Date:- 9/2/23

Report

In this day we learn about some special codes & symbols and it’s meaning.

CAS no.: Chemical Abstracts Service

 It is a Numerical designation for chemicals series.
 It can be up to 10-Digit and 3 hyphenated part.

GHS:- Globally Harmonised System

 It is established in 2003by UN (United Nation)
 It includes criteria for the heat, physical and environmental hazard.

GHS classification NFPA

CAT 1 :- Severe Hazard 4
CAT 2 :- Serious Hazard 3
CAT 3 :- Moderate Hazard 2
CAT 4 :- Slight Hazard 1
CAT 5 :- Minimal Hazard 0

NFPA:-
It’s is a National Fire Protection Association

Pressure unit (hPa): Hectopascal

1hPa = 0.1kPa

CERCLA:-
Comprehensive Environmental Response, Compensation and Liability Act.

HMIS:-
Health Management Information System

EC no.
The European Community no. is a unique 7 Digit Identifier that was assigned to
substances for regulatory purpose
OECD:-
Organisation for economic co-operation and development
 It is established by 36 members of countries

TRANSPORTATION CLASS
 There are 9 types of class with its sub parts.

1) Explosive Substance & Articles

2) Gases
Flammable gas
Non-Flammable gas
Toxic gas
3) Flammable liquid
4) Solid
Flammable solid
Liable to spontaneous combustion
5) Agents
Oxidising agent
Organic peroxide
6) Toxic substances
Toxic
Infectious substances
7) Radioactive material
8) Corrosive
9) Miscellaneous

RCRA:- Resource conservation and Recovery Act

 This is created for public law that is for proper management of
hazardous and non hazardous solid waste.

EU:- European Union

 It is a community of 27 members

OSHRC:-
The Occupational Safety & Health Review Commission is established in 1970,
by Washington DC.
Date:- 10/2/23

 Fire Extinguisher:-
-DCP ( Dry Chemical Powder)
In this extinguisher has mono ammonium phosphate as solvent to
prevent fire.

Packing Group:-
- A packing group mama a grouping according to the degree of
danger presented by hazardous material.
Packing group I :- Great Danger
Packing group II :- Medium Danger
Packing group III :- Minor Danger

EPA :-
Environmental Protection Agency
- It is founded in December 2,1970.

EPCRA :-
Emergency Planning and Community Right-to-know Act
- Established in 1986

IARC:-
International Agency for Research on Cancer
- Group 1:- Carcinogenic to Human
- Group 2:- Probably Carcinogenic to Human
- Group 3:- Possibly Carcinogenic to Human

NTP:- National Toxicity Program

What is Chemical Pneumonitis ?

- It is an inflammation of the lung caused by aspiration or
inhaling irritation.
- There are generally two types of pneumonitis
1) Acute Toxicity
 2) Chronic Toxicity

1) Acute Toxicity:-
It occurs when the toxin is administered to an organism in a
single potent does.
- Sudden onset, Quickly changing, Relatively short reaction time
are the features of this kind

2) Chronic Toxicity:-
It occurs when the toxin is administered in small does over a
period of time.
- Gradual onset, Slowly changing and harming the organism,
Damage is caused bit by bit over time are the features of this

There is also one kind of toxicity existed, Aspiration Toxicity.

- Aspiration Toxicity is posed by aspiration including various
severe acute effects such as chemical pneumonia, pulmonary
injury or death.

CLP:- Classification, Labelling and Packaging

- The CLP regulation is based the United Nations GHS and it’s
purpose is to ensure a high level of protection of health and
environment as well as the free movement of substances,
mixtures and articles.

IBC :- International Bulk Chemical code

- It provide an International standard for the safe carriage in bulk
by sea of dangerous chemicals and noxious liquid substances.

Date:- 11/02/23

Date:- 13/02/23
Styrene: It’s storage temperature maintained under 13-14C.
There is 2 tank of styrene with capacity of 60KL.
CHILLER :-
- Capacity: 52 TR
- Temperature: 9-10c

Bather Valve:- 200 mmWC

CAPACITY OF TANK’s:-

1) Styrene -> 60Kl + 60KL (T-730) A&B

2) Butyl Acrylate-> 200KL (T-704)
3) Mehta Methacrylate -> 120 KL (T-702)
4) Ethyl Acrylate -> 100KL (T-703)
5) Acrylonitrile -> 18KL (T-701)
6) Methacrylic Acid -> 30 KL (T-705)
7) Acrylic Acid -> 30 KL (T-706)
8) 50% aq. Acrylamide -> 50KL (T-711)

PUMP:-
There is all tank has same power and capacity pump provided.
- RPM-2850
- Discharge-5 m3/hr
FLOW DIAGRAM OF BUTYL ACRYLATE
Date:-14/2/23

 Tanker Unloading
- When Tanker is came with required material then check the all
things will noticeably
- Then check the all material before unloading in the pressure of
safety in charge
- Check flame arrest or is provided at the exuast of the tanker
- If all notes are completed before the unloading then go for the
QC sample check
- After QC approval chiller water unit is running for the
temperature control of tank loading
- Once the tanker is in the unloading area remove the ignition
key from the socket
- Place wheel chokes to prevent accidental movement of the
tanker
- If the tanker temperature is more then 25c contact shift in
charge/plant manager
- Connect the earthing cable tong to the tanker, the indicator
light on the earthing device change from red to green
- Ensure chilled water inlet and outlet valves are open in the heat
exchanger
- We are the required PPE’s for the unloading of the tanker
- Wear safety harness while running the top lid of the tanker
- Now open the top lids by wearing the safety harness
- Connect the unloading flexible hose to the tanker liquid
discharge port
- Now open the suction valve of the unloading pump
- Slowly open the bottom wall of the tanker and fill the suction
line of the pump
- Start the pump check the pressure slowly open the discharge
valve through heat exchanger and check for level rise in the
tank from DCS
- When unloading will completed pump will stop automatically
by activation of dry run protection level switch now close
dischargeable and bottom valve
- Note down the final level north temperature of the tank from
DCS. calculate and not down material transferred checklist
- Close manual valve of tanker and close the lids of the tanker
- Unclamped the earthing cable tongs and remove the wheel
choke
- And remove the tank for the clearance for the tanker final
weight.

 Inhibitors
- Hydroquinone mono- methyl ether
- EBC For Styrene
- Topanol for Mehta Methacrylate
Diagram of Acrylo Nitrile
Date:- 15/2/23

TR – Ton of Refrigeration
1 TR = 3.5269 KW

CoP of Pump is,

Co-efficient of Pump

 Types of Chiller:-
HVAC (Heating, Ventilation and Air Condition)
1. Air cooler
2. Centrifugal
3. Hybrid
4. Magnetic Bearing
5. Heat Recovery

 Types of Heat Transmitter:-

1) Capacitance level transmitter
2) Hydrostatic level transmitter
3) Magnetic level transmitter
4) Radar field level transmitter
5) Ultrasonic level transmitter
6) Guided microwave level transmitter
7) Liquid level transmitter

Capacitance LT:-
- It is used liquid stored in a tank or container as a dielectric
medium between 2 or more electrodes. The energy capacity of
the capacitor circuit in increases when there is more and
decreases if there is less liquid
- By measuring the variations in the capacitance value.
capacitance level transmitters can calculate the current field
level of the tank or container
Hybrid LT:-
- It is also known as personal level transmitter.
- This transmitters help in determining fluid contents of a
container by measuring the pressure of resting body of the fluid
within it.
- The greater than the force of liquid the greater than the
volume of fluid

Magnetic LT:-
- This transmitters use a magnetic object, which is suspended in
a baoyent float
- This is usually in a narrow auxiliary column, to restrict later on
movements of the float.
- While the float is on top of the liquid, the moment of the float
is measured by a different magnetic device.
- This allows a Precise and stable fill level to be transmitted
- This method is suitable for continuous measurement owning to
do tendency of the float to rise or sink based on the liquid level

Radar fill LT:-

- This transmitters work on the principle of a radar by using radio
wave emissions
- This transmitters are normally mounted at the top of tank filled
with liquid
- Transmitters sends a radar signals into the liquid, and receives a
reflection of the signal. The transmitters then analyse the
current field level of the tank based on the time taken by the
transmitted signal in return.

Ultrasonic LT:-
- An ultraviolet level transmitter is mounted or near the top of a
container containing liquid
- Transmitter sends out in ultrasonic pulse.
- The Ultrasonic pulse hits that surface of the liquid and gates
reflected.
 - The sensors then calculates the fill level based on the time
between the transmitted or received signal.

Guided Microwave LT:-

- This transmitters work by sending a microwave poles through a
sensor cable or rod.
- The signal hits the surface of the liquid and travels back to the
sensor and then to the transmitter housing
- The electronics integrated in the transmitter housing determine
the feeling level based on the time taken by the signal to travel
down the censor and back up again
- This type of level transmitters are used in industrial applications
in all areas of process technology.

Liquid LT:-
- Those are engineered for detecting level of liquids.
- Liquid level transmitters are also used for detecting interface
between 2 different liquids such as oil and water.
- Liquid level transmitters are mainly used for liquid level sensing
in storage tanks, transport tanks as well as water storage tanks.
- These pressure transmitters measure the level by measuring
the head pressure of liquid.

Date:- 16/2/23

Diagram of Styrene Storage

  PESO:-
Petroleum & Explosives Safety Organisation

PESO CLASSIFICATION:-
There are types of class available as class A, class B & class C.
Class A:- Petroleum having a flash point below 23c.
- Ex. Petrol, Hex-an,Methanol, M.E.K., Benzene, pentane, SBP
solvent, etc.

Class B:- Petroleum having flash point 23c and above but below 65c.
 - Ex. Diesel, Kerosene, MTO (mineral turpentine oil), Aeromax,
etc.

Class C:- Petroleum having flash point 65c and above but below 93c.
- Ex. LDO (Light Diesel Oil), Furnace oil.

 PESO condition

1.Total transparency and accountability in the system

2.Online availability of records, application status & statistics to
the public through public domain.
3.Conceptualization of G2C(Government to Citizen)e-governance
module through its public domain website.
4.Speedy disposals of proposals, grant & renewal of licenses, etc.
5.Centralized maintenance of data on
approval/license/suspension/ cancellation/accident
investigations. 
6.Optimum Utilisation of existing Man power.
7.Digitization of all the records/licenses.
8.Efficient Office Administration
9.Automated receipts and maintenance of Revenue.
10.Scrutiny of monthly returns – reliable monitoring of transaction
of Explosives across the Country.
11.A highly communicative and user-friendly website as a public
interface.
12.Website in adherence to Right to Information Act.
13.Internet and e-mail services to Officials of PESO.
14.Computerization of all 25 Offices of PESO including
Departmental Testing Station
15.The entire work force of PESO becomes computer savvy.
16.Modern work environment.
17.Current Developments.

 Products involved in PESO:

Explosives, petroleum, compressed gases, pressure vessels, gas
cylinders, cross-country pipelines, LNG, CNG, Auto LPG, CBG,
Ammonium Nitrate, flame proof electrical fittings, etc.

Date:- 21/2/23

 Types of permits:
- Height permit (1.8m)
- Hot permit
- Confined permit
- General work permit
- Exivasion permit (1.5m)
- Tanker unloading permit
- Hazardous waste permit

 RM dispensing:-
- In here batch RM was contain as per required weight balance
per different batch

 Empty Drums shifting to ETP

- After use of material some batches are directly used by
washing of hot water and some drums are like non company
drums are washing through to ETP.

 Hazardous waste shifting to ETP

- Here some materials that have no use after using it.
- That unused materials like hand gloves, product lums, etc are
collected in huge bag and after it specific weight gain it moves
into the ETP for treatment

 Dustbin waste segregation & shifting to ETP

- Here huge bag contains Lumms of product, meshes, ropes,
cotton
 - And also there are some several types of dustbin available for
some small amount waste generated during the period.
- Green bin:- PPE’s, hand gloves, etc
- Red bin:- papers, small cottons, burnable waste
- Yellow bin:- metal waste(steel wire), metal container,
buckets ,etc

 FG stock:-
- Packaging product and RM are separated in batch as per batch
no., Net weight, Gross weight, and also code of the product
- Here some final product is also RM of the some different
product

 Types of hazardous waste

- Used cotton waste
- Burnable waste
- Plastic waste
- Polymer waste
- Used meshes
- PPE’s
- Waste drums

Date:- 22/2/23

 Ammonia charging
- One car boy weight of container = 50kg
- Use to increase pH & viscosity of the product

 Self cleaning filter

- Piston operated type cleaning filter
- Filter area = 3925 cm
- Filtration rating = 125(micron) 120 mesh no
- Filter element = welded wedge wire
- Wiper ring surface cleaning filter
 - Pressure = 10 bar
- Temperature = 60c
- MOC = SS-316

 Centrifugal pump
- Discharge = 15m3/hr
- Total Head = 30m
- Power = 1.927 kW
- Speed = 2870 RPM

 Digital bottom XV
- 0(zero) -> it’s Off
- 1(one) -> it’s On

 Types of jacket for reaction

i. Plain jacket
ii. Half pipe coil jacket (improve high velocity & turbulence)
iii. Dimple jacket

 Set-points :-
- PRV =
- Rupture Disk = 5.7 kg/cm2

Date:- 23/2/23
Draw overall process block diagram

Date:-24/2/23

Explore some new area

And also learn about how to use NanoBrook Particle size, it’s
viscosity check in QC department AKA sample test.
Date:- 27/2/23

 Derivative NMA
- Derivative NMA is a N-Methaylaniline
- It is used for the bonding of monomers and it also increase the
viscosity of product

 Charging :-

PIDISYN 400

BMSL

Date:- 28/2/23
- Today I take sample from BL 301B to production Quality LAB

 In production quality lab:

I learn to use of pH meter (for PIDISOL 400)

- pH range = 2-4
- And my taste result was 4

Learn to use of viscosity meter (nanoBrook)

- Dip the spindle in sample as marked line on it
- There are some spindles are used product wise

PRODUCT NAME SPINDLE NO RPM

BMSL 2 20
6080 3 20
326 N 5 20
126 M 4 20
FGNG 7 20
128 M 2 20
7400 2/3 20
5401 1/3 20
1380 3 20
HEERA 7 20
P-76 2 20
E-MUL 2 20
FF-103 HS 1 20
848 2 20
CB 481 3 20
9462-C 2 20
827 4 20
PIDISYN 500 2 20
PIDISYN 400 2 20

- To find viscosity with spindle

 Viscosity = Speed of viscosity meter * Reading of viscosity
meter divided by 100

Solidity Test:
- Heating sample material
- By weight range of 1-1.1 gm
- At 105c for 90 min
- My reading is 44.03% solidity

DATE:- 1/3/23
same as yesterday

DATE:- 2/3/23
- Batch 1380’s RM shifted vessel wise Ground floor to 2nd floor
- Charged all vessel v-102, v-146,v-105, v-109, v-107 & v-108

DATE:- 3/3/23
 - Charged new product PIDICRYL 3616 with very carefully and
safely
- Seen repairing of CAN filter because material is leaking from it.
- Re-adjustment of Ball type NRV of scrubber’s pump A.

 Transferring of material one tanker to another tanker

DATE:-4/3/23

- See the changing of strainer of T-711.

- Removing lumps from V-101B and operation of Bottom dev
valve.

DATE:-7/3/23
  PACKING OF DRUMS:-
- Before start the packing of drums ensure that a packing stream
line is clear/line up and ready for for packing
- After that, ensure the cleaning filters are cleaned before the
use of it.
- If it contain lumps in it clean it with HOT DM WATER. Also check
the discharge valve or hose pipe is not open without informing
- Filling of drums should be use the proper mesh for removal of
impurities and drums contain it’s accurate weight during
packing of material
- Filling material doesn’t contain more or less in its by net weight

 FILTER CLEANING:-
- If batch is ready for dispatch, before then the starting of
material packing; filters are should be ready with clean wash
period of 1-2 hours of packing was started
- If it contain thick layer of previous batch material then clean it,
because it may cause the chocking lumps in it
- Quickly clean it with HOT DM WATER. After then use it for next
dispatching batch.

DATE:-9/3/23
- New line up of tanker from direct blender to tanker
- Water draining of overall process plant due to leakage and re-
lineup from cooling tower
- Charging RM in V-102 & V-101 by me

DATE:- 10/3/23
- Charging my self v-102 (1380 product) under the guidance of
field operator Mr. Mayur
- Ammonia charging (T-123)
- Urea charged 388kg’s in V-142
- Charged V-105, V-109, V-108.
DATE:- 11/3/23
- Pleasure meeting with Head of Plant Mr. Manish Vyas.
- Learn some new way to observation of work of equipment for
easy to learning
- Charging & packing

DATE:- 13/3/23

 Cement test of sample 7400

- In this test sample of product is mix with a 25 gms of cement
and stirred it
- After complete mixing, check the colour of sample should be in
a light greenish
- After that paste is spread in thin layer of that on cotton for 24
hrs
- After 24 hrs it can be survive without any crack it will ready for
packing

Change V-103
Charging of V-105, V-108, V-109
RM shifting of next batch

DATE:- 14/3/23
- Vessel charging 304
- Vessels charge 305,309,311,302
- Adjustment of proper flow for reactor
Q. Use of 47% Caustic solution?

DATE:- 15/3/23
- Scrubber filter water filling
 - J
- S

DATE:- 16/3/23
- RM charging v-102
- Sample collected from BL-101A & BL-301B

DATE:- 17/3/23
- Manufacturing of BMSL
- Charged V-102,101,146
- After some time adding catalyst in V-305,309 and V-308,346
- Adding defamer in BL-101B

DATE:- 20/3/23
- SOP translated in Gujarati language
- Sample testing
- Information about DCS panel.

DATE:- 21/3/23
- Information on Hot & Cold Well
- In QC; sample testing of 7400D
pH
viscosity
particle size
cement test
solid test

DATE:- 22/3/23
- same as yesterday
DATE:- 23/3/23
- reaction study started
- these is 3 type of process
i. Co-Monomer
ii. Homo-Monomer
iii. Solution Monomer
- In detailed after completed it

DATE:- 24/3/23
- Installing of HP jet cleaner in BL-101 A
- Rotation variation in V-305, so kept it in under observation
- Weight calibration of V-302
- V-104 Pump dismantle because pump couldn’t get suction
while charging

DATE:- 25/3/23
- Handling of Tanker loading

DATE:- 27/3/23
- Continued shift A batch of FGNG by me on DCS
- Sample testing

DATE:- 28/3/23
- Sampling of BL

DATE:- 29/3/23
- Cleaning of R-301 with use of High Pressure Jet Pump.
- Charging of V-102, V-107&108
- TT of R-101 stuck because of lumps
DATE:- 30/3/23
- DCS handling series 1 under guidance
- BL 101B sampling from Bottom

DATE:- 31/3/23
- DCS controlling of series 1 Under guidance
- Taking manually temperature of R-301
- V-108 chaser charging
- Sample of BL 101B

DATE:- 1/4/23
- Sample tests
- Charging of Chaser’s

DATE:- 3/4/23
- Operating jet pump
- Line up of BMSL vessel to tanker

DATE:- 4/4/23
- Learning DCS
- Charging

Date:- 7/4/23
- Changing of PG in nitrogen circulation line
- Re feeding of sample of MMA in tanker because it has some
previous hold up material found it in
- And see the High Pressure Gun working to clean the surface of
are of filters
Date:- 8/4/23
- Handling of overall reaction of 126M on DCS and take samples
of it

Date:- 10/4/23
- Tested bunch of samples

Date:- 11/4/23
- Continued A-shift FGNG production on DCS
- START new batch of 6080 production on DCS, I make its V-102,
V-103
- Continued 6080’s , V-123, V-111, V-146.

Date:- 12/4/23
- Samples
- Dcs
- Audit in plant

Date:- 13/4/23
- Learn how to creat new batch in portal

Date:- 14/3/23
- Calibration of vessel’s of series 2
- Vessel transfer of V-111 & V-146 to BD

Date:- 17/4/23 – 19/4/23

- In college, due to preparation and coordinating in our college’s
“National Tech-Fest event ( Techzians )”.
Date:- 20/4/23 – 22/4/23
- Take on leave due to family purpose

Date:- 24/4/23
- Handling reaction of BMSL
- Take samples
- Charging of V-111,142

Date:- 25/4/23
- Nothing to do

Date:- 26/4/23
- Charging
- Caustic analysis of 500’s before chaser material to gain 9 pH
At the ratio of 1:5 and 1:10 solutions

Date:- 27/4/23
- Samples & charging
- RM shifting

Date:- 28/4/23
- Loose drums of 400 material to me contain in one and more
- Vessel charging of Emul
- Vessel transfer of V-111 & V-146 of Emul on DCS

Date:- 29/4/23
- Again take before chaser sample of 500 for caustic solution
Date:- 1/5/23
- Handling of overall ground floor charge ( due to shortage of
operator)
-> Packing
-> HP jet pump
-> Drum operation