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Glasfarbe 1 KG GL 58 - GB - en - 6 - Rep263093
Glasfarbe 1 KG GL 58 - GB - en - 6 - Rep263093
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Safety data sheet in accordance with regulation (EC) No 1907/2006
Signal word
Danger
Hazard statements ***
H226 Flammable liquid and vapour.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H361d Suspected of damaging the unborn child.
H412 Harmful to aquatic life with long lasting effects.
H315 Causes skin irritation.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.
Hazardous component(s) to be indicated on label (Regulation (EC) No. 1272/2008)
contains 4,4'-Isopropylidenediphenol, oligomeric reaction products with
1-chloro-2,3-epoxypropane;Butyl glycolate;Cyclohexanone
2.3. Other hazards
No special hazards have to be mentioned.
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Safety data sheet in accordance with regulation (EC) No 1907/2006
Butyl glycolate
CAS No. 7397-62-8
EINECS no. 230-991-7
Registration no. 01-2119514685-36
Concentration >= 3 < 10 %
4-Hydroxy-4-methylpentan-2-one
CAS No. 123-42-2
EINECS no. 204-626-7
Registration no. 01-2119473975-21
Concentration >= 1 < 10 %
General information
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconscious place in recovery position and seek medical advice.
After inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, administer
artificial respiration.
After skin contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use recognised skin
cleanser. Do NOT use solvents or thinners.
After eye contact
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10
minutes and seek immediate medical advice.
After ingestion
If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain
immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Until now no symptoms known so far.
4.3. Indication of any immediate medical attention and special treatment needed
Hints for the physician / treatment
Treat symptomatically
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Safety data sheet in accordance with regulation (EC) No 1907/2006
Information regarding Safe handling, see Section 7. Information regarding personal protective measures,
see Section 8. Information regarding waste disposal, see Section 13.
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Safety data sheet in accordance with regulation (EC) No 1907/2006
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Safety data sheet in accordance with regulation (EC) No 1907/2006
Butyl glycolate
Type of value Derived No Effect Level (DNEL)
Reference group Worker
Duration of exposure Long term
Route of exposure dermal
Mode of action Systemic effects
Concentration 34,7 mg/kg
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Safety data sheet in accordance with regulation (EC) No 1907/2006
Cyclohexanone
Type of value Derived No Effect Level (DNEL)
Reference group Worker
Duration of exposure Long term
Route of exposure inhalative
Mode of action Systemic effects
Concentration 100 mg/m³
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Safety data sheet in accordance with regulation (EC) No 1907/2006
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Safety data sheet in accordance with regulation (EC) No 1907/2006
Butyl glycolate
Type of value PNEC
Type Freshwater
Concentration 0,05 mg/l
Cyclohexanone
Type of value PNEC
Type Freshwater
Concentration 0,0329 mg/l
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Safety data sheet in accordance with regulation (EC) No 1907/2006
particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use appropriate, certified
respirators. Full mask, filter A
Hand protection
There is no one glove material or combination of materials that will give unlimited resistance to any
individual or combination of chemicals.
For prolonged or repeated handling nitrile rubber gloves with textile undergloves are required.
Material thickness > 0,5 mm
Breakthrough time < 30 min
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use, storage, maintenance and
replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/ chemical damage and poor
maintenance.
Barrier creams may help to protect the exposed areas of the skin, they should however not be applied
once exposure has occurred.
Eye protection
Use safety eyewear designed to protect against splash of liquids.
Body protection
Cotton or cotton/synthetic overalls or coveralls are normally suitable.
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Safety data sheet in accordance with regulation (EC) No 1907/2006
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UN 1263
14.2. UN proper shipping name
PAINT
14.3. Transport hazard class(es)
Class 3
14.4. Packing group
Packing group III
Remarks Transport according to 2.3.2.5 of the IMDG Code
14.5. Environmental hazards
no
Air transport ICAO/IATA
14.1. UN number
UN 1263
14.2. UN proper shipping name
PAINT
14.3. Transport hazard class(es)
Class 3
14.4. Packing group
Packing group III
14.5. Environmental hazards
-
Information for all modes of transport
14.6. Special precautions for user
Transport within the user's premises:
Always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Other information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
no
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