TERM END/ATKT EXAMINATION, DECEMBER – 2019

Program:

Semester -

Subject: Subject Code:

Max. Marks: 70 Max. Time: 2.30 Hrs
Student’s ID No.:
Read this before you look at the
1. Write your ID number in the question paper at the place specified for it
2. Ensure that you have entered all the details on the answer book and
have obtained Invigilator’s signature
3. Do not write / mark anything on the question paper
4. Using question paper for rough work is strictly prohibited
Section – A
(Answer all questions. Each question carries 2 marks.)
Small Answer type (Answer in one/two lines)

1. In how many ways can the letters of the word 'LEADER' be arranged?
2. Calculate the bond order of carbon monoxide (CO) heterogeneous diatomic molecules.
3. What is Pauli’s exclusion principle?
4. Write the decomposition mechanism of nitrogen pentaoxide (N2O5)?
5. What is a Belousov-Zhabotinsky reaction?
Section – B
(Answer any five questions. Each question carries 8 marks.)
Brief Answer type (Answer in 300 to 400 words)
6. Define lattice energy. Calculate lattice energy (U) of the formation of CsCl using following
data:
Cs(s) 80kJmol-1 Cs(g) 375 kJmol-1 Cs+(g)
Cl2(g) 242kJmol-1 2Cl(g)
Cl(g) -398kJmol-1 Cl-(g)
Cs(s) + ½Cl2(g) -625kJmol-1 CsCl(s)

7. Write the short notes of operator?

8. Describe briefly the various postulates of wave mechanics.
9. Verify that the wave function Ψ(x) = xe-ax2 is an eigenfunction of the two operator
d2/dx2-4a2x2. What is the corresponding eigen value?
10. Discuss the unimolecular reaction of Landemann theory.
11. Explain the Michaelis-Menten Mechanism for Enzyme Catalysis.
12. Solve the following differential:
d d d d x
dx √
(i) 4 x (ii) (x4 + 4x) (iii) (log x-7) (iv) (e – 3x2)
dx dx dx

MATS University, Examination Dept. Press, TERM END/ATKT Examination, DECEMBER. - 2019 Page 1 of 2
 13. (a) Calculate the maxima and minima of the function f (x) = x3 – 9x2 + 24x – 18.
(b) Solve the following integration:
100
1
(i) ʃ 3x dx 2
(ii)) ∫ dP
10 P

Section – C
(Answer any one question. Question carries 20 marks.)
Long Answer type (Answer in 600 words)
14. Discuss the kinetic of the following reaction:
(i) formation of Hydrogen- bromine
(ii) Decomposition of ethane
15. Discuss the following methods of kinetic fast reaction :
(i) Relaxation Method
(ii) Flow method
(iii) Nuclear magnetic resonance method
(iv) Flash photolysis

MATS University, Examination Dept. Press, TERM END/ATKT Examination, DECEMBER. - 2019 Page 2 of 2