PRE – PSPSM SK025

SET 2

NO SCHEME MARK
1
(i) rate = k [C4H6]2 1

(ii) 5.83 x 10-5 = k (0.1)2 1

k = 5.83 x 10-3 M-1 s-1 1

(iii) k = rate
[C4H6]2

= 1.7 x 10-3 M s-1 = 0.17 M-1 s-1 1

(0.1)2 M2

(iv) k1 Ea 1 1 1
ln ( ) = − ( − )
k2 R T1 T2

5.83x10−3 Ea 1 1 1
ln ( )= − ( − )
0.17 8.314 573 K 673 K

Ea = 108.14 kJ mol-1 1

(v)
Potential energy

Ea = 108 kJ mol-1 Label y-

2 C4H6 (g) axis

Shape

∆H = -150 kJ mol-1 Ea & ∆H

C4H6 &
C8H12 (g) C8H12

Reaction progress

TOTAL 10
NO SCHEME MARK
∆Hf = -1220 kJ
2 Ca(s) + F2(g) CaF2(s)

∆Ha = +178 kJ Bond energy = +158 kJ

Ca(g) 2F(g)
8
IE1 = +590 kJ ∆Hlattice = ?
Each eq
1 mark
EA x 2 = -328(2) kJ
Ca+(g) All ∆H
labelled

IE2 = +1150 kJ

Ca2+(g) + 2F-(g)

∆Hf = ∆Ha + bond energy + IE1 + IE2 + EAx2 + ∆Hlattice @

1
-1220 = +178 + 158 + 590 + 1150 + (-382x2) + ∆Hlattice

∆Hlattice = -2640 kJ mol-1 (unit insist)

1

TOTAL 10
NO SCHEME MARK
3 (a)
(i) Sn2+(aq) 1
Cl2(g) 1
Ag+(aq) 1

(ii) Cl2 > Ag+ > Sn2+ 1

(b)
(i) Anode: Pb(s) → Pb2+(aq) + 2e- 1
Cathode: 2H+(aq) + 2e- → H2(g) 1

(ii) Pb(s) | Pb2+(aq,1 M) | H+(aq,1.35x10-5 M) | H2(g,1 atm) | Pt(s) 1

TOTAL 7
NO SCHEME MARK

4 Major product:

Mechanism:

TOTAL 5
NO SCHEME MARK
5
(i) Methylbenzene @ Toluene 1

(ii)

(iii) Br2, FeBr3 : Electrophilic aromatic substitution 1

Br2, uv : Free radical substitution 1

TOTAL 7
NO SCHEME MARK

R is formed by the stability of 3° free radical. 1

TOTAL 7
NO SCHEME MARK
7

(i)
3

(ii)

TOTAL 6

MAX 5
NO SCHEME MARK

8
1

Another Grignard reagent and carbonyl compound:

TOTAL 7
NO SCHEME MARK
9
(a)

(b) Heptane < 1-hexanol < Pentanoic acid 1

• Heptane only has Van der Waals forces (London dispersion) so it

1
cannot form hydrogen bonding with water. It is insoluble in water.

• 1-hexanol can form hydrogen bonding with water but it has large
1
alkyl group which is large hydrophobic area. It is partially soluble in

water.

• Pentanoic acid can form more hydrogen bonding with water at its
1
alkyl group (hydrophobic area) is smaller compared to 1-hexanol.

Pentanoic acid is soluble in water.

TOTAL 9
NO SCHEME MARK
10
(a)

• Z is primary aliphatic amine. It has an alkyl group (cyclohexyl) as

1
electron donating group which increases the electron density on nitrogen
atom. So, nitrogen is more available to accept H+.
• X and Y are aromatic amine. They are less basic than Z because the lone 1
pair on nitrogen is delocalised into benzene ring causing nitrogen is less
available to accept H+.
• While X is less basic than Y because it has NO2 as electron withdrawing
1
group which decreases the electron density on nitrogen. So, nitrogen is
less available to accept H+.

(b)

1
Equation

2
Two
Observations

TOTAL 7
NO SCHEME MARK

11 In acidic medium:

In basic medium:

Ala-Ser:

Ser-Ala:

TOTAL 4
NO SCHEME MARK

12 Polymer:

Reagent initiator: H2O2 @ CH3OOCH3 1

TOTAL 2