Nitrogen family

Fluor
apatite Cag Poy Catz stronglayeron teeth enamel

iTmi

IE d upto sb thenM BP M upto sb then d

IE d upto sb then P
Density A

THEM extra stability

common O S 3 3 5
All elements are polyatomic astate
Except N all show allotropy 1 Groupos 5
Bit is more stable than Bist
Ito rino tho to

FLN smallsize
Anomalous properties
ofN high EN
absence
of d orbitals
N N bond is weaker than P P bond due to interelectronicrepulsion
catenation is weaker

idty
MP
Basicity
PH
Nine

AsHz
pie
Sbu
Ash

NH
big Bit

1395 156.7 185 195 2

BP PH CASH NH C Sblt C Bill
 185.5 210.6 238.5 254.6 290

Bondangle NH PH 7 ASH Sbt

1078 53

Ips sn fy gj m
pure Porbitals
are used

Halides Ex and EX
Oxides ER and E
addie Except Nf all trihalidaON
Na Pas are unstable
Ago 56203 Amphoteric
All trihalides except Bit are
Biao Basic covalent

ff nano not 2120 nad

small amt of NO OH NO

MHyzCy0 5 Nat 4120 t G20

d
Balm Bat 3 2 Pure
d very Na
Nan Nat Nz

NEN
Ny is relatively inert high BE of
non polar
LD is in bonding MO
a

15
Isotopes MN
lit Ng LizN 2 02 2m01s
d 2000K
Mg Na mg n
USE Manufacture of NH3
 Inert atmosphere
big Na is refrigerant

MD formed in soil
by decay ofnitrogenous organic matter
NAJI NH t 2110 NHyzC0 I 2mHz t not coz

2NHyU 6101712
2MHz 2h20 t Call
HylzSOyt2Naon
2NH3t2n20tN92S0
arts t S B NH
amm.s
Haber's Process Nat 3112 I 2MHz AH 46 KImol
favored at low T high P
700K 200atm
Iron oxide catalyst t Afo 120 Promoter

odour
colorless
gas with pungent
2fell 3NHy0H Rally21120 s t 3NHyU
Brown Ppt
2ns Out 2NHyon Zn OHL NHyzSOy
white Ppt
t cutfar UNH La a
Ca Napa
Blue deep Blue
ya
colorless

Oxides of Mitogen
 II

nI N NEN É
in 0 in o
IN NI Nally

Orn NYO O
of O
0 KN Naos
6 N

Nab NO 0

4 0
I
Hit stringacid tox agent
Lab
22
Nano 112504 Manso t HMO
4 I No
UNH 502 No HNO
bar 41,0
0120 commerrapep
Incest
 Hmo attacks most metals except Au Pt

36 t 84140 del 36 NO HO t 4420

U KNO cont Cu N0,2 21102 2120

2n IN Zn NO t Nao 20
030 2n N037 t 420
t Moz
HMO

Ia
c f
MIO

coz I
i
g sp agony no gagging
Brown
Poy

my White toxic unstable glows in dark

I Phosphorous Red non toxic stable
Black Most stable 4 B form

Put on PI nanjo
sod hypophosphite whiteP Its RedP

p
Effwhite p
P
P p

RedP
p

PH Carat 120 Gloat PH

I Cazrat na calls t PHz
Nonflammable Removes
when Pure but containsimp of pally a Py impurities
 rotten fishsmell
gas with
Colorless
highly poisonous
explodes on contact with ox agents like HMOs 92 Bra rap
Slightly soluble in water

p Pa
I pay 502 t 5242

Pag
2
pug t 502

Clycoon Plz avocet Hypo

ROH t Pll R I t Hypo
Ron Pus Rel t Poll t ha
0
PU Pll Cl

Pls exists as payt put in solid state

Ips dsp'd
Ag pas Age Pls
240PM
Sn PUT snaut Pay
a
PFL202pm
u
in the presence moisture to nel
Pazhydrolyses of give
it fumes in moisture
PA t 3420 Hypo t 344
 Oxoacidsnd
F
uff oh
H TOH
OH
on

Phosphoric acid
Orthophosphorousacid
43002
07 Good Hypo
H3POy

Redagent
q
0 150 50 cydobimetaphosphoricaci

9 IPOD
Hypo
Pyrophosphoricacid

644107 OF
no
off
pH
to 14 0
f
o
ffo
Polymetaphosphoricacid

HPOz
n

YHPO 34300 t PH

Agno Ks Ag Hmo HzPOy

 e

Group as to
Oxygenfamily
2 6

O S se Te Po

radices T ii
BP M upto Te then d

acidity 120 Has a Hase Hate

thermal Hao
stability Has Hase Hate
All hydrides except 120 are reducing agents and Red PowerM down
the group
M.P BP of11,0 are highest H bonding
 420 Has Hase Kate
Banged
1040 92

I.to

I
d d
Pbo Pbo 02
Ag20 Agt or

no
2120 621ft 02
obtained from air
Industrially y is

Ozonf
Paleblue
302
Figs 203 AH 142UTmol

gas dark blue liq violet blacksolid

conc too ppm headache nausea
ox agent O o to

Pbs Pbsoy 02 released which can be titrated

again
i s o

NO
B for estimation ofOz
No to
depletion
ofOzlayer in upperatmosphere
Germicide
uses disinfectant
Sterilising water
Bleaching oils ivory flour starchele
to prepare Kandy
Sulphur Yellow Rhombic x stableat R T
Monoclinic B
Rhombic S K Monoclinic s
transitiontemp

SHS's
Is s
s Ess if breaks into

Ss crown shape
g
I
Sais paramagnetic like Oz

Imp Rxn
so is formed as byproduct of roasting
res Foz 502
so is colorlessgas with pungentsmell highly soluble in 120
NaOH 502 Naso tha
NaHSO SO

so t 42 50242
SO 02 É SO

Moist so acts as a Red agent felt I n't soya

Mnoy Mnt soy

04
0 Hojo 0
1
0
0
50 OH
12503 112504 Peroxodi
125208 sulphuricau
 Pyrosulphun.ca
o
É
Oleum 12520

cut 2112584 Caso tsk

s t Hason 582
C
ty
112504
coat 502
Downloadnotesfrom canvasdassesnotes
bit.ly

Agenfamily
f Catz fluorspar insoluble fluorides
Nasher
36 Pou
Cryolite

Carz Fluoroapatite

Seawater is mainly Mad soln 2.57 bymass

f Iodides Bromides

F U Br I At

SizeM IE d M.P A density p

Bp p
EA U F Br I
BE 427 Bra Fa Iz
Bond length Fa U2 Bra C Iz
E 92
Fa
f
7 Bra 7 Iz OxPower 2742 Bra Iz
287 1.36 1.09 0.54

Fa can displace G Bi I from their soln

42 Bi s t
Bra I
Oxstate Group ox state 17
Colors
of halogens
Fa Yellow
GreenishYellow it to tag Éoj In
4
f
Bra Red lig onlyshows 2 0.5

L violet solid
 I F to
Properties
of Hx
42 Hat Hoy acidity HF HU CHBV CHI
Bry Is HBr Horr y BMPP HU CH Br CHF
HU CH Br CH
HI
HF
I 02 12

Fs rzcrjjda bhond IE

mingagen
É o
oareenishyellowgaswitnpungent.su
hig
Is soluble in water

Yifitigeniata Ct Mno Mno

Mno

t
Nacl hasty Mraz NAHso Uz

f g
KMIO t na
ka t Mnd Uz my
HCl to I 42 no Deacon's Process

Nall a h Naont Ust ha

dnode

Runoff
pay HastCla nuts
Alta All 92
Nata Nacl Pls ixagent
feta ay Sst Cla Sall It has greataffinity for H
nieces na
A NH t t Nz
92 NHull
excess
unstableoily lig
na.sn
3
46

Mfs
mad t na on
q
the Nacl Maceo

Calor caloll cell

tag e no

Composition Powder Ca 0412.692 610712.2120

of Bleaching
non nuts
yahoo.I.ngnau.tt n wa d
ox bleaching
properties
colored substance 107 colorlesssubstance

Phosgene Collz
Teargas CAMO

Concha concMNO AquaRegia can dissolvenoble

3 1 metals like Au Pt

Au If Audi two
Pt I
14920 Nacht Wat ha
Pty NO

Natecoz I Nall t Coat720

N9250 Nall that 502
 redagent

X Inter
halogen compounds
Hypohalous Hox
all covalent molecules diamagnetic
Halous HXOz UF gas rest all are eitherlis orsole
Halic
4
HX03 M.p B p an higher than expected
Perhalic More reactive than halogens
Hxoy

xx 4s HI Hot
Imagen
I
Bigger
Momen

halogy laser EN
12 342 2243
Chat Fz 2 IF excess
1 I

Il
Brat 32 2 Br f
g serpents auf
Brat Fyn 2 Buts
d

39 am
Noblegenes o
largest atomic radio in the period vow radius

very high LE
low EA
very

All noblegases except Rn occur in atmosphere

Ar is major component
He Ne
monazite
Pint Found in It byvol
thereminerals

Ra rn He

He Me Ar Kr Xe Rn

density T
ffgistvemax.enm.cm
P P
M.P lowB m p I bp bcoz
of weak v DW forces

All noblegates monoatomic

Colorless odorless tasteless

Sparingly soluble in water

He has lowest bp 4.2k known substance
ofany
O2 has Xe have almost identical
1175 1170 Kalmol
IE
EI
Xelg t 219 It Xerz s
Xelg t 2219 LPs Xefy s
1 5
Xelgs t 3518
1 20
Ims Xe f Is

Xefy to Fy Xe f
 Kef 9 Xe t Hf to
Xefy I Xe t Xel t HF 02
Xero
Gh t HF
XeO

hyd.sn
Xero t 120 P
eofytH XeFot2110
XeoE t HF

Very Pfs XeF PET

Xefy Sbf
xef Sbf