (2) 1.6 × 106 s-1
chemical reaction is equal to (3) 1.6 × 103 s-1 (4) 3.2 × 106 s-1
(1) Ae–Ea/RT (2) AeEa/RT
(3) AeRT/Ea (4) Ae–RT/Ea 11. The rate constants k1 and k2 for two different
reactions are 1016  e–2000/T and 1015  e–1000/T,
6. The correct expression for Arrhenius equation respectively. The temperature at which k1 = k2 is
containing effect of temperature on the rate constant 1000
is (T2 > T1) (1) 2000 K (2) K
2.303
k Ea  T1T2 
(1) log10 2    (3) 1000 K (4)
2000
K
k1 2.030R  T2  T1  2.303
k2 R  T1  T2  12. The activation energies of the forward and
(2) log10    backward reactions in the case of a chemical
k1 2.030Ea  T1T2 
reaction are 30.5 and 45.4 kJ/mol respectively.
k 2 Ea  T2  T1 
(3) log10    The reaction is
k1 R  T1T2  (1) Exothermic
k2 Ea  T2  T1  (2) Endothermic
(4) log10    (3) Neither exothermic nor endothermic
k1 2.303R  T2T1 
(4) Independent of temperature
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13. In a zero-order reaction, for every 10ºC rise of

temperature, the rate is doubled. If the temperature
is increased from 10ºC to 100ºC, the rate of the
reaction will become
(1) 256 times (2) 512 times
(3) 64 times (4) 128 times
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (3) 8. (3)
2. (2) 9. (4)
3. (2) 10. (2)
4. (1) 11. (2)
5. (1) 12. (1)
6. (4) 13. (2)
7. (3)

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